CN1535309A - 作为流变助剂的混合聚亚烷基二醇羟烷基异硬脂酰胺 - Google Patents
作为流变助剂的混合聚亚烷基二醇羟烷基异硬脂酰胺 Download PDFInfo
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- CN1535309A CN1535309A CNA028099990A CN02809999A CN1535309A CN 1535309 A CN1535309 A CN 1535309A CN A028099990 A CNA028099990 A CN A028099990A CN 02809999 A CN02809999 A CN 02809999A CN 1535309 A CN1535309 A CN 1535309A
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- Prior art keywords
- composition
- amine
- surfactant system
- hydroxyethyl
- surfactant
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- -1 hydroxyalkyl isostearamides Chemical class 0.000 title claims abstract description 247
- 239000002671 adjuvant Substances 0.000 title claims abstract 3
- 229920001515 polyalkylene glycol Polymers 0.000 title claims description 8
- 238000000518 rheometry Methods 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 153
- 239000004094 surface-active agent Substances 0.000 claims abstract description 144
- 239000007788 liquid Substances 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 23
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001451 polypropylene glycol Polymers 0.000 claims description 84
- 239000013543 active substance Substances 0.000 claims description 58
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 38
- 150000001408 amides Chemical class 0.000 claims description 37
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 36
- 244000060011 Cocos nucifera Species 0.000 claims description 36
- 150000003839 salts Chemical class 0.000 claims description 34
- 238000004140 cleaning Methods 0.000 claims description 25
- 230000008719 thickening Effects 0.000 claims description 25
- 230000001737 promoting effect Effects 0.000 claims description 23
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
- 150000001412 amines Chemical class 0.000 claims description 17
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 12
- 125000002091 cationic group Chemical group 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- LMVSBYPDMNAXPF-UHFFFAOYSA-N N-(decanoyl)ethanolamine Chemical compound CCCCCCCCCC(=O)NCCO LMVSBYPDMNAXPF-UHFFFAOYSA-N 0.000 claims description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 9
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 9
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 9
- 229940063953 ammonium lauryl sulfate Drugs 0.000 claims description 9
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 9
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 9
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 claims description 8
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 239000002453 shampoo Substances 0.000 claims description 6
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 239000006210 lotion Substances 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 claims description 3
- AZLWQVJVINEILY-UHFFFAOYSA-N 2-(2-dodecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCOCCOCCO AZLWQVJVINEILY-UHFFFAOYSA-N 0.000 claims description 2
- 229940100491 laureth-2 Drugs 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 4
- 229940043264 dodecyl sulfate Drugs 0.000 claims 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 3
- 239000004743 Polypropylene Substances 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 7
- KZVIUXKOLXVBPC-UHFFFAOYSA-N 16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(N)=O KZVIUXKOLXVBPC-UHFFFAOYSA-N 0.000 abstract 1
- 150000002169 ethanolamines Chemical class 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 40
- 125000004432 carbon atom Chemical group C* 0.000 description 35
- 125000000217 alkyl group Chemical group 0.000 description 31
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 24
- 239000003921 oil Substances 0.000 description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 19
- 239000000047 product Substances 0.000 description 18
- 229960003237 betaine Drugs 0.000 description 17
- 239000000375 suspending agent Substances 0.000 description 17
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 239000002585 base Substances 0.000 description 11
- 235000013599 spices Nutrition 0.000 description 11
- 244000068988 Glycine max Species 0.000 description 10
- 235000010469 Glycine max Nutrition 0.000 description 10
- 125000003368 amide group Chemical group 0.000 description 10
- 150000002191 fatty alcohols Chemical class 0.000 description 10
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 9
- BQODPTQLXVVEJG-UHFFFAOYSA-N [O].C=C Chemical group [O].C=C BQODPTQLXVVEJG-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 125000002769 thiazolinyl group Chemical group 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 7
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 238000007046 ethoxylation reaction Methods 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 150000002632 lipids Chemical class 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 150000003904 phospholipids Chemical class 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- QBKSIHCSDPPLJI-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]tetradecan-1-ol;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCC(CO)N(CCO)CCO QBKSIHCSDPPLJI-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical group 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 229910052728 basic metal Inorganic materials 0.000 description 3
- 150000003818 basic metals Chemical group 0.000 description 3
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000000118 hair dye Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000000516 sunscreening agent Substances 0.000 description 3
- IQGWPPQNIZBTBM-UHFFFAOYSA-N 2-aminoethanol;sulfuric acid Chemical compound NCCO.OS(O)(=O)=O IQGWPPQNIZBTBM-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 208000006558 Dental Calculus Diseases 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000005466 alkylenyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229960002989 glutamic acid Drugs 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
%盐 | 粘度(cps) | |||
A | B | C | D | |
0 | 220 | 140 | 500 | 125 |
1 | 3900 | 17000 | 7000 | 3650 |
2 | 5700 | 92000 | 29000 | 14800 |
3 | 90000 | 3000 | 34000 | 18300 |
4 | 120000 | 15500 | 8000 | |
5 | 200 |
%盐 | 粘度(cps) | ||||
A | B | C | D | E | |
0 | 1800 | 40 | 40 | 5 | 5 |
0.25 | 2000 | 60 | 70 | 10 | 20 |
0.50 | 4399 | 70 | 180 | 40 | 50 |
0.75 | 20,596 | 80 | 700 | 160 | 180 |
1.00 | 24,195 | 180 | 1700 | 1500 | 900 |
1.25 | 3999 | 800 | 2999 | 3099 | 2399 |
1.50 | 1300 | 1200 | 5599 | 4599 | 4499 |
%盐 | 粘度(cps) | |||
A | B | C | D | |
0 | 260 | 2999 | 120 | 1500 |
0.25 | 1800 | 15,597 | 600 | 9098 |
0.50 | 3799 | 25,095 | 3599 | 19,996 |
0.75 | 7598 | 32,093 | 6399 | 29,394 |
1.00 | 13,197 | 32,393 | 11,698 | 31,993 |
1.25 | 16,297 | 23,495 | 17,596 | 30,993 |
1.50 | 17,897 | 9398 | 22,295 | 14,697 |
%盐 | 粘度(cps) | ||||
A | B | C | D | E | |
0 | 560 | 10 | 20 | 10 | 5 |
0.25 | 700 | 20 | 30 | 20 | 10 |
0.50 | 1900 | 30 | 80 | 40 | 20 |
0.75 | 4499 | 80 | 220 | 540 | 180 |
1.00 | 6699 | 360 | 2699 | 1300 | 1400 |
1.25 | 5899 | 1400 | 4299 | 1500 | 2200 |
1.50 | 1300 | 1900 | 5499 | 3399 | 3399 |
%盐 | 粘度(cps) | |||
A | B | C | D | |
0 | 10* | 16* | 20* | 26* |
1 | 25 | 26* | 90* | 118* |
2 | 30 | 62* | 2,400* | 3,430* |
3 | 35 | 334 | 16,000* | 12,600* |
4 | 65 | 1188 | 153,000* | 1,680* |
5 | 450 |
组分 | wt% | |
A | 水 | 适量到100% |
B | 盐(氯化钠) | 0.50 |
C | EDTA二钠 | 0.20 |
D | ALES | 6.72 |
E | ALS | 2.50 |
F | C12-13烷基磷酸钾 | 1.20 |
G | 亚麻酸酰氨基(Linoleamido)丙基PG二铵 | 0.60 |
H | 颗粒悬浮剂 | 0.14 |
I | PPG2羟乙基椰油酰胺 | 1.50 |
J | PPG1.5羟乙基异硬脂酰胺 | 0.50 |
K | 霍霍巴颗粒 | 0.70 |
L | DMDM乙内酰脲 | 0.50 |
M | 香料 | 0.10 |
Claims (46)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/855,826 US6635607B2 (en) | 2001-05-15 | 2001-05-15 | Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants |
US09/855,826 | 2001-05-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1535309A true CN1535309A (zh) | 2004-10-06 |
CN1272419C CN1272419C (zh) | 2006-08-30 |
Family
ID=25322164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028099990A Expired - Lifetime CN1272419C (zh) | 2001-05-15 | 2002-05-03 | 作为流变助剂的混合聚亚烷基二醇羟烷基异硬脂酰胺 |
Country Status (21)
Country | Link |
---|---|
US (1) | US6635607B2 (zh) |
EP (1) | EP1395644B1 (zh) |
JP (1) | JP4514393B2 (zh) |
KR (1) | KR100887861B1 (zh) |
CN (1) | CN1272419C (zh) |
AR (1) | AR035893A1 (zh) |
AT (1) | ATE397652T1 (zh) |
AU (1) | AU2002342563B2 (zh) |
BR (1) | BR0209673B1 (zh) |
CA (1) | CA2447042C (zh) |
CO (1) | CO5650174A2 (zh) |
DE (1) | DE60226972D1 (zh) |
EG (1) | EG23011A (zh) |
ES (1) | ES2311064T3 (zh) |
IL (2) | IL158452A0 (zh) |
MX (1) | MXPA03010415A (zh) |
PL (1) | PL200946B1 (zh) |
RU (1) | RU2298582C2 (zh) |
TW (1) | TW573008B (zh) |
WO (1) | WO2002092740A1 (zh) |
ZA (1) | ZA200308357B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101553283B (zh) * | 2006-12-08 | 2013-12-11 | 荷兰联合利华有限公司 | 浓缩的表面活性剂组合物 |
CN104771346A (zh) * | 2015-03-19 | 2015-07-15 | 苏州谷力生物科技有限公司 | 一种香茅草洗手液及其制备方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050014671A1 (en) * | 2003-07-14 | 2005-01-20 | Queen Craig B. | Solvated nonionic surfactants and fatty acids |
US20050026805A1 (en) * | 2003-07-14 | 2005-02-03 | Ici Americas, Inc. | Solvated nonionic surfactants and fatty acids |
US7037840B2 (en) * | 2004-01-26 | 2006-05-02 | Micron Technology, Inc. | Methods of forming planarized surfaces over semiconductor substrates |
JP4337585B2 (ja) * | 2004-03-10 | 2009-09-30 | 新日本理化株式会社 | 増粘剤組成物及びその製造方法、並びに該増粘剤組成物による増粘方法 |
US7456139B2 (en) * | 2004-05-07 | 2008-11-25 | Croda Uniqema, Inc. | Solvated nonionic surfactants |
KR101087405B1 (ko) * | 2005-12-08 | 2011-11-25 | 애경산업(주) | 주방용 액체 세제 조성물 |
DE102006031377A1 (de) * | 2006-07-06 | 2007-02-15 | Clariant International Limited | Kosmetische oder dermatologische Reinigungsmittel enthaltend sekundäre Alkansulfonate |
US8828364B2 (en) * | 2007-03-23 | 2014-09-09 | Rhodia Operations | Structured surfactant compositions |
DE102011003170A1 (de) | 2010-11-10 | 2012-05-10 | Evonik Goldschmidt Gmbh | Zusammensetzung enthaltend Mischungen von Isostearinsäureamid, Glycerinester und Wasser |
BR112016010950B1 (pt) | 2013-11-22 | 2020-03-10 | Colgate-Palmolive Company | Composição que é um sabonete líquido para as mãos ou para lavagem do corpo |
MX2018007870A (es) | 2015-12-31 | 2018-11-09 | Colgate Palmolive Co | Composiciones de limpieza. |
US20210221739A1 (en) * | 2016-06-16 | 2021-07-22 | Kao Corporation | Rheology modifier |
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GB783778A (en) | 1954-03-24 | 1957-10-02 | Marchon Products Ltd | Improvements in or relating to detergents |
US2991296A (en) | 1959-02-26 | 1961-07-04 | Oscar L Scherr | Method for improving foam stability of foaming detergent composition and improved stabilizers therefor |
GB962585A (en) | 1961-11-03 | 1964-07-01 | Unilever Ltd | Detergent compositions |
US3882038A (en) | 1968-06-07 | 1975-05-06 | Union Carbide Corp | Cleaner compositions |
DE2930061A1 (de) | 1979-07-25 | 1981-02-19 | Hoechst Ag | Waescheweichspuelmittel |
JP3608844B2 (ja) | 1995-06-13 | 2005-01-12 | 川研ファインケミカル株式会社 | 高粘度液体洗浄剤組成物 |
JP3524223B2 (ja) * | 1995-07-10 | 2004-05-10 | 川研ファインケミカル株式会社 | ポリオキシプロピレン脂肪酸イソプロパノールアミド混合物を含有する増粘された洗浄剤組成物 |
US6200554B1 (en) | 1996-10-16 | 2001-03-13 | The Procter & Gamble Company | Conditioning shampoo compositions having improved silicone deposition |
DE19650151A1 (de) | 1996-12-03 | 1998-06-04 | Basf Ag | Alkoxylierte Amide und ihre Verwendung in Wasch-, Reinigungs- und Körperpflegemitteln |
EP0946498A2 (de) | 1996-12-03 | 1999-10-06 | Basf Aktiengesellschaft | Verfahren zur abtrennung von glycerin aus glycerin und fettsäureamide enthaltenden reaktionsgemischen, daraus erhaltene alkoxylierte amide und deren verwendung |
DE69932706T2 (de) | 1998-03-11 | 2007-08-02 | Mona Industries, Inc. | Verbesserte alkanolamide |
US6531443B2 (en) * | 1998-03-11 | 2003-03-11 | Mona Industries, Inc. | Alkanolamides |
DE10039742A1 (de) | 2000-08-12 | 2002-02-28 | Goldwell Gmbh | Verwendung propoxylierter C¶10¶-C¶18¶-Fettsäurealkanolamide in Haarwaschmitteln |
US6514918B1 (en) * | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
US20020173435A1 (en) * | 2000-08-18 | 2002-11-21 | Librizzi Joseph J. | Viscous, mild, and effective cleansing compositions |
-
2001
- 2001-05-15 US US09/855,826 patent/US6635607B2/en not_active Expired - Lifetime
-
2002
- 2002-05-03 EP EP02769678A patent/EP1395644B1/en not_active Expired - Lifetime
- 2002-05-03 AT AT02769678T patent/ATE397652T1/de not_active IP Right Cessation
- 2002-05-03 DE DE60226972T patent/DE60226972D1/de not_active Expired - Lifetime
- 2002-05-03 CA CA2447042A patent/CA2447042C/en not_active Expired - Lifetime
- 2002-05-03 BR BRPI0209673-0A patent/BR0209673B1/pt active IP Right Grant
- 2002-05-03 AU AU2002342563A patent/AU2002342563B2/en not_active Ceased
- 2002-05-03 ES ES02769678T patent/ES2311064T3/es not_active Expired - Lifetime
- 2002-05-03 WO PCT/US2002/014174 patent/WO2002092740A1/en not_active Application Discontinuation
- 2002-05-03 CN CNB028099990A patent/CN1272419C/zh not_active Expired - Lifetime
- 2002-05-03 IL IL15845202A patent/IL158452A0/xx active IP Right Grant
- 2002-05-03 RU RU2003136093/04A patent/RU2298582C2/ru active
- 2002-05-03 KR KR1020037014810A patent/KR100887861B1/ko active IP Right Grant
- 2002-05-03 MX MXPA03010415A patent/MXPA03010415A/es active IP Right Grant
- 2002-05-03 PL PL370692A patent/PL200946B1/pl unknown
- 2002-05-06 TW TW91109343A patent/TW573008B/zh not_active IP Right Cessation
- 2002-05-13 AR ARP020101740A patent/AR035893A1/es active IP Right Grant
- 2002-05-14 EG EG20020496A patent/EG23011A/xx active
- 2002-05-15 JP JP2002140756A patent/JP4514393B2/ja not_active Expired - Lifetime
-
2003
- 2003-10-16 IL IL158452A patent/IL158452A/en unknown
- 2003-10-27 ZA ZA200308357A patent/ZA200308357B/en unknown
- 2003-10-31 CO CO03097211A patent/CO5650174A2/es active IP Right Grant
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101553283B (zh) * | 2006-12-08 | 2013-12-11 | 荷兰联合利华有限公司 | 浓缩的表面活性剂组合物 |
CN104771346A (zh) * | 2015-03-19 | 2015-07-15 | 苏州谷力生物科技有限公司 | 一种香茅草洗手液及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US6635607B2 (en) | 2003-10-21 |
BR0209673B1 (pt) | 2013-02-05 |
IL158452A0 (en) | 2004-05-12 |
PL200946B1 (pl) | 2009-02-27 |
ATE397652T1 (de) | 2008-06-15 |
JP4514393B2 (ja) | 2010-07-28 |
KR100887861B1 (ko) | 2009-03-06 |
JP2003082386A (ja) | 2003-03-19 |
RU2298582C2 (ru) | 2007-05-10 |
EG23011A (en) | 2003-12-31 |
AR035893A1 (es) | 2004-07-21 |
EP1395644B1 (en) | 2008-06-04 |
CO5650174A2 (es) | 2006-06-30 |
IL158452A (en) | 2006-06-11 |
AU2002342563B2 (en) | 2007-01-04 |
KR20040021603A (ko) | 2004-03-10 |
ZA200308357B (en) | 2004-09-03 |
MXPA03010415A (es) | 2004-03-09 |
TW573008B (en) | 2004-01-21 |
PL370692A1 (en) | 2005-05-30 |
CA2447042A1 (en) | 2002-11-21 |
ES2311064T3 (es) | 2009-02-01 |
US20030036498A1 (en) | 2003-02-20 |
DE60226972D1 (de) | 2008-07-17 |
CN1272419C (zh) | 2006-08-30 |
RU2003136093A (ru) | 2005-05-20 |
CA2447042C (en) | 2010-09-28 |
BR0209673A (pt) | 2004-09-14 |
EP1395644A1 (en) | 2004-03-10 |
WO2002092740A1 (en) | 2002-11-21 |
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C56 | Change in the name or address of the patentee |
Owner name: CRODA USA CO., LTD. Free format text: FORMER NAME: UNIQEMA AMERICAS LLC |
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CP01 | Change in the name or title of a patent holder |
Address after: American Delaware Patentee after: Croda Americas LLC Address before: American Delaware Patentee before: CRODA UNIQEMA Inc. |
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CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20060830 |