CN1611523A - 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 - Google Patents
环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 Download PDFInfo
- Publication number
- CN1611523A CN1611523A CN 200310108370 CN200310108370A CN1611523A CN 1611523 A CN1611523 A CN 1611523A CN 200310108370 CN200310108370 CN 200310108370 CN 200310108370 A CN200310108370 A CN 200310108370A CN 1611523 A CN1611523 A CN 1611523A
- Authority
- CN
- China
- Prior art keywords
- alcohol
- epoxy alkane
- catalyst
- organic zinc
- monohydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001335 aliphatic alkanes Chemical class 0.000 title claims abstract description 59
- 239000004593 Epoxy Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims description 57
- 239000002685 polymerization catalyst Substances 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 claims abstract description 62
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 56
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 54
- 239000011701 zinc Substances 0.000 claims abstract description 54
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000002904 solvent Substances 0.000 claims abstract description 30
- 238000009835 boiling Methods 0.000 claims abstract description 19
- 239000000725 suspension Substances 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 6
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 3
- -1 cycloalkyl zinc Chemical compound 0.000 claims description 37
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 33
- 238000002360 preparation method Methods 0.000 claims description 27
- 230000000379 polymerizing effect Effects 0.000 claims description 26
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 238000010926 purge Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 15
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 2
- 235000013824 polyphenols Nutrition 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 34
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 25
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 238000001035 drying Methods 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical group CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 10
- DWYXCLJOOFXYGU-UHFFFAOYSA-N C(C)CC1=CC=CC=C1.[Zn] Chemical compound C(C)CC1=CC=CC=C1.[Zn] DWYXCLJOOFXYGU-UHFFFAOYSA-N 0.000 description 9
- 229920004890 Triton X-100 Polymers 0.000 description 7
- 239000013504 Triton X-100 Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Catalysts (AREA)
- Polyethers (AREA)
Abstract
Description
Claims (16)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101083709A CN1329423C (zh) | 2003-10-31 | 2003-10-31 | 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101083709A CN1329423C (zh) | 2003-10-31 | 2003-10-31 | 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1611523A true CN1611523A (zh) | 2005-05-04 |
CN1329423C CN1329423C (zh) | 2007-08-01 |
Family
ID=34758576
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003101083709A Expired - Lifetime CN1329423C (zh) | 2003-10-31 | 2003-10-31 | 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1329423C (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103562265A (zh) * | 2011-06-03 | 2014-02-05 | 住友精化株式会社 | 聚环氧烷粒子及其制造方法 |
CN103562266A (zh) * | 2011-06-03 | 2014-02-05 | 住友精化株式会社 | 聚环氧烷粒子及其制造方法 |
CN105722889A (zh) * | 2013-11-22 | 2016-06-29 | 陶氏环球技术有限责任公司 | 用于环氧化物单体聚合的锌催化剂/添加剂系统 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4917440B1 (zh) * | 1970-09-08 | 1974-04-30 | ||
CN1015621B (zh) * | 1989-12-25 | 1992-02-26 | 浙江大学 | 制备窄分子量分布聚氧烯烃的方法 |
JP3073054B2 (ja) * | 1991-07-11 | 2000-08-07 | 住友精化株式会社 | アルキレンオキシド重合体の製造方法 |
US6800583B2 (en) * | 1999-06-02 | 2004-10-05 | Basf Aktiengesellschaft | Suspension of multimetal cyanide compounds, their preparation and their use |
JP2002105195A (ja) * | 2000-09-28 | 2002-04-10 | Nippon Shokubai Co Ltd | アルキレンオキシド重合用触媒の製造方法 |
JP2002265592A (ja) * | 2001-03-07 | 2002-09-18 | Sumitomo Seika Chem Co Ltd | アルキレンオキシド重合体の製造方法 |
-
2003
- 2003-10-31 CN CNB2003101083709A patent/CN1329423C/zh not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103562265A (zh) * | 2011-06-03 | 2014-02-05 | 住友精化株式会社 | 聚环氧烷粒子及其制造方法 |
CN103562266A (zh) * | 2011-06-03 | 2014-02-05 | 住友精化株式会社 | 聚环氧烷粒子及其制造方法 |
CN103562266B (zh) * | 2011-06-03 | 2016-01-20 | 住友精化株式会社 | 聚环氧烷粒子及其制造方法 |
US9416226B2 (en) | 2011-06-03 | 2016-08-16 | Sumitomo Seika Chemicals Co., Ltd. | Polyalkylene oxide particles and production method for the same |
US9447237B2 (en) | 2011-06-03 | 2016-09-20 | Sumitomo Seika Chemicals Co., Ltd. | Polyalkylene oxide particles and production method for the same |
TWI563012B (zh) * | 2011-06-03 | 2016-12-21 | Sumitomo Seika Chemicals | |
CN105722889A (zh) * | 2013-11-22 | 2016-06-29 | 陶氏环球技术有限责任公司 | 用于环氧化物单体聚合的锌催化剂/添加剂系统 |
CN105722889B (zh) * | 2013-11-22 | 2016-12-07 | 陶氏环球技术有限责任公司 | 用于环氧化物单体聚合的锌催化剂/添加剂系统 |
Also Published As
Publication number | Publication date |
---|---|
CN1329423C (zh) | 2007-08-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1524103A (zh) | 环氧烷烃聚合物的制造方法 | |
CN1479755A (zh) | 从苯乙烯和二环戊二烯单体制造的热聚合共聚物 | |
CN1248983A (zh) | 硅烷封端的迈克尔加聚聚合物 | |
CN1240459A (zh) | 聚硅烷类的制造方法 | |
CN111560119B (zh) | 一种二甲基二苯基聚硅氧烷的制备方法 | |
CN1342719A (zh) | 稀土催化体系及其催化丁二烯顺式聚合工艺 | |
CN112608480A (zh) | 一种不对称型硅油及其制备方法和应用 | |
CN1091110C (zh) | 含有13族元素的化合物其制备方法与用途 | |
CN1720251A (zh) | 低聚硅倍半氧烷及其制造方法和用途 | |
CN106957433B (zh) | 可光/热双重交联的超支化聚碳硅烷苯并环丁烯树脂及其制备方法 | |
CN1611523A (zh) | 环氧烷烃聚合催化剂和不同分子量聚环氧烷烃的制备方法 | |
CN1295271C (zh) | 一种聚氯乙烯用稀土钙锌稳定剂及其制备方法 | |
CN1260267C (zh) | 具有不饱和端基的高支化聚酯的生产方法 | |
US7491783B2 (en) | Process for highly purified polyhedral oligomeric silsesquioxane monomers | |
CN1944481A (zh) | 制备粉末涂料用丙烯酸树脂的方法 | |
CN1042920A (zh) | 二环戊二烯与降冰片烯衍生物的共聚反应及其所得共聚物 | |
CN1169840C (zh) | 球形催化剂载体MgCl2-醇-有机络合剂复合物的制备方法 | |
CN1073967A (zh) | 以苄基甲苯和苄基二甲苯为主要成分的组合物及其作为电介质的应用 | |
EP1373357A1 (en) | Method for preparing biodegradable polyester and itself prepared thereby | |
CN1130394C (zh) | 间规聚苯乙烯制备的催化剂 | |
CN1880361A (zh) | 有机聚硅烷的制备方法 | |
CN1228390C (zh) | 阻燃性硅橡胶组合物 | |
CN116096785A (zh) | 烷基功能化的聚硅氧烷的制备方法 | |
US6235859B1 (en) | Production process for polyvinyl ether and catalyst used for the process | |
CN1208354C (zh) | 茂金属钛化合物及其用途 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI CHEMICAL RESEARCH INST; APPLICANT Free format text: FORMER OWNER: SHANGHAI CHEMICAL RESEARCH INST Effective date: 20070330 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20070330 Address after: 200062 Shanghai Yunling Road No. 345 Applicant after: SHANGHAI Research Institute OF CHEMICAL INDUSTRY Co-applicant after: SHANGHAI LIANSHENG CHEMICAL Co.,Ltd. Address before: 200062 Shanghai Yunling Road No. 345 Applicant before: Shanghai Research Institute of Chemical Industry |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20070801 |