CN100577911C - Method for increasing inking printing pigment ink color fastness - Google Patents
Method for increasing inking printing pigment ink color fastness Download PDFInfo
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- CN100577911C CN100577911C CN200710024154A CN200710024154A CN100577911C CN 100577911 C CN100577911 C CN 100577911C CN 200710024154 A CN200710024154 A CN 200710024154A CN 200710024154 A CN200710024154 A CN 200710024154A CN 100577911 C CN100577911 C CN 100577911C
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- 238000007639 printing Methods 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000000049 pigment Substances 0.000 title claims description 45
- 239000004744 fabric Substances 0.000 claims abstract description 26
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 23
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 239000000853 adhesive Substances 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000976 ink Substances 0.000 claims description 41
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical group O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 12
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 229940015043 glyoxal Drugs 0.000 claims description 6
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 6
- 229960003511 macrogol Drugs 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 2
- 229920002642 Polysorbate 65 Polymers 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 2
- 229940051250 hexylene glycol Drugs 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 2
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 2
- 229940099511 polysorbate 65 Drugs 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 5
- 239000012190 activator Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 241000322338 Loeseliastrum Species 0.000 description 4
- 238000004855 creaseproofing Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- -1 dihydroxymethyl Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010006 anti-felting Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention relates to a method used to increase inking printing dye ink color fastness. It includes the following steps: orderly adding dye color paste, polyhydric alcohol, adhesive, cross linking agent, surface activator in proportion into container; adding water to mix evenly; stirring, filtrating to form super fine dye ink; jet printing on the fabric; drying, baking to fix. The printing film formed by cross linking agent makes the super fine dye particle can tolerate dry wet friction, can increase its color fastness on the fabric without influencing on ink injecting performance.
Description
Technical field
The present invention relates to a kind of method that improves inking printing pigment ink color fastness, belong to technical field of textile printing.
Background technology
Along with the development of digitizing technique with popularize, the digital ink-jet fabric printing technique becomes the most potential ecological spinning technology of 21 century, and wherein digital inking printing is to solve one of key link of Digital ink jet printing technology with the research and development of pigment ink-jet inks.But because ink has added a large amount of polyalcohols in process for preparation.Easily cause the swelling of printed film under wet environment in spray printing hydrophily of polyalcohol after the fabric face, the fastness to wet rubbing that causes superfine pigment to adhere on fabric reduces.
In order to solve the low problem of ink-jet printed fabric fastness to wet rubbing, need carry out preliminary treatment to the fabric of spray printing or stamp product behind the spray printing is carried out post processing.So not only increase treatment process, improved production cost, and be easy to generate environmental pollution.Add crosslinking agent in printing ink, the ability that improves printed film tolerance wet environment becomes the shortcut that improves the ink print durability.Yet general film forming matter joins the problem that is prone in the ink-jet printing ink and is: (1) causes the gathering of superfine pigment particle in the ink, produces flocculation, precipitation; (2) quality of forming film is not high, after spray printing is to the fabric, can not form densification, continuous, smooth printed film at fabric face; Damaged easily when (3) printed film is rubbed under wet environment, cause pigment particles to come off.In inking printing pigment ink, add crosslinking agent and can overcome above-mentioned shortcoming.
Crosslinking agent is mainly used in finishing functions of textile fabrics in the textile printing and dyeing field at present, as: many aspects such as fabric anti-crease and Iron-free.
Chinese patent CN1039456A discloses with polybasic carboxylic acid COTTON FABRIC has been carried out technology and the employed catalyst that formaldehyde-free durable is pressed boiling hot arrangement, esterification and crosslinked takes place with cellulose in the textiles in the crosslinked character of this technology utilization polybasic carboxylic acid under the effect of catalyst, thereby obtains the durable press effect; Chinese patent CN1431359A discloses a kind of by using dihydroxy dihydroxymethyl cyclic ethylene urea, and BTCA or sol-gel technique are anchored at method on the textiles with cyclodextrin, develop the textiles with nest's effect; Chinese patent CN1552989A discloses a kind of formaldehyde-free crease-proofing finishing agent and manufacture method thereof, comprises acetic acid in this crease proofing agent, sodium acetate, chitosan and crosslinking agent citric acid, glyoxal; Chinese patent CN1566514A discloses a kind of crosslinking agent glyoxal and an amount of reformation agent ethylene glycol or diethylene glycol (DEG) of comprising, and mixture of catalysts is used for the wrinkle resistant processing agent of fabric; Chinese patent CN1621606A discloses the reactive organic silicon modified aqueous polyurethane wool anti-felting finish agent of a kind of anionic; Chinese patent CN1704523A discloses a kind of production process of the aqueous polyurethane with end-blocking or unsaturated bond structure and to the method for sorting of crease-proofing textiles containing, guarantor's type; Chinese patent CN1865579A discloses a kind of crease proofing agent at soybean fiber fabric, comprises: glyoxal, magnesium chloride, aqueous polyurethane, triethanolamine, softener and bleeding agent.
But crosslinking agent is used for pigment ink-jet inks textiles is carried out digital inking printing, improve the method for COLOR FASTNESS by the quality that improves crosslinked film forming and do not appear in the newspapers as yet.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, thereby provide a kind of method that improves inking printing pigment ink color fastness, by in inking printing pigment ink, adding crosslinking agent, after the ink spray printing is to fabric, in the process of curing fixation, utilize the film properties that is cross-linked into of crosslinking agent, form continuously at fabric face, fine and close, smooth printed film, make the superfine pigment particle in the ink can tolerate dried wet friction, thereby reach the purpose that improves COLOR FASTNESS.
Main solution of the present invention is achieved in that
The method that the present invention improves inking printing pigment ink color fastness adopts following processing step:
1, the preparation of inking printing pigment ink:
Getting dispersible pigment color paste is: 5～25 weight %, polyalcohol is: 15～40 weight %, adhesive is: 10～20 weight %, crosslinking agent is: 10～20 weight %, surfactant is: 0.3～1 weight %, said components is added in the container in proportion successively, and add water and be: 10～50 weight % mix, stirred 10-20 minute under 400～600 rev/mins of conditions with mixer, be mixed with pigment ink-jet inks after filtration;
2, ink-jet printed:
Use the ink-jet decorating machine spray printing to fabric pigment ink-jet inks, in temperature be: 80～100 ℃, the time is: dry under 1～10 minute the condition, in temperature be then: 130～160 ℃, the time is: curing fixation under 1～10 minute the condition.
Polyalcohol of the present invention is: ethylene glycol, 1, ammediol, 1,4-butanediol, 1, one or more mixtures in 6-hexylene glycol, diglycol, triethylene-glycol, tetraethylene-glycol, Macrogol 200, PEG400, Macrogol 600, glycerol, the pentaerythrite.
Crosslinking agent of the present invention is: glyoxal, glutaraldehyde, crosslinking agent EH, crosslinking agent FH, diglycidyl ether, aqueous polyurethane, BTCA, pentamethylene tetrabasic carboxylic acid, citric acid, maleic acid, malic acid, the third three acid, propylene three acid, poly, one or more mixtures in poly-vinyl alcohol-acrylic acid.
Surfactant of the present invention is the polyoxyethylene alkyl ether class: polysorbate60, polysorbate65, Tween 80; Triton x-100, Qu Latong X-10; Polyoxyethylene ester class: this dish 20, this dish 40, this dish 60, span 80; Or one or more mixtures in the peregal os-15, OP-10, peregal A-20, peregal AEO-10, paregal O.
The dispersible pigment color paste of one of component of the present invention is the good superfine pigment mill base of dispersion stabilization, two polyalcohol of component is the composition of two or more polyalcohols, three adhesive of component is the COAT PRINTING adhesive, four crosslinking agent of component is the composition of one or more crosslinking agents, five glass or plastic containers of component.
Compared with the prior art the present invention has the following advantages:
The present invention mixes the filtering with microporous membrane of back with 0.5 μ m by add an amount of crosslinking agent in inking printing pigment ink, by the ink-jet decorating machine spray printing to fabric; In the process of curing fixation, utilize the film properties that is cross-linked into of crosslinking agent, form continuously at fabric face, fine and close, smooth printed film, make the superfine pigment particle in the ink can tolerate dried wet friction, under the prerequisite that does not influence the ink jet performance, improved the COLOR FASTNESS of superfine pigment particle on fabric in the ink.
The specific embodiment
Following the present invention will be further described in conjunction with the embodiment in the subordinate list:
Embodiment one:
1, the preparation of inking printing pigment ink:
Get paratonere mill base 25g, diglycol 10g, glycerol 5g, adhesive HY-FB 20g, aqueous polyurethane 10g, citric acid 5g, OP-10 0.3g, deionized water 24.7g.Said components is added in the container successively, mix, under 450 rev/mins of conditions, stirred 10 minutes, filter (miillpore filter of 0.5 μ m) and be made into the superfine pigment red ink with mixer;
2, ink-jet printed:
Use the ink-jet decorating machine spray printing to the woven calico of cotton textiles the superfine pigment red ink, in temperature be: 80 ℃, the time is: in drying in oven, in temperature be then: 150 ℃, the time is: curing fixation under 3 minutes the condition under 3 minutes the condition.Obtain sample A, the color fastness of test fabric adopts crock fastness instrument and color measurement and color match instrument.The results are shown in Table 1.
Embodiment two:
1, the preparation of inking printing pigment ink:
Get pigment yellow mill base 15g, diglycol 15g, Macrogol 200 10g, 1,4-butanediol 10g, glycerol 5g, adhesive FWT (BASF AG) 10g, crosslinking agent EH 5g, BTCA 10g, paregal O 0.5g, Tween 80 0.5g, deionized water 19g.Said components is added in the container successively, mix, under 500 rev/mins of conditions, stirred 15 minutes, filter (miillpore filter of 0.5 μ m) and be made into the yellow ink of superfine pigment with mixer;
2, ink-jet printed:
Use the ink-jet decorating machine spray printing to the woven calico of cotton textiles the yellow ink of superfine pigment, in temperature be: 90 ℃, the time is: in drying in oven, in temperature be then: 140 ℃, the time is curing fixation under 4 minutes condition under 2 minutes the condition.Obtain sample B, the color fastness of test fabric adopts crock fastness instrument, color measurement and color match instrument.The results are shown in Table 1.
Embodiment three:
1, the preparation of inking printing pigment ink:
Get alizarol saphirol mill base 15g, 1,4-butanediol 10g, glycerol 15g, adhesive HY-FB (Qingdao Hai Yi company) 20g, BTCA 10g, polysorbate60 0.5g, deionized water 29.5g.Said components is added in the container successively, mix, under 550 rev/mins of conditions, stirred 12 minutes, filter (miillpore filter of 0.5 μ m) and be made into the superfine pigment blue ink with mixer;
2, ink-jet printed:
Use the ink-jet decorating machine spray printing to the woven calico of cotton textiles the superfine pigment blue ink, in temperature be: 85 ℃, the time is: in drying in oven, in temperature be then: 135 ℃, the time is curing fixation under 3.5 minutes condition under 4 minutes the condition.Obtain sample C, the color fastness of test fabric adopts crock fastness instrument, color measurement and color match instrument.The results are shown in Table 1.
Embodiment four:
1, the preparation of inking printing pigment ink:
Pigment black mill base 5g, diglycol 15g, 1, ammediol 10g, glycerol 5g, WH-A self-crosslinking pigment printing binding agent (Jiangsu Province Yixing City Rong Mao chemical industry Co., Ltd) 15g, glyoxal 5g, aqueous polyurethane 10g, OP-100.3g, deionized water 34.7g.Said components is added in the container successively, mix, under 580 rev/mins of conditions, stirred 10 minutes, filter (miillpore filter of 0.5 μ m) and be made into the superfine pigment black ink with mixer;
2, ink-jet printed:
Use the ink-jet decorating machine spray printing to the woven calico of cotton textiles the superfine pigment black ink, in temperature be: 95 ℃, the time is: in drying in oven, in temperature be then: 155 ℃, the time is curing fixation under 2.5 minutes condition under 3 minutes the condition.Obtain sample D, the color fastness of test fabric adopts crock fastness instrument, color measurement and color match instrument.The results are shown in Table 1.
The crock fastness of the ink-jet printed fabric of table 1
| Sample | Dry fastness (level) | Fastness to wet rubbing (level) |
| A | 3～4 | 2～3 |
| B | 4 | 3 |
| C | 3～4 | 2～3 |
| D | 3 | 2～3 |
Claims (4)
1, a kind of method that improves inking printing pigment ink color fastness is characterized in that adopting following processing step:
(1), the preparation of inking printing pigment ink:
Getting dispersible pigment color paste is: 5～25 weight %, polyalcohol is: 15～40 weight %, adhesive is: 10～20 weight %, crosslinking agent is: 10～20 weight %, surfactant is: 0.3～1 weight %, said components is added in the container in proportion successively, and add water and be: 10～50 weight % mix, stirred 10-20 minute under 400～600 rev/mins of conditions with mixer, be mixed with pigment ink-jet inks after filtration;
(2), ink-jet printed:
Use the ink-jet decorating machine spray printing to fabric pigment ink-jet inks, in temperature be: 80～100 ℃, the time is: dry under 1～10 minute the condition, in temperature be then: 130～160 ℃, the time is: curing fixation under 1～10 minute the condition.
2, a kind of method that improves inking printing pigment ink color fastness according to claim 1, it is characterized in that described polyalcohol is an ethylene glycol, 1, ammediol, 1,4-butanediol, 1, one or more mixtures in 6-hexylene glycol, diglycol, triethylene-glycol, tetraethylene-glycol, Macrogol 200, PEG400, Macrogol 600, glycerol, the pentaerythrite.
3, a kind of method that improves inking printing pigment ink color fastness according to claim 1 is characterized in that described crosslinking agent is a glyoxal, glutaraldehyde, crosslinking agent EH, crosslinking agent FH, diglycidyl ether, aqueous polyurethane, BTCA, pentamethylene tetrabasic carboxylic acid, citric acid, maleic acid, malic acid, the third three acid, propylene three acid, poly, one or more mixtures in poly-vinyl alcohol-acrylic acid.
4, a kind of method that improves inking printing pigment ink color fastness according to claim 1 is characterized in that described surfactant is: one or more mixtures in polysorbate60, polysorbate65, Tween 80, triton x-100, Qu Latong X-10, this dish 20, this dish 40, this dish 60, span 80, peregal os-15, OP-10, peregal A-20, peregal AEO-10, the paregal O.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710024154A CN100577911C (en) | 2007-07-23 | 2007-07-23 | Method for increasing inking printing pigment ink color fastness |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710024154A CN100577911C (en) | 2007-07-23 | 2007-07-23 | Method for increasing inking printing pigment ink color fastness |
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| Publication Number | Publication Date |
|---|---|
| CN101100815A CN101100815A (en) | 2008-01-09 |
| CN100577911C true CN100577911C (en) | 2010-01-06 |
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| CN200710024154A Expired - Fee Related CN100577911C (en) | 2007-07-23 | 2007-07-23 | Method for increasing inking printing pigment ink color fastness |
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Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101531848B (en) * | 2009-03-24 | 2011-10-05 | 深圳市墨库数码耗材有限公司 | An environment-friendly digital ink-jet direct printing textile ink and method for preparing same |
| CN101851867B (en) * | 2010-06-02 | 2012-08-01 | 黄文泉 | Textile printing and dyeing ink and preparation method thereof |
| CN102127333A (en) * | 2011-01-12 | 2011-07-20 | 郑州鸿盛数码科技股份有限公司 | Direct ink-jet printing disperse dye ink and use method thereof |
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| CN110205838B (en) * | 2019-06-17 | 2021-12-24 | 浙江海印数码科技有限公司 | Cyan ink-jet ink for ink-jet printing of polyester fabric, preparation process thereof and ink-jet printing method |
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| CN113026384B (en) * | 2021-03-18 | 2023-01-03 | 常州喜莱维纺织科技有限公司 | Fabric micro-printing method |
| CN114960235A (en) * | 2021-07-31 | 2022-08-30 | 上海九裕纺织科技有限公司 | Printing production process of nylon fabric |
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