CN1397661A - Sputtering target for high resistance transparent conductive membrane and mfg. method of high resistance transparent conductive membrane - Google Patents

Sputtering target for high resistance transparent conductive membrane and mfg. method of high resistance transparent conductive membrane Download PDF

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Publication number
CN1397661A
CN1397661A CN02124433A CN02124433A CN1397661A CN 1397661 A CN1397661 A CN 1397661A CN 02124433 A CN02124433 A CN 02124433A CN 02124433 A CN02124433 A CN 02124433A CN 1397661 A CN1397661 A CN 1397661A
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oxide
high resistance
nesa coating
sputtering target
mole
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CN1320155C (en
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高桥诚一郎
池田真
渡边弘
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Mitsui Mining and Smelting Co Ltd
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Mitsui Mining and Smelting Co Ltd
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    • A—HUMAN NECESSITIES
    • A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22C—PROCESSING MEAT, POULTRY, OR FISH
    • A22C29/00—Processing shellfish or bivalves, e.g. oysters, lobsters; Devices therefor, e.g. claw locks, claw crushers, grading devices; Processing lines
    • A22C29/02—Processing shrimps, lobsters or the like ; Methods or machines for the shelling of shellfish
    • A22C29/021—Cleaning operations on shellfish, e.g. evisceration, brushing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/02—Cleaning by the force of jets or sprays
    • A—HUMAN NECESSITIES
    • A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22C—PROCESSING MEAT, POULTRY, OR FISH
    • A22C29/00—Processing shellfish or bivalves, e.g. oysters, lobsters; Devices therefor, e.g. claw locks, claw crushers, grading devices; Processing lines
    • A22C29/04—Processing bivalves, e.g. oysters
    • A22C29/043—Cleaning operations on bivalves, e.g. evisceration, brushing, separation of meat and shell material
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/40—Shell-fish

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  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
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  • Food Science & Technology (AREA)
  • Physical Vapour Deposition (AREA)
  • Manufacturing Of Electric Cables (AREA)

Abstract

The present invention provided a sputtering target for a highly resistant transparent conductive film which can be basically used by a DC magnetron sputtering apparatus, and deposit a transparent and highly resistant film, and to provide a manufacturing method of the highly resistant transparent conductive film using the target. The indium oxide sputtering gate for the highly resistant transparent conductive film to deposit the highly resistant transparent conductive film with the resistivity of about 0.8-10 times 10<-3> Omega cm contains indium oxide and tin oxide as necessary, and also contains an insulating oxide.

Description

The high resistance nesa coating is with the manufacture method of sputtering target and high resistance nesa coating
Technical field
The present invention relates to be about 0.8～10 * 10 in making resistivity -3Employed high resistance nesa coating is with sputtering target (Sputtering targot) and use its to make the manufacture method of the high resistance nesa coating of high resistance nesa coating during the high resistance conductive film of Ω cm.
Background technology
Because Indium sesquioxide-stannic oxide (In 2O 3-SnO 2Composite oxides, hereinafter referred to as ' ITO ') the visible light permeability height of film, and electroconductibility height is so prevent that as what nesa coating was widely used in liquid crystal indicator, glass frosting is with heating film and infrared reflection film etc.
For example, with regard to employed nesa coating in the flat pannel display (FPD), (resistivity is about 2 * 10 to select low resistance -4Ω cm) nesa coating.
On the other hand, on principle, be installed in that such FPD etc. goes up and the resistance-type button control panel nesa coating that uses, as requiring characteristic, the high-resistance nesa coating of needs.Yet there are the following problems at present: if use the ITO that is used to FPD, must be extremely thin film, can not guarantee the intensity of button control panel like this.
In addition,, just can not use, have the bigger problem of facility investment than the low-cost DC magnetic controlled tube sputtering apparatus of high frequency magnetron if the resistance of sputtering target self is become high resistance.
Summary of the invention
In view of such situation, the object of the present invention is to provide the manufacture method of a kind of high resistance nesa coating with sputtering target and high resistance nesa coating, can use the DC magnetic controlled tube sputtering apparatus basically, can be made into transparent and high-resistance film.
In order to achieve the above object, the 1st mode of the present invention is high resistance nesa coating sputtering target, is to be used to form resistivity to be about 0.8～10 * 10 -3The high resistance nesa coating Indium sesquioxide base sputtering target of the high resistance conductive film of Ω cm is characterized in that, contains Indium sesquioxide and stannic oxide as required, and contains the insulativity oxide compound.
In the 1st mode,, can not make the resistivity of target self produce big variation, and improve the resistivity of formed nesa coating by in the Indium sesquioxide base sputtering target, adding the insulativity oxide compound.
The 2nd mode of the present invention is high resistance nesa coating sputtering target, it is characterized in that, in the 1st mode, described insulativity oxide compound is be selected from silicon oxide, aluminum oxide, tantalum oxide, hafnia, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, Scium trioxide, titanium oxide, zirconium white, vanadium oxide, boron oxide, gallium oxide, zinc oxide, chromic oxide, manganese oxide, ferric oxide, molybdenum oxide, phosphorus oxide and oxidation lanthanide at least a.
In the 2nd mode,, can not make the resistivity of target self produce big variation, and improve the resistivity of formed nesa coating by adding silicon oxide, aluminum oxide, tantalum oxide, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide etc.
The 3rd mode of the present invention is high resistance nesa coating sputtering target, it is characterized in that, in the 2nd mode, described insulativity oxide compound is a silicon oxide.
In the 3rd mode,, can not make the resistivity of target self produce big variation, and improve the resistivity of formed nesa coating by adding silicon oxide.
The 4th mode of the present invention is high resistance nesa coating sputtering target, it is characterized in that, in arbitrary mode of the 1st～3, with respect to 1 mole of indium, the element that constitutes described insulativity oxide compound is 0.00001～0.26 mole.
In the 4th mode,, can not make the resistivity of target self produce big variation, and improve the resistivity of formed nesa coating by adding the insulativity oxide compound of specified rate.
The 5th mode of the present invention is high resistance nesa coating sputtering target, it is characterized in that, in arbitrary mode of the 1st～4, with respect to 1 mole of indium, contains 0～0.3 mole of tin (Sn).
In the 5th mode, become the sputtering target that contains stannic oxide based on Indium sesquioxide, as required.
The 6th mode of the present invention is high resistance nesa coating sputtering target, it is characterized in that, in arbitrary mode of the 1st～5, can form resistivity by the DC magnetron sputtering is 0.8～10 * 10 -3The nesa coating of Ω cm.
In the 6th mode, can be made into high-resistance nesa coating by the DC magnetron sputtering.
The 7th mode of the present invention is the manufacture method of high resistance nesa coating, it is characterized in that, use contains the Indium sesquioxide base sputtering target that Indium sesquioxide reaches stannic oxide as required and contains the insulativity oxide compound, and forming resistivity by the DC magnetron sputtering is 0.8～10 * 10 -3The nesa coating of Ω cm.
In the 7th mode, by using the Indium sesquioxide base sputtering target that has been added with the insulativity oxide compound, can not make the resistivity of target self produce big variation, be 0.8～10 * 10 and form resistivity by the DC magnetron sputtering -3The nesa coating of Ω cm.
The 8th mode of the present invention is the manufacture method of high resistance nesa coating, it is characterized in that, in the 7th mode, described insulativity oxide compound is be selected from silicon oxide, aluminum oxide, tantalum oxide, hafnia, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, Scium trioxide, titanium oxide, zirconium white, vanadium oxide, boron oxide, gallium oxide, zinc oxide, chromic oxide, manganese oxide, ferric oxide, molybdenum oxide, phosphorus oxide and oxidation lanthanide at least a.
In the 8th mode, by using the Indium sesquioxide base sputtering target that has been added with silicon oxide, aluminum oxide, tantalum oxide, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide etc., can not make the resistivity of target self produce big variation, be 0.8～10 * 10 and form resistivity by the DC magnetron sputtering -3The nesa coating of Ω cm.
The 9th mode of the present invention is the manufacture method of high resistance nesa coating, it is characterized in that, in the 8th mode, described insulativity oxide compound is a silicon oxide.
In the 9th mode, by using the Indium sesquioxide base sputtering target that has been added with silicon oxide, can not make the resistivity of target self produce big variation, be 0.8～10 * 10 and form resistivity by the DC magnetron sputtering -3The nesa coating of Ω cm.
The 10th mode of the present invention is the manufacture method of high resistance nesa coating, it is characterized in that, in arbitrary mode of the 7th～9, with respect to 1 mole of indium, the element that constitutes described insulativity oxide compound is 0.00001～0.26 mole.
In the 10th mode, by using the Indium sesquioxide base sputtering target of the insulativity oxide compound that has added specified rate, can not make the resistivity of target self produce big variation, be 0.8～10 * 10 and form resistivity by the DC magnetron sputtering -3The nesa coating of Ω cm.
The 11st mode of the present invention is the manufacture method of high resistance nesa coating, it is characterized in that, in arbitrary mode of the 7th～10, with respect to 1 mole of indium, contains 0～0.3 mole of tin (Sn).
In the 11st mode, can use with Indium sesquioxide as main body, contain the sputtering target of stannic oxide as required, forming resistivity by the DC magnetron sputtering is 0.8～10 * 10 -3The nesa coating of Ω cm.
High resistance nesa coating sputtering target of the present invention is based on Indium sesquioxide, contains stannic oxide and contain the oxidate sintered body of insulativity oxide compound as required, each oxide compound can exist with the original form of oxide compound or composite oxides form or sosoloid form, is not particularly limited.
At this, with regard to the insulativity oxide compound, can list silicon oxide, aluminum oxide, tantalum oxide, hafnia, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, Scium trioxide, titanium oxide, zirconium white, vanadium oxide, boron oxide, gallium oxide, zinc oxide, chromic oxide, manganese oxide, ferric oxide, molybdenum oxide, phosphorus oxide and oxidation lanthanide etc.
With regard to the insulativity oxide compound, preferably generate the energy insulativity oxide compound lower than Indium sesquioxide 0～1600 ℃ of scope internal standard.This is that chemical is more stable because compare with Indium sesquioxide, is difficult to decompose.
The amount of preferred insulativity oxide compound is in the following scope: with respect to 1 mole of indium, the element that constitutes this insulativity oxide compound is 0.00001～0.26 mole.Reason is, if lack than this scope, then the effect of Tian Jiaing is not remarkable, and, as if more than this scope, the too high in resistance of formed nesa coating then.
And tin (Sn) is 0～0.3 mole with respect to 1 mole of indium.Containing under the situation of tin, with respect to 1 mole of indium, the content of tin is 0.001～0.3 mole scope, is preferably 0.01～0.15 mole scope, more preferably 0.05～0.1 mole scope.If be in this scope, just can suitably control the density and the degree of excursion of the carrier electrons of sputtering target, guarantee that electroconductibility is in the good scope.And, add if exceed this scope, the degree of excursion of the carrier electrons of sputtering target is reduced, and electroconductibility is developed to the direction of deterioration, so inadvisable.
High resistance nesa coating of the present invention has the resistance value that can be carried out the degree of sputter by the DC magnetron sputtering with sputtering target, and can form resistivity is 0.8～10 * 10 -3The nesa coating of Ω cm.
Certainly, using the high frequency magnetic controlled tube sputtering apparatus also can form resistivity is 0.8～10 * 10 -3The nesa coating of Ω cm.
Below, the manufacture method of sputtering target of the present invention is described, this only is an example, manufacture method is not limited to this.
At first, constituting the initial feed of sputtering target of the present invention, generally is In 2O 3, SnO 2, SiO 2Powder.And, can be raw material also with these simple substance, compound, composite oxides etc.When using simple substance, compound, need in advance through becoming the operation of oxide compound.
For with desired fit rate with these raw material powder mix, the method for moulding do not do special qualification, can use existing known various damp process or drying process.
With regard to drying process, can list (Cold Press) method of colding pressing or hot pressing (Hot Press) method etc.In cold press process, powder mix is filled in the pressing mold, be made into formed body, fire under the atmospheric atmosphere gas or under the oxygen atmosphere gas, sintering.In pressure sintering, powder mix directly placed carry out sintering in the pressing mold.
With regard to damp process, for example, preferably use filtering shaping method (opening flat 11-286002 communique) with reference to the spy.This filtering type method of forming is, use is reduced pressure from the ceramic raw material slurry and is discharged moisture and obtain the filtering type pressing mold that is made of non-water soluble material of formed body, and the slurry formed by powder mix, ion exchanged water and organic additive of modulation, this slurry is injected the filtering type pressing mold, only discharge the moisture the slurry and make formed body from this side decompression of strainer, behind resulting ceramic molding drying defatted, fire.Above-mentioned filtering type pressing mold, be by have more than 1 the moulding that removes the water hole with counterdie, be disposed at this moulding and constitute with the strainer on the counterdie and the forming mould plate of seizing on both sides by the arms from above by the sealing member that is used to seal this strainer with water flowing, can assemble above-mentioned moulding counterdie, forming mould plate, sealing member and strainer respectively, only the moisture from this side decompression discharge slurry of this strainer with dismantling.
In the whole bag of tricks, firing temperature is preferably 1300～1600 ℃, more preferably 1300～1450 ℃.Then, implement to be used to process, be shaped to the mechanical workout of intended size, make target.
Description of drawings
Fig. 1 is the figure that concerns between the transmitance at the resistivity of oxygen partial pressure and wavelength 550nm of expression embodiment 1.
Fig. 2 is the figure that concerns between the transmitance at the resistivity of oxygen partial pressure and wavelength 550nm of expression comparative example 1.
Fig. 3 is the figure that concerns between the transmitance at the resistivity of oxygen partial pressure and wavelength 550nm of expression embodiment 2.
Embodiment
Below, by embodiment the present invention is described, but is not limited to this.
(embodiment 1)
Prepare the In of purity＞99.99% 2O 3Powder and SnO 2The SiO of powder and purity＞99.9% 2Powder.According to SnO 2Be 10wt%, SiO 2Be 5wt%, In 2O 3For ratio and the full dose of 85wt% is that 1.5Kg prepares this powder (for 1 mole of In, Si is equivalent to about 0.13 mole), adopt the filtering shaping method to obtain formed body.Then, under oxygen atmosphere gas, 1550 ℃ of conditions, this fired body is carried out 8 hours fire, sintering.Process this sintered compact, obtain relative density with respect to theoretical density and be 100% target.The body resistivity of this target is 2.4 * 10 -4Ω cm.
Use this target, under the following conditions, come film forming, obtain the film that thickness is 1200 by the DC magnetron sputtering.
Target size: φ=6in. τ=6mm
Sputter mode: DC magnetron sputtering
Gas barrier: rotor pump+cryopump
Arrive vacuum tightness: 4.0 * 10 -5[Torr]
Ar pressure: 3.0 * 10 -3[Torr]
Oxygen pressure: 1～10 * 10 -5[Torr]
Substrate temperature: 200 ℃
Sputtering power: 300W (power density 1.6W/cm 2)
Use substrate: Denpax (liquid-crystal display glass) t=1.8mm
By resistivity and the transmitance of analyzing this film, obtain Fig. 1 such at the relation between the transmitance of the resistivity of oxygen partial pressure and wavelength 550nm.
(comparative example 1)
Prepare the In of purity＞99.99% 2O 3Powder and SnO 2Powder.According to SnO 2Be 10wt%, In 2O 3For ratio and the full dose of 90wt% is that 1.5Kg prepares this powder, adopt the filtering shaping method to obtain formed body.Then, under oxygen atmosphere gas, 1550 ℃ of conditions, this fired body is carried out 8 hours fire, sintering.Process this sintered compact, obtain relative density with respect to theoretical density and be 99.6% target.The body resistivity of this target is 1.7 * 10 -4Ω cm.
Use this target, under the condition identical, come film forming, obtain the film that thickness is 2000 by the DC magnetron sputtering with embodiment 1.By resistivity and the transmitance of analyzing this film, obtain Fig. 2 such at the relation between the transmitance of the resistivity of oxygen partial pressure and wavelength 550nm.
(embodiment 2)
Prepare the In of purity＞99.99% 2O 3Powder and SnO 2The SiO of powder and purity＞99.9% 2Powder.According to SnO 2Be 10wt%, SiO 2Be 10wt%, In 2O 3For ratio and the full dose of 80wt% is that 1.5Kg prepares this powder (for 1 mole of In, Si is equivalent to about 0.26 mole), adopt the filtering shaping method to obtain formed body.Then, under oxygen atmosphere gas, 1550 ℃ of conditions, this fired body is carried out 8 hours fire, sintering.Process this sintered compact, obtain relative density with respect to theoretical density and be 100% target.The body resistivity of this target is 4.0 * 10 -4Ω cm.
Use this target, under the condition identical, come film forming, obtain the film that thickness is 1200 by the DC magnetron sputtering with embodiment 1.By resistivity and the transmitance of analyzing this film, obtain Fig. 3 such at the relation between the transmitance of the resistivity of oxygen partial pressure and wavelength 550nm.
(embodiment 3)
Prepare the In of purity＞99.99% 2O 3Powder and SnO 2The SiO of powder and purity＞99.9% 2Powder.According to SnO 2Be 10wt%, SiO 2Be 5wt%, In 2O 3For ratio and the full dose of 85wt% is that 1.5Kg prepares this powder (for 1 mole of In, Si is equivalent to about 0.13 mole), adopt the filtering shaping method to obtain formed body.Then, under oxygen atmosphere gas, 1450 ℃ of conditions, this fired body is carried out 8 hours fire, sintering.Process this sintered compact, obtain relative density with respect to theoretical density and be 100% target.The body resistivity of this target is 3.0 * 10 -4Ω cm.
Use this target, under the condition identical, come film forming, obtain the film that thickness is 1200 by the DC magnetron sputtering with embodiment 1.Analyze the resistivity and the transmitance of this film, demonstrate with Fig. 1 and be close to equal oxygen partial pressure characteristic.
By above result as can be seen, the body resistivity of embodiment 1～3 is 10 -4The Ω cm order of magnitude demonstrates with the existing ITO target shown in the comparative example 1 and is close to equal value, and the DC magnetron sputtering is fine.
And as can be known, compare with the oxygen partial pressure dependency of the existing ITO film shown in the comparative example 1, also having shown in the embodiment 1～3 is close to equal characteristic, can use the film of existing ITO film.
Compare with the resistivity in the preferred oxygen partial pressure of the existing ITO film shown in the comparative example 1, the resistivity of embodiment 1 becomes 10 times size, and, with regard to embodiment 2, become 100 times size.
In fact, be about 150 if the thickness will be applicable to commodity the time is set, in embodiment 1, sheet resistance is about 700 Ω.On the other hand, in embodiment 2, sheet resistance is about 7000 Ω.In addition, if thickness is set at 1500 , in embodiment 1, sheet resistance is about 70 Ω.On the other hand, in embodiment 2, sheet resistance is about 700 Ω.
In addition, we know, by increasing SnO 2Addition, can generate current carrier, have the tendency that reduces resistance.Hence one can see that, not only SiO 2, and by adjusting SnO 2Addition also can the controlling resistance rate.
As known from the above, by control SnO 2, SiO 2Amount, can obtain best resistivity.
As described above, the present invention can provide a kind of resistivity that is used to form to be about 0.8～10 * 10 -3The high resistance nesa coating Indium sesquioxide base sputtering target of the nesa coating of Ω cm, promptly, contain Indium sesquioxide and stannic oxide as required and contain the high resistance nesa coating sputtering target of insulativity oxide compound, thus, can adopt basic DC magnetic controlled tube sputtering apparatus to make the high resistance nesa coating that can form transparent and high-resistance film.

Claims (11)

1. a high resistance nesa coating sputtering target is to be used to form resistivity to be about 0.8～10 * 10 -3The high resistance nesa coating Indium sesquioxide base sputtering target of the high resistance conductive film of Ω cm is characterized in that:
Contain Indium sesquioxide and stannic oxide as required, and contain the insulativity oxide compound.
2. high resistance nesa coating sputtering target as claimed in claim 1 is characterized in that:
Described insulativity oxide compound is be selected from silicon oxide, aluminum oxide, tantalum oxide, hafnia, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, Scium trioxide, titanium oxide, zirconium white, vanadium oxide, boron oxide, gallium oxide, zinc oxide, chromic oxide, manganese oxide, ferric oxide, molybdenum oxide, phosphorus oxide and oxidation lanthanide at least a.
3. high resistance nesa coating sputtering target as claimed in claim 2 is characterized in that: described insulativity oxide compound is a silicon oxide.
4. as any described high resistance nesa coating sputtering target in the claim 1～3, it is characterized in that: with respect to 1 mole of indium, the element that constitutes described insulativity oxide compound is 0.00001～0.26 mole.
5. as any described high resistance nesa coating sputtering target in the claim 1～4, it is characterized in that:, contain 0～0.3 mole of tin (Sn) with respect to 1 mole of indium.
6. as any described high resistance nesa coating sputtering target in the claim 1～5, it is characterized in that: forming resistivity by the DC magnetron sputtering is 0.8～10 * 10 -3The nesa coating of Ω cm.
7. the manufacture method of a high resistance nesa coating is characterized in that: use the Indium sesquioxide base sputtering target that contains Indium sesquioxide and stannic oxide as required and contain the insulativity oxide compound, forming resistivity by the DC magnetron sputtering is 0.8～10 * 10 -3The nesa coating of Ω cm.
8. the manufacture method of high resistance nesa coating as claimed in claim 7 is characterized in that: described insulativity oxide compound is be selected from silicon oxide, aluminum oxide, tantalum oxide, hafnia, niobium oxides, yttrium oxide, cerium oxide, Praseodymium trioxide, beryllium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, Scium trioxide, titanium oxide, zirconium white, vanadium oxide, boron oxide, gallium oxide, zinc oxide, chromic oxide, manganese oxide, ferric oxide, molybdenum oxide, phosphorus oxide and oxidation lanthanide at least a.
9. the manufacture method of high resistance nesa coating as claimed in claim 8 is characterized in that: described insulativity oxide compound is a silicon oxide.
10. as the manufacture method of any described high resistance nesa coating in the claim 7～9, it is characterized in that: with respect to 1 mole of indium, the element that constitutes described insulativity oxide compound is 0.00001～0.26 mole.
11. the manufacture method as any described high resistance nesa coating in the claim 7～10 is characterized in that:, contain 0～0.3 mole of tin (Sn) with respect to 1 mole of indium.
CNB021244332A 2001-06-26 2002-06-26 Sputtering target for high resistance transparent conductive membrane and mfg. method of high resistance transparent conductive membrane Expired - Lifetime CN1320155C (en)

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Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5788028A (en) * 1980-11-14 1982-06-01 Asahi Glass Co Ltd Formation of electrically conductive transparent film of indium oxide
US5071800A (en) * 1989-02-28 1991-12-10 Tosoh Corporation Oxide powder, sintered body, process for preparation thereof and targe composed thereof
JP2989886B2 (en) * 1990-11-30 1999-12-13 日東電工株式会社 Analog touch panel
JPH05222526A (en) * 1992-02-07 1993-08-31 Asahi Glass Co Ltd Sputtering target for transparent conductive film consisting of ito and production thereof
JPH0664959A (en) * 1992-08-19 1994-03-08 Tosoh Corp Sintered compact of ito
US5433901A (en) * 1993-02-11 1995-07-18 Vesuvius Crucible Company Method of manufacturing an ITO sintered body
JP3864425B2 (en) * 1994-03-22 2006-12-27 東ソー株式会社 Aluminum-doped zinc oxide sintered body, method for producing the same, and use thereof
JP3803132B2 (en) * 1996-01-31 2006-08-02 出光興産株式会社 Target and manufacturing method thereof
JP3501614B2 (en) * 1997-02-26 2004-03-02 株式会社オプトロン ITO sintered body, method of manufacturing the same, and method of forming ITO film using the ITO sintered body
JP3841388B2 (en) * 1998-02-16 2006-11-01 日鉱金属株式会社 Protective film for optical disk and sputtering target for forming protective film of optical disk
JP3780100B2 (en) * 1998-05-15 2006-05-31 株式会社神戸製鋼所 Transparent conductive film with excellent processability
JP2000067657A (en) * 1998-08-26 2000-03-03 Internatl Business Mach Corp <Ibm> Transparent conductive film excellent in infrared transmission and its manufacture

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