CN100344830C - Pigment release agent for cold transfer printing paper - Google Patents
Pigment release agent for cold transfer printing paper Download PDFInfo
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- CN100344830C CN100344830C CNB2006100265811A CN200610026581A CN100344830C CN 100344830 C CN100344830 C CN 100344830C CN B2006100265811 A CNB2006100265811 A CN B2006100265811A CN 200610026581 A CN200610026581 A CN 200610026581A CN 100344830 C CN100344830 C CN 100344830C
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- Prior art keywords
- transfer printing
- printing paper
- release agent
- acrylic acid
- cold transfer
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/03—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by pressure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Paper (AREA)
- Decoration By Transfer Pictures (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a pigment release agent for cold transfer printing paper, which comprises components: 35wt% to 80 wt% of the copolymer of acrylic acid and styrene monomer, 0.05 wt% to 0.5 wt% of silicon dioxide, 0.2 wt% to 1.8 wt% of sulfonated castor oil, 0.1 wt% to 0.8 wt% of three-butonate, 5 wt% to 30 wt% of starch with thr etherification degree of 0.7 to 1.2 and balance of water. The pigment release agent has the production process: sodium bisulfite and potassium persulfate are added to the emulsion of an initiating agent under the condition of stirring, when the temperature is heat to 50 DEG C; the mixing liquid of butyl acrylate, acrylic acid and styrene monomer set by a formulation is added dropwisely into the emulsion of the initiating agent; polymerizing temperature rise is triggered to 70 DEG C to 85 DEG C; acrylic acid and styrene monomer and the emulsion of the initiating agent are reacted for 1 to 2 hours under the temperature, the copolymer of acrylic acid and styrene monomer is formed after mixing liquid of butyl acrylate; the sulfonated castor oil, the silicon dioxide, the three-butonate and the starch with the etherification degree of 0.7 to 1.2 are added to copolymerization emulsion, then water is added to be regulated into 100 wt%, and thus, the pigment release agent for cold transfer printing paper is formed. Transfer printing paper coated with the release agent has the function of shielding carriers, which not only has the advantages of good printing adaptability and good transitivity, but also simultaneously has the characteristics of imbibition prevention, weigh resistance, quick transfer printing of patterns to fabrics, moisture resistance and tear resistance required for adapting the production in the form of paper web, etc. in transfer printing.
Description
Technical field
The present invention relates to the dyeing industry in the textile industry, the prescription that specifically is meant a kind of pigment release agent for cold transfer printing paper is with synthetic.
Background technology
Transfer printing paper has become a kind of new method that dairy industry is decorated and printing in textiles is processed.It is earlier with printing process with suitable dye ink, the pattern or the literal of stamp wanted in the printshop on speciality paper, be printed to a kind of transfer printing paper, to the one side and the fabric driving fit of being printed of dyestuff be arranged on this transfer printing paper again, make dye ink break away from and peel off by the pressure effect from paper, with the pattern on the transfer printing paper or words transfer printing to fabric.Method for transfer printing can be divided into dried transfer printing at present, i.e. thermal transfer and pressure-sensitive transfer printing; Reached wet transfer printing, promptly cold transfer is peeled off with the solvent transfer and is peeled off this two big class of method.According to Japan's " process technology " " transfer printing " special edition in 1972 introduction, transfer printing is that the researcher of French Prouvost Masurel company found that before 14 years this technology was only applicable on the dacron fabric at that time.After this patent of method for transfer printing the earliest, through the time more than 8 years, just puts into production in nineteen sixty-eight reluctantly application in 1958, and this is a kind of sublimed method hot melt transfering printing process by the Sublistatic invention.Introduce according to Germany's " chemical fibre " 1973 the 8th phases, in the transfer printing paper supply side, the printing house off-the-shelf of layout and generation this two big class of objective converted products that the client provides pattern are voluntarily arranged, the fabric width of transfer printing paper is at 70-200cm.According to Britain's " tame association meeting will dyes " 1971 and Japan's " process technology " " transfer printing " special edition in 1972 introduction, during general sublimed method transfer printing, be transferred to dyestuff on the fabric from transfer printing paper, can not all be absorbed by fiber, total some dyestuff remains on fabric face and the paper substrate, it is lower to become transfering printing process Dry Sack rate, the main cause that the PRINTED FABRIC COLOR FASTNESS is relatively poor.Evidence is arranged, and below 200 ℃ or 200 ℃ the time, the dyestuff that can distil has 139 kinds, but only has 39 dyestuffs can be used for the manufacturing of transfer printing paper, and through the dyestuff of residual 20%--30% nearly on the paper substrate after the transfer printing.Therefore, in age afterwards, how the focus of the maximum of transfer printing is minimized dyestuff residual on the paper substrate, both helped saving cost with regard to being, help to solve of the pollution of dyestuff residue again, so just invented wet transfer printing technology environment.The sublimed method transfering printing process only can be handled the chemical fibre kind fabric, fabrics of polyester especially, and cellulose fibre has only the wet transfer printing of employing technology.For dyestuff can fully be shifted from transfer printing paper, want on paper substrate, to be coated with earlier last layer transfer layer or peel ply, as Japanese request of speciallyying permit a kind of hot melt transfevent separation layer of introducing in No. 22094 in 1970, its prescription is 30 parts of 100% phenolic resins, 3 parts of ethyl celluloses, 15 parts of powdered whitings, 15 parts of china clay, 37 parts of ethyl acetates are made into 100 parts.Be coated on this material on the paper substrate of transfer printing paper, as the transfer layer or the peel ply of transfer printing printing ink.After the seventies in last century, the transfer layer or the peel ply of multiple transfer printing printing ink have occurred, but its limitation has all been arranged, can not really intactly embody or be applied on the cold-transfer printing technology, be transferred to again on the various fibers.
Summary of the invention
Can't be applied to a difficult problem on the natural fabrics such as cotton and wool in order to solve present sublimed method or melt and dissolved method transfer printing, the separating treatment agent that patent of the present invention provides a kind of cold transfer printing paper to use, the cold transfer printing paper of after this separating treatment agent coating, making with separation layer, can be applied in cellulose fibre, azelons such as hair and silk, and it is on the natural fabric such as cotton, also can be used on the synthetic fabrics, and simple to operation.
Patent of the present invention solves the technical scheme that its technical problem adopts: a kind of pigment release agent for cold transfer printing paper, it is characterized in that filling a prescription by mass percentage and be: acrylic acid and styrene copolymer are 35%--80%, silica is 0.05%-0.5%, turkey red oil is 0.2%-1.8%, tributyl is 0.1%--0.8%, the starch of degree of etherification falling 0.7-1.2 is 5%--30%, and water adjusts to 100%.The copolymerization method of its acrylic acid and styrene copolymer and the production routine of isolating agent are: the emulsion with triethanolamine, lauryl sodium sulfate and water constitute, under stirring condition, add sodium hydrogensulfite and potassium peroxydisulfate, and be warmed up to 50 ℃ as initator; Butyl acrylate, acrylic acid and styrene monomer mixed liquor are added dropwise in this initator emulsion, and initiated polymerization is warming up to 70 ℃-85 ℃, under this temperature, after continuing to react 1h-2h, is acrylic acid and styrene copolymer; In acrylic acid and styrene copolymer emulsion, the starch of the turkey red oil that adding is filled a prescription by described mass percent, silica, tributyl, degree of etherification falling 0.7-1.2, water adjusts to 100%; Be the cold transfer printing paper isolating agent.This cold transfer printing paper isolating agent liquid that is creamy white, viscosity is 300-1600pa.s, examining the flow velocity of grace cup in the time of 25 ℃ is 20-50 second; The natural fabric that can be used for cotton, hair and silk, and on the synthetic fabrics of terylene, polyamide fibre and the acrylic fibers cold transfer printing paper and cold-transfer printing technology used.Because this cold transfer printing paper isolating agent is a kind of high-molecular copolymer, be coated on the paper substrate of transfer printing paper, can form a kind of similar membranaceous medium, can produce a kind of temporary shielding, make dyestuff when printing equipment printing pattern pattern, do not produce strong compatibility with the paper substrate of transfer printing paper.Simultaneously, the isolating agent used of this cold transfer printing paper can impel dye ink to peel off very soon to be transferred on the fabric.
The described transfer printing paper that scribbles isolating agent of patent of the present invention, effect with shielding carrier, good printing adaptability and metastatic are not only arranged, simultaneously when transfer printing, also have anti-imbibition, resistant to pressure, the quick transferring floral designs are to fabric, and adaptation roll web form is produced essential moisture resistance, characteristics such as anti tear.This transfer printing paper that scribbles isolating agent has also solved transfer printing paper when transfer printing, and the excessive difficult problem of dyestuff residual quantity has not only been saved dying material on the paper, and has reduced the pollution to environment.
The specific embodiment
Embodiment 1
Standard type pigment release agent (PE-2 type isolating agent)
With in the reactor, earlier 2.5g triethanolamine, 58g water and 1g lauryl sodium sulfate are injected the emulsion of making in experiment, under stirring condition, add 1g sodium hydrogensulfite and 0.5g potassium peroxydisulfate, be warmed up to 50 ℃ as initator; Butyl acrylate 400g, acrylic acid 40g and styrene 100g monomer mixed solution that prescription is set are added dropwise in the initator emulsion, behind the initiated polymerization, system is warming up to 70 ℃-85 ℃ automatically, under this temperature, after continuing reaction 1h-2h, promptly become acrylic acid and styrene copolymer.In this copolymer emulsion, add prescription and set turkey red oil 3g/kg, the gas phase grade silicon dioxide 3g/kg of percentage (adopting the high-specific surface area rate), add starch 250g (hydroxyl shields) and suitable quantity of water about degree of etherification falling 0.7-1.2 again, behind the above-mentioned substance that stirs, add tributyl 3g or wetting agent 2g again, last water is adjusted to 1000g (100%), is cold transfer printing paper with standard type pigment release agent (PE-2 type).This cold transfer printing paper isolating agent liquid that is creamy white, viscosity is 800-900pa.s, examines grace cup flow velocity 30-40 second.
Embodiment 2
Cotton type fabric pigment release agent for cold transfer printing paper
Fill a prescription by mass percentage:
Acrylic acid and styrene copolymer are 70%,
Silica is 0.3%,
Turkey red oil is 0.2%,
The starch of degree of etherification falling about 1.2 is 18%,
Tributyl is 0.4%,
Water adjusts to 100%.
In the industrial reactor, earlier 2.5kg triethanolamine, 58kg water and 1kg lauryl sodium sulfate are injected the emulsion of making, under stirring condition, add 1kg sodium hydrogensulfite and 0.5kg potassium peroxydisulfate, be warmed up to 50 ℃ as initator; Butyl acrylate 500kg, acrylic acid 50kg and styrene 150kg monomer mixed solution that prescription is set are added dropwise in the initator emulsion, behind the initiated polymerization, system is warming up to 70 ℃-85 ℃ automatically, under this temperature, after continuing reaction 1.5h, promptly become acrylic acid and styrene copolymer.In this copolymer emulsion, add prescription and set turkey red oil 2kg (0.2%), the gas phase grade silicon dioxide 3kg (0.3%) of percentage ((adopting the high-specific surface area rate), the starch 180kg (hydroxyl shields) and an amount of distilled water that add degree of etherification falling about 1.2 again, behind the above-mentioned substance that stirs, add tributyl 4kg (0.4%) again, adjust to 1000kg with distilled water at last, be cold transfer printing paper with cotton type pigment release agent.This cold transfer printing paper isolating agent liquid that is creamy white, viscosity is 900pa.s, examines grace cup flow velocity about 40 seconds.
Embodiment 3
Wool (protide fiber) type fabric pigment release agent for cold transfer printing paper
Fill a prescription by weight percentage:
Acrylic acid and styrene copolymer are 50%,
Silica is 0.2%,
Turkey red oil is 0.4%,
The starch of degree of etherification falling about 1.2 is 25%,
Tributyl is 0.5%,
Water adjusts to 100%.
In the industrial reactor, earlier 2.5kg triethanolamine, 58kg water and 1kg lauryl sodium sulfate are annotated the emulsion that the people makes, under stirring condition, add 1kg sodium hydrogensulfite and 0.5kg potassium peroxydisulfate, be warmed up to 50 ℃ as initator; Butyl acrylate 340kg, acrylic acid 60kg and styrene 100kg monomer mixed solution that prescription is set are added dropwise in the initator emulsion, behind the initiated polymerization, system is warming up to 70 ℃-85 ℃ automatically, under this temperature, after continuing reaction 2h, promptly become acrylic acid and styrene copolymer.In this copolymer emulsion, add prescription and set turkey red oil (0.4%) 4kg, the gas phase grade silicon dioxide 2kg (0.2%) of percentage (adopting the high-specific surface area rate), the starch 250kg (hydroxyl shields) and an amount of distilled water that add degree of etherification falling about 1.2 again, behind the above-mentioned substance that stirs, add tributyl 5kg (0.5%) again, adjust to 1000kg with distilled water at last, be cold transfer printing paper wool type pigment release agent.This cold transfer printing paper is with the isolating agent liquid that is creamy white, and viscosity is 950--1100pa.s, examines grace cup flow velocity 30--35 second.
Embodiment 4
Synthetic fiber (terylene, polyamide fibre and acrylic fibers) type fabric pigment release agent for cold transfer printing paper
Fill a prescription by weight percentage:
Acrylic acid and styrene copolymer are 62%,
Silica is 0.4%,
Turkey red oil is 0.9%,
The starch of degree of etherification falling about 1 is 20%,
Tributyl is 0.7%,
Wetting agent PH316 emulsion is 2%,
Water adjusts to 100%.
In the industrial reactor, earlier 2.5kg triethanolamine, 58kg water and 1kg lauryl sodium sulfate are injected the emulsion of making, under stirring condition, add 1kg sodium hydrogensulfite and 0.5kg potassium peroxydisulfate, be warmed up to 50 ℃ as initator; Butyl acrylate 400kg, acrylic acid 40kg and styrene 180kg monomer mixed solution that prescription is set are added dropwise in the initator emulsion, behind the initiated polymerization, system is warming up to 70 ℃-85 ℃ automatically, under this temperature, after continuing reaction 1h-2h, promptly become acrylic acid and styrene copolymer.In this copolymer emulsion, add prescription and set turkey red oil 9kg (0.9%), the gas phase grade silicon dioxide 4kg (0.4%) of percentage (adopting the high-specific surface area rate), the starch 200kg (hydroxyl shields) and an amount of distilled water that add degree of etherification falling about 1.2 again, behind the above-mentioned substance that stirs, add wetting agent PH316-2kg (2%), tributyl 7kg (0.7%) again, adjust to 1000kg with distilled water at last, be cold transfer printing paper synthetic fiber type pigment release agent.This synthetic fiber type cold transfer printing paper isolating agent liquid that is creamy white, viscosity is 900pa.s, examines grace cup flow velocity 30--40 about second.
Claims (4)
1. pigment release agent for cold transfer printing paper, it is characterized in that: prescription is by mass percentage: acrylic acid and styrene copolymer are 35%--80%, silica is 0.05%-0.5%, turkey red oil is 0.2%-1.8%, tributyl is 0.1%--0.8%, the starch of degree of etherification falling 0.7-1.2 is 5%--30%, and water adjusts to 100%.
2. pigment release agent for cold transfer printing paper according to claim 1, it is characterized in that: the copolymerization method of described acrylic acid and styrene copolymer and the production routine of isolating agent are: triethanolamine, lauryl sodium sulfate and water are constituted emulsion, under stirring condition, add sodium hydrogensulfite and potassium peroxydisulfate, be warmed up to 50 ℃ as initator; Butyl acrylate, acrylic acid and styrene monomer mixed liquor are added dropwise in this initator emulsion, and initiated polymerization is warming up to 70 ℃-85 ℃, under this temperature, after continuing to react 1h-2h, is acrylic acid and styrene copolymer; The starch of the turkey red oil that adding is filled a prescription by described mass percent in acrylic acid and styrene copolymer emulsion, silica, tributyl, degree of etherification falling 0.7-1.2, water adjusts to 100%; Be pigment release agent for cold transfer printing paper.
3. pigment release agent for cold transfer printing paper according to claim 1 and 2 is characterized in that: this pigment release agent for cold transfer printing paper liquid that is creamy white, and viscosity is 300-1600pa.s, examining grace cup flow velocity in the time of 25 ℃ is 20-50 second.
4. pigment release agent for cold transfer printing paper according to claim 1 and 2, it is characterized in that: this pigment release agent for cold transfer printing paper is used for the natural fabric of cotton, hair and silk, and on the synthetic fabrics of terylene, polyamide fibre and the acrylic fibers cold transfer printing paper and cold-transfer printing technology used.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100265811A CN100344830C (en) | 2006-05-16 | 2006-05-16 | Pigment release agent for cold transfer printing paper |
| PCT/CN2006/003486 WO2007134499A1 (en) | 2006-05-16 | 2006-12-19 | Graft copolymer, process of preparation and use thereof, colorant release agent and articles thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100265811A CN100344830C (en) | 2006-05-16 | 2006-05-16 | Pigment release agent for cold transfer printing paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1844573A CN1844573A (en) | 2006-10-11 |
| CN100344830C true CN100344830C (en) | 2007-10-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100265811A Active CN100344830C (en) | 2006-05-16 | 2006-05-16 | Pigment release agent for cold transfer printing paper |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN100344830C (en) |
| WO (1) | WO2007134499A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302391B (en) * | 2007-05-09 | 2011-02-16 | 上海长胜纺织制品有限公司 | Connection material for cold transfer printing paper and preparation thereof |
| DK177321B1 (en) * | 2011-05-10 | 2013-01-02 | Skandinavisk HTP ApS | Paper for transfer pattern printing |
| CN109098022A (en) * | 2018-08-16 | 2018-12-28 | 浙江美格机械股份有限公司 | A kind of application method of transfer printing carrier coating and the coating |
| CN113145077A (en) * | 2021-03-24 | 2021-07-23 | 西安理工大学 | Epoxy modified starch baseFe3O4Method for preparing adsorbent material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168936A (en) * | 1997-05-14 | 1997-12-31 | 北京服装学院 | Material and method for transfer printing textiles |
| JPH10166745A (en) * | 1996-12-06 | 1998-06-23 | Sony Corp | Thermal transfer print sheet |
| CN1324418A (en) * | 1998-08-26 | 2001-11-28 | 丹麦香港有限公司 | Pattern carrier for use in transfer pattern printing and the use of a non-crystalline saccharide syrup in a dispension for coating a paper web so as to abtain such a pattern carrier |
| CN1584196A (en) * | 2004-06-16 | 2005-02-23 | 吴江市凌志纺织有限公司 | Transferring printing process for natural fabric |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4133193A1 (en) * | 1991-10-07 | 1993-04-08 | Basf Ag | WAFER POLYMERISATE DISPERSIONS |
| DE19806745A1 (en) * | 1998-02-18 | 1999-08-19 | Bayer Ag | Aqueous polymer dispersion useful as surface sizing agent for paper, cardboard etc. |
| US6090884A (en) * | 1998-05-07 | 2000-07-18 | S. C. Johnson Commercial Markets, Inc. | Starch degradation/graft polymerization composition, process, and uses thereof |
| DE10004893A1 (en) * | 2000-02-04 | 2001-08-16 | Bayer Ag | Two-component system for giving a stone-wash effect to dyed fabric of or containing cotton wool, comprises a cellulase(s) and an aqueous polymer dispersion comprising a styrene/(meth)acrylate copolymer grafted on starch |
| WO2004078807A2 (en) * | 2003-02-28 | 2004-09-16 | Dow Global Technologies Inc. | Starch-based polymers |
-
2006
- 2006-05-16 CN CNB2006100265811A patent/CN100344830C/en active Active
- 2006-12-19 WO PCT/CN2006/003486 patent/WO2007134499A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10166745A (en) * | 1996-12-06 | 1998-06-23 | Sony Corp | Thermal transfer print sheet |
| CN1168936A (en) * | 1997-05-14 | 1997-12-31 | 北京服装学院 | Material and method for transfer printing textiles |
| CN1324418A (en) * | 1998-08-26 | 2001-11-28 | 丹麦香港有限公司 | Pattern carrier for use in transfer pattern printing and the use of a non-crystalline saccharide syrup in a dispension for coating a paper web so as to abtain such a pattern carrier |
| CN1584196A (en) * | 2004-06-16 | 2005-02-23 | 吴江市凌志纺织有限公司 | Transferring printing process for natural fabric |
Non-Patent Citations (1)
| Title |
|---|
| 亲水性转移印花原纸的生产工艺实践 牛庆平，上海造纸，第34卷第4期 2003 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007134499A1 (en) | 2007-11-29 |
| CN1844573A (en) | 2006-10-11 |
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