CN110183925A - A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back - Google Patents

A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back Download PDF

Info

Publication number
CN110183925A
CN110183925A CN201910433880.4A CN201910433880A CN110183925A CN 110183925 A CN110183925 A CN 110183925A CN 201910433880 A CN201910433880 A CN 201910433880A CN 110183925 A CN110183925 A CN 110183925A
Authority
CN
China
Prior art keywords
coupling agent
heat transfer
solid material
material block
hydroxyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910433880.4A
Other languages
Chinese (zh)
Inventor
赵建设
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINXIANG XINBEIR INFORMATION MATERIAL CO Ltd
Original Assignee
XINXIANG XINBEIR INFORMATION MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINXIANG XINBEIR INFORMATION MATERIAL CO Ltd filed Critical XINXIANG XINBEIR INFORMATION MATERIAL CO Ltd
Priority to CN201910433880.4A priority Critical patent/CN110183925A/en
Publication of CN110183925A publication Critical patent/CN110183925A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of solid material blocks and preparation method thereof applied for heat transfer colour ribbon back, raw material including following weight percent: methyl methacrylate 30%-35%, isobornyl methacrylate 5%-10%, hydroxyl silane coupling agent 0.5%-1%, hydroxyl-terminated polydimethylsiloxane 7%-9%, 0.5%-1% containing amino silicane coupling agent, toluene 40%-45%, butanone 5%-10% and azodiisobutyronitrile 0.5%-1%, present invention employs vacuum drying methods to apply mother liquor solidification for back obtained for solid material block, facilitate the storage and transport of back coating material, it ensure that quality when back coating material uses.

Description

A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back
Technical field
The present invention relates to thermal transfer technology fields, and in particular to it is a kind of for heat transfer colour ribbon back apply solid material block and its Preparation method.
Background technique
Heat transfer colour ribbon is the basic consumptive material of thermal transfer technology, with the fast development of electronic computer industry, this heat The application field of quick consumable material is more and more wider, gradually expands to and can answer from the single temperature-sensitive typewriter applied to office realm The printing of bar code for multiple fields such as food, drugs plays increasingly important role in national economy.
Heat transfer colour ribbon carbon ribbon is generally made of three parts such as basement membrane, heat-resisting back coating, ink coatings, is printed in thermal transfer On machine, heat-resisting back coating is directly contacted with heat-transferring head, and thermal transfer ink is directly contacted with stock, heat-transferring head wink when work Between heat release, the heat of heat release point sends thermal transfer ink coating to by heat-resisting back coating and basement membrane, ink melt and by thermoprint Onto stock, text, image are formed, so there is heat-resisting back coating heat-insulated, reduction friction, reduction print head to attach dust, Print head is protected, the effect in the service life of print head is extended.
Heat-resisting back coating is to form layer protecting film, the back on existing market after being coated on the solidification of the basement membrane back side by back coating liquid Masking liquid is mostly to be formed with propylene using organic silicone oil, acrylate and some silane coupling agents (such as isocyanates coupling) The modified organic siliconresin of acid esters, then it will be dissolved in toluene, ethyl acetate equal solvent is made into solid containing generally 20%-30%'s Solution, however the low back coating liquid volume contained admittedly is big, all causes great inconvenience for storing and transporting, if but back coating liquid consolidate Containing excessively high, since resulting resin still has the unreacted active site in part, it may occur that further cross-linking reaction, The denaturation of resin is caused to fail to be unfavorable for storing.
Summary of the invention
It is an object of the invention to: can not be stored when for existing back coating liquid large arch dam, low reservoir volume containing when admittedly compared with Greatly, it is not easy to the problem of storing and transporting, a kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back is provided.
To solve the above problems, The technical solution adopted by the invention is as follows:
A kind of solid material block applied for heat transfer colour ribbon back, the raw material including following weight percent: methacrylic acid Methyl esters 30%-35%, isobornyl methacrylate 5%-10%, hydroxyl silane coupling agent 0.5%-1%, hydroxy-end capped silicon Rubber 7%-9%, 0.5%-1% containing amino silicane coupling agent, two isobutyl of toluene 40%-45%, butanone 5%-10% and azo Nitrile 0.5%-1%.
Preferably, the hydroxyl silane coupling agent are as follows: 3- methacryloxypropyl trimethoxy silane.
Preferably, described to contain amino silicane coupling agent are as follows: 3- aminopropyl triethoxysilane.
A kind of preparation method of the solid material block applied for heat transfer colour ribbon back:
(1) by methyl methacrylate, isobornyl methacrylate, hydroxyl silane coupling agent and methylbenzene raw material, It is added in reaction kettle by above-mentioned weight percent, dissolves azodiisobutyronitrile with appropriate butanone, reaction kettle is added after mixing In, 70-72 DEG C of reaction 2-3h of temperature control；
(2) by hydroxyl-terminated polydimethylsiloxane and containing amino silicane coupling agent, suitable fourth is dissolved in by above-mentioned weight percent It in ketone, is added in reaction kettle after mixing, after keeping the temperature 72 DEG C of sustained response 2-3h, closes heating, naturally cool to room temperature, Discharging, obtains semi-finished product；
(3) it by semi-finished product obtained by step (2), is put into vacuum oven in batches, it is dry at being 60 DEG C in temperature, often Drying time needed for 1kg semi-finished product is 1-2h, obtains white chunks product.
Preferably, cold-trap is provided with before the vacuum pump of the vacuum oven of the step (3).
Preferably, according to required ratio, solvent appropriate is added into the blocky back paint, low-grade fever is sufficiently stirred Dissolution can be used, and the solvent is toluene, any one in ethyl acetate.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
1, the present invention is made by the way that the solvent in back coating liquid to be drained to vacuum drying method and carries on the back painting solid material block, from And the reactivity site in system is controlled, and overcome can not storing for the solid back coating liquid that the prior art is produced, it is low to contain admittedly The disadvantages of back coating liquid reservoir volume is big, not readily transportable；
2, the present invention is made back by two-step method and applies mother liquor, and the first step is different by methyl methacrylate, methacrylic acid Norbornene ester, hydroxyl silane coupling agent synthetic resin main chain and control introduce hydroxyl amount, facilitate second step reaction molecular The control of amount prevents the appearance of excessive cross-linking reaction, avoids because of single step reaction, caused by synthetic resin structure be unfavorable for controlling The problem of broadening is easy with molecular weight distribution；
3, extracted solvent is condensed back to by the present invention by the way that cold-trap is arranged before the vacuum pump of vacuum oven It receives, effective utilization has been carried out to solvent, economizing on resources reduces cost.
Specific embodiment
All features disclosed in this specification can be with any other than mutually exclusive feature and/or step Mode combines.
Embodiment 1
A kind of solid material block applied for heat transfer colour ribbon back, the raw material including following weight percent: methacrylic acid Methyl esters 30%, isobornyl methacrylate 5%, hydroxyl silane coupling agent 0.5%, hydroxyl-terminated polydimethylsiloxane 7% contain amino Silane coupling agent 0.5%, toluene 40%, butanone 5%% and azodiisobutyronitrile 0.5%.
The hydroxyl silane coupling agent are as follows: 3- methacryloxypropyl trimethoxy silane.
It is described to contain amino silicane coupling agent are as follows: 3- aminopropyl triethoxysilane.
A kind of preparation method of the solid material block applied for heat transfer colour ribbon back:
(1) by methyl methacrylate, isobornyl methacrylate, hydroxyl silane coupling agent and methylbenzene raw material, It is added in reaction kettle by above-mentioned weight percent, dissolves azodiisobutyronitrile with appropriate butanone, reaction kettle is added after mixing In, temperature control 70 reacts 2h；
(2) by hydroxyl-terminated polydimethylsiloxane and containing amino silicane coupling agent, suitable fourth is dissolved in by above-mentioned weight percent It in ketone, is added in reaction kettle after mixing, after keeping the temperature 72 DEG C of sustained response 2h, closes heating, naturally cool to room temperature, out Material, obtains semi-finished product；
(3) it by semi-finished product obtained by step (2), is put into vacuum oven in batches, it is dry at being 60 DEG C in temperature, often Drying time needed for 1kg semi-finished product is 1h, obtains white chunks product.
Cold-trap is additionally provided with before the vacuum pump of the vacuum oven of the step (3).
A kind of application method of the solid material block applied for heat transfer colour ribbon back are as follows: according to required ratio, Xiang Suoshu Solvent appropriate is added in blocky back paint, low-grade fever dissolution, which is sufficiently stirred, can be used, and the solvent is toluene, in ethyl acetate Any one.
Embodiment 2
A kind of solid material block applied for heat transfer colour ribbon back, the raw material including following weight percent: methacrylic acid Methyl esters 32%, isobornyl methacrylate 8%, hydroxyl silane coupling agent 0.7%, hydroxyl-terminated polydimethylsiloxane 8% contain amino Silane coupling agent 0.8%, toluene 42%, butanone 8% and azodiisobutyronitrile 0.8%.
The hydroxyl silane coupling agent are as follows: 3- methacryloxypropyl trimethoxy silane.
It is described to contain amino silicane coupling agent are as follows: 3- aminopropyl triethoxysilane.
A kind of preparation method of the solid material block applied for heat transfer colour ribbon back:
(1) by methyl methacrylate, isobornyl methacrylate, hydroxyl silane coupling agent and methylbenzene raw material, It is added in reaction kettle by above-mentioned weight percent, dissolves azodiisobutyronitrile with appropriate butanone, reaction kettle is added after mixing In, 71 DEG C of reaction 2.5h of temperature control；
(2) by hydroxyl-terminated polydimethylsiloxane and containing amino silicane coupling agent, suitable fourth is dissolved in by above-mentioned weight percent It in ketone, is added in reaction kettle after mixing, after keeping the temperature 72 DEG C of sustained response 2.5h, closes heating, naturally cool to room temperature, Discharging, obtains semi-finished product；
(3) it by semi-finished product obtained by step (2), is put into vacuum oven in batches, it is dry at being 60 DEG C in temperature, often Drying time needed for 1kg semi-finished product is 1.5h, obtains white chunks product.
Cold-trap is provided with before the vacuum pump of the vacuum oven of the step (3).
A kind of application method of the solid material block applied for heat transfer colour ribbon back are as follows: according to required ratio, Xiang Suoshu Solvent appropriate is added in blocky back paint, low-grade fever dissolution, which is sufficiently stirred, can be used, and the solvent is toluene, in ethyl acetate Any one.
Embodiment 3
A kind of solid material block applied for heat transfer colour ribbon back, the raw material including following weight percent: methacrylic acid Methyl esters 35%, isobornyl methacrylate 10%, hydroxyl silane coupling agent 1%, hydroxyl-terminated polydimethylsiloxane 9% contain amino Silane coupling agent 1%, toluene 45%, butanone 10% and azodiisobutyronitrile 1%.
The hydroxyl silane coupling agent are as follows: 3- methacryloxypropyl trimethoxy silane.
It is described to contain amino silicane coupling agent are as follows: 3- aminopropyl triethoxysilane.
A kind of preparation method of the solid material block applied for heat transfer colour ribbon back:
(1) by methyl methacrylate, isobornyl methacrylate, hydroxyl silane coupling agent and methylbenzene raw material, It is added in reaction kettle by above-mentioned weight percent, dissolves azodiisobutyronitrile with appropriate butanone, reaction kettle is added after mixing In, 72 DEG C of reaction 3h of temperature control；
(2) by hydroxyl-terminated polydimethylsiloxane and containing amino silicane coupling agent, suitable fourth is dissolved in by above-mentioned weight percent It in ketone, is added in reaction kettle after mixing, after keeping the temperature 72 DEG C of sustained response 3h, closes heating, naturally cool to room temperature, out Material, obtains semi-finished product；
(3) it by semi-finished product obtained by step (2), is put into vacuum oven in batches, it is dry at being 60 DEG C in temperature, often Drying time needed for 1kg semi-finished product is 2h, obtains white chunks product.
Cold-trap is provided with before the vacuum pump of the vacuum oven of the step (3).
A kind of application method of the solid material block applied for heat transfer colour ribbon back are as follows: according to required ratio, Xiang Suoshu Solvent appropriate is added in blocky back paint, low-grade fever dissolution, which is sufficiently stirred, can be used, and the solvent is toluene, in ethyl acetate Any one.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although passing through ginseng According to the preferred embodiment of the present invention, invention has been described, it should be appreciated by those of ordinary skill in the art that can To make various changes to it in the form and details, without departing from the present invention defined by the appended claims Spirit and scope.

Claims (6)

1. a kind of solid material block applied for heat transfer colour ribbon back, it is characterised in that: the raw material including following weight percent: first Base methyl acrylate 30%-35%, isobornyl methacrylate 5%-10%, hydroxyl silane coupling agent 0.5%-1%, hydroxyl Base blocks silicon rubber 7%-9%, 0.5%-1% containing amino silicane coupling agent, toluene 40%-45%, butanone 5%-10% and idol Nitrogen bis-isobutyronitrile 0.5%-1%.
2. a kind of solid material block applied for heat transfer colour ribbon back according to claim 1, it is characterised in that: described to contain hydroxyl Base silane coupling agent are as follows: 3- methacryloxypropyl trimethoxy silane.
3. a kind of solid material block applied for heat transfer colour ribbon back according to claim 1, it is characterised in that: described to contain ammonia Base silane coupling agent are as follows: 3- aminopropyl triethoxysilane.
4. a kind of preparation method of the solid material block applied for heat transfer colour ribbon back, it is characterised in that:
(1) by methyl methacrylate, isobornyl methacrylate, hydroxyl silane coupling agent and methylbenzene raw material, by upper It states weight percent to be added in reaction kettle, dissolves azodiisobutyronitrile with appropriate butanone, be added in reaction kettle after mixing, control Warm 70-72 DEG C of reaction 2-3h；
(2) it by hydroxyl-terminated polydimethylsiloxane and containing amino silicane coupling agent, is dissolved in suitable butanone by above-mentioned weight percent, It is added in reaction kettle after mixing, after keeping the temperature 72 DEG C of sustained response 2-3h, stops heating, after naturally cooling to room temperature, Discharging, obtains semi-finished product；
(3) it by semi-finished product obtained by step (2), is put into vacuum oven in batches, dry at being 60 DEG C in temperature, every 1kg half Drying time needed for finished product is 1-2h, obtains white chunks product.
5. a kind of preparation method of solid material block applied for heat transfer colour ribbon back according to claim 4, feature exist In: cold-trap is provided with before the vacuum pump of the vacuum oven of the step (3).
6. a kind of application method of solid material block applied for heat transfer colour ribbon back according to claim 1, feature exist In: according to required ratio, solvent appropriate is added into the blocky back paint, low-grade fever dissolution, which is sufficiently stirred, to be made It is toluene, any one in ethyl acetate with, the solvent.
CN201910433880.4A 2019-05-23 2019-05-23 A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back Pending CN110183925A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910433880.4A CN110183925A (en) 2019-05-23 2019-05-23 A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910433880.4A CN110183925A (en) 2019-05-23 2019-05-23 A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back

Publications (1)

Publication Number Publication Date
CN110183925A true CN110183925A (en) 2019-08-30

Family

ID=67717423

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910433880.4A Pending CN110183925A (en) 2019-05-23 2019-05-23 A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back

Country Status (1)

Country Link
CN (1) CN110183925A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370356A (en) * 2018-10-08 2019-02-22 河南师范大学 A kind of barcode ribbon back coating coating consolidates block and preparation method thereof
CN110746533A (en) * 2019-09-29 2020-02-04 浙江天浩数码科技有限公司 Preparation method of acrylate back coating liquid and preparation method of carbon ribbon
CN116144261A (en) * 2022-11-18 2023-05-23 福建鸣友新材料科技有限公司 Heat-resistant coating for thermal transfer carbon ribbon, preparation method and coating process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001066662A2 (en) * 2000-03-03 2001-09-13 Dow Corning Corporation Laminate adhesive having bis-silanes, multifunctional acrylates and ethylenically unsaturated acids
JP2004175814A (en) * 2002-11-22 2004-06-24 Dow Corning Toray Silicone Co Ltd Matt thermosetting type silicone ink composition and method for forming matt surface
CN106626855A (en) * 2012-09-11 2017-05-10 凸版印刷株式会社 Heat-sensitive transfer recording medium
CN109370356A (en) * 2018-10-08 2019-02-22 河南师范大学 A kind of barcode ribbon back coating coating consolidates block and preparation method thereof
CN109504227A (en) * 2018-10-08 2019-03-22 路飞 A kind of production method of printer barcode ribbon back coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001066662A2 (en) * 2000-03-03 2001-09-13 Dow Corning Corporation Laminate adhesive having bis-silanes, multifunctional acrylates and ethylenically unsaturated acids
JP2004175814A (en) * 2002-11-22 2004-06-24 Dow Corning Toray Silicone Co Ltd Matt thermosetting type silicone ink composition and method for forming matt surface
CN106626855A (en) * 2012-09-11 2017-05-10 凸版印刷株式会社 Heat-sensitive transfer recording medium
CN109370356A (en) * 2018-10-08 2019-02-22 河南师范大学 A kind of barcode ribbon back coating coating consolidates block and preparation method thereof
CN109504227A (en) * 2018-10-08 2019-03-22 路飞 A kind of production method of printer barcode ribbon back coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
冯新德等: "《高分子辞典》", 30 June 1998 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370356A (en) * 2018-10-08 2019-02-22 河南师范大学 A kind of barcode ribbon back coating coating consolidates block and preparation method thereof
CN110746533A (en) * 2019-09-29 2020-02-04 浙江天浩数码科技有限公司 Preparation method of acrylate back coating liquid and preparation method of carbon ribbon
CN116144261A (en) * 2022-11-18 2023-05-23 福建鸣友新材料科技有限公司 Heat-resistant coating for thermal transfer carbon ribbon, preparation method and coating process thereof

Similar Documents

Publication Publication Date Title
CN110183925A (en) A kind of solid material block and preparation method thereof applied for heat transfer colour ribbon back
CN102766382B (en) Hollow alkali washing aluminum aqueous protective paint and preparation method and application thereof
CN102533068B (en) Ultraviolet curing aluminized transferring coating and preparation method and application thereof
CN105636996B (en) The manufacturing method of polyvinyl alcohol resin and thus obtained polyvinyl alcohol resin
CN104356320B (en) Waterborne epoxy ester-acrylic hybrid resin and preparation method thereof
CN102351982B (en) Waterborne acrylic resin and metal flashing paint applying same
CN103409046B (en) A kind of aqueous PET bottom-coating and its preparation method and application
CN105949378A (en) Water-based acrylic emulsion resin, water-based coating emulsion and preparation method
CN104592462B (en) A kind of silica sol modified acrylic emulsion and its preparation, application
CN115820066B (en) Water-based coating for thermal transfer ink-jet printing, and preparation method and application thereof
CN103555113A (en) Coating composition for transferable laser anti-counterfeiting plate and method for preparing transferable laser anti-counterfeiting plate
CN102888161A (en) Environment-friendly water-based high-adhesion PET (polyethylene terephthalate) precoat coating composition as well as preparation method and application
CN101338175A (en) Water-emulsion type paper-plastic composite adhesive and method for preparing same
CN101147902A (en) Using method and product of water polyurethane used for coating prime glue
CN102352163A (en) Anti-sticking acrylic acid paint for coating and preparation method thereof
CN105601970A (en) Release film with overweight release force and preparation method thereof
US10274852B2 (en) Coating compositions for forming toner coatings
CN102731728A (en) Adhesive for digital inkjet printing ink-absorption coating and preparation method thereof
JP2004524386A5 (en)
CN107828363A (en) A kind of steel plate laminated adhesive of heat cure and preparation method thereof
CN109627876A (en) A kind of thermal transfer mould release and preparation method thereof for digital printing
CN109439216A (en) A kind of heating visbreaking protective film that heating visbreaking glue is process
CN108997899A (en) A kind of aqueous PET bottom-coating and preparation method thereof
CN102653646B (en) Ink used for color filter, and preparation methods of ink and color filter
CN109337007A (en) A kind of packing box green printing technique

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190830