KR0178333B1 - Bacillus bacterium and bactericide and preparation method thereof - Google Patents

Bacillus bacterium and bactericide and preparation method thereof Download PDF

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KR0178333B1
KR0178333B1 KR1019960027631A KR19960027631A KR0178333B1 KR 0178333 B1 KR0178333 B1 KR 0178333B1 KR 1019960027631 A KR1019960027631 A KR 1019960027631A KR 19960027631 A KR19960027631 A KR 19960027631A KR 0178333 B1 KR0178333 B1 KR 0178333B1
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hours
dried
bactericidal
water
mgo
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KR980007984A (en
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배경석
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배경석
주식회사워터스
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment

Abstract

본 발명은 CaO 및/또는 MgO와 산호초(coral sand), 화강암, 맥반석 및 제올라이트(zeolite)로 구성되는 군으로부터 선택되는 적어도 1종 이상의 광물을 200메쉬(mesh) 이하로 파쇄한 후, 에탄올에 용해한 에틸셀룰로오즈와 고르게 혼합하여 상온에서 48시간 동안 건조하여 증류수로 세척하여 2차건조시킨 다음, 100℃에서 과산화수소와 24시간 동안 반응시키고 증류수로 세척하여 3차 건조한 후 적당한 크기로 분쇄함을 특징으로 하는 음용수용 정균 및 살균제와 이의 제조방법에 관한 것으로, 제조되는 정균 및 살균제는 소규모의 정수에 적용이 용이하며 정균 및 살균효과가 우수할 뿐만아니라 인체에 무해하며 정수된 물의 맛을 변화시키지 않고 장기간 사용할 수 있는 효과가 있다.In the present invention, at least one or more minerals selected from the group consisting of CaO and / or MgO, coral sand, granite, elvan and zeolite are crushed to 200 mesh or less, and then dissolved in ethanol. After mixing evenly with ethyl cellulose, dried at room temperature for 48 hours, washed with distilled water and then dried for 2 hours, then reacted with hydrogen peroxide at 100 ℃ for 24 hours, washed with distilled water and dried 3 times, and then ground to a suitable size The present invention relates to bacteriostatic bacteria and disinfectants for drinking water, and to a method of manufacturing the bactericidal bacteria. The bactericidal bacteria and bactericides produced are easy to apply to small-scale purified water, have excellent bactericidal and bactericidal effects, and are harmless to the human body. It can be effective.

Description

음용수용 정균 및 살균제와 이의 제조방법Bacillus bacterium and bactericide and preparation method thereof

제1도는 본 발명 정균 및 살균제의 제조공정도이다.1 is a manufacturing process chart of the bacteriostatic bactericidal agent and the present invention.

본 발명은 음용수로 사용되는 물의 정제에 사용되는 정균 및 살균제와 이의 제조방법에 관한 것으로, 좀더 구체적으로는 CaO 및/또는 MgO와 산호초(coral sand), 화강암, 맥반석 및 제올라이트(zeolite)로 구성되는 군으로부터 선택되는 적어도 1종 이상의 광물을 200메쉬(mesh) 이하로 파쇄한 후, 에탄올에 용해한 에틸셀룰로오즈와 고르게 혼합하여 상온에서 48시간 동안 건조하고 증류수로 세척하여 2차건조시킨 다음, 100℃에서 과산화수소와 24시간 동안 반응시키고 증류수로 세척하여 3차 건조한 후 적당한 크기로 분쇄함을 특징으로 하는 음용수용 정균 및 살균제와 이의 제조방법에 관한 것이다.The present invention relates to bacteriostatic and bactericidal agents used in the purification of water used as drinking water, and more particularly, to CaO and / or MgO and coral sand, granite, elvan, and zeolite. After crushing at least one mineral selected from the group to 200 mesh or less, and evenly mixed with ethyl cellulose dissolved in ethanol, dried at room temperature for 48 hours, washed with distilled water and then dried secondly, at 100 ℃ It relates to a bacterium for drinking water and fungicide characterized in that it is reacted with hydrogen peroxide for 24 hours, washed with distilled water, and then pulverized to an appropriate size.

일반적으로 천연수를 음용수로 이용하기 위해서는 천연수를 정제하여야 하며, 천연수중의 토사, 먼지등을 제거하기 위해서는 모래, 자갈등을 이용하여 여과를 하고, 콜로이드상의 물질을 제거하기 위해서는 명반을 사용하며, 천연수중의 미생물등을 정균 및 살균하기 위해서는 표백분, 염소, 오존등을 사용하고 자외선을 이용한 살균방법이 사용되기도 한다.In general, to use natural water as drinking water, natural water should be purified. To remove soil and dust in natural water, it is filtered using sand and gravel, and alum is used to remove colloidal substances. In order to sterilize and sterilize microorganisms in natural water, bleaching powder, chlorine, ozone, etc., and ultraviolet sterilization method may be used.

그러나, 종래의 정수방법에 있어서 미생물의 정균 및 살균공정은 화학약품을 사용하므로 인체에 해를 끼칠 수도 있을 뿐만 아니라 음용수에서 이취가 나기도 하며 정수되는 물에 계속적으로 정균 및 살균용 화학약품을 투입하여야 하므로 대규모의 정수에만 적용할 수 있고 가정용 정수기등과 같이 소규모의 정수에는 적용할 수 없을 뿐만아니라 적용되더라도 번거롭고 정수비용이 과다하게 소요되는 문제점이 있었다.However, in the conventional water purification method, the bacteriostatic and sterilization process of microorganisms uses chemicals, which may not only harm the human body, but also cause odor from drinking water, and the chemicals for sterilization and sterilization should be continuously added to the purified water. Therefore, it can be applied only to large-scale water purification and not only to small-scale water purification, such as household water purifier, but also has a problem in that it is cumbersome and excessively costly water purification.

따라서, 본 발명의 목적은 소규모의 정수에 적용이 용이하며 정균 및 살균 효과가 우수할 뿐만아니라 인체에 무해하며 정수된 물의 맛을 변화시키지 않고 장기간 사용할 수 있는 음용수용 정균 및 살균제를 제공하는 데 있다.Accordingly, an object of the present invention is to provide a bactericidal bactericidal agent and bactericide which can be easily applied to small-scale purified water, has excellent bacteriostatic and bactericidal effects, and is harmless to the human body and can be used for a long time without changing the taste of purified water. .

본 발명의 또 다른 목적은 상기 목적의 음용수용 정균 및 살균제의 제조방법을 제공하는 데 있다.Still another object of the present invention is to provide a method for preparing bacteriostatic bacteria and fungicides for drinking water.

상기 목적 뿐만아니라 용이하게 표출될 수 있는 또 다른 목적을 달성하기 위하여 본 발명에서는 정균 및 살균작용이 있고 인체에 무해하며 이온상태의 미네랄을 생성하는 CaC2및 또는 MgO2와 정균 및 살균작용의 보조효과를 발현시키며 각종 원적외선과 미네랄을 방출하여 인체에 유용한 효과를 제공하는 산호초, 화강암, 맥반석 및 제올라이트로 구성되는 군으로 부터 선택되는 적어도 1종이상의 광물로 구성되는 정균 및 살균제를 사용하므로서 소규모의 정수에 적용이 용이하며 인체에 무해하고 정균 및 살균효과를 장시간 유지할 수 있었다.In order to achieve the above object as well as another object that can be easily expressed in the present invention has bacteriostatic and bactericidal action, harmless to the human body and assists in the bacteriostatic and bactericidal action with CaC 2 and / or MgO 2 to produce ionic minerals. Small-scale water purification by using bacteriophages and fungicides composed of at least one mineral selected from the group consisting of coral reef, granite, ganban stone and zeolite which expresses the effect and releases various far infrared rays and minerals to provide useful effects to the human body. Easy to apply, harmless to human body and could maintain bacteriostatic and bactericidal effect for a long time.

본 발명을 좀 더 구체적으로 설명하면 다음과 같다.The present invention is described in more detail as follows.

본 발명의 음용수용 정균 및 살균제는 MgO 및/또는 CaO와 산호초(coral sand), 화강암, 맥반석 및 제올라이트(zeolite)로 구성되는 군으로 부터 선택되는 적어도 1종이상의 광물을 200메쉬(mesh) 이하로 파괴하고, 에탄올에 용해한 에틸셀룰로오즈와 고르게 혼합한 후, 상온에서 48시간 이상 동안 건조하고 증류수로 세척하여 2차 건조시킨 다음 100℃에서 과산화수소와 25시간동안 반응시키고 증류수로 세척하여 3차 건조시키고 적당한 크기로 분쇄하므로서 제조된다.The bacteriostatic bactericidal agent and bactericide for drinking water of the present invention may contain at least one or more minerals selected from the group consisting of MgO and / or CaO and coral sand, granite, elvan and zeolite to 200 mesh or less. Destroyed, mixed evenly with ethyl cellulose dissolved in ethanol, dried at room temperature for more than 48 hours, washed with distilled water and then dried for 2 hours, reacted with hydrogen peroxide at 100 ° C. for 25 hours, washed with distilled water, and dried 3 times. It is prepared by grinding to size.

상술한 방법으로 제조된 살균 및 정균제는 MgO2및/또는 CaO2와 산호초, 화강암, 맥반석 및 제올라이트로 구성되는 군으로 부터 선택되는 적어도 1종이상의 광물 분말이 에틸셀룰로오즈와 고르게 혼합되어 있는 것이다.The bactericidal and bacteriostatic agents prepared by the above-mentioned method are MgO 2 and / or CaO 2 and at least one mineral powder selected from the group consisting of coral reefs, granites, ganban stones and zeolites is evenly mixed with ethyl cellulose.

본 발명의 정균 및 살균제에 사용되는 CaO 또는 MgO는 과산화수소와 반응하여 CaO2또는 MgO2로 되며, 미량의 CaO2와 MgO2는 물속의 CO2 2-와 반응하여 최종적으로 Ca2+와 Mg2+가 되어 이온상태의 미네랄이 되고 2분자의 HCO3를 발생하게 되어 인체에 유해한 물질은 발생되지 않게 되는 것이다.CaO or MgO used in the bacteriostatic and bactericidal agents of the present invention reacts with hydrogen peroxide to CaO 2 or MgO 2 , and trace amounts of CaO 2 and MgO 2 react with CO 2 2- in water and finally Ca 2+ and Mg 2 + Becomes ionic mineral and generates 2 molecules of HCO 3 so that no harmful substances are generated.

즉, 본 발명은 MgO2또는 CaO2가 의약품에도 사용되고 있으며, 일부는 살정제로도 사용되고 있고, 살충, 살균제로도 사용되고 있지만, 인체에는 무해하다는 점을 이용하여 천연수중의 미생물 특히, 세균을 정균 또는 살균하는 데 사용하였다.That is, in the present invention, MgO 2 or CaO 2 is used in pharmaceuticals, some of which are used as spermicides, insecticides and fungicides, but harmless to the human body, using microorganisms in natural water, especially bacteria Used to sterilize.

그러나, MgO2또는 CaO2는 일반적으로 화학적인 반응 예를들어 황산마그네슘 농수용액에서 과산화수소 존재하에 과산화나트륨을 첨가하여 침전되는 침전물을 회수하여 얻어지므로 인체에 해를 끼치는 불순물을 함유할 가능성이 높고 제조원가도 비싸므로 본 발명에서는 광물로 존재하므로 수득이 용이하고 값싼 CaO 또는 MgO를 과산화수소와 반응시켜 제조하여 사용한다.However, MgO 2 or CaO 2 is generally obtained by recovering a precipitate which is precipitated by adding a chemical reaction, for example, sodium peroxide in a magnesium sulfate aqueous solution in the presence of hydrogen peroxide, and thus is likely to contain impurities that are harmful to the human body. In the present invention, since it is expensive, since it is present as a mineral, it is easily obtained and prepared by reacting cheap CaO or MgO with hydrogen peroxide.

산호초, 화강암, 맥반석 및 제올라이트를 그대로 사용할 수도 있지만 정균 및 살균력을 향상시키기 위하여 금속이온 특히, 아연이나 구리이온등을 흡착시킨 것을 사용하는 것이 더욱 바람직하다.Coral reef, granite, elvan and zeolite may be used as they are, but in order to improve bactericidal and bactericidal power, it is more preferable to use metal ions, in particular zinc or copper ions.

에틸셀룰로오즈는 CaO 및 MgO와 산호초, 화강암, 맥반석 및 제올라이트의 입자를 응집시키기 위하여 사용되는 응집제로서 사용되는 광물을 균질하게 혼합한 다음, 에탄올에 용해한 에틸셀룰로오즈에 첨가하여 혼합하는 것이 효과적이다.Ethyl cellulose is effective to homogeneously mix CaO and MgO with minerals used as flocculant used to flocculate particles of coral reef, granite, elvan and zeolite, and then add and mix with ethyl cellulose dissolved in ethanol.

또한, 에틸셀룰로오즈 대신에 메틸셀룰로오즈, 벤젠셀룰로오즈, 카르복사메틸셀룰로오즈등을 사용할수도 있지만, 에틸셀룰로오즈를 사용하는 것이 인체에 무해하므로 더욱 바람직하다.In addition, methyl cellulose, benzene cellulose, carboxymethyl cellulose, and the like may be used instead of ethyl cellulose, but it is more preferable to use ethyl cellulose because it is harmless to the human body.

뿐만 아니라, CaO, MgO, 산호초, 화강암, 맥반석 및 제올라이트의 선택 및 혼합비율은 반복실험에 의하여 가장 바람직한 효과가 발현되도록 선택할 수 있음은 본 발명이 속하는 기술분야에서 통상의 지식을 가진자이면 용이하게 유추 가능하다.In addition, the selection and mixing ratio of CaO, MgO, coral reef, granite, elvan and zeolite can be selected to express the most desirable effect by repeated experiments as long as those skilled in the art to which the present invention belongs Can be inferred.

다음의 실시예는 본 발명을 좀더 구체적으로 설명하는 것이지만, 본 발명의 범주를 한정하는 것은 아니다.The following examples further illustrate the invention, but do not limit the scope of the invention.

[실시예 1]Example 1

CaO 100g, MgO 100, 산호초 25g, 화강암 25g, 맥반석 25g 및 제올라이트 25g을 각각 200메쉬 이하로 파쇄하여 균질하게 될 때까지 혼합한 다음, 에탄올 300ml에 에틸셀룰로오즈 200g을 용해한 용액을 첨가하여 고르게 혼합하여 상온에서 48시간 동안 건조시킨 후 증류수로 세척하여 2차 건조(상온, 48시간)시킨다.CaO 100g, MgO 100, Coral Reef 25g, Granite 25g, Elvan 25g, and Zeolite 25g are each mixed up to 200 mesh or less until homogeneous, and then a solution of 200g of ethyl cellulose dissolved in 300ml of ethanol is added and mixed evenly. After drying for 48 hours, the mixture was washed with distilled water and dried secondly (at room temperature, 48 hours).

건조된 혼합물을 100℃에서 과산화수소와 24시간 반응시킨 후, 증류수로 세척하고 3차건조(상온, 48시간)건조시킨 다음, 이를 적당한 크기로 분쇄하여 본 발명의 음용수용 정균 및 살균제를 제조하였다.The dried mixture was reacted with hydrogen peroxide at 100 ° C. for 24 hours, washed with distilled water, and then dried in tertiary drying (at room temperature, 48 hours), and then ground to a suitable size to prepare bacterium bacterium and bactericide for drinking water of the present invention.

제조된 정균 및 살균제를 이용하여 살균력시험을 행하였다.The bactericidal power test was performed using the prepared bacteriostatic and bactericidal agents.

각각 3개씩의 멸균된 비이커에 천연수를 채취하여 3시간동안 방치한 후, 1ml씩 취하여 19ml의 플레이트 카운트 아가(plate count agar) 배지의 페트리디쉬(petri dish)에 접종한 다음, 36℃에서 72시간동안 배양하여 생균수를 측정한다.Natural water was collected in three sterilized beakers, left for 3 hours, 1 ml each, inoculated in a petri dish of 19 ml plate count agar medium, and then 72 at 36 ° C. Incubate for time to measure viable count.

그다음에 상기에서 제조된 살균제를 각각 3, 5, 10g 첨가하여 1시간∼3시간 방치하고 상기와 동일한 방법으로 생균수를 측정하고 그 결과를 표1에 기재하였다.Then, 3, 5, and 10 g of the fungicides prepared above were added and left for 1 hour to 3 hours, and the number of viable cells was measured by the same method as described above, and the results are shown in Table 1.

상기 표1로부터 알 수 있는 바와같이, 살균력 시험결과 원수의 미생물 농도가 4.10×10 CFU/ml이고 3g의 살균제를 첨가하여 60분간 정치하였을 때 생균수가 5.07×10 CFU/ml로 나타나 이미 살균효과가 있음을 알 수 있으며, 10g의 살균제를 첨가하고 180분간 정치시켰을 경우 생균수가 1.09×10 CFU/ml이었고 원수의 균중 97.3%가 사멸된 것임을 알 수 있는 바, 본 발명의 정균 및 살균제는 상당히 높은 살균력을 갖는 것이 명백하였다.As can be seen from Table 1, the microbial concentration of the raw water is 4.10 × 10 When CFU / ml and 3g of fungicide was added and left for 60 minutes, the viable cell count was 5.07 × 10 It can be seen that CFU / ml has a bactericidal effect, and the number of viable bacteria is 1.09 × 10 It was clear that the bacterium and bactericide of the present invention had a considerably high bactericidal power as it can be seen that the CFU / ml and 97.3% of the bacteria in the raw water were killed.

Claims (2)

MgO 및/또는 CaO와 산호초(coral sand), 화강암, 맥반석 및 제올라이트(zeolite)로 구성되는 군으로 부터 선택되는 적어도 1종이상의 광물을 200메쉬(mesh) 이하로 파쇄하고, 에탄올에 용해한 에틸셀룰로오즈와 고르게 혼합한 후, 상온에서 48시간 이상 동안 건조하고 증류수로 세척하여 2차 건조시킨 다음 100℃에서 과산화수소와 24시간동안 반응시키고 증류수로 세척하여 3차 건조시키고 적당한 크기로 분쇄함을 특징으로 하는 음용수용 정균 및 살균제의 제조방법.MgO and / or CaO and at least one mineral selected from the group consisting of coral sand, granite, elvan and zeolite are crushed to 200 mesh or less, and ethyl cellulose dissolved in ethanol and After mixing evenly, dried at room temperature for more than 48 hours, washed with distilled water and then dried for 2 hours, then reacted with hydrogen peroxide at 100 ℃ for 24 hours, washed with distilled water, tertiary dried and ground to a suitable size Method for producing water soluble bacterium and bactericide. MgO2및/또는 CaO2와 산호초, 화강함, 맥반석 및 제올라이트로 구성되는 군으로 부터 선택되는 적어도 1종이상의 광물로 구성됨을 특징으로 하는 음용수용 정균 및 살균제.A bacterium and bactericide for drinking water, characterized by consisting of MgO 2 and / or CaO 2 and at least one mineral selected from the group consisting of coral reefs, granules, elvan and zeolites.
KR1019960027631A 1996-07-09 1996-07-09 Bacillus bacterium and bactericide and preparation method thereof KR0178333B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030070490A (en) * 2002-02-25 2003-08-30 임용택 a filtration plant water sand filter

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030070490A (en) * 2002-02-25 2003-08-30 임용택 a filtration plant water sand filter

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