CN1482110A - Nourishing liquid fertilizer for plant and method for preparing the same - Google Patents
Nourishing liquid fertilizer for plant and method for preparing the same Download PDFInfo
- Publication number
- CN1482110A CN1482110A CNA031354882A CN03135488A CN1482110A CN 1482110 A CN1482110 A CN 1482110A CN A031354882 A CNA031354882 A CN A031354882A CN 03135488 A CN03135488 A CN 03135488A CN 1482110 A CN1482110 A CN 1482110A
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- China
- Prior art keywords
- liquid
- acid
- sulfate
- nitric acid
- preparation
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- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 68
- 239000003337 fertilizer Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 34
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 29
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 18
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 18
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 17
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 9
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 9
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 9
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 9
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004202 carbamide Substances 0.000 claims abstract description 9
- 229910000365 copper sulfate Inorganic materials 0.000 claims abstract description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 9
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 9
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 9
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 9
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 8
- 229930006000 Sucrose Natural products 0.000 claims abstract description 8
- 239000004327 boric acid Substances 0.000 claims abstract description 8
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 6
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 6
- 239000008103 glucose Substances 0.000 claims abstract description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims description 25
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 11
- 239000011591 potassium Substances 0.000 claims description 11
- 230000020477 pH reduction Effects 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 150000002815 nickel Chemical class 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 7
- 239000005720 sucrose Substances 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 235000015097 nutrients Nutrition 0.000 claims description 4
- 230000001863 plant nutrition Effects 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- 239000003784 tall oil Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 2
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 abstract 1
- 235000010338 boric acid Nutrition 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 229960000355 copper sulfate Drugs 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 229960003390 magnesium sulfate Drugs 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- 229940099596 manganese sulfate Drugs 0.000 abstract 1
- 235000007079 manganese sulphate Nutrition 0.000 abstract 1
- 239000011702 manganese sulphate Substances 0.000 abstract 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 abstract 1
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 229940053662 nickel sulfate Drugs 0.000 abstract 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 abstract 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- 235000019794 sodium silicate Nutrition 0.000 abstract 1
- 229960004793 sucrose Drugs 0.000 abstract 1
- 239000007921 spray Substances 0.000 description 25
- 241000196324 Embryophyta Species 0.000 description 18
- 230000000050 nutritive effect Effects 0.000 description 18
- 239000011575 calcium Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 240000007594 Oryza sativa Species 0.000 description 7
- 235000007164 Oryza sativa Nutrition 0.000 description 7
- 235000016709 nutrition Nutrition 0.000 description 7
- 235000009566 rice Nutrition 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000035764 nutrition Effects 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 241000219109 Citrullus Species 0.000 description 5
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 5
- 244000061176 Nicotiana tabacum Species 0.000 description 5
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 5
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 235000008935 nutritious Nutrition 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000005649 metathesis reaction Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 208000015380 nutritional deficiency disease Diseases 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 2
- 235000002202 Biophytum sensitivum Nutrition 0.000 description 1
- 241001247986 Calotropis procera Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- 241001244920 Eucomis bicolor Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 244000126968 Kalanchoe pinnata Species 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- 235000006092 Stevia rebaudiana Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- -1 hydrogen (H +) ion Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002366 mineral element Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000037039 plant physiology Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000034655 secondary growth Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The liquid fertilizer is compounded with potassium dihydrogen phosphate, potassium nitrate, boric acid, urea, calcium nitrate, magnesium sulfate, zinc sulfate, copper sulfate, manganese sulfate, nickel sulfate, ammonium molybdate, iron trichloride or ferrous sulfate, sodium silicate or sodium metasilicate, cane sugar or glucose, nitric acid, phosphoric acid, alcohol, rosin and sulfuric acid. Applying the liquid fertilizer can avoid pollution to soil, environment and river, and its application is saving in labor. The liquid fertilizer is non-toxic, harmless and pollution-free.
Description
Technical field
The present invention relates to plant nutrient liquor body fertilizer and preparation method thereof.
Background technology
The trend of the current development of fertilizer in the world is high density, fluidization.Liquid fertilizer is a kind of typical high concentration fertilizer, and liquid fertilizer has obtained using comparatively widely abroad at present.In the U.S., liquid fertilizer accounts for more than 15% of composite fertilizer's total amount, accounts for about 30% of whole chemical fertilizer total amounts.Domestic present production at liquid fertilizer has also obtained some progress aspect developing and applying.As the Xinjiang of farm type pilot and Beijing of rural area type pilot, liquefied ammonia is directly used the extend trial project that has been listed in the Ministry of Agriculture, has obtained some achievements.Utilize domestic existing raw material resources of chemical fertilizer manufacturing enterprise and processing condition, it is multiple fertile to have developed phosphoric acid by wet process liquid, multiple fertile, the kinds such as diammonium phosphate liquid is fertile again, the multiple fertilizer of coarse whiting liquid of urea-ammonium nitrate liquid, these liquid fertilizers have all been obtained the applications well effect in use in the farmland.This shows that the Application and Development of liquid fertilizer is the tool potentiality extremely.
Liquid fertilizer is as a kind of novel fertilizer variety, have the advantages that easy to use, nontoxic, harmless, pollution-free, absorption rate is fast, strengthen crop anti-adversity, the quality that can improve crop has the effect of significant increase output, also has the ability of drought resisting, waterlogging-resistant, resistant to lodging, hot-dry wind tolerance, disease and insect resistance.From retrieving document, the existing more bibliographical information of the development of domestic relevant liquid fertilizer and application, the liquid fertilizer kind of having reported in the domestic literature in recent years is also a lot, as " peasant's board liquid fertilizer ", the Pekinese in Henan " day Feng Su " and " spray just ", the efficient liquid fertilizer of " boor " board in Shaanxi, " Tian Bao good fortune is faced liquid fertilizer " in Shandong, " spy overcharges " the high efficiency nutritious liquid fertilizer in Guangxi etc.; The prescription (CN1060946) of a kind of jarovize growth promotor for crop of Chinese patent has been reported a kind of prescription of agricultural plants liquid fertilizer, select nitrogen, phosphorus, potassium, sulphur, chlorine, boron, iron, manganese, zinc, molybdenum, copper, cobalt, calcium, 14 kinds of essences of magnesium, total content is 10～65%, and pH is 2～5.Weaker concn is 0.05～2.5%, and pH is 4～6.5, has the volume increase of accelerating the ripening, prevents the cure the disease effect of anti-evil of various nutritional deficiency diseases and weeding." prescription of watermelon microelement nutritious liquid and technology (86104121) have been reported a kind of microelement nutritious liquid (being called for short the watermelon element) that is used to produce watermelon to Chinese patent.Select 12 nutritive elements such as cobalt, potassium, boron, manganese, copper, zinc, magnesium, molybdenum, phosphorus, sulphur, nitrogen, nutrient solution concentration 5～6%, pH2.5～4.5, dilution back spraying concentration 60～100PPm, use one one-tenth about half of the plain volume increase of watermelon, pol increases, and the product qualitative change is excellent, and can use with neutral, acid agrichemical.Document " new liquid fertilizer-plant power 2003 " report is the up-to-date minimum plant element nutrition mixed type liquid fertilizer of succeeding in developing of Germany, be applicable to various farm crop, have early flowering, gather in the crops in advance, prolong harvesting time, improve output, improve effects such as quality.Document " TNF, the manure trial of Fuigrow liquid fertilizer soon greatly, " has been reported this three kinds of liquid fertilizers, they are to be the high density foliage fertilizer of main matrix with the organic active composition, be rich in the essential nutritive ingredients of plant such as nitrogen, phosphorus, potassium, various trace elements, amino acid,, form the demand of nutrition according to Different Crop and different growing by different formulated.As seen, the research of liquid fertilizer and application are one of focuses of current research.But do not see with strong acid and to contain N, P, K macroelement as solvent, trace element and rosin such as Ca, Mg, S, Fe, Zn, Cu, its liquid fertilizer stoste pH2～2.5, using pH by dilution in 1: 60 is that 5～5.5 liquid nutritional fertilizer yet there are no report.
Summary of the invention
The purpose of this invention is to provide special nutrient fluids such as a kind of edible paddy rice, be a kind of with original technology, special preparation, make crop obtain to increase production extremely significantly actual effect and colory plant nutrition liquid.
The theory of mineral nutrition of plant physiology, plant is told us: plant become to do up to ten thousand kinds, not only to the demand difference of the amount of nutritive element, and also also different to the selection of beneficial element.Why do not have a kind of product can make paddy rice etc. have tangible effect of increasing production up to now, and its quality significantly improved? major cause is that the full nutrition preparation of nutritive medium runs into the difficulty that is difficult to overcome.Nutrition preparation entirely just can not get the optimum value that crop needs.Research of the present invention was once made a large amount of field experiments to existing numerous leaf leaven, found that result of use is all undesirable, felt plant deeply in the requirement existence very big difference of each growth period to dietetic alimentation, digestion and mineral element.
Calcium (Ca) for example, China's most of soils do not lack Ca.Nutritive medium just must need Ca.Ca is the middle level that is present in cell walls with the form of tartaric acid Ca, can cultivate the ability that strengthens the insect pest of crop enantiopathy, can eliminate some from (as hydrogen, aluminium, sodium) to the Toxicity in Crops effect.Contain Ca in the nutritive medium, can directly be made for thing and absorb, " conduction ", " transportation " are fast, take effect rapidly.But,, all can in replacement(metathesis)reaction, generate novel substance, as CaSO if add inorganic Ca or organic C a in the nutritive medium
4, CaHPO
4Deng, they are materials that the utmost point is insoluble in water, spray in crop surface not decompose absorption, thereby reduce fertilizer efficiency.
The present invention just achieves a solution through doing hundred experiments, and Here it is:
(1) hydrogen (H
+) ion sealing method
Nitric acid is strong acid, and oxidisability is all stronger than any acid, under hydration, and the H of generation
+Can stop and seal Ca
2+To SO
4And HPO
4Move, again nitrate radical (NO because of in replacement(metathesis)reaction, forming
3) compound is all very easily water-soluble again, therefore, the difficult problem of the full nutritive element preparation of having deblocked.
The problem of amount is an example with calcium (Ca) still: the indispensable Ca of plant, but nutritive medium Ca too high levels, can suppress the absorption of crop again to Mg, K, P, and the dissolubility of Mn, B, Fe is reduced, make and do deposits yields nutritional deficiency disease.Therefore, determine the amount of the compound of good various nutritive elements, definite again nitric acid is made the amount of solvent, just can guarantee full nutrition preparation, is beneficial to whole absorptions of crop corresponding amount.Therefore, as solvent, be a great technological breakthrough with nitric acid.
(2) nutritive medium must have a certain amount of C element
Science and technology the older generation tell us to the exploration achievement of plant: carbon (C) element and oxygen (O) element respectively account for 45% in plant stem organization, the approach of also pointing out plant absorption element is three aspects: air, water and soil ground, and determined that effective form of plant absorbing C element is CO
2
Incendiary tree bar is sealed the certain hour that goes out and is become charcoal, extinguishes after many plant points catch fire just to become charcoal ash, breeze or the like.The C element is covered with the plant whole body, and scientific and technological circle claim that the C element is the skeleton of plant, and visible C element is very important, and nutritive medium of the present invention just contains a certain amount of C element.After spraying the cigarette strain, the cigarette strain is obviously increased, and tobacco leaf is big and plump.After being used for paddy rice, the fringe grain of paddy rice is full, defect paddy seldom.
Technical scheme of the present invention is: form (weight decigram) by following feedstock production
Potassium primary phosphate (KH
2PO
4) 0.3～15, saltpetre (KNO
3) 0.2～16, boric acid (H
3BO
3) 0.01～3, urea { CO (NH
4)
20.1～4, nitrocalcite { Ca (NO
3)
20.01～4, sal epsom (MgSO
47H
2O) 0.1～4, zinc sulfate (ZnSO
47H
2O) 0.01～4, copper sulfate (CuSO
45H
2O) 0.01～1.5, manganous sulfate (MnSO
44H
2O) 0.01～1.5, single nickel salt (NiSO
44H
2O) 0.001～0.15, ammonium molybdate { (NH
4)
6Mo
7O
244H
2O}0.01～3.5, iron trichloride or ferrous sulfate (FeCl
36H
2O FeSO
4) 0.001～1.5, water glass or Starso (Na
2SiO
39H
2O) 0.05～1.5, sucrose or glucose (C
12H
22O
11) 0.01～5, nitric acid (HNO
3) 0.01～10 (analytical pure), phosphoric acid { (H
3PO
4) (85 acid) 0.01～5, alcohol (CH
3CH
2OH) 0.01～100 (technical pure), rosin 0.001～0.1.(unit of nitric acid, phosphoric acid, alcohol is volume ml)
Be prepared according to the following steps with above-mentioned raw materials:
1) preparation of No. 1 solution: with potassium primary phosphate 0.3～15, saltpetre 0.2～16, sucrose or glucose 0.01～5 usefulness nitric acid＜3ml and phosphoric acid＜2ml carry out acidification, and temperature is 55～85 ℃, transfers pH=4～6;
2) preparation of No. 2 liquid: will be adjusted into slant acidity pH=4.5～6, the consumption＜0.5ml of sulfuric acid or nitric acid under water glass or Starso 0.05～1.5 usefulness sulfuric acid or the nitric acid normal temperature;
3) preparation of No. 3 liquid: will carry out acidification under boric acid 0.01～3, nitrocalcite 0.01～4, sal epsom 0.1～4, zinc sulfate 0.01～4, copper sulfate 0.01～1.5, manganous sulfate 0.01～1.5, single nickel salt 0.001～0.15, ammonium molybdate 0.01～3.5 usefulness nitric acid normal temperature, transfer pH=3～5, nitric acid dosage＜1ml:
4) preparation method of No. 4 liquid: earlier rosin 0.01～0.1 is dissolved to liquid state, uses nitric acid＜3ml and phosphoric acid＜1ml that iron trichloride or ferrous sulfate 0.001～1.5 and liquid rosin are carried out acidification, pH=3.5～5.5 again with alcohol＜100ml;
5) preparation of No. 5 liquid: 0.1～4 usefulness phosphoric acid＜0.5ml handles to slant acidity with urea, pH=4～5.5;
6) No. 1 liquid and No. 2 liquid mixing backs is standby;
7) No. 3 liquid, No. 4 liquid and No. 5 liquid mixing backs are standby;
8) with 6) and 7) reserve liquid add nitric acid＜4ml and mix, filter then, adjust pH=5～7, last machine seals, vanning is put in storage.
Using method: 1, foliage-spray: every bag of (or every bottle) 250ml converts 15 kilograms in water (1: 60); Based on blade back, the leaf pros and cons all sprays, and regards thing particular case spray 2～3 times as.2, replace base manure to irritate root: every bag of (or every bottle) 250ml converts 30～60 kilograms in water; Down irritate from the plant top tip part, regard thing particular case pouring 2～10 times as.
The present invention has following positively effect compared with the prior art:
Nutritive medium of the present invention not only can spray the blade face but also can replace fertilising, irritate root, and crop " two " is benefited, and benefit is extremely many.Be used at present obtaining effect preferably on five kinds of crops such as paddy rice, wheat, corn, flue-cured tobacco, tealeaves.Also can be used for plants such as potato, sugarcane, fruit tree, vegetables, flowers.Two important feature of the present invention are: 1, nutritive medium can replace base manure, and makes one's way in life on some crop; 2, solve period of seedling establishment (crop is transplanted just can be survived), many crops all have a period of seedling establishment (promptly spending one period just can survive) after transplanting, and the period of seedling establishment of the plant that has reaches the several months.Solve period of seedling establishment and be raise the efficiency, the important behave of environmental benefit and commodity benefit, have very high practical value.Using of nutritive liq fertilizer of the present invention, the pollution that can greatly avoid various inorganic fertilizers, fertilizer that soil, environment, rivers are caused, and amount of application is few, the saving of labor, save time, laborsaving, economical and practical again, nontoxic, harmless, pollution-free.
It below is the experiment situation that nutritive medium of the present invention is used for some farm crop.
Table 1 is part farm crop experiment demonstration effect
| Part farm crop experiment demonstration effect | ||||
| The crop title | Spray date and number of times | Extension rate | Spray the time | Effect of increasing production (%) remarks |
| Rice and wheat | Sprayed once in 5-7 days before the packing, the neat phase spray once grouting phase spray of fringe once | Every bag is converted water 15kg=1: 60 | Early after 3 of 10 preceding noons | 20-35 is best in quality, flavor is good |
| Tobacco leaf | Transplant spray in 25-30 days and once transplant spray in 40-45 days once | The same | The same | 15-30 falls yellow good, good roasting, and first-class cigarette increases income 10% |
| The tealeaves mulberry leaf | The whole growth phase stops repeating again in 2 months after spray 3 times to spray every spray in 15 days 1 time | The same | The same | 30-70 |
| Most plants are used before and after transplanting | The seedling phase transplants spray in preceding 2 days, irritates each 1 time, after normal root water is watered in transplanting, spray, irritate each once, continuous 3 times.Blue or green, prime of life plant usage is the same | 1: 180 1: 120 | The same | Transplant the back and just can survive no period of seedling establishment.Can consumption to make root moistening for well. |
| Flowers | Respectively 1 bud phase spray of flower spray in earlier stage, filling, each 1 full-bloom stage filling root of filling 1 time | 1: 180 1: 120 1: 120 | The same | Advance flowering period is bright in luster |
| The watermelon pineapple | Flower sprays 1 fruit expanding period spray of 1 young fruit period spray 1 time in earlier stage | 1: 60 every bag convert water 15kg | The same | Fruit is big, fruit is sweet |
| Leaf vegetables | Spray in seedling stage, each 1 secondary growth of filling sprayed totally 2 times 1 time every 10 days mid-term | 1: 120 1: 60 | The same | Look loose, flavor delicate fragrance is sweet tender |
Table 2 is for being applied to the effect relatively (in Different Altitude, different region, different soil fertility, under the different weather condition, under equal tillage condition, use with not using nutritive medium of the present invention and compare, poor is divided obvious) behind the paddy rice
Now calculate more than 20% with every mu of volume increase of 2.1 yuan/kg of national annual grain price:
| Do not spray | After spraying | Increase both production and value | |||
| Average yield per mu | The per mu yield value | Average yield per mu | The per mu yield value | Volume increase | Volume increase |
| ??(kg) | Unit | ??(kg) | Unit | ??(kg) | Unit |
| ??450 | ??945 | ??540 | ????1134 | ??90 | ????189 |
Table 3 for be applied to behind the tobacco leaf effect relatively
Tobacco leaf is in kind K326: 10 yuan/kg of flat fare
| Do not spray | After spraying | Increase both production and value | |||
| Per mu yield (kg) | The output value (unit) | Per mu yield (kg) | The output value (unit) | Per mu yield (kg) | The output value (unit) |
| ??130 | ??1300 | ??156 | ??1560 | ??26 | ??260 |
Nutritive medium of the present invention is demonstrated altogether ground vegetables such as Haikou, Dali and is promoted 19 mu, and amount of increase in production is about 15%.Demonstration is promoted 16 mu on wheat, volume increase about 15%.In addition, on flowers, tealeaves, use, also all obtained positive effect.
Embodiment
Embodiment 1:
Choose following raw materials according and weighing (gram)
Potassium primary phosphate 0.3, saltpetre 0.2, boric acid 0.01, urea 0.1, nitrocalcite 0.1, sal epsom 0.1, zinc sulfate 0.01, copper sulfate 0.01, manganous sulfate 0.01, single nickel salt 0.001, ammonium molybdate 0.01, iron trichloride 0.001, water glass 0.05, sucrose 0.01, nitric acid 1ml (analytical pure), phosphoric acid (85 acid) 1ml, alcohol 0.1ml (technical pure), rosin 0.001, sulfuric acid 0.1ml.
Be prepared according to the following steps with above-mentioned raw materials:
1) preparation of No. 1 solution: potassium primary phosphate, saltpetre, sucrose are carried out acidification with nitric acid 0.01ml and phosphoric acid 0.01ml, and temperature is 55～85 ℃, transfers pH=4～5.5;
2) preparation of No. 2 liquid: with being adjusted into slant acidity pH=4.5～6 under the sulfuric acid normal temperature, the vitriolic consumption is 0.1ml with water glass;
3) preparation of No. 3 liquid: boric acid, nitrocalcite, sal epsom, zinc sulfate, copper sulfate, manganous sulfate, single nickel salt, ammonium molybdate with carrying out acidification under the nitric acid normal temperature, are transferred pH=2～4, and nitric acid dosage is 0.1ml;
4) preparation method of No. 4 liquid: with alcohol 0.1ml rosin is dissolved to liquid state earlier, iron trichloride and liquid rosin is carried out acidification, pH=4～5.5 with nitric acid 0.03ml and phosphoric acid 0.01ml again;
5) preparation of No. 5 liquid: urea is handled to slant acidity pH=4～5.5 with phosphoric acid 0.1ml;
6) No. 1 liquid and No. 2 liquid mixing backs is standby;
7) No. 3 liquid, No. 4 liquid and No. 5 liquid mixing backs are standby;
8) with 6) and 7) reserve liquid add nitric acid 0.1ml and mix, filter then, adjust pH=5～7, last machine seals, vanning is put in storage.
Embodiment 2:
Choose following raw materials according and weighing (gram) (choosing intermediate value)
Potassium primary phosphate 1.4, saltpetre 1, boric acid 0.01, urea 2, nitrocalcite 0.02, sal epsom 0.5, zinc sulfate 0.5, copper sulfate 0.1, manganous sulfate 0.01, single nickel salt 0.001, ammonium molybdate 0.05, iron trichloride 0.05, water glass 0.15, sucrose 0.1, nitric acid 0.15ml (analytical pure), phosphoric acid (85 acid) 0.33ml, alcohol 0.01ml (technical pure), rosin 0.001, sulfuric acid 0.001ml.
Press the method preparation of embodiment 1.
Embodiment 3:
Choose following raw materials according and weighing (gram)
Potassium primary phosphate 15, saltpetre 16, boric acid 3, urea 4, nitrocalcite 4, sal epsom 4, zinc sulfate 4, copper sulfate 1.5, manganous sulfate 1.5, single nickel salt 0.15, ammonium molybdate 0.01～3.5, ferrous sulfate 1.5, Starso 1.5, glucose 5, nitric acid 10ml (analytical pure), phosphoric acid (85 acid) 5ml, alcohol 100ml (technical pure), rosin 0.1.
Press the method preparation of embodiment 1.
Claims (2)
1, a plant nutrient liquor body fertilizer is characterized in that this liquid fertilizer is to be prepared from by following materials of weight proportions:
Potassium primary phosphate 0.3～15, saltpetre 0.2～16, boric acid 0.01～3, urea 0.1～4, nitrocalcite 0.01～4, sal epsom 0.1～4, zinc sulfate 0.01～4, copper sulfate 0.01～1.5, manganous sulfate 0.01～1.5, single nickel salt 0.001～0.15, ammonium molybdate 0.001～3.5, iron trichloride or ferrous sulfate 0.001～1.5, water glass or Starso 0.05～1.5, sucrose or glucose 0.01～5, nitric acid 0.01～10, phosphoric acid 0.01～5, alcohol 0.01～100, rosin 0.001～0.1, sulfuric acid 0.001～0.005.
2, the preparation method of the described plant nutrition liquid of claim 1 fertilizer is characterized in that carrying out according to the following steps:
1) preparation of No. 1 solution: with potassium primary phosphate 0.3～15, saltpetre 0.2～16, sucrose or glucose 0.01～5 usefulness nitric acid＜3ml and phosphoric acid＜2ml carry out acidification, and temperature is 55～85 ℃, transfers pH=4～6;
2) preparation of No. 2 liquid: will be adjusted into slant acidity pH=4.5～6, the consumption＜0.5ml of sulfuric acid or nitric acid under water glass or Starso 0.05～1.5 usefulness sulfuric acid or the nitric acid normal temperature;
3) preparation of No. 3 liquid: will carry out acidification under boric acid 0.01～3, nitrocalcite 0.01～4, sal epsom 0.1～4, zinc sulfate 0.01～4, copper sulfate 0.01～1.5, manganous sulfate 0.01～1.5, single nickel salt 0.001～0.15, ammonium molybdate 0.01～3.5 usefulness nitric acid normal temperature, transfer pH=2～4, nitric acid dosage＜1ml:
4) preparation method of No. 4 liquid: earlier rosin 0.01～0.1 is dissolved to liquid state, uses nitric acid＜3ml and phosphoric acid＜1ml that iron trichloride or ferrous sulfate 0.001～1.5 and liquid rosin are carried out acidification, pH=3.5～5.5 again with alcohol＜100ml;
5) preparation of No. 5 liquid: 0.1～4 usefulness phosphoric acid＜0.5ml handles to slant acidity with urea, pH=4～5.5;
6) No. 1 liquid and No. 2 liquid mixing backs is standby;
7) No. 3 liquid, No. 4 liquid and No. 5 liquid mixing backs are standby;
8) with 6) and 7) reserve liquid add nitric acid＜4ml and mix, filter then, adjust pH=5～7, last machine seals, vanning is put in storage.
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|---|---|---|---|
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