CN1091190C - Material and method for transfer printing textiles - Google Patents
Material and method for transfer printing textiles Download PDFInfo
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- CN1091190C CN1091190C CN97111774A CN97111774A CN1091190C CN 1091190 C CN1091190 C CN 1091190C CN 97111774 A CN97111774 A CN 97111774A CN 97111774 A CN97111774 A CN 97111774A CN 1091190 C CN1091190 C CN 1091190C
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- transfer printing
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- fabric
- tinsel
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Abstract
The present invention relates to a material and a method for transferring printing textiles. Because a metal foil or the back surface of the metal foil is coated with film forming substances, the original paper used for transferring printing is substituted, and therefore, the textiles have multiple printing number, long service life, smooth and flat surface, superior printing quality, no paper consumption, little printing ink consumption, low cost and obvious economic benefit. The method can use the original edition making and printing transferring equipment and process, can be favorable for popularization, can be used for transferring textiles and have wide application range.
Description
The present invention relates to a kind of from the solid carrier with the printing method of dye transfer to the fabric.
In numerous textile printing process, because transfer printing can be printed the decorative pattern of very fine, and technology is simple, saving of labor, not water, small investment, and instant effect quite is subjected to people's welcome.Technology always is that dyestuff is made printing ink, according to giving fixed pattern or text printout to transfer paper, pastes mutually with the front of fabric then, and together by printing machine, the distillation of dyestuff makes fabric be dyed the fixed colored type that gives when relying on heating.This technology is very high to flatness, the requirement of strength of transfer paper, and in concrete production process, its transfer paper is by the adjustment to heating-up temperature, pressure, at most can only transfer printing three times.After the transfer printing three times, papery is decreased, and has a large amount of dyestuffs to reside on the paper in company with ink addition agent, and waste is big, the cost height.The planarization of transfer paper reduces also makes pattern, pattern produce certain dislocation, error when printing, if papery does not reach requirement, the fabric of printing flower type does not reach due meticulous and readability yet.Japan Patent JP 7138889 " has the preparation of the cloth of metal flower type " and has introduced to deposit metal in transfer techniques and forms metal film on the pet film in addition, is coated with the adhesive of isocyanide ester on the surface of this metal film.Before adhesive is not dried, will wait to print cloth therewith metal film paste mutually, press down boiling hotly being lower than 150 ℃, this metal film is transferred on the cloth together in company with adhesive.Though be printed on colored type on this method fabric but the surface is not soft, be not suitable for dress, preferably as ornament, and not to use dye printing.Do base material with tinsel, carry out the transfer printing of fabric, have not yet to see report with dyestuff.
The present invention proposes a kind of transfer printing that can repeatedly repeat for solving the weak point that the former technology of transfer printing exists, and printing quality is good, and technological operation is simple, transfer printing base material and method for transfer printing thereof that cost is low.
The present invention can realize in the following method that fabric carries out transfer printing and at first prepares base material, with the transfer printing dye printing ink that modulates, with pattern, decorative pattern or the literal of roller with desire printing, be printed on the tinsel, base material, then, take the method for transfer printing, base material is pasted mutually with printing fabric face, pass through transfer printing machine, under chosen temperature, pressure, press and scald certain hour, make dye sublimation to fabric, constitute the fabric of wounded in the battle type.
Below the present invention is done concrete narration: to base material as transfer printing, some metals can be made paillon foil, but choose the intensity height, the metal that ductility is good, the tinsel needs of using for the adaptation transfer printing are very thin, the tinsel thickness that we select for use is 0.001～0.2 millimeter, selects wherein a kind of of aluminium foil, alloy foil, antirust aluminium foil, Copper Foil or copper alloy paillon foil for this reason.The transfer printing base material also can be coated with heatproof resin material with the tinsel back side and make, can find and the bonding very firm film forming matter of paillon foil for our used tinsel, the resin that we select for use can be heatproof plastics such as polytetrafluoroethylene (PTFE) or polyimides.
The dye ink used as transfer printing comprises adhesive, better cohesiveness be arranged with tinsel, uses as transfer printing, and optionally kind, prescription are a lot, the transfer printing ink formulations below we have adopted:
Dyestuff: 10～30%
Adhesive: 1～10%
Emulsifying agent: 1～10%
Bleeding agent: 1～10%
Thickener: 1～10%
Residue percentage is water.The above-mentioned weight ratio that is all.This prescription all is suitable for for producing the base material that scribbles film forming matter on tinsel or the tinsel.Specifically, used dyestuff is in the transfer printing ink formulations:
A kind of in anthraquinone type, azo-type, the amino-type DISPERSE DYES, as the CI disperse red 60, CI Disperse Blue-56, CI disperse yellow 23, CI disperse blue 20;
Or Monoazo type, diaza cyanines, half cyanines cation dyes is a kind of, red 23 as CI alkalescence, CI basic yellow 24, CI basic yellow 53;
Or a kind of in the triphenylmenthane, diphenyl-methane, xanthene basic-dyeable fibre, as the CI alkaline purple 3, CI basic yellow 2, CI alkali red 1:1;
Or a kind of in the spirit color, as: CI solvent yellow 19, CI solvent blue 23;
Or a kind of in the oil-soluble dyes, as: CI solvent red 30.
The adhesive that uses in the transfer printing ink formulations should be considered kind, the character of tinsel, simultaneously also to consider not answer the distillation characteristic of dyestuff under used process conditions in the overslaugh printing ink, specifically can select a kind of of acrylic compounds or polyvinyl acetate class for use; Used emulsifying agent, bleeding agent and thickener are used always by general textile printing and dyeing industry.
The present invention because the characteristics of base material are the heat transfer efficiency height, makes used dye sublimation when the concrete transfer printing of fabric transfer printing, to carry out the transfer printing operating temperature low than make base material of paper, and control easily.The process conditions that this technology adopted are: transition temperature is 150～230 ℃, and shifting the printing time is 20～60 seconds.Since this technology with former be that the transfering printing process of base material is similar to paper, so the present invention can use original device fabrication, needn't change.Because metal forming will repeatedly be used, prevent as far as possible that when running operation paillon foil from producing wrinkle.
The present invention has the following advantages compared to existing technology: 1, because the conductivity of heat of metal is better than paper, be weaker than paper again with the affinity of dyestuff, the dyestuff that is printed on the metal base almost completely is transferred.Experiment showed, tens of times of the transfer printing repeatedly of colored type that one-step print makes, all shift up to dyestuff and finish.The auxiliary agent that retains on the base material is easy to clean up, and cleaning process do not damage base material, so base material can use over thousands of time.Like this, the just dyestuff that primary transfer ran out, cost is very low, compared with prior art, becomes instinct to reduce hundreds of times.2, retain in the nontoxic or low toxicity of auxiliary agent on the base material, so environmental pollution is very little.3, base material distortion hardly in the service condition scope, the surface is extremely level and smooth, so it is meticulous, clear to print the flower type, does not go out substandard products, and steady quality is reliable.4, this technology and the used technology of original transfer printing factory are basic identical, can use original equipment.Be suitable for rayon, science fabric, BLENDED FABRIC and through the transfer printing of the natural fabric of modification, wide application.
Embodiments of the invention are as follows:
Embodiment 1: at first in following ratio preparation printing ink, disperse red 60 dyestuff: 15%; Adhesive: 4%; Emulsifying agent: 2%; Bleeding agent: 4%; Thickener: 5%; Water: 70%.Printing ink is applied on the aluminium foil of 0.04 millimeters thick.Pressed boiling hot 40 seconds with dacron at 200 ℃ of following aluminium foils.The finished product lovely luster.Repeat transfer printing 20 times under similarity condition, the bright-coloured degree of fabric is with for the first time.
Embodiment 2: the alloy foil with 0.06 millimeters thick is made base material, and disperse blue 20 dye inks, ink formulations are printed the real silk fabric through modification with embodiment 1.Pressed boiling hot 40 seconds at 180 ℃.Printing finished product lovely luster, 3～4 grades of soaping fastnesses.Under similarity condition, print 20 times and form and aspect are constant.
Embodiment 3: with the antirust aluminium foil of 0.01 millimeters thick, adopt CI basic yellow 24 dyestuffs preparation printing ink, ink formulations is printed acrylic fabric with embodiment 1.Press boiling hot transfer printing 40 seconds at 200 ℃.It is beautiful to print the finished product color and luster, 4～5 grades of soaping fastnesses.Can repeat transfer printing 20 times under the similarity condition and form and aspect are constant.
Embodiment 4: adopt pure molten CI solvent yellow 19, CI solvent blue 23 dyestuffs preparation transfer ink, prescription is as example 1, antirust aluminium foil left-hand seat in 0.02 millimeters thick is painted lotus and lotus leaf, and this antirust aluminium foil that has pattern is pasted mutually with the real silk fabric front of modification, presses boiling hot 50 seconds in 190 ℃ on pressing machine.The colored type third dimension of sample is strong, lovely luster, and it is constant substantially to print 25 form and aspect repeatedly.
Claims (5)
1, a kind of fabric method for transfer printing, with printing equipment and transfer printing printing ink, pattern, decorative pattern or literal with desire is printed are printed on the transfer printing base material, it is characterized in that the transfer printing base material selects tinsel for use, the thickness of tinsel is 0.001～0.2 millimeter; The transfer printing ink by weight than prescription is:
Dyestuff: 10～30%
Adhesive: 1～10%
Emulsifying agent: 1～10%
Bleeding agent: 1～10%
Thickener: 1～10%
Water: all the other; Used dyestuff is in the transfer printing ink formulations:
A kind of in anthraquinone type, azo-type, the amino-type DISPERSE DYES;
Or a kind of in the Monoazo type, diaza cyanines, half cyanines cation dyes;
Or a kind of in the triphenylmenthane, diphenyl-methane, xanthene basic-dyeable fibre;
Or a kind of in the spirit color;
Or a kind of in the oil-soluble dyes.
2, fabric method for transfer printing according to claim 1 is characterized in that adhesive therefor is in the transfer printing ink formulations: acrylic compounds or polyvinyl acetate class a kind of.
3, fabric method for transfer printing according to claim 1 is characterized in that shifting in the method for printing process employing, and the transfer printing process condition is: transition temperature is 150～230 ℃, and shifting the printing time is 20～60 seconds.
4, the fabric transfer printing base material of the described fabric method for transfer printing employing of a kind of claim 1 is characterized in that the transfer printing base material is a tinsel, and the thickness of tinsel is 0.001～0.2 millimeter.
5,, it is characterized in that tinsel is wherein a kind of of aluminium foil, alloy foil, antirust aluminium foil, Copper Foil or copper alloy paillon foil as the fabric transfer printing base material as described in the claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97111774A CN1091190C (en) | 1997-05-14 | 1997-05-14 | Material and method for transfer printing textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97111774A CN1091190C (en) | 1997-05-14 | 1997-05-14 | Material and method for transfer printing textiles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1168936A CN1168936A (en) | 1997-12-31 |
| CN1091190C true CN1091190C (en) | 2002-09-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97111774A Expired - Fee Related CN1091190C (en) | 1997-05-14 | 1997-05-14 | Material and method for transfer printing textiles |
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| CN (1) | CN1091190C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10865518B2 (en) | 2016-12-27 | 2020-12-15 | Newtech Textile Technology Development (Shanghai) Co., Ltd. | Paperless transfer printing method |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101063890B1 (en) * | 2002-07-12 | 2011-09-15 | 홍펭 왕 | The apparatus for paperless transfer printing and the process thereof |
| CN100344830C (en) * | 2006-05-16 | 2007-10-24 | 上海迪纺纺织科技有限公司 | Pigment release agent for cold transfer printing paper |
| CN102059868A (en) * | 2010-09-30 | 2011-05-18 | 刘奎 | Double-face multicolor printing process and method for manufacturing flag thereby |
| CN102304862B (en) * | 2011-07-15 | 2013-03-20 | 北京印月明印染新技术有限公司 | Printing technology for pure cotton or polyester-cotton jean |
| CN110626106A (en) * | 2019-08-29 | 2019-12-31 | 庄合作 | Transfer printing method for wall colored drawing or human body colored drawing tattoo and application of gentian violet solution |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85107346A (en) * | 1985-09-17 | 1987-09-02 | 厦门市科学技术局 | Colored ink for transferring and printing method |
-
1997
- 1997-05-14 CN CN97111774A patent/CN1091190C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85107346A (en) * | 1985-09-17 | 1987-09-02 | 厦门市科学技术局 | Colored ink for transferring and printing method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10865518B2 (en) | 2016-12-27 | 2020-12-15 | Newtech Textile Technology Development (Shanghai) Co., Ltd. | Paperless transfer printing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1168936A (en) | 1997-12-31 |
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Granted publication date: 20020918 Termination date: 20160514 |