CN102992435A - Organic-inorganic composite adsorptive rural well water disinfecting ceramic chip - Google Patents

Abstract

The invention relates to an organic-inorganic composite adsorptive rural well water disinfecting ceramic chip. The ceramic chip is rich in the organic matter of biological source and the inorganic matter of mineral source, thereby having strong complexing adsorption effect, peculiar smell elimination effect, disinfectant and antiseptic effect and poison prevention and health protection effect; and without chemical reaction and chemical medicines, the ceramic chip can convert the well water, which exceeds the domestic drinking water hygiene practice standard, into the domestic water meeting the 'Drinking Water Health Standards', based on the adsorptive concentration principle, thus, the harm of extremely high heavy metal content in underground water to the local villagers in remote rural areas caused by geological reasons is reduced.

Description

Two-shipper composite adsorption rural well water sterilization pottery sheet

Technical field the present invention relates to a kind of two-shipper composite adsorption rural well water sterilization pottery sheet, effective ingredient is tourmalinite nano powder, negative ion powder, medical stone powder, sepiolite powder, ooze silver-colored activated carbon, biogenic activated earth, biological activity lipid fatty amide, high-molecular biologic are lived plain polymerization element, the active bond weighting agent through mix, polyreaction, repeatedly the multiple die mould, oven dry, flushing, enure of admittedly adsorbing becomes the techniques such as hollow out sheet, makes two-shipper composite adsorption rural well water sterilization pottery sheet.Total metal is the denier element that needs in the human body, but optional.When content of 6-valence Cr ions surpasses 0.1mg/L, just may cause human body to be poisoned.It stimulates, and corrodes mucocutaneous and Digestive tract, and accumulates in human body, even cause the bent cancer of digestive tube.A large amount of absorption chromic salts may cause the necrosis of oral cavity, esophagus and stomach and intestine, liver kidney cardiac muscle Steatosis, and severe patient involves central nervous system and very fast death.The national hygiene standard for drinking water regulation is no more than 0.05mg/L, and the sexavalent chrome of high-quality water preferably levels off to zero.The content of chromium is generally atomic in the underground water, but because the pollution of trade effluent, or due to the geologic background, the chrome content of some areas underground water is increased severely, and can reach 0.2～0.7mg/L, substantially exceed sanitary standard for drinking water.Aspect the tap water dechromisation, mostly use for reference trade effluent dechromisation treatment technology, yet the aspects such as both water quality, application target, technical requirements, cleanup standard there is larger difference at present, not ideal enough in actual applications.Therefore, people wish to have a kind of safe and reliable, sterilised filtration absorption complex function, rural well water sterilization except total metal product always.The present invention has very strong complexing absorption, removes peculiar smell, sterilization and anticorrosion, preventing poison nourishing function because it is rich in biogenic organism, mineral sources inorganics.

Background technology the object of the present invention is to provide a kind of safe and reliable two-shipper composite adsorption rural well water sterilization pottery sheet, on the basis that does not need chemical reaction and pharmaceutical chemicals, by the adsorption and enrichment principle, can the well water of Drinking Water hygienic practice standard will be surpassed, convert the domestic water that meets " Drinking Water hygienic practice " to, the rural area is from far-off regions because the underground water heavy metal content that Geological Reasons causes is too high to reduce, and the harm of causing for local villager.For national and the common people have increased available water source, reduced because the tremendous economic loss that disease causes.This two-shipper composite adsorption rural well water sterilization pottery sheet, adsorption and enrichment removing heavy metals effect is remarkable, good stability, technique is simple, and cost is low, and is easy to use, is widely used.Belong to nontoxic, harmless, non-stimulated, non-corrosiveness, food grade, the two-shipper composite adsorption rural well water sterilization pottery sheet of environment-friendly type.

Summary of the invention main points of the present invention are to select suitable component, and through mix, polyreaction, admittedly adsorb die mould repeatedly again, dry, rush Xian, the technique such as high-temperature calcination, precision work form, make two-shipper composite adsorption rural well water sterilization pottery sheet.The prescription following (component and weight percent % thereof) that the present invention selects: tourmalinite nano powder 20-30; Negative ion powder (1500 order) 10-20; Medical stone powder (2000 order) 10-20; Sepiolite powder (2000 order) 5-10; Ooze silver-colored activated carbon 4-5; Biogenic activated earth 5-10; Biological activity lipid fatty amide 2-3; High-molecular biologic plain polymerization element 1-5 alive; The active bond weighting agent adds to 100.

The advantage of tourmalinite nano powder action principle single crystal tourmalinite maximum is that can to produce permanent weak current be 0.06 milliampere(mA), and its characteristic roughly is divided into following five.(1) produces negative ion and have the effect of deodorizing.(2) behind the brine electrolysis water electrolysis, can obtain the stabilization of active function, the chlorine at interface, the passivation of iron (prevent red iron rust to generate and red water occurs), water reducing, remove the various effects such as silicon-dioxide and binding (microorganism aggregate).Tourmalinite and water reaction just can be processed all very unmanageable problems of fluidization lotion and chemical substance.(3) dwindling water molecules bundle water molecules (H2O) is not Individual existence, and its molecule can mutually combine, and forms molecular beam.The water that molecular beam is less can be removed chlorine or impurity, and taste is good, and can improve the seepage force of health.4) emitting far infrared ray (the growth light of 4-14 micron) far infrared rays can be penetrated into health deep layer position, and warm cell stimulates circulation, and makes metabolism smooth and easy.Tourmalinite far infrared rays emissivity nearly 100%, numerical value is high than other mineral.(5) contain effective trace mineral tourmalinite and contain various natural mineral matters, wherein have many and human necessary mineral substance identical.By the effect of weak current, mineral substance easily is absorbed, and is splendid mineral origin.

The action principle of negative ion powder: the mechanism of gas molecule ionization in (1) permanent negative aeroion generating function air, main outer boundary ionizer is to the result of gas effect, and ionizer has ultraviolet ray, radioactive rays, photovoltaic effect etc.Composition in the anion powder has pyroelectricity and piezoelectricity, therefore can cause the potential difference between the composition crystal in the situation that there is temperature and pressure to change (even small variation), this static is up to 1,000,000 electron-volts, thereby air is ionized, the electron attachment of being hit is in contiguous water and oxygen molecule and make it be converted into negative aeroion, i.e. negative oxygen ion.(2) composition in the stronger far-infrared transmitting function ion powder is the aluminium take boracic as feature, sodium, iron, the silicate material of lithium ring texture, isomorph is grown, because of its pyroelectricity and piezoelectricity, make its polarity ion cause that in the equilibrium theory of tide vibration moment of dipole changes the electromagnetic radiation that produces far infrared band, if add to by a certain percentage by (for example fiber) in the product, make it by the free ion of self, impurity ion and ionic substance, impurity and two, three phonon sympathetic responses produce radiation, affect ionic linkage polarity vibration organic and the inorganic molecule interlinkage, having formed stronger radiation broadband, is more than 90% according to the test anion powder to far emittance.The far infrared performance of anion powder to the health care of human body and other effect mainly contain the following aspects 1. far infrared can accelerate the water molecules motion; make ortho-water become active water; thereby seepage force, diffusive force, solvency power, the metabolism power of water are strengthened, and produce the water conservation film.2. far infrared can play the expansion capillary vessel for the recycle system, strengthens blood circulation, enhances metabolism, and strengthens the effect of lymphokinesis.3. far infrared can make cell activation for cell tissue, makes old dead cell drainage or gives regenerative power, can strengthen cellular energy, the effects such as the function of enhancing cell and vigor.(3) negative oxygen ion that produces in the good antibiotic and sterilizing function anion powder has higher activity, and very strong redoxomorphism is arranged, and can destroy the activity of cytolemma or the cellular plasm organized enzyme of bacterium, thereby reaches the purpose of antibiotic and sterilizing.

The action principle of medical stone powder: be a kind of to biological nontoxic, harmless and have certain bioactive composite minerals or a medicinal rock.The parent rock Chang Weizhong of medical stone, acid magmatic rock.Its chemical composition also has a small amount of rare elements, rare earth element, radioelement except common Ca, Mg, Si, Al, Fe, K, Na.Medical stone has the performances such as adsorptivity, solvability, PH modulability, biological activity and mineralising.Free metal ion in its energy planar water.Contain Al203 approximately 15% in the medical stone, it is typical intermediate oxide, in the aqueous solution, meet the alkali reduction pH value that reacts, meet the acid raising pH value that reacts, function with two-ways regulation PH. through the medical stone that bubble is crossed, leachable to trace elements such as human body and organism useful major element K, Na, Ca, Mg, P and Si, Fe, Zn, Cu, Mo, Se, Mn, Sr, Ni, V, Co, Li, Cr, I, Ge, Ti.Medical stone can also hold the necessary amino acid of human body in the aqueous solution, but widespread use health care, food, beverage and purification of water quality, sewage disposal, anticorrosion, deodorization, fresh-keeping, decontamination, porcelain making and the fields such as plant husbandry and aquaculture.

The action principle of sepiolite: sepiolite belongs to rhombic system or single rhombic system; The chemical composition of sepiolite is silicon (Si) and magnesium (Mg); Chemical formula is Mg8 (H2O) 4[Si6016] 2 (OH) 48H2O, wherein generally between 54～60%, MgO content is many in 21～25% scopes for SiO2 content, and Mohs' hardness is between 2～2.5; Physique is light, and density is 1～2.2g/cm3; Shrinking percentage is low, and plasticity-is good, can be dissolved in hydrochloric acid.Have satin luster, sometimes be wax-like gloss; Streak is white in color, and is opaque, and the smooth and sticking tongue of sense of touch and the extremely strong performances such as absorption, decolouring and dispersion also have high thermostability, and high thermal resistance can reach 1500～1700 ℃, and formative nature, insulativity, anti-salinity are all very good.Purposes is sorbent material, discoloring agent, filtering medium very extensively; Molecular sieve, be used for chemical industry, sugaring, wine brewing; Ion-exchanger, scavenging agent, shiny pharmaceutical; Particulate stain removal agent and sorbent material; Catalyzer, suspension agent, thickening material and thixotropic agent; The cigaratte filter raw material; The support material of sterilant, soil disinfection, preparation special material, preparation animal formulation, domestic animal packing ring; The special ceramics parts of nuclear power, rocket, satellite aspects; The special mud of anti-salt, high temperature resistance.

Ooze the action principle of silver-colored activated carbon: activated carbon and silver are combined, not only organic pollutants is had adsorption, also have germicidal action, and in activated carbon, can not grow bacterium, solved container and the high problem of nitrite content sometimes occurred.When water when oozing silver-colored activated carbon, silver ions will slow release out, play sterilization.Since activated carbon to except the middle look that anhydrates, smell, chlorine, iron, arsenic, mercury, prussiate, phenol etc. has better effects, therefore bacteria-eliminating efficacy is employed in the small containers more than 90%.

The action principle of biogenic activated earth: the biogenic activated earth is to be base-material by biological leaf rock potter's clay raw material, forms through precision work, and it has enough physical strengths.Can avoid in the process of washing away, because of the friction fragmentation.Have enough chemical stabilities, in alkalescence, neutral, sour water or do not dissolve in the oil.To process and purify acid, in, the best product of alkaline water.Has certain particle through joining.Grain filtrate material is light, and specific surface area is large, and the absorption suspending power is strong, and have wear-resisting, resistance to erosion, micropore is many, retaining power is strong, the advantages such as stable chemical performance.Surface irregularity and corner angle are arranged.Can ensure filtration velocity, the more abundant dirty ability that contains is arranged again.Can adapt to and reach the Depurative design requirement of water or oil.The biogenic activated earth is water factory, the comparatively ideal filtering material in filter tank and refinery oil strain pond.Product does not contain harmful metal ion and poisonous and harmful impurity.Not only suspended solid impurities, turbidity, colourity, iron, manganese, volatility toxic and harmful are had interception, filtration, absorption, diffusion, in the BAF water treatment system, reduction CODCr, " three nitrogen " (ammonia nitrogen, nitrate nitrogen, nitrite nitrogen), total phosphorus are had positive effect.Organic industrial sewage that can be biochemical, industrial assorted draining, micro polluted source etc. can be processed, quartz sand, hard coal etc. can be in water treatment, replaced fully as filtration medium.

The action principle of fatty amide: participate in the adjusting of organism several functions as organic endogenous biological activity lipid.In addition, fatty amide interrelates with other lipid Molecular regulator again.When being generated by corresponding NAPE hydrolysis such as ANA and PEA, with the formation of another Cell regulate material phosphatidic acid, the arachidonic acid that the ANA degraded generates is synthetic relevant with twenty carbon alkanes by activating its special Phospholipase A2.Can think thus, fatty amide is the organic component of biological effect lipid family.The high biological activity of the comparatively simple compound of these structures, receptor-mediated mechanism of action, endogenous is synthetic and constantly the illustrating of degradation pathway, and will make them may be confirmed as the new biological regulation material of a class.The action principle of high-molecular biologic plain polymerization element alive is as organic disinfectant component, amino in this component all has very high activity, make resultant of reaction be positive polarity, therefore be easy to usually be electronegative each bacterioid, viral absorption, thereby suppress and intervened enzyme system and the splitting function of bacterium, virus, make the breeding function forfeiture of bacterium, virus, thereby suppress and intervened enzyme system and the splitting function of bacterium, virus, make the breeding function forfeiture of bacterium, virus, reach sterilizing function.

Active bond weighting agent carrier plays the moulding effect.

The preparation method of product of the present invention is:

1), with tourmalinite nano powder, negative ion powder (1500 order), medical stone powder (2000 order), sepiolite powder (2000 order), ooze live plain polymerization element, active bond weighting agent of silver-colored activated carbon, biogenic activated earth, biological activity lipid fatty amide, high-molecular biologic and prepare in proportion;

2), the raw material embryo that will be mixed, molded in the punching block of pack on request fixed ready-made different shaped shape, different size,

3), through high-temperature calcination (150-180 ℃);

4), the cooling after, finished product packing.

The present invention compares with existing product and has the following advantages: the special antibiotic ceramic material of (1) biomineral source two-shipper, and nontoxic non-stimulated, non-corrosiveness does not produce toxicity; (2) the antibiotic rate effect is remarkable.Antibiotic rate can reach 100%; (3) because it is rich in biogenic organism, mineral sources inorganics, have very strong adsorption and enrichment, the removing heavy metals effect is remarkable, sterilization and anticorrosion, preventing poison nourishing function.(4) stable chemical nature need not carry out the adjustment of pH value in treating processes, reduced cost and the step of water treatment.(5) use mineral substance as raw material, reduced production cost.

The present invention is described in further detail below in conjunction with embodiment for embodiment:

Be configured according to following table institute column data (weight percent %) and described step thereof:

Tourmalinite nano powder 20-30; Negative ion powder (1500 order) 10-20; Medical stone powder (2000 order) 10-20; Sepiolite powder (2000 order) 5-10; Ooze silver-colored activated carbon 4-5; Biogenic activated earth 5-10; Biological activity lipid fatty amide 2-3; High-molecular biologic plain polymerization element 1-5 alive; The active bond weighting agent adds to 100.

Prescription two:

Tourmalinite nano powder 25-30; Negative ion powder (1500 order) 15-20; Medical stone powder (2000 order) 12-20; Sepiolite powder (2000 order) 6-10; Ooze silver-colored activated carbon 4.5-5; Biogenic activated earth 6-10; Biological activity lipid fatty amide 2.5-3; High-molecular biologic plain polymerization element 2-5 alive; The active bond weighting agent adds to 100.

Claims (2)

1. the present invention relates to a kind of two-shipper composite adsorption rural well water sterilization pottery sheet, it is characterized in that having following prescription (component and weight percent % thereof): tourmalinite nano powder 20-30; Negative ion powder (1500 order) 10-20; Medical stone powder (2000 order) 10-20; Sepiolite powder (2000 order) 5-10; Ooze silver-colored activated carbon 4-5; Biogenic activated earth 5-10; Biological activity lipid fatty amide 2-3; High-molecular biologic plain polymerization element 1-5 alive; The active bond weighting agent adds to 100.

2. the preparation method of the described two-shipper composite adsorption of claim 1 rural well water sterilization pottery sheet is characterized in that having following step:

1), with tourmalinite nano powder, negative ion powder (1500 order), medical stone powder (2000 order), sepiolite powder (2000 order), ooze live plain polymerization element, active bond weighting agent of silver-colored activated carbon, biogenic activated earth, biological activity lipid fatty amide, high-molecular biologic and prepare in proportion;

2), the raw material embryo that will be mixed, molded in the punching block of pack on request fixed ready-made different shaped shape, different size,

3), through high-temperature calcination (150-180 ℃);

4), the cooling after, finished product packing.