CN1358441A - Copper-carried montmorillonite solid and liquid disinfectant and preparation process - Google Patents
Copper-carried montmorillonite solid and liquid disinfectant and preparation process Download PDFInfo
- Publication number
- CN1358441A CN1358441A CN 01145558 CN01145558A CN1358441A CN 1358441 A CN1358441 A CN 1358441A CN 01145558 CN01145558 CN 01145558 CN 01145558 A CN01145558 A CN 01145558A CN 1358441 A CN1358441 A CN 1358441A
- Authority
- CN
- China
- Prior art keywords
- copper
- montmorillonite
- preparation
- water
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052901 montmorillonite Inorganic materials 0.000 title claims abstract description 48
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 11
- 239000007787 solid Substances 0.000 title abstract description 4
- 239000000645 desinfectant Substances 0.000 title 1
- 239000010949 copper Substances 0.000 claims abstract description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052802 copper Inorganic materials 0.000 claims abstract description 36
- 239000000725 suspension Substances 0.000 claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000005342 ion exchange Methods 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 9
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001431 copper ion Inorganic materials 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 22
- 239000003899 bactericide agent Substances 0.000 claims description 15
- 239000002270 dispersing agent Substances 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- 159000000000 sodium salts Chemical class 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- 235000002639 sodium chloride Nutrition 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 238000001694 spray drying Methods 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 230000003760 hair shine Effects 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 230000000855 fungicidal effect Effects 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002734 clay mineral Substances 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- 230000002070 germicidal effect Effects 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 239000007943 implant Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 description 10
- 238000005119 centrifugation Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000012531 culture fluid Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 208000035473 Communicable disease Diseases 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 241000385540 bacterium 10 Species 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 235000015598 salt intake Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a copper-carried montmorillonite solid or suspension liquid germicide and its preparation method. It is characterized by that it is a montmorillonite containing exchangeable copper ion, and the copper element content being in the montmorillonite is 0.5-6.5 wt%, and its preparation method includes the following steps: utilizing the ion exchange capacity of clay mineral to implant the Cu(2+) with bactericidal and fungicidal power into sodium base montmorillonite lattice to obtain copper-carried montmorillonite contaiing active copper ions, drying-grinding or spraying-drying to obtain solid powder or making it into suspension liquid preparation. The invented germicide possesses xtensive application fields and its production process is simple and cost is low.
Description
Technical field
It is solid-state with suspension liquid bactericide and preparation method thereof to the present invention relates to a kind of copper-loaded montmorillonite.
Background technology
Copper-based fungicide, fungicide are used widely in fields such as agricultural, aquacultures.Compare with organic synthesis bactericide, fungicide, the inorganic compound of copper has advantages such as safe, that antibacterial range is wide, the term of validity is long, as copper sulphate, Kocide SD etc.But on using, directly use copper-containing compound need expend a large amount of copper, be unfavorable for reducing production costs, in addition, excessive copper can be residual in soil, causes environmental pollution.The copper-loaded montmorillonite that the present invention relates to utilizes the slowly releasing effect of clay mineral, and the remaining electric charge of copper-loaded back mineral surfaces, has improved the biologically active of copper ion greatly, is the important improvement to existing copper-based fungicide, fungicide.Compare with traditional copper compound type antibacterial agent, it only contains a little copper element, and antibiotic effect obviously strengthens, and less to the negative effect of environment.
Summary of the invention
It is solid-state with suspension liquid bactericide and preparation method thereof to the purpose of this invention is to provide a kind of copper-loaded montmorillonite.
Bactericide is a kind of montmorillonite that contains commutative copper ion, and by weight percentage, the content of copper in montmorillonite is 0.5~6.5%.
Preparation method's step is as follows:
1) adopts na-montmorillonite; Perhaps, make na-montmorillonite through following steps through separating calcium base, the magnesium base montmorillonite of purifying:
A) montmorillonite adds water and stirs together with the sodium salt that is equivalent to the about 5-15% of ore weight, makes the suspension ore pulp of concentration about 10%;
B) under 40~100 ℃ of temperature, the ion-exchange reactions time is no less than six hours, during stir frequently;
C) behind the centrifugal or filtering means dehydration, water cleans 1-2 time;
2) add the mantoquita that copper content is equivalent to ore weight 2-10%, or its water-containing crystal salt, add the ore pulp that water is made concentration about 10% again, stir the back under 40~100 ℃ of temperature, the ion-exchange reactions time is no less than six hours, during stir frequently;
3) behind the centrifugal or filtering means dehydration, clean 1-2 time, and dehydration again;
4) the step 3) gains are cool naturally shines dryly, or dries being lower than under 80 ℃ of temperature, selects for use suitable equipment to be ground to less than 300 orders, obtains water content less than 10% powder, stand-by;
Perhaps: the step 3) gains add maximum 5% dispersant, add water and stir, and make the ore pulp of 10-30%, select for use suitable spray drying device to carry out drying, and the spray dryer EAT should be controlled at 150~180 ℃ of scopes; The discharging opening temperature is no more than 70 ℃, obtains water content less than 10% powder, and is stand-by;
Perhaps: step (3) gains add maximum 5% dispersant, add water and stir, and make the suspension of debita spissitudo again, and are stand-by.
Said sodium salt is sodium chloride, sodium nitrate, sodium sulphate.Mantoquita is copper sulphate, copper chloride, copper nitrate.Dispersant is a sodium tripolyphosphate, tetrasodium pyrophosphate, one or more in the sodium lignosulfonate.
Advantage of the present invention is:
1) utilize the cation exchange capacity (CEC) of natural montmorillonite to carry copper ion, production cost is low;
2) copper content is low in bactericide, the fungicide, has reduced the environment residual quantity;
3) slow-release capability of montmorillonite is renderd a service lastingly product sterilization, antifungal;
4) safe in utilization, applied widely.
Embodiment
The raw material that the present invention uses is the natural montmorillonite of purifying through separating, and has another name called bentonite.The purification technique of montmorillonite is well-known, and it comprises that pulverizing, making beating make suspension, classification and collect approximately steps such as particle less than 2 μ.This highly purified montmorillonite is the clay mineral of a kind of light green color, light yellow tool layered crystal structure.Separate purification process and can select conventional mining equiment for use.
Be applicable to that dispersant requirement of the present invention is not very strict.The dispersant of recommending to use is a sodium tripolyphosphate, one or more in tetrasodium pyrophosphate and the sodium lignosulfonate.The purpose that adds dispersant is the viscosity that reduces slurry, makes the atomized drying of high concentration slurry become possibility, thereby reduces energy consumption for drying; In addition, dispersant can increase the stability of suspension, delays its precipitation.
In manufacturing process of the present invention, it is not very strict that the water yield that relevant step is added requires, and under the prerequisite that equipment such as stirring, mixing and atomized drying can run well, should reduce water, to reduce production costs as far as possible.Stirring and mixing can be selected conventional equipment for use, and the time limit of mixing is advisable can form obviously uniform slurry.
Ion-exchange reactions is carried out in two steps, and the first step is used sodium salt solution, makes the Na in the solution
+Ca in the ion exchange montmorillonite mineral lattice
2+, Mg
2+With other interlayer cation, said sodium salt is sodium chloride, sodium nitrate, sodium sulphate.Second step was used copper salt solution, made the Cu in the solution
2+Na in the ion exchange montmorillonite mineral lattice
+With other interlayer cation, said mantoquita is copper sulphate, copper chloride, copper nitrate.The requirement of sodium salt and mantoquita usage amount is not very strict, and generally speaking, the sodium salt consumption is not less than 8% of montmorillonite dry weight, and copper content is not less than 2.5% of montmorillonite dry weight and is advisable in the mantoquita.
Copper-loaded later montmorillonite can be selected the conventional drying method for use, and baking temperature should be above 80 ℃; Also can the natural drying drying at the arid climate environment, again it is ground to granularity and is not more than 300 orders.
The most handy spray drying device of slurry carries out drying, and the spray dryer EAT is controlled at 150~180 ℃ of scopes, and the discharging opening temperature is no more than 70 ℃.Spray dried products is a kind of runny pressed powder.Being used for spray drying device of the present invention is routinely, and technical is well-known.
Preparation of the present invention has two types, and water content is less than<10% pressed powder and contain the suspension of dispersant.Wherein the solid powder preparation copper content is generally between 2~3%.When dilute with water, swelling and mechanical agitation by montmorillonite are easy to form uniform aqueous dispersion.
Embodiment 1: the preparation of granular pattern copper-loaded montmorillonite bactericide, fungicide
1.1 somewhere ca-montmorillonite lump ore separates the back purity of purifying and reaches more than 95%.Take by weighing 100g purification ore, add water 900ml, stir and make suspension.
1.2 add 10g NaCl, the back that stirs (needing 20 minutes approximately) is heated to about 60 ℃, ion-exchange reactions six hours, during stir frequently.
1.3 centrifugation, supernatant liquor inclines.Add water 900ml again, stir, centrifugation, supernatant liquor inclines.Repeat 1-2 time.Again make volume and be one liter suspension.
1.4 add CuSO
45H
2O 9g fully stirs, be heated to about 60 ℃, ion-exchange reactions six hours, during stir frequently.
1.5 centrifugation, supernatant liquor inclines.Add water 900ml again, stir, centrifugation, supernatant liquor inclines.
1.6 add 5 gram sodium tripolyphosphates, add water 300ml, fully stir, make to mix, be no more than atomized drying under 180 ℃ of temperature condition at EAT, obtain water content less than 10% powder, stand-by.
The copper-loaded montmorillonite bactericide, the fungicide copper content that make by above-mentioned steps are 2.6%.
Embodiment 2: the anti-microbial property of copper-loaded montmorillonite
2.1 bacterial classification
Escherichia coli, staphylococcus aureus (providing) by Zhejiang Microbe Inst.
2.2 microorganism culture experiment
The bacterium incubated overnight: bacterium is in overnight incubation under the aerobic situation (about 12 hours), 37 ℃ of temperature, and culture fluid is made suspension with centrifugation washed twice (10,000 change) with distilled water flushing, and bacterial content is 10
4/ ml~10
5/ ml.
Add 0,1,2.5,5,10 and 20 milligram of copper-loaded montmorillonite in 100ml distilled water respectively, vibration makes to mix, and shaken cultivation is 24 hours then, 37 ℃ of cultivation temperature.
Growth analysis: respectively after 0,2,4,6 and 24 hour, in above-mentioned mixed liquor, take out 0.1ml solution, dilute and be finite concentration, dull and stereotypedly cultivated 37 ℃ of temperature 24 hours.Carry out plate count then.Each sample is done three parallel cultivation countings, averages.
2.3 bactericidal effect (see Table 1 and table 2)
Table 1: Escherichia coli count results in the culture fluid (individual/ml)
?0mg | 1mg | 2.5mg | 5mg | 10mg | 20mg | |
?0h | ?9.2×10 4 | 8.35×10 4 | 8.35×10 4 | 8.35×10 4 | 8.35×10 4 | 8.35×10 4 |
?2h | ?9.3×10 4 | 5.2×10 4 | 3.0×10 4 | 1.5×10 4 | 6.4×10 3 | 0 |
?4h | ?8.65×10 4 | 1.6×10 4 | 8.9×10 3 | 70 | 0 | 0 |
?6h | ?8.2×10 4 | 7.3×10 2 | 0 | 0 | 0 | 0 |
?24h | ?8.35×10 4 | 0 | 0 | 0 | 0 | 0 |
Table 2: staphylococcus aureus count results in the culture fluid (individual/ml)
?0mg | 1mg | ?2.5mg | ?5mg | ?10mg | ?20mg | |
?0h | ?1.19×10 5 | 1.19×10 5 | ?1.19×10 5 | ?1.19×10 5 | ?1.19×10 5 | ?1.19×10 5 |
?2h | ?9.8×10 4 | 8.9×10 4 | ?5.2×10 4 | ?9.7×10 3 | ?0 | ?0 |
?4h | ?9.37×10 4 | 1.2×10 4 | ?6.1×10 3 | ?0 | ?0 | ?0 |
?6h | ?7.5×10 4 | 9.5×10 2 | ?0 | ?0 | ?0 | ?0 |
?24h | ?6.35×10 4 | 0 | ?0 | ?0 | ?0 | ?0 |
First behavior of table 1 and table 2 (contains bacterium 10 for each hundred milliliters
4~10
5The weight of individual/copper-loaded montmorillonite of ml) adding in the distilled water, first classifies as and adds the time of cultivating behind the copper-loaded montmorillonite, and all the other be dull and stereotyped cultivation counting statistics result (mean values of three parallel sample).
Experimental result shows that copper-loaded montmorillonite all has the very strong ability of killing for Gram-negative bacteria (Escherichia coli) and gram-positive bacteria (Staphylococcus aureus).When using 20mg copper-loaded montmorillonite (concentration is 200mg/L) in the 100ml water body, can in 2 hours, this two bacterioid be killed fully.
The invention provides a kind of is the bactericide, fungicide and preparation method thereof of active component with the copper-loaded montmorillonite.The raw material sources that this invention relates to are abundant, and preparation method's technological process is simple, and low production cost is easy to promotion and implementation.The bactericide that makes based on the present invention, sterilization and the antimicrobial treatment that fungicide can be widely used in environment, public utility and commodity, the feed addictive of prevention, control animal alimentary canal infectious disease, the antibiotic filler of industries such as plastics, paper, cosmetics, textile, the preparation of antibiotic paint and antibacterial film etc.
Claims (5)
1. the solid-state and suspension liquid bactericide of copper-loaded montmorillonite is characterized in that it is a kind of montmorillonite that contains commutative copper ion, and by weight percentage, the content of copper in montmorillonite is 0.5~6.5%.
2. the solid-state preparation method with the suspension liquid bactericide of a copper-loaded montmorillonite is characterized in that its step is as follows:
1) adopts na-montmorillonite; Perhaps, make na-montmorillonite through following steps through separating calcium base, the magnesium base montmorillonite of purifying:
A) montmorillonite adds water and stirs together with the sodium salt that is equivalent to the about 5-15% of ore weight, makes the suspension ore pulp of concentration about 10%;
B) under 40~100 ℃ of temperature, the ion-exchange reactions time is no less than six hours, during stir frequently;
C) behind the centrifugal or filtering means dehydration, water cleans 1-2 time;
2) add the mantoquita that copper content is equivalent to ore weight 2-10%, or its water-containing crystal salt, add the ore pulp that water is made concentration about 10% again, stir the back under 40~100 ℃ of temperature, the ion-exchange reactions time is no less than six hours, during stir frequently;
3) behind the centrifugal or filtering means dehydration, clean 1-2 time, and dehydration again;
4) the step 3) gains are cool naturally shines dryly, or dries being lower than under 80 ℃ of temperature, selects for use suitable equipment to be ground to less than 300 orders, obtains water content less than 10% powder, stand-by;
Perhaps: the step 3) gains add maximum 5% dispersant, adding water stirs, make the ore pulp of 10-30%, select for use suitable spray drying device to carry out drying, the spray dryer EAT should be controlled at 150~180 ℃ of scopes, the discharging opening temperature is no more than 70 ℃, obtains water content less than 10% powder, and is stand-by;
Perhaps: step (3) gains add maximum 5% dispersant, add water and stir, and make the suspension of debita spissitudo again, and are stand-by.
3. a kind of copper-loaded montmorillonite according to claim 2 is solid-state with suspension liquid bactericide and preparation method thereof, it is characterized in that said sodium salt is sodium chloride, sodium nitrate, sodium sulphate.
4. a kind of copper-loaded montmorillonite according to claim 2 is solid-state with suspension liquid bactericide and preparation method thereof, it is characterized in that said mantoquita is copper sulphate, copper chloride, copper nitrate.
5. a kind of copper-loaded montmorillonite according to claim 2 is solid-state with suspension liquid bactericide and preparation method thereof, it is characterized in that said dispersant is a sodium tripolyphosphate, tetrasodium pyrophosphate, one or more in the sodium lignosulfonate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01145558 CN1358441A (en) | 2001-12-27 | 2001-12-27 | Copper-carried montmorillonite solid and liquid disinfectant and preparation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01145558 CN1358441A (en) | 2001-12-27 | 2001-12-27 | Copper-carried montmorillonite solid and liquid disinfectant and preparation process |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1358441A true CN1358441A (en) | 2002-07-17 |
Family
ID=4678233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 01145558 Pending CN1358441A (en) | 2001-12-27 | 2001-12-27 | Copper-carried montmorillonite solid and liquid disinfectant and preparation process |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1358441A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003077674A1 (en) * | 2002-03-18 | 2003-09-25 | Zhejiang University | A feed additive of nanometer size, a process preparing the same and a feed containing the feed additive of nanometer size |
CN100364406C (en) * | 2006-01-16 | 2008-01-30 | 宁夏大学 | Ion-oxide type/organic montmorillonite germicide and its preparing method |
CN100364409C (en) * | 2006-04-07 | 2008-01-30 | 浙江大学 | Preparation method and purpose of copper-carried silicate antimicrobial agent |
CN100381055C (en) * | 2006-04-07 | 2008-04-16 | 浙江大学 | Preparation method and purpose of zinc-carried silicate antimicrobial agent |
CN102578150A (en) * | 2012-02-08 | 2012-07-18 | 福建师范大学 | Method for preparing tea saponin/copper compound antibacterial agent |
CN105454293A (en) * | 2016-01-11 | 2016-04-06 | 济南康众医药科技开发有限公司 | Inorganic plant fungicide |
CN105519577A (en) * | 2016-01-11 | 2016-04-27 | 济南康众医药科技开发有限公司 | Novel application of Smecta in controlling vegetable diseases |
CN105639191A (en) * | 2015-12-31 | 2016-06-08 | 西南大学 | Feed additive for protecting intestinal health of hybrid snakehead fish and preparation method of feed additive |
CN108854587A (en) * | 2018-06-28 | 2018-11-23 | 山东大学 | A kind of high-throughput, antibacterial type doping hectorite-metal ion reverse osmosis composite membrane preparation method |
WO2021102746A1 (en) * | 2019-11-27 | 2021-06-03 | 惠州学院 | Dry powder paint with long-lasting antibacterial and antifungal effect and preparation method therefor |
-
2001
- 2001-12-27 CN CN 01145558 patent/CN1358441A/en active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003077674A1 (en) * | 2002-03-18 | 2003-09-25 | Zhejiang University | A feed additive of nanometer size, a process preparing the same and a feed containing the feed additive of nanometer size |
CN100364406C (en) * | 2006-01-16 | 2008-01-30 | 宁夏大学 | Ion-oxide type/organic montmorillonite germicide and its preparing method |
CN100364409C (en) * | 2006-04-07 | 2008-01-30 | 浙江大学 | Preparation method and purpose of copper-carried silicate antimicrobial agent |
CN100381055C (en) * | 2006-04-07 | 2008-04-16 | 浙江大学 | Preparation method and purpose of zinc-carried silicate antimicrobial agent |
CN102578150A (en) * | 2012-02-08 | 2012-07-18 | 福建师范大学 | Method for preparing tea saponin/copper compound antibacterial agent |
CN102578150B (en) * | 2012-02-08 | 2013-11-20 | 福建师范大学 | Method for preparing tea saponin/copper compound antibacterial agent |
CN105639191A (en) * | 2015-12-31 | 2016-06-08 | 西南大学 | Feed additive for protecting intestinal health of hybrid snakehead fish and preparation method of feed additive |
CN105454293A (en) * | 2016-01-11 | 2016-04-06 | 济南康众医药科技开发有限公司 | Inorganic plant fungicide |
CN105519577A (en) * | 2016-01-11 | 2016-04-27 | 济南康众医药科技开发有限公司 | Novel application of Smecta in controlling vegetable diseases |
CN108854587A (en) * | 2018-06-28 | 2018-11-23 | 山东大学 | A kind of high-throughput, antibacterial type doping hectorite-metal ion reverse osmosis composite membrane preparation method |
CN108854587B (en) * | 2018-06-28 | 2021-05-25 | 山东大学 | Preparation method of high-flux antibacterial doped hectorite-metal ion reverse osmosis composite membrane |
WO2021102746A1 (en) * | 2019-11-27 | 2021-06-03 | 惠州学院 | Dry powder paint with long-lasting antibacterial and antifungal effect and preparation method therefor |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101696136B (en) | Passivating agent for reducing bioavailability of heavy metals in livestock waste compost and using method thereof | |
US20140065306A1 (en) | Nanostructured calcium-silver phosphate composite powders, process for obtaining the powders and bactericidal and fungicidal applications thereof | |
RU2407289C1 (en) | Nanostructured biocide composition | |
DE102007020242A1 (en) | Biocatalysts, processes for their preparation and their use | |
CN1358441A (en) | Copper-carried montmorillonite solid and liquid disinfectant and preparation process | |
CN1188039C (en) | Light-stable inorganic powder silver-carried long-effective anti-bacterial powder and its preparation method | |
CN111067917A (en) | Composite material loaded with nano zinc oxide and preparation method thereof | |
CN101050365A (en) | Modifying agent for bottom material of pond for breeding aquatic products | |
Ma et al. | Antibacterial Activity of Cu 2+-ZnO-modified 13X Zeolite against E. coli and S. aureus | |
CN1201661C (en) | Copper-bearing sepiolite, palygorskite solid and suspension liquid fungicide and its preparation method | |
CN108033509B (en) | Biomass water body multistage water treatment agent | |
CN101746865A (en) | Purifying material, preparation method thereof and method utilizing purifying material to purify water | |
CN1283154C (en) | Stilbite carrier zine series inorganic germicide | |
KR100949719B1 (en) | Antibacterial zeolite resin composition | |
CN108530655A (en) | A kind of antibacterial plastic concentrate and preparation method for antibiotic plastic | |
CN106467439A (en) | A kind of drainage scheme for planting healthy agricultural product | |
CN100502659C (en) | Copper-carried rectorite bactericide and preparation method thereof | |
JP2969316B2 (en) | Sterilization materials using metal ions and zeolite compounds | |
Zuo et al. | Synergistic promotion system of montmorillonite with Cu2+ and benzalkonium chloride for efficient and broad-spectrum antibacterial activity | |
CN1151718C (en) | Animal and fowl disinfectant using nano material as carrier and preparation method thereof | |
CN1230078C (en) | High temp. resistant, colour fastness inorganic antimicrobial mildew preventive agent and its preparing method | |
CN1162336C (en) | Efficient nano water improver and its preparing process | |
CN114532364B (en) | Method for preparing nano-selenium/attapulgite composite antibacterial material by using olive leaf extract | |
CN118104645B (en) | Preparation method of hectorite with antibacterial property | |
KR0178333B1 (en) | Bacillus bacterium and bactericide and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C12 | Rejection of a patent application after its publication | ||
RJ01 | Rejection of invention patent application after publication |