CN1586269A - Use of titanium pole support montmorillonid in fodder additive - Google Patents
Use of titanium pole support montmorillonid in fodder additive Download PDFInfo
- Publication number
- CN1586269A CN1586269A CNA2004100533089A CN200410053308A CN1586269A CN 1586269 A CN1586269 A CN 1586269A CN A2004100533089 A CNA2004100533089 A CN A2004100533089A CN 200410053308 A CN200410053308 A CN 200410053308A CN 1586269 A CN1586269 A CN 1586269A
- Authority
- CN
- China
- Prior art keywords
- feed
- montmorillonite
- titanium
- titanium pole
- titanium pillared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000010936 titanium Substances 0.000 title claims abstract description 36
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 36
- 239000000654 additive Substances 0.000 title 1
- 230000000996 additive effect Effects 0.000 title 1
- 241001465754 Metazoa Species 0.000 claims abstract description 18
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 8
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 6
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 5
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 5
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 45
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 45
- 239000000126 substance Substances 0.000 claims description 13
- 231100000614 poison Toxicity 0.000 claims description 10
- 230000007096 poisonous effect Effects 0.000 claims description 10
- 238000001179 sorption measurement Methods 0.000 claims description 9
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 244000000010 microbial pathogen Species 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229930195730 Aflatoxin Natural products 0.000 claims description 2
- 239000005409 aflatoxin Substances 0.000 claims description 2
- 244000144972 livestock Species 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 5
- 230000003000 nontoxic effect Effects 0.000 abstract description 5
- 241000228197 Aspergillus flavus Species 0.000 abstract description 3
- 239000003674 animal food additive Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 241000272496 Galliformes Species 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 230000001717 pathogenic effect Effects 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 206010012735 Diarrhoea Diseases 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 238000001727 in vivo Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 231100000957 no side effect Toxicity 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 231100000611 venom Toxicity 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910018516 Al—O Inorganic materials 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 241000282898 Sus scrofa Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 238000007233 catalytic pyrolysis Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003937 drug carrier Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000000273 veterinary drug Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Fodder In General (AREA)
- Feed For Specific Animals (AREA)
Abstract
The present invention discloses the application of titanium pole supported montmorillonoid in fodder industry. Titanium pole supported montmorillonoid is used as feed additive added into the feed for fowls, livestock and aquatic animal polluted by toxic and harmful matters. Titanium pole supported montmorillonoid with excellent surface activity and great specific surface area can adsorb Pb, Cd, Hg and other heavy metals as well as As, F, organic phosphorus, aspergillus flavus and pathogenic microbe in animal body, and titanium pole supported montmorillonoid is non-toxic and smell-less, is not absorbed by animal and may be drained safely. The present invention is safe and effective green feed additive.
Description
Technical field
The present invention relates to the application of the clay mineral with layer structure of titaniferous, be specifically related to the application of a kind of titanium pillared montmorillonite in feed industry.
Background technology
Titanium pillared montmorillonite claims titanium crosslink montmorillonite or titaniferous montmorillonite porous material again, it is a kind of interchangeability of utilizing montmorillonite mineral interlayer ion or molecule, by methods such as ion-exchanges titanium base nuclear polycation is introduced its interlamination region, the molecular level mesh composite that obtains after roasting.Titanium pillared montmorillonite is big owing to interplanar distance, the surface-active height, and the big and Heat stability is good of specific area has obtained extensive studies and application in petrochemical industry and environmental protection field as selected adsorbent, catalyst and catalyst carrier etc.Titanium pillared montmorillonite can be used for the catalytic pyrolysis of oil, also can be used as the selective reduction catalyst of some pernicious gas such as the oxynitrides (NOx) in the selectivity catalysis atmosphere, some chemical substance is had good selection adsorptivity, in the processing of debirs, heavy metal and nuke rubbish, have very big application potential.The pillared illiteracy of titanium is taken off yet there are no and is used for animal husbandry production, particularly in the feed addictive but up to now.
Titanium pillared montmorillonite is by montmorillonite and titanium oxide (TiO
2) form.Montmorillonite is 2: 1 type layer structures, and promptly the silicon-oxy tetrahedron of two-dimensional arrangements and alumina octahedral are formed by stacking by 2: 1 types, and its main component is SiO
2, Al
2O
3And Fe
2O
3, secondly the Si-O tetrahedron and the Al-O octahedron of formation montmorillonite crystal are interlayer exchangeable cations MgO, CaO, K
2O, Na
2O.Montmorillonite is nontoxic, is not absorbed by body, has water imbibition, suspension, dispersiveness, caking property and thixotropy, thereby can be used as medicine and pharmaceutical carrier, particularly can be used for the treatment of diarrhoea and and other enterogastric diseases.Known montmorillonite is used for the prevention and the treatment (CN1326746A) of diarrhea of livestock and birds and other enterogastric diseases as veterinary drug and feed addictive composition; Nano montmorillonite adds the heavy-metal residual (CN1371619A) that feed addictive that sodium chloride, shitosan makes is used to reduce livestock and poultry, aquatic products.More than there is no the report of titanium pillared montmorillonite as feed addictive.
Because the interplanar distance of montmorillonite, surface-active all not as titanium pillared montmorillonite, are added large usage quantity with poisonous and harmful substance in the montmorillonite adsorption feed, absorption affinity is lower.As the adsorbance to arsenic in the animal body, under the equal conditions, the adsorbance of titanium pillared montmorillonite is 20 times of montmorillonite.For safer, green food is provided to the mankind, safety and sanitation to the food chain front end should give bigger concern, therefore, seek and provide adsorption capacity stronger, safer adsorbent, poisonous and harmful substance in the feed is removed, and is main purpose of the present invention.
TiO
2Be inorganic constituents, nontoxic, tasteless, no carcinogenesis does not absorb in animal body, can be used as indicator in the animal digestion metabolic test.Therefore to be used for animal be nontoxic, harmless to titanium pillared montmorillonite, and noresidue in vivo has no side effect, and is safe.
In China, montmorillonite aboundresources, process technology maturation.Has the report of closing, about 1.5 ten thousand yuan/ton of the price of titanium pillared montmorillonite.And the production of titanium pillared montmorillonite can not exert an influence to environment.
The invention scheme
The open scheme of the present invention is:
Titanium pillared montmorillonite is as the application of poisonous and harmful substance in the feed addictive adsorption feed.
Application process is: titanium pillared montmorillonite dry powder makes an addition to by in the feed of wherein one or more pollutions of arsenic, fluorine, heavy metal, organophosphor, mould, aflatoxins and pathogenic microorganism, mix directly feeding animals of back thoroughly, by weight percentage, described titanium pillared montmorillonite dry powder accounts for the 0.01-0.5% of described feed.
Heavy metal in the feed of described pollution mainly is meant: lead, cadmium and mercury.
Because titanium pillared montmorillonite is bigger than the interlamellar spacing of the montmorillonite of common not titaniferous post, specific area is big, absorption property is strong, can effectively adsorb above-mentioned poisonous and harmful substance in vivo, and directly excretes with ight soil.So eliminated the harm of above-mentioned venomous injurant confrontation animal greatly, reduced virulent material residual in aquatic animal, to produce the aquatic animal that meets international and domestic sanitary standard.This titaniferous montmorillonite also has the promotion growth of animal simultaneously, improves feed efficiency, the effect of control diarrhoea and other enterogastric diseases.
At external mimic biology concrete conditions in the establishment of a specific crime, with titanium pillared montmorillonite and montmorillonite arsenic, lead, cadmium, mercury, fluorine, aspergillus flavus, organophosphor etc. have been carried out adsorption experiment respectively.The result shows that titanium pillared montmorillonite all has good suction-operated to above-mentioned substance, and adsorption rate reaches 95%, 95%, 95%, 95%, 90%, 85%, 85% respectively.And montmorillonite has only 20-50% to the adsorption rate of above-mentioned substance.Further, titanium pillared montmorillonite is made an addition to by in the feed of wherein one or more pollutions of arsenic, heavy metal lead, cadmium, mercury etc., fluorine, aspergillus flavus, organophosphor and pathogenic microorganism, to livestock and poultry (pig, chicken, duck etc.) and aquatic livestock (fish, shrimp, shellfish etc.), adding proportion is 0.01-0.5%, find that titanium pillared montmorillonite can effectively adsorb above-mentioned poisonous and harmful substance in vivo, and directly excrete with ight soil.Eliminate the harm of above-mentioned venomous injurant confrontation animal, reduce their residual in aquatic animal, titanium pillared montmorillonite also has the promotion growth of animal simultaneously, improves feed efficiency, the effect of control diarrhoea and other enterogastric diseases.
Because it is nontoxic, harmless that montmorillonite and titanium are, noresidue in vivo, the material that has no side effect, so titanium pillared montmorillonite is a kind of safe green feed additive.Residual and poisonous and harmful substance exceeds standard and happens occasionally and today that the international trade barrier is stern day by day at present feed Chinese traditional medicine, presses for the feed addictive of the safety that can reduce feed and aquatic animal medicament residue and poisonous and harmful substance.Therefore use titanium pillared montmorillonite will have broad application prospects as poisonous and harmful substance in the feed addictive adsorption feed.
Claims (3)
1, titanium pillared montmorillonite is as the application of poisonous and harmful substance in the feed addictive adsorption feed.
2, according to of the application of the described titanium pillared montmorillonite of claim 1 as poisonous and harmful substance in the feed addictive adsorption feed, it is characterized in that application process is: titanium pillared montmorillonite dry powder makes an addition to by in the feed of wherein one or more pollutions of arsenic, fluorine, heavy metal, organophosphor, mould, aflatoxins and pathogenic microorganism, mix directly feeding animals of back thoroughly, by weight percentage, described titanium pillared montmorillonite dry powder accounts for the 0.01-0.5% of described feed.
3, application process according to claim 2 is characterized in that: the heavy metal in the feed of described pollution mainly is meant: lead, cadmium and mercury.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100533089A CN1273034C (en) | 2004-07-22 | 2004-07-22 | Use of titanium pole support montmorillonid in fodder additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100533089A CN1273034C (en) | 2004-07-22 | 2004-07-22 | Use of titanium pole support montmorillonid in fodder additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1586269A true CN1586269A (en) | 2005-03-02 |
| CN1273034C CN1273034C (en) | 2006-09-06 |
Family
ID=34602815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100533089A Expired - Fee Related CN1273034C (en) | 2004-07-22 | 2004-07-22 | Use of titanium pole support montmorillonid in fodder additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1273034C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104522755A (en) * | 2014-12-29 | 2015-04-22 | 晨光生物科技集团股份有限公司 | Process for removing aflatoxin in cottonseeds |
| CN105124249A (en) * | 2015-08-31 | 2015-12-09 | 蚌埠龙达农业专业合作社 | Aquatic product mixed culturing feed capable of self degradation and preparation method of aquatic product mixed culturing feed |
| CN107318768A (en) * | 2017-07-14 | 2017-11-07 | 合肥合丰牧业有限公司 | A kind of fattening method for reducing mutton smell of mutton |
| CN108404864A (en) * | 2018-04-16 | 2018-08-17 | 贵州大学 | Activated carbon supported titanium pillared montmorillonite composite material |
-
2004
- 2004-07-22 CN CNB2004100533089A patent/CN1273034C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104522755A (en) * | 2014-12-29 | 2015-04-22 | 晨光生物科技集团股份有限公司 | Process for removing aflatoxin in cottonseeds |
| CN104522755B (en) * | 2014-12-29 | 2017-11-17 | 晨光生物科技集团股份有限公司 | The removing process of aflatoxin in a kind of cottonseed |
| CN105124249A (en) * | 2015-08-31 | 2015-12-09 | 蚌埠龙达农业专业合作社 | Aquatic product mixed culturing feed capable of self degradation and preparation method of aquatic product mixed culturing feed |
| CN107318768A (en) * | 2017-07-14 | 2017-11-07 | 合肥合丰牧业有限公司 | A kind of fattening method for reducing mutton smell of mutton |
| CN108404864A (en) * | 2018-04-16 | 2018-08-17 | 贵州大学 | Activated carbon supported titanium pillared montmorillonite composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1273034C (en) | 2006-09-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhejiang Huineng Animal Medicine Co., Ltd. Assignor: Zhejiang University Contract fulfillment period: 2008.10.28 to 2014.9.5 contract change Contract record no.: 2008330001772 Denomination of invention: Use of titanium pole support montmorillonid in fodder additive Granted publication date: 20060906 License type: Exclusive license Record date: 2008.11.7 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.10.28 TO 2014.9.5; CHANGE OF CONTRACT Name of requester: ZHEJIANG PROVINCE HUINENG ANIMAL DRUGS CO., LTD. Effective date: 20081107 |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060906 Termination date: 20130722 |