CN1336970A - 含高线密度比两组线的织物的抗穿刺材料 - Google Patents

含高线密度比两组线的织物的抗穿刺材料 Download PDF

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CN1336970A
CN1336970A CN00802900A CN00802900A CN1336970A CN 1336970 A CN1336970 A CN 1336970A CN 00802900 A CN00802900 A CN 00802900A CN 00802900 A CN00802900 A CN 00802900A CN 1336970 A CN1336970 A CN 1336970A
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C·鲍特革尔
A·费尔斯
B·多洛夫－兰姆佩
C·保穆格特
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TEVORON PRODUCTS CO
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Abstract

本发明涉及一种包括至少一个双层织物的抗穿刺材料,该织物由两层机织物构成,这两层机织物以某一角度交叉绞合,其特征在于,该织物由第一组线和第二组线构成,第一组线含3.5－20线/厘米且线密度至少420分特,而第二组线含0.5－8线且线/厘米密度至少50分特,第二组线横对第一组线,且其中第一组线的线密度与第二组线的线密度之比>4.2,更优选>7.5。在一优选实施方案中,第一组线是对－芳族聚酰胺制造的经线而第二组线是聚酯纱的纬线,并且第一组线和第二组线的每厘米线数之比>1。

Description

含高线密度比两组线的织物的抗穿刺材料
本发明涉及抗穿刺材料及其制品，该材料包括一种织物，该织物具有两组高线密度比的线。
本领域公知由高强度纤维制备的抗穿刺物品，例如防弹背心、头盔、车辆嵌板和防护罩。在许多应用中，特别是在防弹背心(ballisticvest)中，将该纤维用于机织物或针织物。可用一种基质将这些织物涂层或浸透，以便得到硬防弹材料(hard ballistic material)，或者可以不用基质，从而获得软防弹材料。
特别是，由EP310199已知防弹机织物。其中公开的织物是由高强高模量超高分子量聚合物的长丝纱组成，且经线与纬线的聚合物材料不同。
俄罗斯专利RU2096542公开了经线和纬线为聚对-亚苯基对苯二酰胺(PPTA)的防弹夹克用防弹织物，其中经线线密度对纬线线密度的比小于4.17。一般地，经线的线密度143-588分特(dtex)，纬线的线密度为588-930，纬线的线密度等于或高于经线的线密度。特别指出经纬线密度比介于1.59和4.17之间的防弹织物，其挠曲性能获得提高。
现已发现，如下的抗穿刺材料其防弹性能获得改进，该材料含至少一个由两层沿某一角度交叉绞合的机织物组成的双层织物，特征在于该织物由两组纱线组成，第一组线含3.5-20根/厘米，并且纤度至少420分特，而第二组线含0.5-8线/厘米，并且纤度至少50分特，该第二组纱线横对第一组线，并且其中第一组线的线密度与第二组线的线密度的比＞4.2，且第一组与第二组的线数/厘米比＞1。
优选地，该抗穿刺材料的第一组线线密度与第二组线线密度的比＞7.5。第一组线的线数为3.5-20线/厘米。更优选，该数为4-15线/厘米，最优选5-12线/厘米。第二组线的线数为0.5-8线/厘米。更优选，该数为1-6线/厘米，最优选2-4线/厘米。为了有效地生产优选第一组线作经线，而第二组线作纬线。第二组线横对第一组线。虽然通常这些组彼此基本垂直，但这不是必须的。可相对第一组线以90°以外的角度提供第二组线。
该抗穿刺材料还由其纱线成分对本发明非决定性的第二组线(优选纬线)组成。但是优选，这些线具有高强度和高模量。当这些线选自聚酯、聚乙烯、聚丙烯、聚酰胺和芳族聚酰胺的纱线时，情况尤为如此。最优选，第二组线由聚酯纱线制造。
第一组线(优选经线)是高强高模量的，并且最可取地，其选自芳族聚酰胺，更具体地，对-芳族聚酰胺的纱线。最优选的是，聚对-亚苯基对苯二酰胺(PPTA)。在优选的实施方案中，选择不同的聚合物制造经线和纬线，例如，优选经线是对-芳族聚酰胺纱线而纬线是聚酯纱线的织物。
在满足要求的线密度比时，所选第一组线的线密度应至少约420分特，优选420-3360分特，更优选420-1680分特，最优选约840-1100分特。所选第二组线的线密度应至少为约50分特，更优选介于50-280分特，最优选介于约80-140分特。
术语“线”含义为任何种类的线，例如短纤纱，加捻的短纤纱，加捻的长丝纱，无捻交络丝，优选无捻长丝纱。
在优选实施方案中，该双层的两个织物层的每一层的线被粘在一起，例如，通过接结，或优选地，用粘合材料。该粘合材料可为加到这些线上或该织物上的粘合材料，例如作为一种整理剂。该粘合材料也能是一种施加到该双层的两织物层之间的粘合剂层。粘合材料包括，热塑性、弹性和热固性材料。至少部分第二组线还可能使用一种在压力和/或加热条件下熔融的材料，从而，实现第一组线的线对第二组线的线的粘结，并且还非必要地使两织物层粘合在一起。热塑性材料包括聚烯烃例如，聚乙烯和聚丙烯、聚酰胺和聚酯或这些材料的混合物。弹性材料包括，Kraton、橡胶、硅等等。热固性材料包括，环氧树脂、聚酯树脂、酚醛树脂、乙烯基酯树脂等等。
在另一优选实施方案中，向该抗穿刺材料外侧的至少一侧提供了保护层。该保护层可为热塑性或弹性材料，或者这些材料的混合物。采用该保护层是为了让该织物不受过度磨损的破坏。
该抗穿刺材料包括至少一个双层，该双层由两层以某一角度交叉绞合并非必要地粘合在一起的机织物组成。术语机织包括所有织纹类型，例如平纹组织、缎纹组织、方平组织、斜纹组织等等。优选这些织物为平纹织造的。
抗穿刺材料可含少至一个由两层机织物组成的双层，但通常采用更多的双层。双层的合适数量是5-100个，并最优选使用6-35个双层。在这些双层的至少一个双层中，将两层织物按某一角度紧固在一起。优选的角度为30-90°。最优选约90°的角。用于软装甲时，当所有双层中的织物层以某一角度，优选呈90°紧固时，通常获得最佳性能。一个双层的第一织物层的第一组线可与相邻双层的第一织物层的第一组线平行或成一定角度。
使用粘合层或通过接结将各双层紧固在一起。该粘合层可由前述粘合剂用材料制造，并且厚度介于4-36μ，优选介于8-20μ。
本领域公知这些双层的制造方法。通常，通过在经轴上将经纱整经，随后在织机上织造而制造该织物。可选择性地将该单层浸渍或叠层，并经砑光加工。通过接结、加热或施压将至少两织物层彼此粘合在一起，优选彼此成某一角度。
本发明还涉及用上述机织物按照熟练人员已知方法制造的防弹背心和装甲板。
用以下实施例进一步举例说明本发明。
实施例1
按照本发明制备结构I。该结构包括21个约100克/米2织物的双层，该织物由经向1100分特Kevlar_(DuPont出品)(8.6根线/厘米)，且纬向140分特聚酯(Hoechst Trevira_710)(2根线/厘米)制造。经/纬的比例是7.9。这些层与2张厚10μ的聚乙烯薄膜(LDPE，EKB出品)层叠在一起。结构I的总重量约4300克/米2。
按照本发明制备结构II，且结构II包括20个双层，其织物与结构I用到的相同，并且在各双层的两外侧以及各双层的两织物层之间有1张厚10μ的聚乙烯薄膜(LDPE，EKB出品)。结构II的总重量约4400克/米2。
用9×19Para型DM 11 A1B2子弹测定V50值。其中V50值是使50％的子弹被阻挡且50％的子弹完全穿透的速度。发现结构I的V50为471m/s，结构II的V50为481m/s。
实施例2
仿照结构I采用19张930分特Twaron_(CT709微细长丝，从AkzoNobel出品)代替Kevlar(10.4根经线/厘米，2根纬线/厘米，经/纬比为6.6)制造结构III。结构III的总重量约4330克/米2，V50(用9×19Para型DM 11 A1B2子弹测定)为约490m/s。
对比实施例3
以22张Twaron_织物式样CT709(Akzo Nobel出品)制造结构IV。经线和纬线用930分特Twaron_微细长丝(Akzo Nobel出品)充当(沿经纬向各10.5根线/厘米；经/纬比为1)。结构IV的总重量约4400克/米2，V50(用9×19Para型DM 11 A1B2子弹测定)为约460-465m/s。
实施例4
由50个双层织物制造结构V，该织物源自930分特Twaron_制造(经向9.5根线/厘米，而纬向为140分特Trevira 710 2根线/厘米；经/纬比为6.6)。
在温度115℃和压力2.5MPa时，将这些层与LDPE-共聚物基质(树脂含量35％)层压在一起。总重量为6500克/米2，V50(用357 MagnumFJ CB SC子弹测定)为484m/s。
对比实施例5
结构VI由44层Twaron_CT 709织物(930分特，200克/米2，平纹组织)制造。以PVB-改性酚醛树脂(树脂含量23％)涂层该材料，并在温度160℃和压力1.0MPa下层压。总重量为10800克/米2，V50(用357 Magnum FJ CB SC子弹测定)为487m/s。
采用上述树脂体系、树脂含量和层压条件，不降低V50时，重量不能减少。

Claims (11)

1.一种包括至少一个双层织物的抗穿刺材料，该织物由两层机织物构成，这两层机织物以某一角度交叉绞合，其特征在于，该织物由第一组线和第二组线构成，第一组线含3.5-20线/厘米且线密度至少420分特，而第二组线含0.5-8线/厘米且线密度至少50分特，第二组线横对第一组线，且其中第一组线的线密度与第二组线的线密度之比＞4.2，并且第一组线和第二组线的线数/厘米之比＞1。
2.权利要求1的抗穿刺材料，其中，将该双层的两层的线粘合在一起，优选用粘合材料。
3.权利要求1或2的抗穿刺材料，其中第一组线的线密度与第二组线的线密度之比＞7.5。
4.权利要求1-3中任一项的抗穿刺材料，其中由芳族聚酰胺线组成该第一组线。
5.权利要求1-3中任一项的抗穿刺材料，其中第二组线选自聚酯、聚乙烯、聚丙烯和芳族聚酰胺纱线。
6.权利要求1-5中任一项的抗穿刺材料，其中第一组线由芳族聚酰胺线组成，并且第二组线由聚酯线组成。
7.权利要求1-6中任一项的抗穿刺材料，其中第一组线的线密度为420-3360，优选420-1680分特，并最优选840-1100分特。
8.权利要求1-6中任一项的抗穿刺材料，其中第二组线的线密度为50-280分特，并优选80-140分特。
9.权利要求1-8中任一项的抗穿刺材料，其中第一组线是经线，并且第二组线是纬线。
10.权利要求1-9中任一项的抗穿刺材料，其中为该材料外侧的至少一侧提供一保护层。
11.由权利要求1-10中任一项抗穿刺材料制造的物品。
CN00802900A 1999-01-18 2000-01-12 含高线密度比两组线的织物的抗穿透材料 Expired - Fee Related CN1121519C (zh)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1816728B (zh) * 2003-07-01 2011-05-25 小罗伯特·L·马勒 铠装、特别是人体铠装
CN103518016A (zh) * 2011-03-25 2014-01-15 霍尼韦尔国际公司 改进单向复合物的加工性能的方法
CN105073665A (zh) * 2013-04-09 2015-11-18 贝卡尔特公司 耐热织带
CN105189843A (zh) * 2013-03-15 2015-12-23 霍尼韦尔国际公司 防刺和防弹制品及其制造方法
CN109016745A (zh) * 2018-07-17 2018-12-18 深圳多哚新技术有限责任公司 一种复合遮光布和虚拟现实设备的遮光组件

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1110052B1 (en) * 1999-03-12 2007-08-22 Simula, Inc. Improved fabric armor
US6668868B2 (en) * 2000-08-30 2003-12-30 Warwick Mills, Inc Woven fabric constructions having high cover factors and fill yarns with a weight per unit length less than the weight per unit length of warp yarns of the fabric
US6559079B1 (en) * 2000-12-29 2003-05-06 Second Chance Body Armor, Inc. Thin and lightweight ballistic resistant pad with groups of angularly displaced woven sheets and method
PT1241432E (pt) 2001-03-15 2006-12-29 Teijin Twaron Gmbh Material resistente a penetração compreendo um tecido com elevada razão de densidade linearde dois conjuntos de fios
US6610617B2 (en) * 2001-04-12 2003-08-26 E. I. Du Pont De Nemours And Company Ballistic resistant article
KR100956150B1 (ko) * 2001-05-03 2010-05-06 바데이 인코포레이티드 방탄 용도의 준단방향 직물
US20110314589A1 (en) * 2001-08-27 2011-12-29 Vito Robert A Vibration dampening material
US6922847B2 (en) 2002-07-26 2005-08-02 Second Chance Body Armor, Inc. Multipurpose thin and lightweight stab and ballistic resistant body armor and method
SI1396572T1 (sl) * 2002-09-06 2006-10-31 Teijin Twaron Gmbh Postopek za pripravo hidrofobno obdelane aramidnetkanine in njena uporaba
EP1396698A1 (en) * 2002-09-06 2004-03-10 Teijin Twaron GmbH Penetration-restistant material and articles made of the same
IL152006A0 (en) * 2002-09-30 2003-07-31 Rabintex Ind Ltd Shell for ballistic helmet
CA2524053C (en) 2003-05-08 2011-04-12 Teijin Twaron Gmbh Flexible penetration-resistant package and use thereof
US20050053756A1 (en) * 2003-09-05 2005-03-10 Axelrod Glen S. High strength fiber/fabric/film based animal toy
US7078443B2 (en) * 2003-10-22 2006-07-18 Intellectual Property Holdings, Llc Viscoelastic foam layer and composition
JP2007520371A (ja) 2004-01-01 2007-07-26 ディーエスエム アイピー アセッツ ビー．ブイ． 耐弾物品
EP2051038A3 (en) * 2004-07-02 2009-12-02 DSM IP Assets B.V. Flexible ballistic-resistant assembly
DE102005022868A1 (de) * 2005-05-18 2006-11-23 Boeckmann, Volker A. Einlage für Rückhaltewand auf Stück- und Massengutaufbauten für Land- und Wasserfahrzeuge
EP1896255B1 (en) 2005-06-30 2010-05-05 DSM IP Assets B.V. Ballistic-resistant article
US20070232173A1 (en) * 2005-09-13 2007-10-04 Bain Allan D Non-plain-woven laminated structures
ITMI20052019A1 (it) * 2005-10-24 2007-04-25 Lanzi Egisto S P A Soletta antinfortunistica
MX2008013693A (es) 2006-04-26 2008-12-17 Dsm Ip Assets Bv Material laminar multi-estratificado y proceso para su preparacion.
CA2650440C (en) 2006-04-26 2015-06-23 Dsm Ip Assets B.V. Multilayered material sheet and process for its preparation
EP1908581A1 (en) * 2006-10-05 2008-04-09 Novameer B.V. Process for producing fabrics comprising unidirectionally arranged polymeric tapes
EP2047975A1 (en) * 2007-10-09 2009-04-15 Novameer B.V. Advanced antiballistic materials
AU2008317960B2 (en) 2007-10-31 2014-07-10 Dsm Ip Assets B.V. Material sheet and process for its preparation
US20100275764A1 (en) * 2007-12-28 2010-11-04 Egres Jr Ronald G Fabric architectures for improved ballistic impact performance
US20100003452A1 (en) 2008-04-29 2010-01-07 Dsm Ip Assets B.V. Stack of first and second layers, a panel and ballistic resistant article comprising the stack or panel
TWI487820B (zh) * 2008-05-26 2015-06-11 Teijin Aramid Gmbh 阻礙穿刺之物品
US20100154621A1 (en) * 2008-11-11 2010-06-24 University Of Delaware Ballistic Resistant Fabric Armor
ITFI20080245A1 (it) * 2008-12-22 2010-06-23 Manifattura Pri Ma Tex S R L Articolo tessile anti-perforazione tri-strato.
JP2012524678A (ja) 2009-04-23 2012-10-18 ディーエスエム アイピー アセッツ ビー．ブイ． 圧縮シート
ITMI20090863A1 (it) * 2009-05-18 2010-11-19 Lenzi Egisto Spa Indumento antiproiettile ed antilama, e struttura protettiva in materiale tessile multistrato
CN101881582B (zh) * 2009-12-09 2015-03-25 湖南中泰特种装备有限责任公司 一种防刺防弹材料及制备方法
US20110185463A1 (en) * 2010-01-29 2011-08-04 Safariland, Llc Soft Body Armor Including Reinforcing Strips
WO2012004392A1 (en) 2010-07-08 2012-01-12 Dsm Ip Assets B.V. Ballistic resistant article
KR101887712B1 (ko) 2010-07-29 2018-08-10 디에스엠 아이피 어셋츠 비.브이. 방탄 제품
CA2820423C (en) 2010-12-14 2018-09-11 Dsm Ip Assets B.V. Tape and products containing the same
US9623626B2 (en) 2012-02-28 2017-04-18 Dsm Ip Assets B.V. Flexible composite material and use hereof, process for making a flexible composite material
EP2794258B1 (en) 2011-12-19 2018-03-21 DSM IP Assets B.V. Flexible composite material and use hereof, process for making a flexible composite material
CN102530563B (zh) * 2012-01-13 2015-05-20 吉梦琦 用于高温粉体输送设备上的透气层
ITMI20120244A1 (it) * 2012-02-20 2013-08-21 Automobili Lamborghini Spa Tessuto in fibra di carbonio e processo per la sua fabbricazione
US10900148B2 (en) * 2013-03-13 2021-01-26 Warwick Mills, Inc. Protective mid-cover textiles
US10443160B2 (en) 2013-03-15 2019-10-15 Honeywell International Inc. Breathable light weight unidirectional laminates
US9243355B2 (en) 2013-03-15 2016-01-26 Honeywell International Inc. Ballistic resistant thermoplastic sheet, process of making and its applications
BR112018005306B1 (pt) 2015-09-18 2022-04-26 Dsm Ip Assets B.V. Folha pré-formada, conjunto das mesmas e artigo à prova de balas
PL3397446T3 (pl) 2015-12-28 2021-01-25 Dsm Ip Assets B.V. Sposób wytwarzania taśmy polimerowej z proszku
KR20190013817A (ko) * 2016-05-25 2019-02-11 데이진 아라미드 게엠베하 내관통성 물체
JP2018021290A (ja) * 2016-07-25 2018-02-08 株式会社Ｉｔｏｉ生活文化研究所 和紙糸を用いた生地、これを用いたシューズ、および、これを用いたレザーシューズ
WO2018102397A1 (en) 2016-11-29 2018-06-07 PureTech Health LLC Exosomes for delivery of therapeutic agents
WO2018114266A1 (en) 2016-12-21 2018-06-28 Dsm Ip Assets B.V. Ballistic-resistant assembly
BR112019020478B1 (pt) * 2017-03-31 2023-02-23 Societa' Per Azioni Fratelli Citterio Laminado balístico compreendendo elementos têxteis nos quais fios balísticos cruzam fios não balísticos e estrutura de proteção balística que compreende o dito laminado
CN107323012A (zh) * 2017-07-17 2017-11-07 太仓市特灵化纤有限公司 一种双层复合编织保健益身面料
WO2019034866A1 (en) 2017-08-14 2019-02-21 Bicyclerd Limited BICYCLIC PEPTIDE LIGANDS CONJUGATES AND USES THEREOF
WO2020035096A1 (es) * 2018-08-13 2020-02-20 Michel Baikrich Panel estructurado por una combinación de resina y/o peliculas de termoendurecibles y/o termoestables de melamina con telas tejidas y no tejidas con fibras naturales, sintéticas, poliméricas y/o minerales
KR102128105B1 (ko) * 2019-05-29 2020-06-29 삼성교역(주) 다양한 색상과 우수한 강도를 가지는 이중직 구조의 방호원단
RU2725198C1 (ru) * 2020-02-03 2020-06-30 Закрытое акционерное общество "Научно-производственное объединение специальных материалов" (ЗАО "НПО СМ") Способ получения баллистической ткани для изготовления пулестойкого материала и пулестойкий материал
WO2022038158A1 (en) 2020-08-17 2022-02-24 Bicycletx Limited Bicycle conjugates specific for nectin-4 and uses thereof
WO2022120353A1 (en) 2020-12-02 2022-06-09 Ikena Oncology, Inc. Tead inhibitors and uses thereof
WO2023211889A1 (en) 2022-04-25 2023-11-02 Ikena Oncology, Inc. Polymorphic compounds and uses thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61275440A (ja) * 1985-05-31 1986-12-05 宇部興産株式会社 防弾衣用の耐弾織布
US5229199A (en) * 1985-08-13 1993-07-20 E. I. Du Pont De Nemours And Company Rigid composite comprising woven aramid fabrics coated with an adhesion modifier and embedded in a matrix resin
JPH0799314B2 (ja) * 1986-09-22 1995-10-25 東洋紡績株式会社 耐衝撃性部材
US4748996A (en) * 1987-02-06 1988-06-07 J. B. Martin Company Woven multilayered textile fabrics and attendant method of making
EP0310199A1 (en) * 1987-10-02 1989-04-05 Stamicarbon B.V. Bulletproof woven fabric
JPH0195297A (ja) * 1987-10-05 1989-04-13 Asahi Chem Ind Co Ltd 防弾衣用の耐弾織布
JPH035099U (zh) * 1989-05-22 1991-01-18
JPH0369628A (ja) * 1989-08-08 1991-03-26 Toyobo Co Ltd 複合材成形用基布
US5198280A (en) * 1990-10-25 1993-03-30 Allied-Signal Inc. Three dimensional fiber structures having improved penetration resistance
US5187003A (en) * 1991-11-26 1993-02-16 E. I. Du Pont De Nemours And Company Hybrid ballistic fabric
CZ303692A3 (cs) * 1992-10-06 1993-01-13 Vyzk Ustav Pletarsky A S Neprůstřelná vložka do ochranných vest a způsob její výroby
US5275873A (en) * 1992-12-10 1994-01-04 E. I. Du Pont De Nemours And Company Ballistic structure
JPH0754241A (ja) * 1993-08-18 1995-02-28 Toyobo Co Ltd 複合材成形用の基布
US5976996A (en) * 1996-10-15 1999-11-02 Warwick Mills, Inc. Protective fabric having high penetration resistance
JP3102295B2 (ja) * 1995-04-03 2000-10-23 東レ株式会社 補強用織物およびその製造方法
US5789327A (en) * 1995-08-28 1998-08-04 Rousseau; Wm. Richard Armor panel
RU2096542C1 (ru) * 1996-01-16 1997-11-20 Товарищество с ограниченной ответственностью Производственное предприятие "Терлон" Защитная ткань
US5960470A (en) * 1996-08-02 1999-10-05 Second Chance Body Armor, Inc. Puncture resistant protective garment and method for making same
GB2317622A (en) * 1996-09-28 1998-04-01 Wright M & Sons Ltd Anti-ballistic fabric

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1816728B (zh) * 2003-07-01 2011-05-25 小罗伯特·L·马勒 铠装、特别是人体铠装
CN103518016A (zh) * 2011-03-25 2014-01-15 霍尼韦尔国际公司 改进单向复合物的加工性能的方法
CN105189843A (zh) * 2013-03-15 2015-12-23 霍尼韦尔国际公司 防刺和防弹制品及其制造方法
CN105189843B (zh) * 2013-03-15 2018-02-06 霍尼韦尔国际公司 防刺和防弹制品及其制造方法
CN105073665A (zh) * 2013-04-09 2015-11-18 贝卡尔特公司 耐热织带
CN105073665B (zh) * 2013-04-09 2017-10-20 贝卡尔特公司 耐热织带
CN109016745A (zh) * 2018-07-17 2018-12-18 深圳多哚新技术有限责任公司 一种复合遮光布和虚拟现实设备的遮光组件
CN109016745B (zh) * 2018-07-17 2021-01-01 深圳多哚新技术有限责任公司 一种复合遮光布和虚拟现实设备的遮光组件

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KR100697544B1 (ko) 2007-03-21
EP1144740A1 (en) 2001-10-17
RU2217531C2 (ru) 2003-11-27
CZ299419B6 (cs) 2008-07-23
DK1144740T3 (da) 2004-02-23
AU758613B2 (en) 2003-03-27
NO317268B1 (no) 2004-09-27
HRP20010540B1 (en) 2004-12-31
WO2000042246A1 (en) 2000-07-20
CN1121519C (zh) 2003-09-17
HRP20010540A2 (en) 2002-12-31
PL348777A1 (en) 2002-06-17
JP4559634B2 (ja) 2010-10-13
NO20013359L (no) 2001-07-06
CA2359965C (en) 2006-07-25

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