CN1318379C - 制备α－甲基－β－酮酸酯的方法 - Google Patents

制备α－甲基－β－酮酸酯的方法 Download PDF

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Publication number
CN1318379C
CN1318379C CNB038164949A CN03816494A CN1318379C CN 1318379 C CN1318379 C CN 1318379C CN B038164949 A CNB038164949 A CN B038164949A CN 03816494 A CN03816494 A CN 03816494A CN 1318379 C CN1318379 C CN 1318379C
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CN
China
Prior art keywords
general formula
methyl
reaction
paraformaldehyde
ketoester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB038164949A
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English (en)
Chinese (zh)
Other versions
CN1735586A (zh
Inventor
西塚俊雄
栗原宽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Meiji Seika Kaisha Ltd
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Meiji Seika Kaisha Ltd
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Publication of CN1735586A publication Critical patent/CN1735586A/zh
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Publication of CN1318379C publication Critical patent/CN1318379C/zh
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB038164949A 2002-07-11 2003-07-11 制备α－甲基－β－酮酸酯的方法 Expired - Fee Related CN1318379C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP202214/2002 2002-07-11
JP2002202214 2002-07-11

Publications (2)

Publication Number Publication Date
CN1735586A CN1735586A (zh) 2006-02-15
CN1318379C true CN1318379C (zh) 2007-05-30

Family

ID=30112611

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038164949A Expired - Fee Related CN1318379C (zh) 2002-07-11 2003-07-11 制备α－甲基－β－酮酸酯的方法

Country Status (5)

Country Link
JP (1) JP4316499B2 (cg-RX-API-DMAC7.html)
CN (1) CN1318379C (cg-RX-API-DMAC7.html)
AU (1) AU2003280975A1 (cg-RX-API-DMAC7.html)
TW (1) TW200403221A (cg-RX-API-DMAC7.html)
WO (1) WO2004007420A1 (cg-RX-API-DMAC7.html)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009020211A1 (ja) * 2007-08-08 2009-02-12 Meiji Seika Kaisha, Ltd. α－メチル－β－ケトエステルの新規製造法
CN107188807A (zh) * 2017-07-10 2017-09-22 济南大学 阿拉伯糖制备乙酰丙酸乙酯的方法
CN110483290B (zh) * 2019-08-09 2022-05-31 上海应用技术大学 一种铜催化合成β-酮酸酯的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH560176A5 (en) * 1972-04-24 1975-03-27 Lonza Ag Ethyl alpha-methyl-aceto-acetate prodn. - from formaldehyde gas and acetoacetic ester contg. acetic anhydride and hydrogenation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3326635A1 (de) * 1983-07-23 1985-01-31 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von monomethylsubstituierten methylen-verbindungen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH560176A5 (en) * 1972-04-24 1975-03-27 Lonza Ag Ethyl alpha-methyl-aceto-acetate prodn. - from formaldehyde gas and acetoacetic ester contg. acetic anhydride and hydrogenation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
β-酮酸酯合成法的改进 吴安心等，化学试剂，第20卷第6期 1998 *

Also Published As

Publication number Publication date
TWI310031B (cg-RX-API-DMAC7.html) 2009-05-21
WO2004007420A1 (ja) 2004-01-22
AU2003280975A1 (en) 2004-02-02
TW200403221A (en) 2004-03-01
JP4316499B2 (ja) 2009-08-19
CN1735586A (zh) 2006-02-15
JPWO2004007420A1 (ja) 2005-11-10

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