CN1296753A - Plant insecticide and its preparing process - Google Patents
Plant insecticide and its preparing process Download PDFInfo
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- CN1296753A CN1296753A CN00113939A CN00113939A CN1296753A CN 1296753 A CN1296753 A CN 1296753A CN 00113939 A CN00113939 A CN 00113939A CN 00113939 A CN00113939 A CN 00113939A CN 1296753 A CN1296753 A CN 1296753A
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- plant
- nimbin
- matrine
- oxymatrine
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An insecticide is mainly prepared from nimbin and matrine through mixing. Its advantages are quickly taking its high effect, low toxicity, easy degradation, no residue, and not easily generating resistance for pests.
Description
The present invention relates to a kind of plant insecticide and preparation method thereof.
It mainly is the quality that improves the quantity of crop products, improves crop products that common people use the purpose of agricultural chemicals.More and more higher to the requirement of living environment, quality of life along with the mankind and use chemical pesticide to cause in a large number environmental pollution, the reality of food pollution forces us to have to develop and uses efficient, low toxicity, the easy agrichemical without enviromental pollution for plant of degraded, noresidue.
The seal chinaberry (Azadirachtin) of extracting from Meliaceae plant seal chinaberry (Azadirchta) fruit seed nuclei is a kind of broad-spectrum plant insecticide, it is by growing to the stomach poison function of harmful insect, food refusal effect and to insect growth, and reproductive capability suppresses, destroys the purpose that reaches pest control.Harmless to people and animals and pest natural enemy, and easily degraded, noresidue, free from environmental pollution.
Kuh-seng (Flavescens) is a kind of conventional Chinese medicine, have very strong sterilization, antiviral, improve effects such as body immunity and expelling parasite.Its Main Ingredients and Appearance is matrine, oxymatrine, ammothamnine, Sophocarpine, N-Methylcytisine etc., is referred to as to call alkaloid of sophora flavescens ait.Except that kuh-seng, part plant in the pulse family (as white tattooing, Sophora alopecuroide etc.) is rich in alkaloid of sophora flavescens ait.And these plants distributions are wide, and reserves are big, easily gather.In recent years, alkaloid of sophora flavescens ait except that being extensive use of in the medical treatment, is also widely applied in agricultural fungicides and bactericide.The agricultural fungicides of being produced by alkaloid of sophora flavescens ait is to the person poultry harmless, environmentally safe.
Tea Saponin (Tea saponin, TS) be from the product-tea seed cake after the oil expression of oil tea (Camellia oleifera), tea seeds such as (C.sinensis), to extract and get, belong to the pentacyclic triterpene plant sapogenin glycoside on the structure, have extensive use in many-sides such as medicine, agricultural chemicals, washing, cosmetics, papermaking, ore dressings.Early stage Tea Saponin was once done soil pesticide and was extensive use of, and oil tea cake leachate has the better prevention effect to oncomelania, fly maggot, hookworm and rice blast, the rice sheath blight etc.Be suitable for emulsifier, synergist and the stabilizing agent of used as pesticides.
The objective of the invention is to develop the plant insecticide agricultural chemicals of a class based on Meliaceae plant extracts nimbin, leguminous plant extract alkaloid of sophora flavescens ait.Remedy single plant extracts as insecticide deficiency in use to reach; Urge the long weak point of mending mutually with being mixed of many sections various plants extract, improve result of use, enlarge the scope of application, reduce use cost.
Technical scheme of the present invention: plant insecticide is made up of the composition of following weight ratio:
Nimbin 0.1-90% oxymatrine 0.1-98%
Other plant extracts of matrine 0.1-98% 0-50%
All the other are auxiliary agent.
Other plant extracts is a Tea Saponin.
Said preparation can be diluted to the spray agent that contains nimbin 0.1-1000PPM, oxymatrine 0.1-1000PPM and matrine 0.1-1000PPM concentration.
Said preparation can be made into emulsion, aqua, aqueous emulsion, colloidal suspending agent, soluble powder and wetting powder.
The preparation method of plant insecticide measures the content that prints chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait and the nimbin in other plant material, oxymatrine, matrine, other plant extracts earlier; The content requirement of nimbin 0.1-90%, the oxymatrine 0.1-98% that sets in prescription, matrine 0.1-98%, other plant extracts 0-50% is determined the proportioning ratio of seal chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait and other plant material and mixed then: mixed raw material input is extracted equipment, extract with solvent refluxing, stop extracting after being leached into the extraction content of regulation; Be evaporated to the liquid extract of specified quantity behind the extracting liquid filtering; In the liquid extract that concentrates, add other auxiliary agent of setting by prescription; By standard testing, not meeting standard code as content can be adjusted to up to specification with nimbin elaboration, alkaloid of sophora flavescens ait elaboration, other other plant extracts elaboration.
The present invention has the following advantages and effect:
1, after nimbin and alkaloid of sophora flavescens ait and other plant extracts are mixed, both can overcome the slow shortcoming of seal chinaberry insecticide effect, the advantage that can keep printing chinaberry insecticide long action time again.
2, nimbin and alkaloid of sophora flavescens ait all are botanical pesticides, and being mixed between them kept botanical pesticide low toxicity, efficient, easily degraded, noresidue, to insect be difficult for developing immunity to drugs, advantage free from environmental pollution.
3, being mixed of nimbin and alkaloid of sophora flavescens ait and other plant extracts can enlarge the prevention and treatment range to agricultural pest, and can make it to become one is insecticide, is again bactericidal agent, but also is the novel agrochemical formulations of antivirotic.
Describe technology contents of the present invention in detail with embodiment below.
Embodiment 1: produce (nimbin+oxidation kuh-seng+matrine) missible oil of 1%.
Proportioning components (weight);
Nimbin content 0.3% oxymatrine concentration 0.5%
Matrine content 0.2% surfactant 30%
Stabilizing agent 15% organic solvent 53.8%
PH value conditioning agent 0.2%
Preparation method: the elaboration method that is mixed, the nimbin of setting by prescription, oxymatrine, content of matrine requirements are first with behind the organic solvent dissolution with elaboration nimbin, elaboration oxymatrine, elaboration matrine, add surfactant, stabilizing agent, pH value conditioning agent again and stir and get final product.
Embodiment 2: produce (nimbin+oxidation kuh-seng-matrine) missible oil of 1.5%.
Proportioning components (weight):
Nimbin content 0.5% oxymatrine concentration 0.8%
Matrine content 0.2% surfactant 30%
Stabilizing agent 15% organic solvent 53.3%
PH value conditioning agent 0.2%
Preparation method: the solution method that is mixed.
1, the solution that contains nimbin is produced:
With seal chinaberry seed is raw material, and after first cold press was fuel-displaced, marc was with organic solvent degreasing or no longer degreasing, and after the filtration of organic solvent refluxing extraction, the liquid extract that is evaporated to setting concentration is standby.
2, the solution that contains alkaloid of sophora flavescens ait is produced:
The plant, rhizome, the fruit that are rich in alkaloid of sophora flavescens ait with pulse family are raw material, use the organic solvent refluxing extraction, filter.It is standby that extract is evaporated to the liquid extract of setting concentration.
3, be mixed:
Nimbin, oxymatrine, the content of matrine of setting in prescription determine to contain nimbin solution, contain alkaloid of sophora flavescens ait solution the proportioning ratio and mix, add surfactant, stabilizing agent, organic solvent, pH value conditioning agent then and stir and get final product.
Embodiment 3: produce (nimbin+oxidation kuh-seng+matrine) missible oil of 2%.
Proportioning components (weight):
Nimbin content 0.8% oxymatrine concentration 1%
Matrine content 0.2% surfactant 30%
Stabilizing agent 15% organic solvent 52.8%
PH value conditioning agent 0.2%
Preparation method: mix extraction method.
1, measure earlier seal chinaberry seed marc, be rich in nimbin, oxymatrine, content of matrine in the leguminous plant raw material of alkaloid of sophora flavescens ait; The nimbin of setting by prescription, oxymatrine, content of matrine requirements are determined to print chinaberry seed marc, are rich in the leguminous plant proportion of raw materials ratio of alkaloid of sophora flavescens ait and mix then; Mixed raw material input is extracted equipment, extracts with solvent refluxing, stops extracting after being leached into the extraction content of regulation; Be evaporated to the liquid extract of specified quantity behind the extracting liquid filtering;
2, adding surfactant, stabilizing agent, organic solvent, pH value conditioning agent in the liquid extract that concentrates stirs and gets final product.Not meeting standard code by standard testing such as content can be adjusted to up to specification with nimbin elaboration or alkaloid of sophora flavescens ait elaboration.
Embodiment 4: produce (nimbin+oxidation kuh-seng+matrine) aqueous emulsion of 1.5%.
Proportioning components (weight):
Nimbin content 0.3% oxymatrine concentration 1%
Matrine content 0.2% Tea Saponin 5%
Surfactant 20% stabilizing agent 10%
Preservative 1% organic solvent 20%
PH value conditioning agent 0.2% water 42.3%
Preparation method: the elaboration method that is mixed, the content requirement of the nimbin of setting by prescription, oxymatrine, matrine, Tea Saponin earlier with behind the organic solvent dissolution, adds elaboration nimbin, elaboration oxymatrine, elaboration matrine, elaboration Tea Saponin again in surfactant, stabilizing agent, preservative, pH value conditioning agent and water and stirs and get final product.
Embodiment 5: produce (nimbin+oxidation kuh-seng+matrine) aqueous emulsion of 2.5%.
Proportioning components (weight):
Nimbin content 1% oxymatrine concentration 1.2%
Matrine content 0.3% Tea Saponin 8%
Surfactant 17% stabilizing agent 10%
Preservative 1% organic solvent 20%
PH value conditioning agent 0.2% water 41.3%
Preparation method: mix extraction method.
1, the content of the nimbin in elder generation's mensuration seal chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait and the tea seed marc, oxymatrine, matrine, Tea Saponin; The content requirement of the nimbin of setting in prescription, oxymatrine, matrine, Tea Saponin is determined the proportioning ratio of seal chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait, tea seed marc and is mixed then; Mixed raw material input is extracted equipment, extracts with solvent refluxing, stops extracting after being leached into the extraction content of regulation; Be evaporated to the liquid extract of specified quantity behind the extracting liquid filtering;
2, adding surfactant, stabilizing agent, preservative, organic solvent, pH value conditioning agent and water in the liquid extract that concentrates stirs and gets final product.Not meeting standard code by standard testing such as content can be adjusted to up to specification with nimbin elaboration, alkaloid of sophora flavescens ait elaboration and elaboration Tea Saponin.
Relevant component is selected as follows in above-mentioned five Example formulations:
Surfactant can be selected for use: tween, sapn, OP-10, sell pool, rare, the sldium lauryl sulfate of polyoxy second;
Stabilizing agent can be selected for use: epoxidized vegetable oil;
Organic solvent can be selected for use: methyl alcohol, ethanol, butanone;
The PH conditioning agent can be selected for use: sodium hydroxid, acetic acid;
Preservative is selected for use; Benzoic acid is received.
Claims (5)
1, a kind of plant insecticide is characterized in that said preparation is made up of the composition of following weight ratio:
Nimbin 0.1-90% oxymatrine 0.1-98%
Other plant extracts of matrine 0.1-98% 0-50%
All the other are auxiliary agent.
2, plant insecticide according to claim 1 is characterized in that: other plant extracts is a Tea Saponin.
3, plant insecticide according to claim 1 is characterized in that: said preparation can be diluted to the spray agent that contains nimbin 0.1-1000PPM, oxymatrine 0.1-1000PPM and matrine 0.1-1000PPM concentration.
4, plant insecticide according to claim 1 is characterized in that: said preparation can be made into emulsion, aqua, aqueous emulsion, colloidal suspending agent, soluble powder and wetting powder.
5, a kind of preparation method of plant insecticide is characterized in that: the content of measuring seal chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait and the nimbin in other plant material, oxymatrine, matrine, other plant extracts earlier; The content requirement of nimbin 0.1-90%, the oxymatrine 0.1-98% that sets in prescription, matrine 0.1-98%, other plant extracts 0-50% is determined the proportioning ratio of seal chinaberry seed marc, the leguminous plant raw material that is rich in alkaloid of sophora flavescens ait and other plant material and is mixed then; Mixed raw material input is extracted equipment, extracts with solvent refluxing, stops extracting after being leached into the extraction content of regulation: the liquid extract that is evaporated to specified quantity behind the extracting liquid filtering; In the liquid extract that concentrates, add other auxiliary agent of setting by prescription; By standard testing, not meeting standard code as content can be adjusted to up to specification with nimbin elaboration, alkaloid of sophora flavescens ait elaboration, other plant extracts elaboration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001139398A CN1147234C (en) | 2000-09-30 | 2000-09-30 | Plant insecticide and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001139398A CN1147234C (en) | 2000-09-30 | 2000-09-30 | Plant insecticide and its preparing process |
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| Publication Number | Publication Date |
|---|---|
| CN1296753A true CN1296753A (en) | 2001-05-30 |
| CN1147234C CN1147234C (en) | 2004-04-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB001139398A Expired - Fee Related CN1147234C (en) | 2000-09-30 | 2000-09-30 | Plant insecticide and its preparing process |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100356850C (en) * | 2006-08-08 | 2007-12-26 | 李珍发 | Plant antiviral agent |
| CN102125028A (en) * | 2010-12-17 | 2011-07-20 | 乔建国 | Paste for preventing and curing stem borer |
| CN102246827A (en) * | 2011-08-15 | 2011-11-23 | 浙江东奇生物科技有限公司 | Compound pesticide |
| CN102484992A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergetic pesticide composition of nimbin and tea saponin |
| CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
| CN102792951A (en) * | 2012-03-21 | 2012-11-28 | 张文龙 | Insecticidal fungicide with matrine and tea saponin |
| CN101926337B (en) * | 2009-12-29 | 2013-01-09 | 华南农业大学 | Pesticide composite of tea saponin and |
| CN102860312A (en) * | 2012-09-28 | 2013-01-09 | 江苏省绿盾植保农药实验有限公司 | Insecticide containing sophoridine and azadirachtin |
| CN103651356A (en) * | 2013-12-04 | 2014-03-26 | 云南省农业科学院农业环境资源研究所 | Application of isoeleutherol for inducing tobacco plants to generate alternaria longipes resistance |
| CN103814912A (en) * | 2014-02-18 | 2014-05-28 | 陶荣芝 | Nimbin emulsion and its preparation method |
| CN104824039A (en) * | 2015-06-02 | 2015-08-12 | 张文龙 | Tea saponin EW (emulsion in water) compound plant source organic insecticide and preparation method thereof |
| CN104886085A (en) * | 2015-06-12 | 2015-09-09 | 福建省德盛生物工程有限责任公司 | Low-volume spray containing sophocarpidine |
| CN105454257A (en) * | 2014-08-15 | 2016-04-06 | 青岛罗素生物技术有限公司 | Oxymatrine oil agent and preparation technology thereof |
| CN106577705A (en) * | 2016-11-22 | 2017-04-26 | 恒大园林集团有限公司 | Compounded ecological pesticide and preparing method thereof |
| CN106966809A (en) * | 2017-04-21 | 2017-07-21 | 山东沃森农业科技有限公司 | A kind of insect prevention cultivation matrix tamed for candidum tissue culturing seedling |
| CN107467088A (en) * | 2017-06-26 | 2017-12-15 | 浦江县昂宝生物技术有限公司 | Malus spectabilis insecticide and preparation method thereof |
| CN108124889A (en) * | 2017-12-11 | 2018-06-08 | 新科环农（北京）生物科技有限公司 | Plant source biopesticide and preparation method thereof |
| CN110800765A (en) * | 2019-11-10 | 2020-02-18 | 金中北 | Plant essential oil cleaning agent |
-
2000
- 2000-09-30 CN CNB001139398A patent/CN1147234C/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100356850C (en) * | 2006-08-08 | 2007-12-26 | 李珍发 | Plant antiviral agent |
| CN101926337B (en) * | 2009-12-29 | 2013-01-09 | 华南农业大学 | Pesticide composite of tea saponin and |
| CN102484992A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergetic pesticide composition of nimbin and tea saponin |
| CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
| CN102125028A (en) * | 2010-12-17 | 2011-07-20 | 乔建国 | Paste for preventing and curing stem borer |
| CN102125028B (en) * | 2010-12-17 | 2013-10-30 | 乔建国 | Paste for preventing and curing stem borer |
| CN102246827A (en) * | 2011-08-15 | 2011-11-23 | 浙江东奇生物科技有限公司 | Compound pesticide |
| CN102246827B (en) * | 2011-08-15 | 2014-06-25 | 高海利 | Compound pesticide |
| CN102792951A (en) * | 2012-03-21 | 2012-11-28 | 张文龙 | Insecticidal fungicide with matrine and tea saponin |
| CN102860312A (en) * | 2012-09-28 | 2013-01-09 | 江苏省绿盾植保农药实验有限公司 | Insecticide containing sophoridine and azadirachtin |
| CN103651356B (en) * | 2013-12-04 | 2015-07-01 | 云南省农业科学院农业环境资源研究所 | Application of isoeleutherol for inducing tobacco plants to generate alternaria longipes resistance |
| CN103651356A (en) * | 2013-12-04 | 2014-03-26 | 云南省农业科学院农业环境资源研究所 | Application of isoeleutherol for inducing tobacco plants to generate alternaria longipes resistance |
| CN103814912A (en) * | 2014-02-18 | 2014-05-28 | 陶荣芝 | Nimbin emulsion and its preparation method |
| CN105454257A (en) * | 2014-08-15 | 2016-04-06 | 青岛罗素生物技术有限公司 | Oxymatrine oil agent and preparation technology thereof |
| CN104824039A (en) * | 2015-06-02 | 2015-08-12 | 张文龙 | Tea saponin EW (emulsion in water) compound plant source organic insecticide and preparation method thereof |
| CN104886085A (en) * | 2015-06-12 | 2015-09-09 | 福建省德盛生物工程有限责任公司 | Low-volume spray containing sophocarpidine |
| CN106577705A (en) * | 2016-11-22 | 2017-04-26 | 恒大园林集团有限公司 | Compounded ecological pesticide and preparing method thereof |
| CN106966809A (en) * | 2017-04-21 | 2017-07-21 | 山东沃森农业科技有限公司 | A kind of insect prevention cultivation matrix tamed for candidum tissue culturing seedling |
| CN107467088A (en) * | 2017-06-26 | 2017-12-15 | 浦江县昂宝生物技术有限公司 | Malus spectabilis insecticide and preparation method thereof |
| CN108124889A (en) * | 2017-12-11 | 2018-06-08 | 新科环农（北京）生物科技有限公司 | Plant source biopesticide and preparation method thereof |
| CN110800765A (en) * | 2019-11-10 | 2020-02-18 | 金中北 | Plant essential oil cleaning agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1147234C (en) | 2004-04-28 |
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