CN1151718C - Animal and fowl disinfectant using nano material as carrier and preparation method thereof - Google Patents
Animal and fowl disinfectant using nano material as carrier and preparation method thereof Download PDFInfo
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- CN1151718C CN1151718C CNB021110964A CN02111096A CN1151718C CN 1151718 C CN1151718 C CN 1151718C CN B021110964 A CNB021110964 A CN B021110964A CN 02111096 A CN02111096 A CN 02111096A CN 1151718 C CN1151718 C CN 1151718C
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- copper
- montmorillonite
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- 239000000645 desinfectant Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000002086 nanomaterial Substances 0.000 title abstract description 5
- 241001465754 Metazoa Species 0.000 title abstract 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 37
- 244000144972 livestock Species 0.000 claims abstract description 34
- 239000010949 copper Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 238000005342 ion exchange Methods 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 244000144977 poultry Species 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 15
- 239000000725 suspension Substances 0.000 claims description 15
- 230000032683 aging Effects 0.000 claims description 14
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 14
- 239000011707 mineral Substances 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 6
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical group [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 150000002505 iron Chemical class 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000009395 breeding Methods 0.000 abstract description 2
- 230000001488 breeding effect Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 241000272496 Galliformes Species 0.000 abstract 1
- 150000001879 copper Chemical class 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 235000013601 eggs Nutrition 0.000 abstract 1
- 230000012447 hatching Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 238000000703 high-speed centrifugation Methods 0.000 description 8
- 239000006228 supernatant Substances 0.000 description 8
- 238000000746 purification Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 244000000010 microbial pathogen Species 0.000 description 4
- 208000035473 Communicable disease Diseases 0.000 description 3
- 238000009360 aquaculture Methods 0.000 description 3
- 244000144974 aquaculture Species 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- -1 timber Substances 0.000 description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229960005486 vaccine Drugs 0.000 description 2
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000589875 Campylobacter jejuni Species 0.000 description 1
- 241000711573 Coronaviridae Species 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 241000702670 Rotavirus Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000011169 microbiological contamination Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses an animal and fowl disinfectant using a nano material as a carrier and a preparation method thereof. The animal and fowl disinfectant is prepared by carrying out the adsorption and the ion exchange reaction on a copper salt, a molysite solution and nano montmorillonite. By weight percentage, the content of the copper element and the iron element is from 1.5% to 6.5% in the montmorillonite, wherein the weight ratio of the copper element to the iron element is 1: 0.25 to 0.50. The disinfectant can be used for sterilizing animal and fowl houses, utensils, animals and fowls and hatching eggs and has the advantages of wide sterilization range, lasting action efficiency, drug resistance prevention, low production cost, high safety, etc. Moreover, the disinfectant has the deodorization function of environment and can efficiently enhance the economic benefit of livestock breeding.
Description
Technical field
The present invention relates to a kind of is the livestock and poultry disinfectant and preparation method thereof of carrier with the nano montmorillonite.
Background technology
Under the feeding and management condition of modern livestock breeding intensification, maximization, automation, mechanization, the deterioration of the ecological environment, the microbiological contamination of its feeding are serious, easily cause the fulminant infectious disease, caused enormous economic loss, have a strong impact on the development of aquaculture to aquaculture.Vaccine injection is mainly adopted in the prevention of these infectious diseases, but because of there is individual difference in limited, the efficient not high and livestock and poultry of the kind of vaccine, still has a large amount of livestock and poultry to catch, and causes immuning failure; There are problems such as the range of application of medicine is limited to, easily developed immunity to drugs, livestock and poultry medicament residue in these treatment of diseases.Therefore, use disinfectant to kill various pathogenic microorganisms in the environment, guarantee the livestock birds health growth the communicable disease perfect method.
Mostly common disinfectant is organic class disinfectant, as epoxide (oxirane, expoxy propane etc.), aldehydes (formaldehyde, glutaraldehyde etc.), alcohols with and corresponding derivative.Because they exist volatile, easy decomposition, poor stability, action time is short and may decompose many shortcomings such as producing harmful substance.
Safe, advantages such as antibacterial range is wide, the term of validity is long, anti-pesticide resistance that inorganic antiseptic has, its Application and Development has obtained the attention of countries in the world in recent years, the antimicrobial treatment that is widely used in products such as household electrical appliance, leather, coating, timber, plastics, film, pottery, paper, cosmetics, cultural goods and toy, but the present sterilization field that is not used for the livestock and poultry environment as yet.
Montmorillonite is a kind of lamellar aluminosilicate, and its unit cell is made up of two-layer silicon-oxy tetrahedron therebetween layer of aluminum oxygen octahedra, connects by shared oxygen atom between the two; Specific surface area 260～700m
2/ g, montmorillonite wafer thickness＜60nm, particle diameter is at 0.1～10 μ m, the high-purity montmorillonite of content 90～98%, it can be according to method of purification of the prior art, to being that raw material is handled and obtained with montmorillonite mineral, the bentonite that contains montmorillonite or other mineral that contain montmorillonite.Method of purification of the prior art can referring to, for example, Rong Kuiyi, Long Xiaoqing: " montmorillonite wet purification modified method and principle ", " mineral products protection with utilize ", 1996, (3): 14-16; Wang Zemin, Zhou Fengqi: " The Purification of Swelled-ground and application study ", " nonmetallic ore ", 1999,22 (3): 19-20; Wu Dongyin, Wei Min, " bentonite wet purification research ", " nonmetallic ore ", 2000,23 (3): 23-24; Wu Dongyin, Wei Min, " The Purification of Swelled-ground and Application and Development ", " mineral products protection and utilization ", 2000, (3): the method for putting down in writing in the documents such as 14-16.
In China part mining area, the higher nano montmorillonite of purity has formed millions of tonnes large ore deposit.Because its surperficial special physicochemical character, have very strong absorption, ion-exchange capacity, to various viruses, as rotavirus, coronavirus, epidemic diarrhea virus, TGE and various pathogen, as Escherichia coli, comma bacillus, campylobacter jejuni, staphylococcus aureus etc. good adsorption capacity being arranged, also is the ideal carrier of inorganic antiseptic.
Summary of the invention
The purpose of this invention is to provide a kind of is the livestock and poultry disinfectant and preparation method thereof of carrier with the nano montmorillonite.
The livestock and poultry disinfectant that with the nano montmorillonite is carrier be adopt mantoquita, iron salt solutions and nano montmorillonite through adsorb, ion-exchange reactions is prepared from, by weight percentage, copper, the ferro element content in montmorillonite is 1.5～6.5%, and wherein the weight ratio of copper, ferro element is 1: 0.25～0.50.
The livestock and poultry disinfectant preparation method who with the nano material is carrier is as follows:
1) will separate the montmorillonite mineral of purifying, and add the NaCl that is equivalent to mineral weight about 5%～15%, high-speed stirred is made the suspension ore pulp of concentration 10%～20%, aging 10～15 hours, washes 4～7 times;
2) add copper chloride or copper nitrate or copper sulphate and 2%～10% iron chloride or ferric nitrate or the iron sulfate that is equivalent to mineral weight 4%～20%, water is made the ore pulp of concentration 5%～10% again, regulating pH value of slurry with diluted sodium hydroxide solution is 4.5～6.5, aging 10～15 hours, wash 4～5 times;
3) after filtration or the centrifugal dehydration, filter residue is used the airslide disintegrating mill dry pulverization process being lower than 80 ℃ of oven dry down, or; Step 2) the gained slurry is spray-dried to water content＜10%.
Disinfectant of the present invention is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this disinfectant to livestock and poultry house, utensil, kind egg and livestock and poultry.
The present invention implants the montmorillonite mineral lattice to the iron ion of antibiotic property copper ion and high electricity price by absorption, ion-exchange reactions, makes copper-loaded, iron ion montmorillonite.On the one hand, utilize iron, copper ion hydration radius is little, electricity price is high, be inserted into mineral lattice, make the cationic nano material that becomes with high positive charge, improve the ability of its absorption pathogenic microorganism to improve the mineral surfaces electromotive force; On the other hand, utilize slowly-releasing, the controlled release effect of huge surface area of nano material and clay mineral, improve the activity of metal ion, and it is more lasting that its effect is renderd a service; Thereby make the mineral after the modification have the ability of stronger absorption pathogenic microorganism, and have the effect of killing various pathogenic microorganisms concurrently by the stripping of metal ion.Therefore, the present invention's disinfectant, with metal ion electrically, premium properties such as the absorption of anti-microbial property and nano montmorillonite, ion exchange organically combine, have advantages such as fungicidal spectrum is wide, effect is renderd a service lastingly, prevent pesticide resistance, production cost is low, safe in utilization, and have the function of environment deodorizing concurrently, can improve the economic benefit of aquaculture effectively.
Embodiment
The present invention is further described in conjunction with following example.
Embodiment 1
1) montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing the 100g purifying montmorillonite, add water 900ml, high-speed stirred is made suspension; Add 15gNaCl, aging 15 hours.
2) high speed centrifugation is abandoned supernatant.Water cleans 7 times, adds water 1900ml again, stirs, and makes suspension again.
3) add CuSO
45H
2O 20g and Fe (NO
3)
310g fully stirs, and with diluted sodium hydroxide solution pH value of slurry is adjusted to 6.5, aging 15 hours.
4) high speed centrifugation is abandoned supernatant liquor.Water cleans 4 times.
5) add water 400ml, fully stir, make material become unit for uniform suspension, be no more than atomized drying under 150 ℃ the condition at EAT, obtain water content less than 10% ultrafine powder.
6) above-mentioned ultrafine powder is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this ultrafine powder to livestock and poultry house, utensil, kind egg and livestock and poultry.
Embodiment 2
1) nano montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing the 100g purifying montmorillonite, add water 400ml, high-speed stirred is made suspension; Add 5gNaCl, aging 10 hours.
2) high speed centrifugation is abandoned supernatant.Water cleans 4 times, adds water 900ml again, stirs, and makes suspension again.
3) add Cu (NO
3)
24g and Fe (Cl)
32g fully stirs, and with diluted sodium hydroxide solution pH value of slurry is adjusted to 4.5, aging 10 hours.
4) filtering means dehydration is washed 5 times.
5) filter residue is used the airslide disintegrating mill dry pulverization process being lower than 80 ℃ of oven dry down.
6) above-mentioned ultrafine powder is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this ultrafine powder to livestock and poultry house, utensil, kind egg and livestock and poultry.
Embodiment 3
1) montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing the 100g purifying montmorillonite, add water 500ml, high-speed stirred is made suspension; Add 10gNaCl, aging 12 hours.
2) high speed centrifugation is abandoned supernatant.Water cleans 5 times, adds water 1500ml again, stirs, and makes suspension again.
3) add CuCl
210g and Fe
2(SO
4)
38g fully stirs, and with diluted sodium hydroxide solution pH value of slurry is adjusted to 5.0, aging 15 hours.
4) high speed centrifugation is abandoned supernatant liquor.Water cleans 4 times.
5) add water 300ml, fully stir, make material become unit for uniform suspension, be no more than atomized drying under 150 ℃ the condition at EAT, obtain water content less than 10% ultrafine powder.
6) above-mentioned ultrafine powder is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this ultrafine powder to livestock and poultry house, utensil, kind egg and livestock and poultry.
Embodiment 4
1) montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing the 100g purifying montmorillonite, add water 800ml, high-speed stirred is made suspension; Add 15g NaCl, aging 15 hours.
2) high speed centrifugation is abandoned supernatant.Water cleans 7 times, adds water 1800ml again, stirs, and makes suspension again.
3) add CuSO
45H
2O 15g and Fe
2(SO
4)
35g fully stirs, and with diluted sodium hydroxide solution pH value of slurry is adjusted to 6.0, aging 15 hours.
4) high speed centrifugation is abandoned supernatant liquor.Water cleans 4 times.
5) add water 400ml, fully stir, make material become unit for uniform suspension, be no more than atomized drying under 150 ℃ the condition at EAT, obtain water content less than 10% ultrafine powder.
6) above-mentioned ultrafine powder is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this ultrafine powder to livestock and poultry house, utensil, kind egg and livestock and poultry.
Embodiment 5
1) montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing the 100g purifying montmorillonite, add water 600ml, high-speed stirred is made suspension; Add 6g NaCl, aging 10 hours.
2) high speed centrifugation is abandoned supernatant.Water cleans 5 times, adds water 1000ml again, stirs, and makes suspension again.
3) add CuCl
215g and FeCl
35g fully stirs, and with diluted sodium hydroxide solution pH value of slurry is adjusted to 5.0, aging 12 hours.
4) centrifugal dehydration is washed 4 times.
5) filter residue is used the airslide disintegrating mill dry pulverization process being lower than 80 ℃ of oven dry down.
6) above-mentioned ultrafine powder is used for the using method of livestock and poultry environment disinfected for spray 0.05%～0.1% water slurry of this ultrafine powder to livestock and poultry house, utensil, kind egg and livestock and poultry.
Claims (4)
1. one kind is the livestock and poultry disinfectant of carrier with the nano montmorillonite, it is characterized in that it is to adopt mantoquita, iron salt solutions and nano montmorillonite to be prepared from through absorption, ion-exchange reactions, by weight percentage, copper, the ferro element content in montmorillonite is 1.5～6.5%, and wherein the weight ratio of copper, ferro element is 1: 0.25～0.50.
2. according to claim 1 a kind of be the livestock and poultry disinfectant of carrier with the nano montmorillonite, it is characterized in that said mantoquita is copper chloride, copper nitrate, copper sulphate.
3. according to claim 1 a kind of be the livestock and poultry disinfectant of carrier with the nano montmorillonite, it is characterized in that said molysite is iron chloride, ferric nitrate, iron sulfate.
4. one kind is the preparation method of the livestock and poultry disinfectant of carrier with the nano montmorillonite, it is characterized in that its step is as follows:
1) will separate the montmorillonite mineral of purifying, and add the NaCl that is equivalent to mineral weight 5%～15%, high-speed stirred is made the suspension ore pulp of concentration 10%～20%, aging 10～15 hours, washes 4～7 times;
2) add copper chloride or copper nitrate or copper sulphate and 2%～10% iron chloride or ferric nitrate or the iron sulfate that is equivalent to mineral weight 4%～20%, water is made the ore pulp of concentration 5%～10% again, regulating pH value of slurry with diluted sodium hydroxide solution is 4.5～6.5, aging 10～15 hours, wash 4～5 times;
3) after filtration or the centrifugal dehydration, filter residue is used the airslide disintegrating mill dry pulverization process being lower than 80 ℃ of oven dry down, or; Step 2) the gained slurry is spray-dried to water content＜10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021110964A CN1151718C (en) | 2002-03-18 | 2002-03-18 | Animal and fowl disinfectant using nano material as carrier and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021110964A CN1151718C (en) | 2002-03-18 | 2002-03-18 | Animal and fowl disinfectant using nano material as carrier and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1371602A CN1371602A (en) | 2002-10-02 |
| CN1151718C true CN1151718C (en) | 2004-06-02 |
Family
ID=4741392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021110964A Expired - Fee Related CN1151718C (en) | 2002-03-18 | 2002-03-18 | Animal and fowl disinfectant using nano material as carrier and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1151718C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100381055C (en) * | 2006-04-07 | 2008-04-16 | 浙江大学 | Preparation method and purpose of zinc-carried silicate antimicrobial agent |
| CN102948427B (en) * | 2011-08-17 | 2014-09-24 | 天津中敖生物科技有限公司 | Sterilizing composition for breeding feeding barn and its preparation method |
| CN103548874B (en) * | 2013-10-25 | 2015-05-20 | 龙口市海盛农牧有限公司 | Environment cleaning agent for cultivation |
| CN105454314A (en) * | 2015-10-29 | 2016-04-06 | 瑞普（天津）生物药业有限公司 | Hatching egg cleaning disinfectant and preparation method thereof |
| CN113198040A (en) * | 2021-03-31 | 2021-08-03 | 北京农业信息技术研究中心 | Control method of livestock and poultry house disinfection robot, electronic equipment and storage medium |
-
2002
- 2002-03-18 CN CNB021110964A patent/CN1151718C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1371602A (en) | 2002-10-02 |
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