CN1469851A - 氢化未取代或烷基取代的芳族化合物的方法 - Google Patents
氢化未取代或烷基取代的芳族化合物的方法 Download PDFInfo
- Publication number
- CN1469851A CN1469851A CNA018171745A CN01817174A CN1469851A CN 1469851 A CN1469851 A CN 1469851A CN A018171745 A CNA018171745 A CN A018171745A CN 01817174 A CN01817174 A CN 01817174A CN 1469851 A CN1469851 A CN 1469851A
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- support
- catalyst
- hydrogenation
- active metal
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
- C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/02—Reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/18—Carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10050709A DE10050709A1 (de) | 2000-10-13 | 2000-10-13 | Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Katalysators mit einem strukturierten oder monolithischen Träger |
| DE10050709.3 | 2000-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1469851A true CN1469851A (zh) | 2004-01-21 |
Family
ID=7659630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA018171745A Pending CN1469851A (zh) | 2000-10-13 | 2001-10-09 | 氢化未取代或烷基取代的芳族化合物的方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20040024274A1 (enExample) |
| EP (1) | EP1330422A2 (enExample) |
| JP (1) | JP2004529068A (enExample) |
| KR (1) | KR20030040533A (enExample) |
| CN (1) | CN1469851A (enExample) |
| AU (2) | AU2002218222A8 (enExample) |
| DE (1) | DE10050709A1 (enExample) |
| IN (1) | IN2003CH00534A (enExample) |
| MX (1) | MXPA03002847A (enExample) |
| PL (1) | PL366054A1 (enExample) |
| RU (1) | RU2003113962A (enExample) |
| WO (1) | WO2002030851A2 (enExample) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106178579A (zh) * | 2016-09-08 | 2016-12-07 | 南京大学 | 尾气处理装置和工艺以及环己烷生产装置 |
| CN109647450A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 用于合成环己胺的加氢催化剂 |
| CN109651169A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 制备环己胺的方法 |
| CN109647456A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 合成环己胺的加氢催化剂 |
| CN109647451A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 用于制备环己胺的加氢催化剂 |
| CN109647455A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺生产环己胺的加氢催化剂 |
| CN109651172A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺加氢制备环己胺的方法 |
| CN109647454A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺制备环己胺的加氢催化剂 |
| CN109651166A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺制备环己胺的方法 |
| CN109647453A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 生产环己胺的加氢催化剂 |
| CN109651165A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺加氢生产环己胺的方法 |
| CN109647452A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 制备环己胺的加氢催化剂 |
| CN109651168A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 合成环己胺的方法 |
| CN111889097A (zh) * | 2020-07-28 | 2020-11-06 | 万华化学集团股份有限公司 | 一种苯胺加氢催化剂、制备方法及应用 |
| CN112004589A (zh) * | 2018-04-20 | 2020-11-27 | 西门子股份公司 | 用于运行反应器设施的方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10128242A1 (de) | 2001-06-11 | 2002-12-12 | Basf Ag | Verfahren zur Hydrierung organischer Verbindungen |
| US6998507B1 (en) | 2004-08-24 | 2006-02-14 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline |
| JP2006130375A (ja) * | 2004-11-02 | 2006-05-25 | Bridgestone Corp | 水素貯蔵及び発生用触媒構造体並びにそれを用いた水素の貯蔵及び発生方法 |
| DE102005001290A1 (de) * | 2005-01-11 | 2006-07-20 | Basf Ag | Vorrichtung und Verfahren zur Entfernung von Kohlenmonoxid aus einem wasserstoffhaltigen Gasstrom |
| RU2414300C1 (ru) * | 2009-08-04 | 2011-03-20 | Инфра Текнолоджиз Лтд. | Носитель для катализатора экзотермических процессов и катализатор на его основе |
| US20150181945A1 (en) | 2013-12-31 | 2015-07-02 | Martin Tremblay | Electronic vaping device |
| JP6306370B2 (ja) * | 2014-02-25 | 2018-04-04 | 千代田化工建設株式会社 | 芳香族化合物の水素化システムおよび水素化方法 |
| EP3515595A1 (de) * | 2016-09-23 | 2019-07-31 | Basf Se | Verfahren zur bereitstellung eines katalytisch aktiven festbetts für die hydrierung organischer verbindungen |
| WO2020176944A1 (en) * | 2019-03-05 | 2020-09-10 | Commonwealth Scientific And Industrial Research Organisation | Ruthenium promoter catalyst compositions |
| KR102475191B1 (ko) * | 2020-12-09 | 2022-12-06 | 희성촉매 주식회사 | 루테늄 복합체가 포함되는 NOx 저장 및 환원 촉매 물품 제조방법 및 이를 포함하는 배기처리 시스템 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1419557A (fr) * | 1961-09-13 | 1965-12-03 | Inst Francais Du Petrole | Nouveau procédé d'hydrogénation catalytique des hydrocarbures aromatiques |
| US3244644A (en) * | 1962-02-13 | 1966-04-05 | Du Pont | Method of preparing a catalyst composition consisting of ruthenium on etaalumina and the product thereof |
| FR1592093A (enExample) * | 1968-02-29 | 1970-05-11 | ||
| US3917540A (en) * | 1970-04-22 | 1975-11-04 | Universal Oil Prod Co | Catalyst for hydrogenation and dehydrogenation of hydrocarbons |
| GB1603101A (en) * | 1977-03-28 | 1981-11-18 | Johnson Matthey Co Ltd | Catalytic methanation of synthesis gas |
| EP0053884A1 (en) * | 1980-11-27 | 1982-06-16 | Johnson Matthey Public Limited Company | Three dimensional interstitial catalyst supports, its manufacture and use |
| DE3513726A1 (de) * | 1985-04-17 | 1986-10-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von katalysatoren fuer die abgasentgiftung |
| US5326253A (en) * | 1990-11-26 | 1994-07-05 | Catalytica, Inc. | Partial combustion process and a catalyst structure for use in the process |
| DE4209631A1 (de) * | 1992-03-25 | 1993-09-30 | Basf Ag | Monolithischer Trägerkatalysator, Verfahren zu seiner Herstellung und seine Verwendung |
| FR2716190B1 (fr) * | 1994-02-17 | 1996-04-12 | Inst Francais Du Petrole | Catalyseur d'hydrogénation et procédé d'hydrogénation du benzène utilisant ledit catalyseur. |
| DE59706719D1 (de) * | 1996-04-26 | 2002-05-02 | Basf Ag | Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines in situ gebildeten Ruthenium-katalysators |
| JP3977883B2 (ja) * | 1996-10-03 | 2007-09-19 | 株式会社日立製作所 | 内燃機関用排ガス浄化触媒 |
| DE19714536A1 (de) * | 1997-04-09 | 1998-10-15 | Degussa | Autoabgaskatalysator |
| FR2771309B1 (fr) * | 1997-11-24 | 2000-02-11 | Messier Bugatti | Elaboration de support de catalyseur en fibres de carbone active |
| DE19827385A1 (de) * | 1998-06-19 | 1999-12-23 | Basf Ag | Tränkverfahren zur Aufbringung von Aktivmasse auf strukturierte Träger oder Monolithe |
-
2000
- 2000-10-13 DE DE10050709A patent/DE10050709A1/de not_active Withdrawn
-
2001
- 2001-10-09 WO PCT/EP2001/011649 patent/WO2002030851A2/de not_active Ceased
- 2001-10-09 CN CNA018171745A patent/CN1469851A/zh active Pending
- 2001-10-09 KR KR20037005111A patent/KR20030040533A/ko not_active Withdrawn
- 2001-10-09 PL PL01366054A patent/PL366054A1/xx not_active Application Discontinuation
- 2001-10-09 MX MXPA03002847A patent/MXPA03002847A/es unknown
- 2001-10-09 EP EP01986667A patent/EP1330422A2/de not_active Withdrawn
- 2001-10-09 AU AU2002218222A patent/AU2002218222A8/en not_active Withdrawn
- 2001-10-09 JP JP2002534241A patent/JP2004529068A/ja not_active Withdrawn
- 2001-10-09 AU AU2002218222A patent/AU2002218222A1/en not_active Abandoned
- 2001-10-09 RU RU2003113962/04A patent/RU2003113962A/ru not_active Application Discontinuation
- 2001-10-09 US US10/398,177 patent/US20040024274A1/en not_active Abandoned
-
2003
- 2003-04-11 IN IN534CH2003 patent/IN2003CH00534A/en unknown
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106178579A (zh) * | 2016-09-08 | 2016-12-07 | 南京大学 | 尾气处理装置和工艺以及环己烷生产装置 |
| CN106178579B (zh) * | 2016-09-08 | 2019-01-15 | 南京大学 | 尾气处理装置和工艺以及环己烷生产装置 |
| CN109647452A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 制备环己胺的加氢催化剂 |
| CN109647454B (zh) * | 2017-10-10 | 2022-02-01 | 中国石油化工股份有限公司 | 苯胺制备环己胺的加氢催化剂 |
| CN109647456A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 合成环己胺的加氢催化剂 |
| CN109647451A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 用于制备环己胺的加氢催化剂 |
| CN109647455A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺生产环己胺的加氢催化剂 |
| CN109651172A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺加氢制备环己胺的方法 |
| CN109647454A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺制备环己胺的加氢催化剂 |
| CN109651166A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺制备环己胺的方法 |
| CN109647453A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 生产环己胺的加氢催化剂 |
| CN109651165A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 苯胺加氢生产环己胺的方法 |
| CN109647450A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 用于合成环己胺的加氢催化剂 |
| CN109651168A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 合成环己胺的方法 |
| CN109651169A (zh) * | 2017-10-10 | 2019-04-19 | 中国石油化工股份有限公司 | 制备环己胺的方法 |
| CN109651172B (zh) * | 2017-10-10 | 2021-11-30 | 中国石油化工股份有限公司 | 苯胺加氢制备环己胺的方法 |
| CN109647455B (zh) * | 2017-10-10 | 2022-04-05 | 中国石油化工股份有限公司 | 苯胺生产环己胺的加氢催化剂 |
| CN109647456B (zh) * | 2017-10-10 | 2021-11-30 | 中国石油化工股份有限公司 | 合成环己胺的加氢催化剂 |
| CN109651166B (zh) * | 2017-10-10 | 2021-11-30 | 中国石油化工股份有限公司 | 苯胺制备环己胺的方法 |
| CN109651169B (zh) * | 2017-10-10 | 2021-11-30 | 中国石油化工股份有限公司 | 制备环己胺的方法 |
| CN109651168B (zh) * | 2017-10-10 | 2021-11-30 | 中国石油化工股份有限公司 | 合成环己胺的方法 |
| CN109647451B (zh) * | 2017-10-10 | 2021-12-28 | 中国石油化工股份有限公司 | 用于制备环己胺的加氢催化剂 |
| CN109647453B (zh) * | 2017-10-10 | 2022-02-01 | 中国石油化工股份有限公司 | 生产环己胺的加氢催化剂 |
| CN109651165B (zh) * | 2017-10-10 | 2022-04-05 | 中国石油化工股份有限公司 | 苯胺加氢生产环己胺的方法 |
| CN112004589A (zh) * | 2018-04-20 | 2020-11-27 | 西门子股份公司 | 用于运行反应器设施的方法 |
| CN111889097A (zh) * | 2020-07-28 | 2020-11-06 | 万华化学集团股份有限公司 | 一种苯胺加氢催化剂、制备方法及应用 |
| CN111889097B (zh) * | 2020-07-28 | 2022-07-12 | 万华化学集团股份有限公司 | 一种苯胺加氢催化剂、制备方法及应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03002847A (es) | 2003-06-19 |
| AU2002218222A1 (en) | 2002-04-22 |
| IN2003CH00534A (enExample) | 2005-04-15 |
| DE10050709A1 (de) | 2002-04-25 |
| EP1330422A2 (de) | 2003-07-30 |
| PL366054A1 (en) | 2005-01-24 |
| WO2002030851A3 (de) | 2002-10-31 |
| AU2002218222A8 (en) | 2005-09-15 |
| WO2002030851A2 (de) | 2002-04-18 |
| US20040024274A1 (en) | 2004-02-05 |
| RU2003113962A (ru) | 2004-11-27 |
| KR20030040533A (ko) | 2003-05-22 |
| JP2004529068A (ja) | 2004-09-24 |
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