CN1339059A - 表面活性剂组合物 - Google Patents
表面活性剂组合物 Download PDFInfo
- Publication number
- CN1339059A CN1339059A CN00803361.7A CN00803361A CN1339059A CN 1339059 A CN1339059 A CN 1339059A CN 00803361 A CN00803361 A CN 00803361A CN 1339059 A CN1339059 A CN 1339059A
- Authority
- CN
- China
- Prior art keywords
- compound
- component
- acid
- surfactant composition
- tensio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 41
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 125000002252 acyl group Chemical group 0.000 claims abstract description 12
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- 239000013543 active substance Substances 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 235000011187 glycerol Nutrition 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 230000008719 thickening Effects 0.000 abstract description 7
- 239000007787 solid Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- -1 alkylbenzene sulfonate Chemical class 0.000 description 33
- 239000002253 acid Substances 0.000 description 17
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 10
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 235000021314 Palmitic acid Nutrition 0.000 description 8
- 235000021355 Stearic acid Nutrition 0.000 description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 8
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 7
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- 150000002632 lipids Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229940125904 compound 1 Drugs 0.000 description 4
- 229940126214 compound 3 Drugs 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003346 palm kernel oil Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 229940125898 compound 5 Drugs 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- WDVWEDIMFKEWMT-UHFFFAOYSA-N 1-amino-2-hydroxytetradecan-3-one Chemical compound CCCCCCCCCCCC(=O)C(O)CN WDVWEDIMFKEWMT-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N Amide-Hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- MWALGVAXKTYXOP-UHFFFAOYSA-N CCCC(C)(C(=O)O)N(C)C(C(=O)C)C(=O)C Chemical compound CCCC(C)(C(=O)O)N(C)C(C(=O)C)C(=O)C MWALGVAXKTYXOP-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960004232 linoleic acid Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- IFDVSPCLJCWIHL-UHFFFAOYSA-N n-(2-hydroxyethyl)-n-methyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(C)CCO IFDVSPCLJCWIHL-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/46—Esters of carboxylic acids with amino alcohols; Esters of amino carboxylic acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
本发明提供甚至在宽pH范围内,甚至在油污存在下,具有优异发泡性、增稠性能、水溶性和稳定性的表面活性剂组合物。本发明提供含有通式(I)的化合物(a)和选自通式(II)化合物和通式(III)化合物的至少一种化合物(b)以及不同于组分(a)和(b)的其它表面活性剂的一种表面活性剂组合物,(a)/(b)的重量比是99.99/0.01至80/20:如(I)(II)(III),在该通式中,R1CO－是具有6－24个碳原子和还可具有羟基的酰基;R2是具有1－3个碳原子的基团;和R3是具有1－6个碳原子的亚烷基或亚链烯基。
Description
技术领域
本发明涉及具有优异的发泡性，增稠性能，水溶性和稳定性的表面活性剂组合物。
背景技术
不仅高的洗净能力而且丰富的泡沫都依赖于洗涤剂，如香波，漂洗液，固体皂，浴液，厨房用洗涤剂，衣服用洗涤剂和住所用洗涤剂。在许多产品中用作主要基料的物质是阴离子表面活性剂，如烷基苯磺酸盐，烷基硫酸盐和聚氧乙烯烷基硫酸盐等。然而，虽然其中任何一种都显示出它的优异洗净能力和起泡能力，问题是，当存在固体物、来自硅氧烷等的油污时，洗净能力和起泡性显著降低。
为了改进洗净能力和/或起泡性的这一降低，已经考察了除该主要基料以外的各种助表面活性剂。已有人首先建议了实际和广泛地用于此类产品中的脂肪酸二乙醇酰胺，和近年来建议了脂肪酸单乙醇酰胺(WO 98/0507,WO 97/44434,JP-A 11-80785等)，基于糖酰胺型的非离子型表面活性剂(WO 94/12610)，酰基肌氨酸盐(WO 96/06596)等。
然而，虽然这些洗涤剂组合物在洗净能力和起泡性上有显著改进，但它们仍然不令人满意。而且，由于以上所述的洗涤剂每天直接与皮肤接触，仍然要求它们在对皮肤温和的弱酸性PH范围内显示出高性能。然而，在普通的表面活性剂体系中遇到这样一个问题，即，即使当从中性到碱性的区域中起泡性能是良好的时，起泡性能却不能在酸性范围中表现出来。
本发明的公开
本发明的目的是提供在宽pH范围内，甚至在油污存在下，具有优异发泡性，增稠性能，水溶性和稳定性的表面活性剂组合物。
本发明提供包括以下所示组分(a)和组分(b)和不同于(a)和(b)的表面活性剂的表面活性剂组合物，(a)/(b)的重量比是99.99/0.01至80/20或99.9/0.1至70/30。
(a)由下式(I)表示的化合物(I)：在通式(I)中，R1CO-是具有6-24个碳原子和还可具有羟基的饱和或不饱和酰基；R2是具有1-3个碳原子的线性或支链烷基；和R3是具有1-6个碳原子的线性或支化亚烷基或具有2-6个碳原子的线性或支化亚链烯基。
(b)选自由通式(II)表示的化合物(II)和由通式(III)表示的化合物(III)的至少一种化合物：
在通式(II)和(III)中，R1CO-、R2和R3具有与以上同样的定义，在每一种化合物中R1、R2和R3相互之间可以相同或不同。
本发明的实施方案
在本发明的组分(a)中，R1CO-是如以上所述的酰基。它优选是具有8-18个碳原子的饱和或不饱和酰基。它包括例如从辛酸，癸酸，十二烷酸，十四酸，十六烷酸，硬脂酸，二十二烷酸，亚油酸，2-乙基己酸，2-辛基十一烷酸，异硬脂酸，油酸，椰油-脂肪酸，棕榈油-脂肪酸，棕榈仁油-脂肪酸，牛油-脂肪酸等衍生的酰基。更优选的是从辛酸，癸酸，十二烷酸，十四酸，十六烷酸，硬脂酸，油酸，椰油-脂肪酸，棕榈油-脂肪酸，棕榈仁油-脂肪酸和牛油-脂肪酸衍生的酰基。在这些酰基中，含有不低于50wt％的从具有12-14个碳原子的脂肪酸衍生的酰基的那些酰基是优选的。更优选的是含有40wt％～100wt％的从具有12个碳原子的脂肪酸衍生的酰基。
为了不降低发泡性，R2是具有1-3个碳原子的线性或支链烷基，优选甲基或乙基。甲基是特别优选的。为了不致于降低表面活性性能，R3是具有1-6个碳原子的线性或支化亚烷基或具有2-6个碳原子的线性或支化亚链烯基。它优选是具有2或3个碳原子的线性或支化亚烷基。
该组分(a)的例子包括，例如，N-(2-羟乙基)-N-甲基辛酰胺，N-(2-羟乙基)-N-甲基癸酰胺，N-(2-羟乙基)-N-甲基十二酰胺，N-(2-羟乙基)-N-甲基十四酰胺，N-(2-羟乙基)-N-甲基十六酰胺，N-(2-羟乙基)-N-甲基硬脂酰胺，N-(2-羟乙基)-N-甲基-椰油-脂肪羧酰胺，N-(2-羟乙基)-N-甲基-棕榈仁油-脂肪酰胺，N-(2-羟丙基)-N-乙基十二酰胺，N-乙基-N-(2-羟丙基)油酰胺和N-乙基-N-(2-羟丙基)异硬脂酰胺。
生产组分(a)的方法不是特别限制的。例如，它能够通过脂肪酸或脂肪酸的低级醇酯与链烷醇胺的缩合反应或脱醇反应，脂肪酸卤化物与链烷醇胺在碱性催化剂存在下的反应，以及在脂肪和油和链烷醇胺或其它类似物之间的酯-酰胺交换反应(氨解)来生产。由这类方法获得的产品常常含有少量的脂肪酸、无机盐、甘油等，但是它们基本上不影响产物的性能。
该组分(b)选自分别由以上所述通式(II)和(III)表示的化合物。没有必要是单种，多种物质可以混合使用。
通式(II)和(III)的R1CO-、R2和R3具有与通式(I)的所有那些相同的意义。在各化合物中，R1、R2和R3相互之间可相同或不同。
由通式(II)表示的化合物的例子包括，例如，辛酸N-辛酰基-N-甲基氨基乙基酯，癸酸N-辛酰基-N-甲基氨基乙基酯，十二烷酸N-辛酰基-N-甲基氨基乙基酯，十四烷酸N-辛酰基-N-甲基氨基乙基酯，十六烷酸N-辛酰基-N-甲基氨基乙基酯，十八烷酸N-辛酰基-N-甲基氨基乙基酯，辛酸N-十二烷酰基-N-甲基氨基乙基酯，癸酸N-十二烷酰基-N-甲基氨基乙基酯，十二烷酸N-十二烷酰基-N-甲基氨基乙基酯，十四烷酸N-十二烷酰基-N-甲基氨基乙基酯，十六烷酸N-十二烷酰基-N-甲基氨基乙基酯，十八烷酸N-十二烷酰基-N-甲基氨基乙基酯，辛酸N-十二烷酰基-N-乙基氨基己基酯，癸酸N-十二烷酰基-N-乙基氨基己基酯，十二烷酸N-十二烷酰基-N-乙基氨基己基酯，十四烷酸N-十二烷酰基-N-乙基氨基已基酯，十六烷酸N-十二烷酰基-N-乙基氨基己基酯，十八烷酸N-十二烷酰基-N-乙基氨基己基酯，椰油-脂肪酸(N-椰油基-N-甲基氨基乙基)酯和棕榈仁油脂肪酸(N-棕榈仁油酰基-N-甲基氨基乙基)酯。
由通式(III)表示的化合物的实例，例如，包括辛酸2-(甲基氨基)乙酯，癸酸2-(甲基氨基)乙酯，十二烷酸2-(甲基氨基)乙酯，十四烷酸2-(甲基氨基)乙酯，十六烷酸2-(甲基氨基)乙基酯，十八烷酸2-(甲基氨基)乙基酯，油酸2-(甲基氨基)乙酯，辛酸2-(乙氨基)乙酯，十二烷酸2-(乙氨基)乙酯，豆蔻酸2-(乙氨基)乙酯，十六烷酸2-(乙氨基)乙基酯，十八烷酸2-(乙氨基)乙基酯，油酸2-(乙氨基)乙酯，辛酸2-(甲基氨基)丙基酯，癸酸2-(甲基氨基)丙基酯，十二烷酸2-(甲基氨基)丙基酯，十四烷酸2-(甲基氨基)丙基酯，十六烷酸2-(甲基氨基)丙基酯，十八烷酸2-(甲基氨基)丙基酯，油酸2-(甲基氨基)丙基酯，椰油-脂肪酸(2-乙基氨基乙基)酯和棕榈仁油脂肪酸(2-乙基氨基乙基)酯。
此外，组分(a)与组分(b)的混合比例，(a)/(b)的重量比，是99.99/0.01至80/20或99.9/0.1至70/30，优选98/2至90/10，考虑到发泡性，增稠和稳定性。
对于本发明的组合物的化合物(I)、(II)和(III)为获得良好的表面活性性能所需要的混合比例，化合物(I)优选是它们总重量的80-99.99wt％，更优选90-98wt％。化合物(II)优选是0.01-20wt％，更优选2-10wt％。化合物(III)优选是0-5wt％。
通过将不同于(a)和(b)的其它表面活性剂(下面称作“其它表面活性剂”)与(a)和(b)结合使用，本发明能够显示出很高的发泡性和增稠性能。本发明的组合物的组分(a)和(b)的总量能够任意地根据所述其它表面活性剂的特性来选择。考虑到水溶性、稳定性、发泡性和增稠性能，组分(a)和(b)两者之和与所述其它表面活性剂的混合比例优选是0.5/99.5至50/50(按重量计)。
用于本发明中的所述其它表面活性剂可以是选自以下这些中的至少一种：硫酸盐型或磺酸盐型的表面活性剂如烷基硫酸盐，聚氧乙烯烷基硫酸盐和烷基苯磺酸盐等，胺氧化物如烷基二甲基胺氧化物和酰氨基丙基二甲基氨氧化物和含酰氨基的甜菜碱如酰氨基丙基二甲基羰基甜菜碱。可使用其中的一种、两种或多种。优选的是，共存一种或多种硫酸盐型表面活性剂。
本发明的表面活性剂组合物通过进一步含有甘油而能够改进粘度。甘油相对于组分(a)和(b)的总量与不同于组分(a)和(b)的表面活性剂的量的总和而言的量优选是20wt％以下，更优选0.01-15wt％。另外，组分(a)、组分(b)和甘油的总量相对于所述其它表面活性剂的混合量的比例优选是0.5/99.5至50/50，更优选1/99至25/75(按重量计)。甘油可单独添加。它可以含有在组分(a)的合成中产生的甘油。
本发明的表面活性剂组合物在pH 4.0-11.0下能够显示出所需性能如发泡性和增稠性能。它可用作洗涤剂的基料。
实施例
实施例1-7和对比实施例1-5
通过使用下面所示的组分，制备了具有表1中所示配方的表面活性剂组合物并在下面所述方法中测试发泡性。结果示于表1中。
<组分>
组分(a)
化合物1：N-(2-羟乙基)-N-甲基月桂酰胺
化合物2：N-(2-羟乙基)-N-甲基椰油-脂肪酰胺
化合物3：N-(2-羟乙基)-N-甲基棕榈仁油-脂肪酰胺
组分(b)
化合物4：月桂酸N-月桂酰基-N-甲基氨基乙基酯
化合物5：椰油-脂肪羧酸(N-椰油基-N-甲基氨基乙基)酯
化合物6：棕榈仁油-脂肪羧酸(N-棕榈仁油酰基-N-甲基氨基乙基)酯(N-palm kerneloyl-N-methylaminoethyl palm kernel-fattycarboxylate)
化合物7：月桂酸2-(甲基氨基)乙基酯
化合物8：椰油脂肪羧酸(2-乙基氨基乙基)酯
化合物9：棕榈仁油-脂肪羧酸(2-乙基氨基乙基)酯
其它表面活性剂
AES：聚氧乙烯(3)月桂基硫酸钠
LAPB：月桂酰酰氨基丙基二甲基羰基甜菜碱
LDMAO：长链烷基(C12)二甲基胺氧化物
MEA：月桂酰单乙醇胺
DEA：月桂酰二乙醇胺
EAA：聚氧乙烯(2)椰油-脂肪单乙醇胺
<评价发泡性的方法>
制备了表面活性剂组合物在去离子水中稀释至20倍的30mL水溶液，并用柠檬酸调节到给定的pH值。将该水溶液置于内径3cm、装有停止旋塞的300mL餐用圆筒中并在25℃下以10cm的振幅振荡10秒共20次。立即测定泡沫体的体积(mL)。
表1
| 实施例 | 对比实施例 | ||||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 1 | 2 | 3 | 4 | 5 | 6 | |||
| 表面活性剂组合物(wt％) | 组分(a) | 化合物1 | 0.18 | 0.36 | 0.90 | 0.90 | 2.70 | 0.60 | |||||||
| 化合物2 | 0.90 | ||||||||||||||
| 化合物3 | 0.90 | ||||||||||||||
| 组分(b) | 化合物4 | 0.02 | 0.03 | 0.06 | 0.06 | 0.18 | 0.30 | ||||||||
| 化合物5 | 0.06 | ||||||||||||||
| 化合物6 | 0.06 | ||||||||||||||
| 化合物7 | 0.01 | 0.04 | 0.04 | 0.12 | 0.10 | ||||||||||
| 化合物8 | 0.04 | ||||||||||||||
| 化合物9 | 0.04 | ||||||||||||||
| 其它表面活性剂 | AES | 11.0 | 11.0 | 11.0 | 9.5 | 9.5 | 9.5 | 9.5 | 11.0 | 11.0 | 9.5 | 9.5 | 11.0 | 11.0 | |
| LAPB | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | ||||||||
| LDMAO | 5.5 | 5.5 | 5.5 | 5.5 | 5.5 | 5.5 | |||||||||
| MEA | 1.0 | ||||||||||||||
| DEA | 1.0 | ||||||||||||||
| EAA | 1.0 | ||||||||||||||
| pH | 6.0 | 6.0 | 6.0 | 7.5 | 7.5 | 7.5 | 7.5 | 6.0 | 6.0 | 7.5 | 7.5 | 6.0 | 6.0 | ||
| 泡沫体积(ml) | 237 | 259 | 275 | 259 | 256 | 249 | 264 | 193 | 216 | 231 | 237 | 221 | 191 | ||
实施例8-16和对比实施例8-11
使用在表2中示出的组分，制备了具有表2中所示配方的表面活性剂组合物并按照实施例1同样的方式测试发泡性。结果示于表2中。
表2
| 实施例 | 对比实施例 | ||||||||||||||
| 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 8 | 9 | 10 | 11 | |||
| 表面活性剂组合物(wt％) | 组分(a) | 化合物1 | 3.0 | 1.0 | 2.0 | 30 | |||||||||
| 化合物3 | 2.0 | 2.0 | 3.0 | 4.0 | 4.0 | ||||||||||
| 组分(b) | 化合物4 | 0.13 | 0.04 | 0.08 | 0.13 | ||||||||||
| 化合物6 | 0.06 | 0.21 | 0.35 | 0.12 | 0.48 | ||||||||||
| 其它表面活性剂 | AES | 18.0 | 19.0 | 18.0 | 17.0 | 18.0 | 18.0 | 17.0 | 16.0 | 16.0 | 20.0 | 18.0 | 18.0 | 15.0 | |
| MEA | 2.0 | ||||||||||||||
| 0EA | 4.0 | ||||||||||||||
| EAA | 5.0 | ||||||||||||||
| 甘油 | 0.50 | 0.50 | 0.50 | 0.20 | 0.30 | 0.40 | 0.40 | ||||||||
| 泡沫体积(ml) | 212 | 238 | 246 | 236 | 208 | 219 | 250 | 243 | 257 | 190 | 199 | 198 | 193 | ||
实施例17-20和对比实施例12-16使用在表3中示出的组分，制备了具有如表3中所示的配方的表面活性剂组合物。它的粘度用普通布氏(B型)粘度计在25℃下测定。结果示于表3中。
表3
| 实施例 | 对比实施例 | ||||||||||
| 17 | 18 | 19 | 20 | 12 | 13 | 14 | 15 | 16 | |||
| 表面活性剂组合物(wt％) | 组分(a) | 化合物1 | 5.0 | ||||||||
| 化合物3 | 5.0 | 5.0 | 5.0 | 4.0 | |||||||
| 组分(b) | 化合物4 | 0.20 | |||||||||
| 化合物6 | 0.15 | 0.35 | 0.60 | ||||||||
| 其它表面活性剂 | AES | 15.0 | 15.0 | 15.0 | 15.0 | 20.0 | 15.0 | 15.0 | 15.0 | 16.0 | |
| MEA | 5.0 | ||||||||||
| DEA | 5.0 | ||||||||||
| EAA | 5.0 | ||||||||||
| 甘油 | 0.50 | 0.50 | 0.50 | 0.50 | |||||||
| 粘度(mPa·s) | 8253 | 3813 | 4065 | 6698 | 12 | 1934 | 1725 | 163 | 1938 | ||
Claims (5)
1.一种表面活性剂组合物，它含有以下所示的组分(a)、以下所示的组分(b)和不同于(a)和(b)的其它表面活性剂，组分(a)/组分(b)的重量比(a)/(b)为99.99/0.01至80/20：
(a)由通式(I)表示的化合物(下面称作化合物(I))：
其中R1CO-是具有6-24个碳原子和还可具有羟基的饱和或不饱和酰基；R2是具有1-3个碳原子的线性或支链烷基；和R3是具有1-6个碳原子的线性或支化亚烷基或具有2-6个碳原子的线性或支化亚链烯基；
(b)选自由通式(II)表示的化合物(下面称作化合物(II))和由通式(III)表示的化合物(下面称作化合物(III))的至少一种化合物：
其中R1CO-、R2和R3具有与以上相同的意义，以及R1、R2和R3可相互之间相同或不同。
2.根据权利要求1所要求的表面活性剂组合物，其中化合物(I)、(II)和(III)各自相对于它们的总量而言的混合比例是化合物(I)80-99.99wt％，化合物(II)0.01-20wt％和化合物(III)0-5wt％。
3.权利要求2所要求的表面活性剂组合物，其中组分(a)和(b)两者的配合总量相对于不同于组分(a)和(b)的其它表面活性剂的配合量的重量比是0.5/99.5到50/50。
4.根据权利要求1-3中任何一项所要求的表面活性剂组合物，它包括相对于组分(a)和(b)和不同于组分(a)和(b)的其它表面活性剂的总量而言的20wt％或20wt％以下的甘油。
5.权利要求4所要求的表面活性剂组合物，其中组分(a)、(b)和甘油的总配合量相对于不同于组分(a)和(b)的其它表面活性剂的配合量的重量比例是0.5/99.5至50/50。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP341649/1999 | 1999-12-01 | ||
| JP34164999 | 1999-12-01 | ||
| JP341649/99 | 1999-12-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1339059A true CN1339059A (zh) | 2002-03-06 |
| CN100372919C CN100372919C (zh) | 2008-03-05 |
Family
ID=18347734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008033617A Expired - Lifetime CN100372919C (zh) | 1999-12-01 | 2000-12-01 | 表面活性剂组合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US6407054B2 (zh) |
| EP (1) | EP1149892B1 (zh) |
| CN (1) | CN100372919C (zh) |
| DE (1) | DE60034215T2 (zh) |
| WO (1) | WO2001040421A1 (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4823430B2 (ja) * | 2001-03-28 | 2011-11-24 | 花王株式会社 | 界面活性剤組成物 |
| JP4712224B2 (ja) * | 2001-05-24 | 2011-06-29 | 花王株式会社 | 濃縮パール化剤組成物 |
| US6774095B2 (en) * | 2001-05-24 | 2004-08-10 | Kao Corporation | Detergent composition |
| EP4299708A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | Liquid hand dishwashing cleaning composition |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3932296A (en) * | 1973-05-29 | 1976-01-13 | The Dow Chemical Company | Corrosion inhibitor |
| US4370174A (en) * | 1981-08-31 | 1983-01-25 | Braithwaite Jr Charles H | Method for removing adhesive residues with an emulsion cleaner |
| EP0670886A1 (en) | 1992-11-30 | 1995-09-13 | The Procter & Gamble Company | Detergent compositions containing polyhydroxy fatty acid amide, sulfated polyhydroxy fatty acid amide and soap |
| JP3515800B2 (ja) * | 1993-12-29 | 2004-04-05 | 川研ファインケミカル株式会社 | ポリオキシエチレン脂肪酸アミド硫酸エステル塩型界面活性剤、該界面活性剤の製造方法および洗浄剤組成物 |
| US5534265A (en) | 1994-08-26 | 1996-07-09 | The Procter & Gamble Company | Thickened nonabrasive personal cleansing compositions |
| JPH09137190A (ja) * | 1995-11-16 | 1997-05-27 | Kao Corp | 洗浄剤組成物 |
| WO1997044434A1 (en) | 1996-05-17 | 1997-11-27 | The Procter & Gamble Company | Low moisture laundry detergent bar with improved bleach stability |
| WO1998000507A2 (en) | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Nonaqueous detergent compositions containing bleach precursors |
| JPH10339783A (ja) | 1997-04-09 | 1998-12-22 | Seiko Epson Corp | 電子時計 |
| JPH10330783A (ja) * | 1997-06-02 | 1998-12-15 | Lion Corp | 洗浄剤組成物 |
| JP3844391B2 (ja) | 1997-12-19 | 2006-11-08 | 電気化学工業株式会社 | モルタル又はコンクリート部材の製造方法 |
-
2000
- 2000-12-01 US US09/726,577 patent/US6407054B2/en not_active Expired - Lifetime
- 2000-12-01 EP EP00978068A patent/EP1149892B1/en not_active Expired - Lifetime
- 2000-12-01 WO PCT/JP2000/008539 patent/WO2001040421A1/ja active IP Right Grant
- 2000-12-01 DE DE60034215T patent/DE60034215T2/de not_active Expired - Lifetime
- 2000-12-01 CN CNB008033617A patent/CN100372919C/zh not_active Expired - Lifetime
-
2001
- 2001-04-12 US US09/726,577 patent/US20010034310A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE60034215T2 (de) | 2007-12-20 |
| CN100372919C (zh) | 2008-03-05 |
| WO2001040421A1 (fr) | 2001-06-07 |
| EP1149892B1 (en) | 2007-04-04 |
| EP1149892A1 (en) | 2001-10-31 |
| US20010034310A1 (en) | 2001-10-25 |
| DE60034215D1 (de) | 2007-05-16 |
| US6407054B2 (en) | 2002-06-18 |
| EP1149892A4 (en) | 2004-06-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8901058B2 (en) | Liquid hand dishwashing detergent composition | |
| US8901059B2 (en) | Liquid hand dishwashing detergent composition | |
| EP1972326B1 (en) | Skin or hair washing composition | |
| CN1215159C (zh) | 表面活性剂组合物 | |
| RU2475524C2 (ru) | Композиция, которая содержит смесь моно-, ди- и триглицеридов и глицерина | |
| JP4348312B2 (ja) | 洗浄剤組成物 | |
| CN1366028A (zh) | 粘性、温和、和有效的清洁组合物 | |
| US11447721B2 (en) | Liquid hand dishwashing cleaning composition | |
| CN1065269C (zh) | 可灌注的液态含水的清洁剂浓缩液 | |
| CN1378586A (zh) | 清洁剂组合物 | |
| US20040258649A1 (en) | Aqueous formulations comprising combinations of anionic and cationic surfactants for generating a yeild point | |
| ES2871098T3 (es) | Composición de limpieza líquida para lavado de vajilla a mano | |
| JP2003073257A (ja) | 皮膚洗浄剤組成物 | |
| US6423678B1 (en) | Alcohol ethoxylate-peg ether of glycerin | |
| CN1339059A (zh) | 表面活性剂组合物 | |
| JP3824761B2 (ja) | 洗浄剤組成物 | |
| JPH08311489A (ja) | 洗浄剤組成物 | |
| JPH1053795A (ja) | 洗浄剤組成物 | |
| JP6134118B2 (ja) | 液体洗浄剤組成物 | |
| JP3644566B2 (ja) | 毛髪洗浄剤組成物 | |
| CA2680538A1 (en) | Biodegradable cleaning compositions | |
| JP3517206B2 (ja) | 界面活性剤組成物 | |
| JP2955032B2 (ja) | 低刺激性洗浄剤組成物 | |
| JP4376543B2 (ja) | 洗浄剤用増粘剤 | |
| JP4176539B2 (ja) | 界面活性剤組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20080305 |