CN1326949C - 颜料颗粒 - Google Patents
颜料颗粒 Download PDFInfo
- Publication number
- CN1326949C CN1326949C CNB038029049A CN03802904A CN1326949C CN 1326949 C CN1326949 C CN 1326949C CN B038029049 A CNB038029049 A CN B038029049A CN 03802904 A CN03802904 A CN 03802904A CN 1326949 C CN1326949 C CN 1326949C
- Authority
- CN
- China
- Prior art keywords
- pigment
- pigments
- granules
- additives
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 180
- 239000000654 additive Substances 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims abstract description 10
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 5
- 239000011147 inorganic material Substances 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 239000011368 organic material Substances 0.000 claims abstract description 4
- 238000004040 coloring Methods 0.000 claims abstract description 3
- 239000008187 granular material Substances 0.000 claims description 33
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 11
- 150000001412 amines Chemical class 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000003595 mist Substances 0.000 claims description 7
- 230000001588 bifunctional effect Effects 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 238000001238 wet grinding Methods 0.000 claims description 4
- 238000012644 addition polymerization Methods 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 abstract description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 239000000975 dye Substances 0.000 description 12
- -1 polyoxyethylene Polymers 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229940087291 tridecyl alcohol Drugs 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- CCTFMNIEFHGTDU-UHFFFAOYSA-N 3-methoxypropyl acetate Chemical compound COCCCOC(C)=O CCTFMNIEFHGTDU-UHFFFAOYSA-N 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N alpha-naphthol Natural products C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- MMXSKTNPRXHINM-UHFFFAOYSA-N cerium(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Ce+3].[Ce+3] MMXSKTNPRXHINM-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- HNMCSUXJLGGQFO-UHFFFAOYSA-N hexaaluminum;hexasodium;tetrathietane;hexasilicate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].S1SSS1.S1SSS1.[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] HNMCSUXJLGGQFO-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- CZIRZNRQHFVCDZ-UHFFFAOYSA-L titan yellow Chemical compound [Na+].[Na+].C1=C(C)C(S([O-])(=O)=O)=C2SC(C3=CC=C(C=C3)/N=N/NC3=CC=C(C=C3)C3=NC4=CC=C(C(=C4S3)S([O-])(=O)=O)C)=NC2=C1 CZIRZNRQHFVCDZ-UHFFFAOYSA-L 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- 239000012463 white pigment Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- AZXGXVQWEUFULR-UHFFFAOYSA-N 2',4',5',7'-tetrabromofluorescein Chemical compound OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 AZXGXVQWEUFULR-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- CAYHVMBQBLYQMT-UHFFFAOYSA-N 2-decyltetradecan-1-ol Chemical compound CCCCCCCCCCCCC(CO)CCCCCCCCCC CAYHVMBQBLYQMT-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- FIWYWGLEPWBBQU-UHFFFAOYSA-N 2-heptylphenol Chemical compound CCCCCCCC1=CC=CC=C1O FIWYWGLEPWBBQU-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
- ABMULKFGWTYIIK-UHFFFAOYSA-N 2-hexylphenol Chemical compound CCCCCCC1=CC=CC=C1O ABMULKFGWTYIIK-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- UVNKQUXHHOZJLS-UHFFFAOYSA-N 2-undecylphenol Chemical compound CCCCCCCCCCCC1=CC=CC=C1O UVNKQUXHHOZJLS-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 239000004440 Isodecyl alcohol Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
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- 229920002359 Tetronic® Polymers 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
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- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
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- YJVBLROMQZEFPA-UHFFFAOYSA-L acid red 26 Chemical compound [Na+].[Na+].CC1=CC(C)=CC=C1N=NC1=C(O)C(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=C12 YJVBLROMQZEFPA-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
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- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
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- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
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- 229950011260 betanaphthol Drugs 0.000 description 1
- DPSWNBLFKLUQTP-UHFFFAOYSA-N bismuth vanadium Chemical compound [V].[Bi] DPSWNBLFKLUQTP-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
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- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
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- PGWFQHBXMJMAPN-UHFFFAOYSA-N ctk4b5078 Chemical compound [Cd].OS(=O)(=O)[Se]S(O)(=O)=O PGWFQHBXMJMAPN-UHFFFAOYSA-N 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- VAPILSUCBNPFBS-UHFFFAOYSA-L disodium 2-oxido-5-[[4-[(4-sulfophenyl)diazenyl]phenyl]diazenyl]benzoate Chemical compound [Na+].[Na+].Oc1ccc(cc1C([O-])=O)N=Nc1ccc(cc1)N=Nc1ccc(cc1)S([O-])(=O)=O VAPILSUCBNPFBS-UHFFFAOYSA-L 0.000 description 1
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 1
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- 239000004744 fabric Substances 0.000 description 1
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- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
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- 230000006641 stabilisation Effects 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- NZFNXWQNBYZDAQ-UHFFFAOYSA-N thioridazine hydrochloride Chemical compound Cl.C12=CC(SC)=CC=C2SC2=CC=CC=C2N1CCC1CCCCN1C NZFNXWQNBYZDAQ-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
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- 239000002023 wood Substances 0.000 description 1
- UQMZPFKLYHOJDL-UHFFFAOYSA-N zinc;cadmium(2+);disulfide Chemical compound [S-2].[S-2].[Zn+2].[Cd+2] UQMZPFKLYHOJDL-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0002—Grinding; Milling with solid grinding or milling assistants
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/045—Agglomeration, granulation, pelleting
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- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0003—Drying, e.g. sprax drying; Sublimation of the solvent
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- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0022—Wet grinding of pigments
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- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0092—Dyes in solid form
- C09B67/0095—Process features in the making of granulates
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Abstract
本发明涉及平均粒度为50—5000μm且BET表面积为≤15m2/g的颜料颗粒，基本包括如下组分：(A)60—90重量%的至少一种颜料，和(B)10—40重量%的至少一种基于聚醚的非离子表面活性添加剂，生产所述颜料颗粒的方法以及对高分子量的有机和无机材料进行着色的方法。
Description
本发明涉及平均粒度为50-5000μm且BET表面积为≤15m2/g的新型颜料颗粒，包括如下组分作为基本成分：
(A)60-90重量％的至少一种颜料，和
(B)10-40重量％的至少一种基于聚醚的非离子表面活性添加剂。
本发明还涉及这些颜料颗粒的生产及其在高分子量的有机和无机材料着色中的用途。
液体体系如涂料、清漆、乳胶漆和印刷油墨通常使用颜料配制剂着色，所述颜料配制剂包含水、有机溶剂或其混合物。除了阴离子、阳离子、非离子或两性分散剂外，这些颜料配制剂通常必须添加用于稳定化的其他助剂，如干壳抑制剂、防冻性增强剂、增稠剂和防结皮剂。
需要在色彩性能和分散性上与液体配制剂相类似，但不要求所述添加并更易于处理的新型颜料制剂。然而，简单干燥液体配制剂不能提供具有类似应用性能的固体颜料制剂。
US-A-4 056 402和US-A-4 127 422描述了用于水性涂饰体系的干燥无尘颜料组合物。然而，这些颜料组合物除了非离子分散剂之外包括作为必要成分的至少10重量％水溶性纤维素醚或水分散性聚乙烯基化合物并因此不同于本发明的颜料颗粒。
EP-A-84 645和EP-A-403 917公开了用于着色水性、醇性和水性/醇性涂料和印刷油墨的高度浓缩的固体颜料配制剂，包括至多30重量％的基于至少双官能胺与氧化丙烯和氧化乙烯的反应产物的添加剂，但以细碎形式存在。
本发明的目的是提供具有全部有利的应用性能，尤其是高颜色强度和在宽范围的应用介质中特别良好的调入分散性的固体颜料制剂。
本发明提供了平均粒度为50-5000μm且BET表面积为≤15m2/g的颜料颗粒，包括如下组分作为基本成分：
(A)60-90重量％的至少一种颜料，和
(B)10-40重量％的至少一种基于聚醚的非离子表面活性添加剂。
本发明进一步提供了一种制备颜料颗粒的方法，包括在部分或所有添加剂(B)存在下在水悬浮液中湿磨颜料(A)并随后将所述悬浮液喷雾造粒，所述喷雾造粒可能的话在加入其余添加剂(B)之后进行。
本发明还进一步提供了一种对高分子量的有机和无机材料进行着色的方法，包括通过搅拌或振摇将颜料颗粒掺入这些材料中。
本发明的颜料颗粒包括作为基本成分的颜料(A)和非离子表面活性添加剂(B)。它们不含增稠剂，如纤维素醚以及成膜剂，如聚乙酸乙烯酯和醇。
本发明颜料颗粒的平均粒度为50-5000μm，尤其是100-1000μm。
本发明颜料颗粒的BET表面积为≤15m2/g，优选≤10m2/g。
本发明颜料颗粒中的组分(A)可以是有机颜料或无机颜料。应理解的是颜料颗粒还可包含各种有机颜料或各种无机颜料的混合物或有机颜料和无机颜料的混合物。
颜料以细碎形式存在。因此，颜料通常具有0.1-5μm的平均粒度。
有机颜料通常为有机彩色、白色和黑色颜料(有色颜料)。无机颜料同样可以是有色颜料且还有光泽颜料和通常用作填料的无机颜料。
下面给出合适有色有机颜料的实例：
-单偶氮颜料：C.I.颜料棕25；
C.I.颜料橙5，13，36，38，64和67；
C.I.颜料红1，2，3，4，5，8，9，12，17，22，23，31，48:1，48:2，48:3，48:4，49，49:1，51:1，52:1，52:2，53，53:1，53:3，57:1，58:2，58:4，63，112，146，148，170，175，184，185，187，191:1，208，210，245，247和251；
C.I.颜料黄1，3，62，65，73，74，97，120，151，154，168，181，183和191；
C.I.颜料紫32；
-双偶氮颜料：C.I.颜料橙16，34，44和72；
C.I.颜料黄12，13，14，16，17，81，83，106，113，126，127，155，174，176和188；
-双偶氮缩合颜料：C.I.颜料黄93，95和128；
C.I.颜料红144，166，214，220，221，242和262；
C.I.颜料棕23和41；
-二苯并[cd，jk]芘-5，10-二酮颜料：C.I.颜料红168；
-蒽醌颜料：C.I.颜料黄147，177和199；
C.I.颜料紫31；
-蒽嘧啶颜料：C.I.颜料黄108；
-喹吖啶酮颜料：C.I.颜料橙48和49；
C.I.颜料红122，202，206和209；
C.I.颜料紫19；
-奎诺酞酮颜料：C.I.颜料黄138；
-二酮基吡咯并吡咯颜料：C.I.颜料橙71，73和81；
C.I.颜料红254，255，264，270和272；
-二嗪颜料：C.I.颜料紫23和37；
C.I.颜料蓝80；
-黄烷士酮颜料：C.I.颜料黄24；
-阴丹酮颜料：C.I.颜料蓝60和64；
-异二氢吲哚颜料：C.I.颜料橙61和69；
C.I.颜料红260；
C.I.颜料黄139和185；
-异二氢吲哚酮颜料：C.I.颜料黄109，110和173；
-异宜和蓝酮颜料：C.I.颜料紫31；
-金属配合物颜料：C.I.颜料红257；
C.I.颜料黄117，129，150，153和177；
C.I.颜料绿8；
-苝酮颜料(Perinonpigmente)：C.I.颜料橙43；
C.I.颜料红194；
-苝系颜料：C.I.颜料黑31和32；
C.I.颜料红123，149，178，179，190和224；
C.I.颜料紫29；
-酞菁颜料：C.I.颜料蓝15，15:1，15:2，15:3，15:4，15:6和16；
C.I.颜料绿7和36；
-皮蒽酮颜料：C.I.颜料橙51；
C.I.颜料红216；
-吡唑并喹唑啉酮颜料：C.I.颜料橙67；
C.I.颜料红251；
-硫靛颜料：C.I.颜料红88和181；
C.I.颜料紫38；
-三芳基碳颜料：C.I.颜料蓝1，61和62；
C.I.颜料绿1；
C.I.颜料红81，81:1和169；
C.I.颜料紫1，2，3和27；
-C.I.颜料黑1(苯胺黑)；
-C.I.颜料黄101(醛连氮黄)；
-C.I.颜料棕22。
合适无机有色颜料的实例是：
-白色颜料：二氧化钛(C.I.颜料白6)，锌白，颜料级氧化锌；硫化锌，锌钡白；
-黑色颜料：氧化铁黑(C.I.颜料黑11)，铁锰黑，尖晶石黑(C.I.颜料黑27)；碳黑(C.I.颜料黑7)；
-彩色颜料：氧化铬，水合氧化铬绿；铬绿(C.I.颜料绿48)；钴绿(C.I.颜料绿50)；群青绿；
钴蓝(C.I.颜料蓝28和36；C.I.颜料蓝72)；群青蓝；锰蓝；
群青紫；钴紫；锰紫；
氧化铁红(C.I.颜料红101)；硫硒化镉(C.I.颜料红108)；硫化铈(C.I.颜料红265)；钼铬红(C.I.颜料红104)；群青红；
氧化铁棕(C.I.颜料棕6和7)，混合棕，尖晶石和刚玉相(C.I.颜料棕29，31，33，34，35，37，39和40)，铬钛黄(C.I.颜料棕24)，铬橙；
硫化铈(C.I.颜料橙75)；
氧化铁黄(C.I.颜料黄42)；镍钛黄(C.I.颜料黄53；C.I.颜料黄157，158，159，160，161，162，163，164和189)；铬钛黄；尖晶石相(C.I.颜料黄119)；硫化镉和硫化镉锌(C.I.颜料黄37和35)；铬黄(C.I.颜料黄34)，钒酸铋(C.I.颜料黄184)。
常用作填料的无机颜料的实例是透明的二氧化硅、磨碎的石英、氧化铝、氢氧化铝、硫化锌、天然云母、天然和沉淀白垩以及硫酸钡。
光泽颜料是具有单相或多相结构的片状颜料，其颜色变换因干涉、反射和吸收现象的相互作用而显著。实例是铝片和铝、氧化铁以及带有一种或多种涂层，尤其是金属氧化物涂层的云母片。
本发明的颜料颗粒中的组分(B)为至少一种基于聚醚的非离子表面活性添加剂。
除了未混合的聚氧化烯，尤其是聚氧化乙烯和聚氧化丙烯外，氧化烯嵌段共聚物尤其可以用作组分(B)。
包含聚氧化丙烯和聚氧化乙烯嵌段的共聚物非常合适。它们象未混合的聚氧化烯一样可以通过这些氧化烯在饱和或不饱和脂族和芳族醇以及脂族胺上的加聚而得到，此时这些起始剂化合物首先与氧化乙烯反应，然后与氧化丙烯反应，或优选首先与氧化丙烯反应，然后与氧化乙烯反应。因此优选的是，组分(B)包含氧化烯与胺或醇的加合物。
合适的脂族醇通常含有6-26个碳原子，优选8-18个碳原子。实例有辛醇、壬醇、癸醇、异癸醇、十一烷醇、十二烷醇、2-丁基辛醇、十三烷醇、异十三烷醇、十四烷醇、十五烷醇、十六烷醇、2-己基癸醇、十七烷醇、十八烷醇、2-庚基十一烷醇、2-辛基癸醇、2-壬基十三烷醇、2-癸基十四烷醇、油醇和9-十八烷醇以及这些醇的混合物如C13/C15和C16/C18醇。特别令人感兴趣的是通过油脂水解和还原而由天然原料得到的脂肪醇和来自羰基合成方法的合成脂肪醇。氧化烯与这些醇的加合物通常具有400-2000的平均分子量Mn。
有用的芳族醇除了α-和β-萘酚及其C1-C4烷基衍生物外还尤其包括苯酚及其C1-C12烷基衍生物，如己基苯酚、庚基苯酚、辛基苯酚、壬基苯酚、异壬基苯酚、十一烷基苯酚、十二烷基苯酚、二-和三-丁基苯酚以及二壬基苯酚。
有用的脂族胺对应于上述脂族醇。
除了氧化烯与这些单官能胺和醇的加合物外，氧化烯与至少双官能胺和醇的加合物非常令人感兴趣。
至少双官能胺优选具有2-5个胺基且尤其具有式H2N-(R-NR1)n-H(R：C2-C6亚烷基；R1：氢或C1-C6烷基；n：1-5)。具体实例是乙二胺、二亚乙基三胺、三亚乙基四胺、四亚乙基五胺、1，3-丙二胺、二亚丙基三胺、3-氨基-1-亚乙基氨基丙烷、六亚甲基二胺、二-六亚甲基三胺、1，6-双(3-氨基丙基氨基)己烷和N-甲基二亚丙基三胺，其中更优选六亚甲基二胺和二亚乙基三胺，最优选乙二胺。
这些胺优选首先与氧化丙烯反应，然后与氧化乙烯反应。嵌段共聚物的氧化乙烯含量通常为约10-90重量％。
基于聚胺的嵌段共聚物通常具有的平均分子量Mn为1000-40000，优选1500-30000。
至少双官能醇优选具有2-5个羟基。实例是C2-C6亚烷基二醇以及对应的二-和聚亚烷基二醇，如乙二醇、1，2-丙二醇、1，3-丙二醇、1，2-丁二醇、1，4-丁二醇、1，6-己二醇、二丙二醇和聚乙二醇、甘油和季戊四醇，其中更优选乙二醇和聚乙二醇，最优选丙二醇和二丙二醇。
特别优选的氧化烯与至少双官能醇的加合物具有中心聚氧化丙烯嵌段，即基于首先与进一步的氧化丙烯反应、然后与氧化乙烯反应的丙二醇或聚丙二醇。嵌段共聚物的氧化乙烯含量通常为10-90重量％。
基于多元醇的嵌段共聚物通常具有的平均分子量Mn为1000-20000，优选1000-15000。
因此，在一个优选实施方案中，组分(B)包含通过氧化丙烯和氧化乙烯与至少双官能胺或醇的依次加聚得到的嵌段共聚物。
这类氧化烯嵌段共聚物是已知的且可以市购，例如以商品名Tetronic和Pluronic(BASF)市购。
氧化烯嵌段共聚物(B)具有不同亲水-亲油平衡(HLB)值，这取决于在其中使用本发明颜料颗粒的应用介质。
为了用于水性、水性/醇性和醇性体系，优选具有的HLB值约为≥10的氧化烯嵌段共聚物(B)，其对应于共聚物的氧化乙烯含量通常≥25重量％。
为了将本发明的颜料颗粒在烃质，例如含矿物油的体系或二甲苯体系或基于硝基纤维素的体系中应用，特别合适的是HLB值为约＜10的氧化烯嵌段共聚物(B)，该HLB值对应于该共聚物的氧化乙烯含量通常＜25重量％。
本发明的颜料颗粒包括60-90重量％，优选70-85重量％的组分(A)和10-40重量％，优选10-30重量％的组分(B)。
它们可有利地通过在部分或所有非离子添加剂(B)存在下在水悬浮液中湿磨颜料(A)并随后将所述悬浮液喷雾造粒而由本发明方法得到，所述喷雾造粒可能的话在加入其余添加剂(B)之后进行。
颜料(A)可以干粉形式或滤饼形式用于本发明方法中。
所用颜料(A)是整理过的产品，即该颜料的初级粒度已经被调整到所需的应用值。尤其在有机颜料情况下，该整理是必需的，因为合成出的粗材料不适合使用。在无机颜料情况下，例如在氧化物和钒酸铋颜料情况下，初级粒度也可以在颜料合成过程中调节，从而可以将合成出的颜料悬浮液直接用于本发明方法中。
因为整理过的颜料(A)通常在干燥过程中或在过滤组件上再附聚，所以将其湿研磨，例如在搅拌介质磨中在水悬浮液中研磨。
湿研磨应在至少一部分用于易于生产的颜料颗粒的添加剂(B)存在下进行，并且优选在湿研磨之前加入全部量的添加剂(B)。
喷雾造粒优选使用同一材料喷嘴(Einstoffdüse)在喷雾塔中进行。此时将悬浮液以较大的液滴喷雾，并蒸发水。添加剂(B)在干燥温度下熔融并因此导致形成具有特别光滑的表面的基本球形颗粒。
在喷雾塔中的气体入口温度通常为180-300℃，优选150-300℃。气体出口温度通常为70-150℃，优选70-130℃。
得到的粒状颜料的残留水分含量通常为＜2重量％。
本发明的颜料颗粒尤其因其优异的着色性能以及尤其是其调入特性而具有显著的用途，这些着色性能与液体颜料配制剂相当，尤其是颜色强度、亮度、色调和遮盖力，搅入特性是指它们可以简单地通过搅拌或振摇而以最小的能量输入分散在应用介质中。
与液体颜料配制剂相比，本发明的颜料颗粒额外具有下列优点：它们具有更高的颜料含量。液体配制剂倾向于在储存过程中发生粘度变化且必须与防腐剂和用于提高防冻性和/或防干性的试剂混合，但本发明的颜料颗粒呈现非常良好的储存稳定性。它们就包装、储存和运输而言在经济上和生态上均是有利的。因为它们不含溶剂，因此在使用上更灵活。
本发明的颜料颗粒具有显著优异的抗磨性、最小的压缩或团聚倾向、均匀的粒度分布、良好的倾倒性、流动性和计量加入性以及处理和应用时的无尘性。
本发明的颜料颗粒对任何类型的高分子量的有机和无机材料的着色非常有用。此时的液体应用介质可以是纯水性的，包含水和有机溶剂如醇的混合物，或仅基于有机溶剂如醇，乙二醇醚，酮如甲基乙基酮，酰胺，如N-甲基吡咯烷酮和二甲基甲酰胺，酯如乙酸乙酯，乙酸丁酯和乙酸甲氧基丙基酯，或芳族或脂族烃，如二甲苯，矿物油和溶剂油。
当本发明的颜料颗粒所包含的添加剂(B)的HLB值如上所述不适合应用介质的特性时，可以首先将颗粒搅入与特定应用介质相容的溶剂中(以最小的能量输入搅入溶剂中再次成为可能)，然后将其引入该应用介质中。例如，具有高HLB值的颜料颗粒在二醇或常用于油漆和涂料工业的其他溶剂如乙酸甲氧基丙基酯中的淤浆可以用于使颜料颗粒与烃质体系或基于硝基纤维素的体系相容。
可以用本发明的颜料颗粒着色的材料的实例包括涂料，例如建筑涂料、工业涂料、汽车涂料、可辐射固化涂料；油漆，包括建筑外墙和建筑内墙用油漆，例如木漆、白漆、刷墙粉、乳胶漆；溶剂性印刷油墨，例如胶版印刷油墨，曲面印刷油墨，甲苯凹版印刷油墨，织物印刷油墨，可辐射固化油墨；水性油墨，包括喷墨油墨；彩色过滤器；建筑材料(通常仅在建筑材料和粒状颜料干混后加入水)，例如硅酸盐打底体系、水泥、混凝土、灰泥、石膏；沥青、堵缝胶；纤维素材料，例如纸张、纸板、硬纸板、木材和木质基材，它们各自可以被涂敷或涂饰；粘合剂；例如用于药物工业中的成膜聚合物保护性胶体；化妆品制品；洗涤剂。
实施例
本发明颜料颗粒的生产和测试
颜料颗粒通过将20kg(实施例1：35kg)添加剂(B)和80kg整理过的颜料(A)的悬浮液球磨至d50值为0.8μm，然后将该混合物使用单一材料喷嘴在喷雾塔中喷雾造粒(气体入口温度170℃，气体出口温度80℃)而生产。
颜料颗粒的颜色强度在水性乳胶漆中以白色稀释体系(报道为DIN55986着色当量(CE))比色测定。为此，在每种情况下将1.25g粒状颜料和50g具有16.4重量％的白色颜料含量(TiO2，Kronos 2043)(BASF测试粘合剂00-1067)的水性苯乙烯-丙烯酸酯基测试粘合剂的混合物在150ml塑料烧杯中通过以1500rpm运行高速搅拌机3分钟而均化。然后使用100μm线绕膜施涂器将所得色浆施涂于黑色和白色试验卡上并干燥30分钟。
将使用颜料的市售含水配制剂生产的对应乳胶漆的CE值设定为标准值100。CE值＜100是指颜色强度高于该标准值，CE值＞100因此是指更低的颜色强度。
下表列出了所生产的颜料颗粒的详情(组成、d50平均粒度、BET表面积)以及各自所得的CE值。所用非离子添加剂(B)如下：
B1：基于乙二胺/氧化丙烯/氧化乙烯的嵌段共聚物，氧化乙烯含量为40重量％且平均分子量Mn为12000
B2：基于乙二胺/氧化丙烯/氧化乙烯的嵌段共聚物，氧化乙烯含量为40重量％且平均分子量Mn为6700
B3：具有中心氧化丙烯嵌段的氧化丙烯/氧化乙烯嵌段共聚物，氧化乙烯含量为50重量％且平均分子量Mn为6500
表
| 实施例号 | 颜料(A) | 添加剂(B) | d50[μm] | BET[m2/g] | CE |
| 1 | C.I.P.Y.42 | B1 | 330 | 4 | 110 |
| 2 | C.I.P.Y.74 | B3 | 270 | 2 | 108 |
| 3 | C.I.P.Y.138 | B3 | 280 | 1 | 105 |
| 4 | C.I.P.Y.184 | B1 | 300 | 1 | 105 |
| 5 | C.I.P.R.101 | B1 | 320 | 4 | 107 |
| 6 | C.I.P.R.112 | B1 | 330 | 1 | 106 |
| 7 | C.I.P.R.122 | B1 | 280 | 2 | 106 |
| 8 | C.I.P.V.19 | B1 | 270 | 1 | 108 |
| 9 | C.I.P.V.23 | B1 | 290 | 1 | 108 |
| 10 | C.I.P.B.15:2 | B2 | 300 | 3 | 109 |
| 11 | C.I.P.B.15:3 | B1 | 300 | 8 | 105 |
| 12 | C.I.P.G.7 | B1 | 280 | 1 | 107 |
| 13 | C.I.P.Bk.7 | B1 | 310 | 5 | 108 |
Claims (6)
1.平均粒度为50-5000μm且BET表面积为≤15m2/g的颜料颗粒，包括如下组分：
(A)60-90重量％的至少一种颜料，和
(B)10-40重量％的至少一种基于聚醚的非离子表面活性添加剂，并且该组分包含氧化烯与胺或醇的加合物，
所述颗粒可通过在部分或所有所述添加剂(B)存在下在水悬浮液中湿磨所述颜料(A)并随后将所述悬浮液喷雾造粒而得到，所述喷雾造粒可能的话在加入其余添加剂(B)之后进行。
2.如权利要求1所要求的颜料颗粒，其中所述组分(B)包含通过氧化丙烯和氧化乙烯与至少双官能胺或醇的依次加聚得到的嵌段共聚物。
3.一种生产如权利要求1或2所要求的颜料颗粒的方法，包括在部分或所有所述添加剂(B)存在下在水悬浮液中湿磨所述颜料(A)并随后将所述悬浮液喷雾造粒，所述喷雾造粒可能的话在加入其余添加剂(B)之后进行。
4.如权利要求3所要求的方法，其中所述喷雾造粒使用同一材料喷嘴在喷雾塔中进行。
5.一种对高分子量的有机和无机材料进行着色的方法，包括通过搅拌或振摇将如权利要求1或2所要求的颜料颗粒掺入这些材料中。
6.如权利要求5所要求的方法，用于对其中液相包含水、有机溶剂或水和有机溶剂的混合物的涂料、油漆、油墨、建筑材料和纤维素体系进行着色。
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| DE10204304A DE10204304A1 (de) | 2002-02-01 | 2002-02-01 | Pigmentgranulate |
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2003
- 2003-01-22 AT AT03734602T patent/ATE525441T1/de active
- 2003-01-22 JP JP2003564142A patent/JP2005526867A/ja active Pending
- 2003-01-22 WO PCT/EP2003/000591 patent/WO2003064540A1/de active Application Filing
- 2003-01-22 KR KR10-2004-7011563A patent/KR20040079953A/ko not_active Application Discontinuation
- 2003-01-22 CN CNB038029049A patent/CN1326949C/zh not_active Expired - Lifetime
- 2003-01-22 US US10/501,328 patent/US7198668B2/en not_active Expired - Lifetime
- 2003-01-22 EP EP03734602A patent/EP1474484B1/de not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2005526867A (ja) | 2005-09-08 |
| US20050090609A1 (en) | 2005-04-28 |
| US7198668B2 (en) | 2007-04-03 |
| KR20040079953A (ko) | 2004-09-16 |
| DE10204304A1 (de) | 2003-08-14 |
| CN1625586A (zh) | 2005-06-08 |
| EP1474484A1 (de) | 2004-11-10 |
| EP1474484B1 (de) | 2011-09-21 |
| ATE525441T1 (de) | 2011-10-15 |
| WO2003064540A1 (de) | 2003-08-07 |
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