CN1304685C - Transfer printing process of natural fiber fabric - Google Patents
Transfer printing process of natural fiber fabric Download PDFInfo
- Publication number
- CN1304685C CN1304685C CNB2004100410341A CN200410041034A CN1304685C CN 1304685 C CN1304685 C CN 1304685C CN B2004100410341 A CNB2004100410341 A CN B2004100410341A CN 200410041034 A CN200410041034 A CN 200410041034A CN 1304685 C CN1304685 C CN 1304685C
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- Prior art keywords
- transfer printing
- paper
- printing
- grey cloth
- stamp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000008569 process Effects 0.000 title claims abstract description 25
- 238000010023 transfer printing Methods 0.000 title claims abstract description 18
- 239000000835 fiber Substances 0.000 title abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000000975 dye Substances 0.000 claims abstract description 15
- 238000007639 printing Methods 0.000 claims abstract description 15
- 239000000985 reactive dye Substances 0.000 claims abstract description 7
- 239000003513 alkali Substances 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 229940095102 methyl benzoate Drugs 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- 230000007704 transition Effects 0.000 abstract description 4
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000007650 screen-printing Methods 0.000 abstract description 2
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010017 direct printing Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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- Coloring (AREA)
Abstract
A transfer printing process of natural fiber fabric comprises the following steps: coating the surface of the web; printing the surface of the roll paper to prepare transfer printing paper, wherein the dye adopted for printing is reactive dye; the grey cloth of the natural fiber fabric is soaked in alkali liquor and then dried by rolling, and the transfer printing paper and the grey cloth are pressurized, so that the dye on the paper is dissociated and transferred and infiltrated into the grey cloth. Because the water-soluble reactive dye is selected, the natural fiber fabric has good coloring and color fixing performance, and each fastness index is improved by 1-1.5 levels compared with that of direct screen printing. The printing process can print patterns with high definition and rich transition layers.
Description
Technical field
The present invention relates to a kind of transfering printing process of natural fabric.
Background technology
In the prior art, China Patent No. 96108188.0 discloses a kind of transfer printing pretreating agent and printing technology of natural fabric, by natural fabric is carried out preliminary treatment, closes the hydroxyl of natural fabric, utilize the distillation principle of water-insoluble dyestuff, under hot conditions, finish transfer printing.Pretreated shortcoming is to admit DISPERSE DYES at the skin formation thermoplastic film of natural fabric, or natural fabric carried out chemical modification, this can make the degradation such as moisture absorbing and sweat releasing, gas permeability of natural fabric, and the fastness and the feel of product all had certain influence.
Cotton cylinder transfering printing process is that used transfer paper is the wood-free paper of 76g/m2 with ROTARY SCREAM PRINTING machined transfer printing paper, and its shortcoming is to print transition effect good " photoengraving " pattern, stamp cost height.
Summary of the invention
The object of the present invention is to provide a kind of transfering printing process of natural fabric, it uses water-soluble reactive colour can carry out transfer printing on natural fabric.
Technical scheme of the present invention is:
A kind of transfering printing process of natural fabric
It comprises following operation
(1) coating operation is promptly carried out coating to the surface of roll web;
(2) revenue stamp process promptly carries out stamp to the surface of roll web, makes transfer printing paper, and the dyestuff that stamp adopted is a REACTIVE DYES;
(3) transfering process rolls after with dipping by lye driedly to the boiling-off cloth of natural fabric, transfer printing paper and grey cloth pressurization, make dyestuff on the paper dissociate out and shift and infiltrate to grey cloth inside.
The natural fabric of indication of the present invention comprises linings such as cotton, fiber crops, real silk, wool
The present invention compared with prior art has following advantage:
1, select water-soluble reactive colour for use, natural fabric is had good colouring and fixing property, color and luster is good, and every fastness index all improves the 1-1.5 level than direct screen printing.
2, revenue stamp process can be printed the pattern of high-resolution, transition levels are rich, and production cost is starkly lower than existing sex change transfer printing and cylinder shifting process.
3, the present invention has good dye uptake in process, so do not have loose colour in the water-washing process behind stamp, blowdown is low, has the good feature of environmental protection.
Description of drawings
Accompanying drawing is the working procedure processing figure of transfer printing; Wherein:
A is the large package car for evenness calender B for evenness calender C
1 is that lining 2 is lye tank (vat) for transfer printing paper 3
The specific embodiment
Grey cloth requires: boiling-off, refining becomes the mercerising lining in vain.
A kind of transfering printing process of natural fabric, it comprises following operation
(1) coating operation is promptly carried out coating to the surface of roll web;
(2) revenue stamp process promptly carries out stamp to the surface of roll web, makes transfer printing paper, and the dyestuff that stamp adopted is a REACTIVE DYES;
(3) transfering process rolls after with dipping by lye driedly to the grey cloth of natural fabric, transfer printing paper and grey cloth pressurization, make dyestuff on the paper dissociate out and shift and infiltrate to grey cloth inside.
Described coating comprises the composition of following weight proportion
Coating material: 1-50%
Non-ionic surface active agent: 1-20%
Preservative agent 1-10%
All the other are organic solvent.
Described coating material comprises stearate, polyethylene glycol, glycerol, third rare acid amides, polyoxyethylene carboxylate, methyl benzoate, acid amides, benzoic acid, described preservative agent is the mixture of benzoic acid, P-hydroxybenzoic acid vinegar, described solvent is one of methyl alcohol, acetone, butanone, industrial alcohol or its mixture, and non-ionic surface active agent is one of leveling agent o, polyoxyethylene nonylphenol ether, triethanolamine list sodium acid esters or its mixture.
The prescription of described alkali lye is
The NaOH:50-150 grams per liter
The Na2SiO3:50-100 grams per liter
All the other are water.
Specifically, the coating operation refers to a side surface of roll web is carried out coating; Its objective is in revenue stamp process, water-soluble active slurry and roll web are isolated, do not allow dyestuff infiltrate paper.Increase the smooth degree of roll web, avoid stamp being brought negative effect because of paper has fault.In transfer process, can drive dyestuff and break away from paper, transfer to well on the cloth base.
Revenue stamp process is the outer surface stamp in coating, and cylindrical fireworks adopt laser plate-making, and concrete parameter is as follows:
Diao Jiao: 80-180
Dimension: 30-90L/CM
Angle: 30-90 °
Dyestuff is selected list or reactive dyes with double active group, processes for use, for example: Sumifix Supra, Diamara SN, Remazol RR, Cibacromc etc.
Thickener is selected sodium alginate and derivative thereof, mixtures such as carboxymethyl cellulose for use.
Surfactant is selected non-ionic surface active agent for use, for example: leveling agent o, polyoxyethylene nonylphenol ether, triethanolamine list sodium acid esters.
It below is the weight ratio prescription of thickening agent
Dyestuff: 1-20%
Thickener: 10-50%
Surfactant: 1-10%
Buffer: 1-10%
All the other are water
Transfering process as shown in drawings, lining 1 at first is immersed in the lye tank (vat) 3, rolled through grey cloth behind the evenness calender A dried, again by the second road evenness calender B with transfer printing paper 2 and lining 1 pressurization, make dyestuff on the paper dissociate out and shift, infiltrate to lining inside.
Provide in the following table and adopt this technology stamp and adopt direct printing fastness difference.
Fabric variety 63 " (40 * 40) (133 * 72)
Variable color washing accounts for that the look unlubricated friction is wet to rub
Direct printing 3332
This technology 4.5 4.5 4.5 3.5
Can be improved preferably by this technology from the wet fastness of rubbing of the above printing with reactive dye of cotton as can be seen.
Printing effect
By the stamp of laser version cylindrical fireworks, the flower type is the straight colour bar versions of three chromatographys, requires centre of all kinds dark also evenly to the both sides gradual change, and the stack of moire transition position color produces the 3rd look of gradual change, the effect of similar photoengraving pattern, and this is that direct printing institute is inaccessible.
Claims (2)
1. the transfering printing process of a natural fabric, it comprises following operation
(1) coating operation is promptly carried out coating to the surface of roll web;
(2) revenue stamp process promptly carries out stamp to the surface of roll web, makes transfer printing paper, and the dyestuff that stamp adopted is a REACTIVE DYES;
(3) transfering process rolls after with dipping by lye driedly to the boiling-off cloth of natural fabric, transfer printing paper and grey cloth pressurization, make dyestuff on the paper dissociate out and shift and infiltrate to grey cloth inside;
It is characterized in that:
Described coating comprises the composition of following weight proportion
Coating material: 1-50%
Non-ionic surface active agent: 1-20%
Preservative agent 1-10%
All the other are organic solvent;
Described coating material comprises stearate, polyethylene glycol, glycerol, third rare acid amides, polyoxyethylene carboxylate, methyl benzoate, acid amides, benzoic acid, described preservative agent is the mixture of benzoic acid, P-hydroxybenzoic acid vinegar, described solvent is one of methyl alcohol, acetone, butanone, industrial alcohol or its mixture, and non-ionic surface active agent is one of leveling agent o, polyoxyethylene nonylphenol ether, triethanolamine list sodium acid esters or its mixture.
2. the transfering printing process of natural fabric according to claim 1, it is characterized in that: the prescription of described alkali lye is
The NaOH:50-150 grams per liter
The Na2SiO3:50-100 grams per liter
All the other are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100410341A CN1304685C (en) | 2004-06-16 | 2004-06-16 | Transfer printing process of natural fiber fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100410341A CN1304685C (en) | 2004-06-16 | 2004-06-16 | Transfer printing process of natural fiber fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1584196A CN1584196A (en) | 2005-02-23 |
| CN1304685C true CN1304685C (en) | 2007-03-14 |
Family
ID=34601542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100410341A Expired - Fee Related CN1304685C (en) | 2004-06-16 | 2004-06-16 | Transfer printing process of natural fiber fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1304685C (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100463805C (en) * | 2005-11-23 | 2009-02-25 | 上海迪纺纺织科技有限公司 | Technology for producing flexible plate transfer printed paper |
| CN100344830C (en) * | 2006-05-16 | 2007-10-24 | 上海迪纺纺织科技有限公司 | Pigment release agent for cold transfer printing paper |
| CN100560859C (en) * | 2007-07-24 | 2009-11-18 | 常州涵源新印花有限公司 | Natural fabric and polyamide fibre wet method transfer printing method |
| CN101148828B (en) * | 2007-07-31 | 2010-05-26 | 杭州万事利丝绸礼品有限公司 | Silk broadcloth thermal transfer printing method |
| CN101974859B (en) * | 2010-09-28 | 2012-11-14 | 刘静 | Method for transferring pattern of textile fabric |
| CN102080334B (en) * | 2010-12-21 | 2012-07-25 | 刘静 | Method for transferring fur indumentum patterns |
| CN102051729B (en) * | 2010-12-28 | 2012-09-05 | 达利丝绸（浙江）有限公司 | Silk chine weaving process and application thereof |
| CN102797175B (en) * | 2012-09-05 | 2015-12-16 | 长胜纺织科技发展(上海)有限公司 | Fixation integration transfer printing is steamed in dyestuff transfer and roasting |
| CN103689838B (en) * | 2013-12-19 | 2015-08-19 | 维柏思特衬布（南通）有限公司 | Lining production line and technique thereof |
| CN104264507A (en) * | 2014-09-24 | 2015-01-07 | 吴江市凌通纺织整理有限公司 | UV-fixing transfer printing method of chemical fiber fabrics |
| CN105780555B (en) * | 2016-03-31 | 2018-08-21 | 南通纺织丝绸产业技术研究院 | A kind of preparation method of transfer white discharge fabric |
| CN107190538B (en) * | 2017-06-02 | 2019-09-10 | 马鞍山市永运家纺有限公司 | A kind of wet transfer printing technique of polyester cotton |
| CN107881817A (en) * | 2017-10-19 | 2018-04-06 | 张逸 | A kind of yarn fabric of no sewage printing and dyeing |
| CN107723974A (en) * | 2017-10-19 | 2018-02-23 | 张逸 | It is a kind of to be shifted and colouring integrated apparatus without sewage printing and dyeing |
| CN107901644A (en) * | 2017-10-19 | 2018-04-13 | 张逸 | One kind is without sewage fabric printing method |
| CN108660815B (en) * | 2018-05-25 | 2021-06-29 | 苏州大学 | Real silk printed fabric and preparation method thereof |
| CN109023919A (en) * | 2018-08-01 | 2018-12-18 | 苏州市天翱特种织绣有限公司 | A kind of preparation method of nano-antiradiation fabric |
| CN115012231B (en) * | 2022-06-10 | 2023-09-19 | 广州迅捷数码科技有限责任公司 | Low-alkali base paste reactive digital printing method |
| CN115216979A (en) * | 2022-07-20 | 2022-10-21 | 临清三和纺织集团有限公司 | Pearlescent powder multicolor simultaneous printing process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138890C (en) * | 1998-08-26 | 2004-02-18 | 丹麦香港有限公司 | Pattern carrier for use in transfer pattern printing and the use of a non-crystalline saccharide syrup in a dispension for coating a paper web so as to abtain such a pattern carrier |
| CN1584195A (en) * | 2004-05-25 | 2005-02-23 | 赵阳 | Natural fabric roller transferring printing process |
-
2004
- 2004-06-16 CN CNB2004100410341A patent/CN1304685C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138890C (en) * | 1998-08-26 | 2004-02-18 | 丹麦香港有限公司 | Pattern carrier for use in transfer pattern printing and the use of a non-crystalline saccharide syrup in a dispension for coating a paper web so as to abtain such a pattern carrier |
| CN1584195A (en) * | 2004-05-25 | 2005-02-23 | 赵阳 | Natural fabric roller transferring printing process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1584196A (en) | 2005-02-23 |
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