CN1283603C - 负载的催化剂以及在该催化剂上进行氢化以制备醇的方法 - Google Patents
负载的催化剂以及在该催化剂上进行氢化以制备醇的方法 Download PDFInfo
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- CN1283603C CN1283603C CNB2003801030080A CN200380103008A CN1283603C CN 1283603 C CN1283603 C CN 1283603C CN B2003801030080 A CNB2003801030080 A CN B2003801030080A CN 200380103008 A CN200380103008 A CN 200380103008A CN 1283603 C CN1283603 C CN 1283603C
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- hydrogenation
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
实施例 | 催化剂时空间速度[g(MA)/ml(cat)·h] | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
2 | 0.1 | 100 | 88.8 | 0.1 | 0.1 | 8.7 | 0.0 | 99.5 |
3 | 0.2 | 100 | 72.5 | 14.4 | 0.9 | 6.3 | 0.0 | 97.5 |
实施例 | p[巴] | T[℃] | H2[I(STP)/h] | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
5 | 80 | 160 | 50 | 100 | 91.4 | 0.7 | 0.1 | 4.4 | 0 | 98.3 |
6 | 90 | 150 | 25 | 100 | 91.1 | 1.8 | 0.3 | 6.6 | 0 | 101.9 |
实施例 | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
C3 | 100 | 19.7 | 0.0 | 20.3 | 0.1 | 0 | 41.3 |
实施例 | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
C5 | 100 | 15.3 | 46.6 | 20.3 | 0.2 | 22.2 | 107.7 |
实施例 | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
8 | 100 | 87.9 | 0.0 | 0.0 | 3.1 | 0.0 | 91.5 |
实施例 | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
10 | 100 | 60.1 | 0.1 | 1.1 | 19.8 | 0.0 | 85.1 |
实施例 | 催化剂 | p[巴] | T[℃] | 进料[g/h] | MA转化率[%] | BDO[%] | GBL[%] | THF[%] | BuOH[%] | SA/SAN[%] | 碳平衡[%] |
12 | F | 80 | 160 | 25 | 94.9 | 93.1 | 1.1 | 0.5 | 4.0 | 0.0 | 105.2 |
13 | F | 80 | 180 | 37.5 | 86.4 | 73.3 | 6.0 | 1.0 | 3.4 | 0.0 | 98.2 |
C7 | C6 | 80 | 160 | 25 | 89.9 | 34.5 | 55.1 | 0.1 | 0.6 | 17.8 | 118.3 |
Claims (15)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10252280.4 | 2002-11-11 | ||
DE10252280A DE10252280A1 (de) | 2002-11-11 | 2002-11-11 | Verbesserter Katalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung an diesem Katalysator |
Publications (2)
Publication Number | Publication Date |
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CN1711229A CN1711229A (zh) | 2005-12-21 |
CN1283603C true CN1283603C (zh) | 2006-11-08 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CNB2003801030080A Expired - Fee Related CN1283603C (zh) | 2002-11-11 | 2003-11-06 | 负载的催化剂以及在该催化剂上进行氢化以制备醇的方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20060030743A1 (zh) |
EP (1) | EP1562882B1 (zh) |
JP (1) | JP2006505399A (zh) |
KR (1) | KR100979619B1 (zh) |
CN (1) | CN1283603C (zh) |
AT (1) | ATE455745T1 (zh) |
AU (1) | AU2003293663A1 (zh) |
DE (2) | DE10252280A1 (zh) |
MY (1) | MY134409A (zh) |
WO (1) | WO2004043890A2 (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5231786B2 (ja) * | 2006-12-05 | 2013-07-10 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
US20140112849A1 (en) | 2011-06-21 | 2014-04-24 | Umicore Ag & Co., Kg | Method for the depositon of metals on support oxides |
US20130131399A1 (en) * | 2011-11-23 | 2013-05-23 | Celanese International Corporation | Catalyst Preparations for High Conversion Catalysts for Producing Ethanol |
BR112016030824B1 (pt) * | 2014-06-30 | 2021-02-23 | Haldor Topsoe A/S | processo para a preparação de etileno glicol a partir de açúcares |
CN107913704B (zh) * | 2016-10-09 | 2020-02-07 | 中国石油化工股份有限公司 | 丁二烯生产1,4-二乙酰氧基丁烷的加氢催化剂 |
WO2018164193A1 (ja) | 2017-03-08 | 2018-09-13 | 三菱ケミカル株式会社 | カルボニル化合物の水素化触媒ならびにアルコールの製造方法 |
JP7342868B2 (ja) * | 2018-07-23 | 2023-09-12 | 三菱ケミカル株式会社 | アルコールの製造方法及び触媒 |
JP7555537B2 (ja) * | 2019-02-15 | 2024-09-25 | 国立大学法人大阪大学 | アルコールの製造方法 |
CN110639513A (zh) * | 2019-10-21 | 2020-01-03 | 大连理工大学 | 一种己二酸直接加氢制1,6-己二醇催化剂的制备方法及应用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2519817A1 (de) * | 1975-05-03 | 1976-11-11 | Hoechst Ag | Verfahren zur herstellung von butandiol-(1.4) |
US4149962A (en) * | 1978-03-20 | 1979-04-17 | Uop Inc. | Hydrocarbon conversion with a superactive multimetallic catalytic composite |
SG74602A1 (en) * | 1996-12-20 | 2000-08-22 | Standard Oil Co | Improved catalysts for the hydrogenation of maleic acid to 1,4-butanediol |
DE10009817A1 (de) | 2000-03-01 | 2001-09-06 | Basf Ag | Verfahren zur Herstellung von Alkoholen an rheniumhaltigen Aktivkohle-Trägerkatalysatoren |
US6713032B2 (en) * | 2002-04-12 | 2004-03-30 | Matsushita Electric Works, Ltd. | Catalyst for removing carbon monoxide in hydrogen rich gas and production method therefor |
-
2002
- 2002-11-11 DE DE10252280A patent/DE10252280A1/de not_active Withdrawn
-
2003
- 2003-11-06 WO PCT/EP2003/012378 patent/WO2004043890A2/de active Application Filing
- 2003-11-06 KR KR1020057008306A patent/KR100979619B1/ko not_active IP Right Cessation
- 2003-11-06 AU AU2003293663A patent/AU2003293663A1/en not_active Abandoned
- 2003-11-06 EP EP03789012A patent/EP1562882B1/de not_active Expired - Lifetime
- 2003-11-06 JP JP2004550945A patent/JP2006505399A/ja active Pending
- 2003-11-06 US US10/534,457 patent/US20060030743A1/en not_active Abandoned
- 2003-11-06 DE DE50312371T patent/DE50312371D1/de not_active Expired - Lifetime
- 2003-11-06 AT AT03789012T patent/ATE455745T1/de not_active IP Right Cessation
- 2003-11-06 CN CNB2003801030080A patent/CN1283603C/zh not_active Expired - Fee Related
- 2003-11-10 MY MYPI20034291A patent/MY134409A/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE10252280A1 (de) | 2004-05-27 |
WO2004043890A2 (de) | 2004-05-27 |
MY134409A (en) | 2007-12-31 |
KR100979619B1 (ko) | 2010-09-01 |
WO2004043890A3 (de) | 2004-07-29 |
JP2006505399A (ja) | 2006-02-16 |
ATE455745T1 (de) | 2010-02-15 |
CN1711229A (zh) | 2005-12-21 |
AU2003293663A1 (en) | 2004-06-03 |
KR20050086487A (ko) | 2005-08-30 |
DE50312371D1 (de) | 2010-03-11 |
EP1562882B1 (de) | 2010-01-20 |
EP1562882A2 (de) | 2005-08-17 |
US20060030743A1 (en) | 2006-02-09 |
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