CN1168936A - Material and method for transfer printing textiles - Google Patents

Material and method for transfer printing textiles Download PDF

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Publication number
CN1168936A
CN1168936A CN 97111774 CN97111774A CN1168936A CN 1168936 A CN1168936 A CN 1168936A CN 97111774 CN97111774 CN 97111774 CN 97111774 A CN97111774 A CN 97111774A CN 1168936 A CN1168936 A CN 1168936A
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CN
China
Prior art keywords
transfer printing
base material
fabric
printing
tinsel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 97111774
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Chinese (zh)
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CN1091190C (en
Inventor
王红凤
于伯龄
夏磊
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Beijing Institute Fashion Technology
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Beijing Institute Fashion Technology
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Filing date
Publication date
Application filed by Beijing Institute Fashion Technology filed Critical Beijing Institute Fashion Technology
Priority to CN97111774A priority Critical patent/CN1091190C/en
Publication of CN1168936A publication Critical patent/CN1168936A/en
Application granted granted Critical
Publication of CN1091190C publication Critical patent/CN1091190C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The inventaed printing method uses metal foil or metal foil with film-forming substance coated on its back to substitute the original transfer printing paper, so that the printing strength is enhanced, more fabrics can be printed and longlife with the printed matter. The printed surface is more neat and smooth, and the printing quality is gooe. No consumption of paper, low consumption of printing ink and low cost so that the economic effect is significant.

Description

Fabric transfer printing base material and method for transfer printing
The present invention relates to a kind of from the solid carrier with the printing method of dye transfer to the fabric.
In numerous textile printing process, because transfer printing can be printed the decorative pattern of very fine, and technology is simple, saving of labor, not water, small investment, and instant effect quite is subjected to people's welcome.Technology always is that dyestuff is made printing ink, according to giving fixed pattern or text printout to transfer paper, pastes mutually with the front of fabric then, and together by printing machine, the distillation of dyestuff makes fabric be dyed the fixed colored type that gives when relying on heating.This technology is very high to flatness, the requirement of strength of transfer paper, and in concrete production process, its transfer paper is by the adjustment to heating-up temperature, pressure, at most can only transfer printing three times.After the transfer printing three times, papery is decreased, and has a large amount of dyestuffs to reside on the paper in company with ink addition agent, and waste is big, the cost height.The planarization of transfer paper reduces also makes pattern, pattern produce certain dislocation, error when printing, if papery does not reach requirement, the fabric of printing flower type does not reach due meticulous and readability yet.Japan Patent JP7138889 " has the preparation of the cloth of metal flower type " and has introduced to deposit metal in transfer techniques and forms metal film on the pet film in addition, is coated with the adhesive of isocyanide ester on the surface of this metal film.Before adhesive is not dried, will wait to print cloth therewith metal film paste mutually, press down boiling hotly being lower than 150 ℃, this metal film is transferred on the cloth together in company with adhesive.Though be printed on colored type on this method fabric but the surface is not soft, be not suitable for dress, preferably as ornament, and not to use dye printing.Do base material with tinsel, carry out the transfer printing of fabric, have not yet to see report with dyestuff.
The present invention proposes a kind of transfer printing that can repeatedly repeat for solving the weak point that the former technology of transfer printing exists, and printing quality is good, and technological operation is simple, transfer printing base material and method for transfer printing thereof that cost is low.
The present invention can realize in the following method that fabric carries out transfer printing and at first prepares base material, with the transfer printing dye printing ink that modulates, with pattern, decorative pattern or the literal of roller with desire printing, be printed on the tinsel, base material, then, take the method for transfer printing, base material is pasted mutually with printing fabric face, pass through transfer printing machine, under chosen temperature, pressure, press and scald certain hour, make dye sublimation to fabric, constitute the fabric of wounded in the battle type.
Below the present invention is done concrete narration: to base material as transfer printing, some metals can be made paillon foil, but choose the intensity height, the metal that ductility is good, the tinsel needs of using for the adaptation transfer printing are very thin, the tinsel thickness that we select for use is 0.001~0.2 millimeter, selects wherein a kind of of aluminium foil, alloy foil, antirust aluminium foil, Copper Foil or copper alloy paillon foil for this reason.The transfer printing base material also can be coated with heatproof resin material with the tinsel back side and make, can find and the bonding very firm film forming matter of paillon foil for our used tinsel, the resin that we select for use can be heatproof plastics such as polytetrafluoroethylene (PTFE) or polyimides.
The dye ink used as transfer printing comprises adhesive, better cohesiveness be arranged with tinsel, uses as transfer printing, and optionally kind, prescription are a lot, the transfer printing ink formulations below we have adopted:
Dyestuff: 10~30%
Adhesive: 1~10%
Emulsifying agent: 1~10%
Bleeding agent: 1~10%
Thickener: 1~10%
Residue percentage is water.The above-mentioned weight ratio that is all.This prescription all is suitable for for producing the base material that scribbles film forming matter on tinsel or the tinsel.Specifically, used dyestuff is in the transfer printing ink formulations:
A kind of in anthraquinone type, azo-type, the amino-type DISPERSE DYES, as the CI disperse red 60, CI Disperse Blue-56, CI disperse yellow 23, CI disperse blue 20;
Or Monoazo type, diaza cyanines, half cyanines cation dyes is a kind of, red 23 as CI alkalescence, CI basic yellow 24, CI basic yellow 53;
Or a kind of in the triphenylmenthane, diphenyl-methane, xanthene basic-dyeable fibre, as the CI alkaline purple 3, CI basic yellow 2, CI alkali red 1:1;
Or a kind of in the spirit color, as: CI solvent yellow 19, CI solvent blue 23;
Or a kind of in the oil-soluble dyes, as: CI solvent red 30.
The adhesive that uses in the transfer printing ink formulations should be considered kind, the character of tinsel, simultaneously also to consider not answer the distillation characteristic of dyestuff under used process conditions in the overslaugh printing ink, specifically can select a kind of of acrylic compounds or polyvinyl acetate class for use; Used emulsifying agent, bleeding agent and thickener are used always by general textile printing and dyeing industry.
The present invention because the characteristics of base material are the heat transfer efficiency height, makes used dye sublimation when the concrete transfer printing of fabric transfer printing, to carry out the transfer printing operating temperature low than make base material of paper, and control easily.The process conditions that this technology adopted are: transition temperature is 150~230 ℃, and shifting the printing time is 20~60 seconds.Since this technology with former be that the transfering printing process of base material is similar to paper, so the present invention can use original device fabrication, needn't change.Because metal forming will repeatedly be used, prevent as far as possible that when running operation paillon foil from producing wrinkle.
The present invention has the following advantages compared to existing technology: 1, because the conductivity of heat of metal is better than paper, be weaker than paper again with the affinity of dyestuff, the dyestuff that is printed on the metal base almost completely is transferred.Experiment showed, tens of times of the transfer printing repeatedly of colored type that one-step print makes, all shift up to dyestuff and finish.The auxiliary agent that retains on the base material is easy to clean up, and cleaning process do not damage base material, so base material can use over thousands of time.Like this, the just dyestuff that primary transfer ran out, cost is very low, compared with prior art, becomes instinct to reduce hundreds of times.2, retain in the nontoxic or low toxicity of auxiliary agent on the base material, so environmental pollution is very little.3, base material distortion hardly in the service condition scope, the surface is extremely level and smooth, so it is meticulous, clear to print the flower type, does not go out substandard products, and steady quality is reliable 4, this technology and the used technology of original transfer printing factory are basic identical, can use original equipment.Be suitable for rayon, science fabric, BLENDED FABRIC and through the transfer printing of the natural fabric of modification, wide application.
Embodiments of the invention are as follows:
Embodiment 1: at first in following ratio preparation printing ink, disperse red 60 dyestuff: 15%; Adhesive: 4%; Emulsifying agent: 2%; Bleeding agent: 4%; Thickener: 5%; Water: 70%.Printing ink is applied on the aluminium foil of 0.04 millimeters thick.Pressed boiling hot 40 seconds with dacron at 200 ℃ of following aluminium foils.The finished product lovely luster.Repeat transfer printing 20 times under similarity condition, the bright-coloured degree of fabric is with for the first time.
Embodiment 2: the alloy foil with 0.06 millimeters thick is made base material, and disperse blue 20 dye inks, ink formulations are printed the real silk fabric through modification with embodiment 1.Pressed boiling hot 40 seconds at 180 ℃.Printing finished product lovely luster, 3~4 grades of soaping fastnesses.Under similarity condition, print 20 times and form and aspect are constant.
Embodiment 3: with the antirust aluminium foil of 0.01 millimeters thick, adopt CI basic yellow 24 dyestuffs preparation printing ink, ink formulations is printed acrylic fabric with embodiment 1.Press boiling hot transfer printing 40 seconds at 200 ℃.It is beautiful to print the finished product color and luster, 4~5 grades of soaping fastnesses.Can repeat transfer printing 20 times under the similarity condition and form and aspect are constant.
Embodiment 4: adopt pure molten CI solvent yellow 19, CI solvent blue 23 dyestuffs preparation transfer ink, prescription is as example 1, antirust aluminium foil left-hand seat in 0.02 millimeters thick is painted lotus and lotus leaf, and this antirust aluminium foil that has pattern is pasted mutually with the real silk fabric front of modification, presses boiling hot 50 seconds in 190 ℃ on pressing machine.The colored type third dimension of sample is strong, lovely luster, and it is constant substantially to print 25 form and aspect repeatedly.

Claims (7)

1, fabric transfer printing base material and method for transfer printing thereof, at first modulate transfer printing printing ink, use printing equipment, pattern, decorative pattern or literal with the desire printing are printed on the transfer printing base material, then, make fabric and transfer printing base material under chosen temperature, pressure, fit and pass through transfer printing machine together, make dye sublimation to fabric, it is characterized in that the transfer printing base material is a tinsel, transfer printing printing ink is printed on the tinsel.
2, fabric transfer printing base material and method for transfer printing thereof according to claim 1 is characterized in that tinsel is wherein a kind of of aluminium foil, alloy foil, antirust aluminium foil, Copper Foil or copper alloy paillon foil.
3, fabric transfer printing base material and method for transfer printing thereof according to claim 1, the thickness that it is characterized in that tinsel is 0.001~0.2 millimeter.
4, fabric transfer printing base material and method for transfer printing thereof according to claim 1 is characterized in that the transfer printing ink by weight than prescription is:
Dyestuff: 10~30%
Adhesive: 1~10%
Emulsifying agent: 1~10%
Bleeding agent: 1~10%
Thickener: 1~10%
Water: all the other.
5, as fabric transfer printing base material and method for transfer printing thereof as described in the claim 1,5, it is characterized in that used dyestuff is in the transfer printing ink formulations:
A kind of in anthraquinone type, azo-type, the amino-type DISPERSE DYES;
Or Monoazo type, diaza cyanines, half cyanines cation dyes is a kind of;
Or a kind of in the triphenylmenthane, diphenyl-methane, xanthene basic-dyeable fibre;
Or a kind of in the spirit color;
Or a kind of in the oil-soluble dyes.
6, as fabric transfer printing base material and method for transfer printing thereof as described in the claim 1,5, it is characterized in that adhesive therefor is in the transfer printing ink formulations: acrylic compounds or polyvinyl acetate class a kind of.
7, fabric transfer printing base material and method for transfer printing thereof according to claim 1 is characterized in that shifting that the transfer printing process conditions are in the method that the printing process adopts: transition temperature is 150~230 ℃, and shifting the printing time is 20~60 seconds.
CN97111774A 1997-05-14 1997-05-14 Material and method for transfer printing textiles Expired - Fee Related CN1091190C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN97111774A CN1091190C (en) 1997-05-14 1997-05-14 Material and method for transfer printing textiles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN97111774A CN1091190C (en) 1997-05-14 1997-05-14 Material and method for transfer printing textiles

Publications (2)

Publication Number Publication Date
CN1168936A true CN1168936A (en) 1997-12-31
CN1091190C CN1091190C (en) 2002-09-18

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004007202A1 (en) * 2002-07-12 2004-01-22 Xiangyang Lu The apparatus for paperless transfer printing and the process thereof
CN100344830C (en) * 2006-05-16 2007-10-24 上海迪纺纺织科技有限公司 Pigment release agent for cold transfer printing paper
CN102059868A (en) * 2010-09-30 2011-05-18 刘奎 Double-face multicolor printing process and method for manufacturing flag thereby
CN102304862A (en) * 2011-07-15 2012-01-04 北京印月明印染新技术有限公司 Printing technology for pure cotton or polyester-cotton jean
CN110626106A (en) * 2019-08-29 2019-12-31 庄合作 Transfer printing method for wall colored drawing or human body colored drawing tattoo and application of gentian violet solution

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108239888B (en) 2016-12-27 2020-07-14 长胜纺织科技发展(上海)有限公司 Paperless transfer printing method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1005279B (en) * 1985-09-17 1989-09-27 厦门市科学技术局 Colored ink for transferring and pattern-printing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004007202A1 (en) * 2002-07-12 2004-01-22 Xiangyang Lu The apparatus for paperless transfer printing and the process thereof
CN100344830C (en) * 2006-05-16 2007-10-24 上海迪纺纺织科技有限公司 Pigment release agent for cold transfer printing paper
CN102059868A (en) * 2010-09-30 2011-05-18 刘奎 Double-face multicolor printing process and method for manufacturing flag thereby
CN102304862A (en) * 2011-07-15 2012-01-04 北京印月明印染新技术有限公司 Printing technology for pure cotton or polyester-cotton jean
CN102304862B (en) * 2011-07-15 2013-03-20 北京印月明印染新技术有限公司 Printing technology for pure cotton or polyester-cotton jean
CN110626106A (en) * 2019-08-29 2019-12-31 庄合作 Transfer printing method for wall colored drawing or human body colored drawing tattoo and application of gentian violet solution

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Publication number Publication date
CN1091190C (en) 2002-09-18

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