CN1280314C - 控制聚合物分子量和结构的方法 - Google Patents

控制聚合物分子量和结构的方法 Download PDF

Info

Publication number
CN1280314C
CN1280314C CNB98803123XA CN98803123A CN1280314C CN 1280314 C CN1280314 C CN 1280314C CN B98803123X A CNB98803123X A CN B98803123XA CN 98803123 A CN98803123 A CN 98803123A CN 1280314 C CN1280314 C CN 1280314C
Authority
CN
China
Prior art keywords
alkyl
group
aryl
formula
replacement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB98803123XA
Other languages
English (en)
Chinese (zh)
Other versions
CN1249759A (zh
Inventor
A·G·安德森
A·格里德内夫
G·莫尔德
E·里扎多
S·H·坦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commonwealth Scientific and Industrial Research Organization CSIRO
EIDP Inc
Original Assignee
Commonwealth Scientific and Industrial Research Organization CSIRO
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commonwealth Scientific and Industrial Research Organization CSIRO, EI Du Pont de Nemours and Co filed Critical Commonwealth Scientific and Industrial Research Organization CSIRO
Publication of CN1249759A publication Critical patent/CN1249759A/zh
Application granted granted Critical
Publication of CN1280314C publication Critical patent/CN1280314C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/38—One oxygen atom with acyl radicals or hetero atoms directly attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB98803123XA 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法 Expired - Fee Related CN1280314C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3472797P 1997-01-10 1997-01-10
US60/034,727 1997-01-10

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNA2006100681573A Division CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Publications (2)

Publication Number Publication Date
CN1249759A CN1249759A (zh) 2000-04-05
CN1280314C true CN1280314C (zh) 2006-10-18

Family

ID=21878221

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB98803123XA Expired - Fee Related CN1280314C (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法
CNA2006100681573A Pending CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA2006100681573A Pending CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Country Status (10)

Country Link
US (3) US6271340B1 (https=)
EP (1) EP0951485B1 (https=)
JP (1) JP2001508485A (https=)
KR (1) KR100504055B1 (https=)
CN (2) CN1280314C (https=)
AU (1) AU750626B2 (https=)
BR (1) BR9807104A (https=)
CA (1) CA2277164C (https=)
DE (2) DE69829588T2 (https=)
WO (1) WO1998030601A2 (https=)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
DE69916455T2 (de) * 1998-07-31 2004-09-09 Ciba Specialty Chemicals Holding Inc. Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler
CA2341384A1 (en) * 1998-09-29 2000-04-06 Ciba Specialty Chemicals Holding Inc. Process for the preparation of polymers containing n->o terminal groups
FR2784111B1 (fr) 1998-10-06 2003-08-01 Atochem Elf Sa Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
US6559255B2 (en) 1999-03-09 2003-05-06 Symyx Technologies Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
DE60027309T2 (de) 1999-07-02 2006-08-31 Symyx Technologies, Inc., Santa Clara Polymerverzweigungen zur immobilisierung von molekülen auf oberflächen oder substraten, wobei die polymere wasserlösliche oder wasserdispergierbare segmente und sonden aufweisen
ATE272610T1 (de) * 1999-07-02 2004-08-15 Ciba Sc Holding Ag Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
DE60015553T2 (de) * 1999-08-12 2005-10-27 Ciba Speciality Chemicals Holding Inc. Polymermischungen mit verbesserter schlagfestigkeit
AU7025600A (en) * 1999-09-08 2001-04-10 School Of Pharmacy, University Of London, The Uniform molecular weight polymers
WO2001023435A1 (en) * 1999-09-30 2001-04-05 Noveon Ip Holdings Corp. Polymerization compositions and methods
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
DE10036801A1 (de) 2000-07-28 2002-02-07 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
WO2002056021A2 (en) 2001-01-10 2002-07-18 Symyx Technologies Inc Polymer brushes for immobilizing molecules to a surface
US6547840B2 (en) 2001-04-02 2003-04-15 Ciba Specialty Chemicals Corporation Candle wax stabilized with imidazolidines
US6849679B2 (en) 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
US20030073835A1 (en) 2001-07-31 2003-04-17 Dario Lazzari Imidazolidinone derivatives
EP1283240A1 (en) * 2001-07-31 2003-02-12 Ciba SC Holding AG Imidazolidinone derivatives
DE10149084A1 (de) 2001-10-05 2003-06-18 Tesa Ag UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung
DE10149083A1 (de) 2001-10-05 2003-04-17 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
US7375175B2 (en) 2002-08-19 2008-05-20 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
US6841636B2 (en) * 2002-08-19 2005-01-11 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
FR2852961B1 (fr) * 2003-03-26 2006-07-07 Atofina Nouveau procede de synthese/fabrication de films acryliques
FR2852963A1 (fr) * 2003-03-26 2004-10-01 Atofina Nouveau procede de synthese/fabrication de films acryliques
DE10322830A1 (de) * 2003-05-19 2004-12-09 Tesa Ag Verfahren zur kontinuierlichen Herstellung von Polymeren aus vinylischen Verbindungen durch Substanz-beziehungsweise Lösungsmittelpolymerisation
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
US7741510B2 (en) * 2005-01-13 2010-06-22 E. I. Du Pont De Nemours And Company Rheology control agents
US7632882B2 (en) * 2005-01-13 2009-12-15 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US7652121B2 (en) * 2005-01-13 2010-01-26 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US20060155021A1 (en) * 2005-01-13 2006-07-13 Lenges Christian P Coating compositions containing rheology control agents
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
US7009011B1 (en) * 2005-05-31 2006-03-07 Xerox Corporation Copolymers of maleic anhydride by stable free redical polymerization
US20070028806A1 (en) * 2005-08-03 2007-02-08 Piro Bonnie D Coating compositions having improved appearance containing coated titanium dioxide pigments
JP5068765B2 (ja) * 2005-12-14 2012-11-07 ノバルティス アーゲー シリコーンヒドロゲルの製造方法
US9051473B2 (en) * 2006-06-14 2015-06-09 Axalta Coating Systems Ip Co., Llc Clear coating compositions comprising dispersed silica nono-particles and processes for using
US20080021147A1 (en) * 2006-06-14 2008-01-24 Jun Lin Process for forming a dispersion of silica nano-particles
EP2027224A2 (en) * 2006-06-14 2009-02-25 E.I. Du Pont De Nemours And Company Coated substrate having enhanced scratch and mar resistance
WO2008031733A2 (en) * 2006-09-12 2008-03-20 Ciba Holding Inc. Imidazolidinone nitroxides as electrode materials for energy storage devices
EP2235146B1 (en) * 2007-12-18 2016-04-20 Basf Se Biodiesel cold flow improver
WO2012000992A1 (en) 2010-06-29 2012-01-05 Basf Se Process for improving the flow properties of polymer melts
TWI413648B (zh) * 2010-12-31 2013-11-01 Chi Mei Corp 共軛二烯－乙烯基芳香烴共聚物及其製備方法
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
FR3030525B1 (fr) * 2014-12-18 2018-05-11 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
CN104788594B (zh) * 2015-04-16 2018-07-24 厦门大学 一种端氨基聚合物的制备方法
JP7356875B2 (ja) 2019-11-20 2023-10-05 キリンホールディングス株式会社 カチオン性重合開始剤
EP3875566B1 (de) 2020-03-06 2023-01-11 Henkel AG & Co. KGaA Nitroxidverbindungen in wasch- oder reinigungsmitteln
EP4240578B1 (en) 2020-11-04 2024-12-18 Alcon Inc. Method for making photochromic contact lenses
EP4514595A1 (en) 2022-04-26 2025-03-05 Alcon Inc. Method for making embedded hydrogel contact lenses

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1528233A (fr) * 1966-06-15 1968-06-07 Sankyo Co Nouveaux composés 4-oxoimidazolidine-1-oxydes tétrasubstitués en position-2, 2, 5, 5 et procédé pour leur préparation
CH579117A5 (https=) * 1973-06-22 1976-08-31 Ciba Geigy Ag
DE2621947A1 (de) * 1975-05-23 1976-12-09 Ciba Geigy Ag Neue hydroxide von 3-alkyl-4-oxo- imidazolidinen
DE3486145T2 (de) 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.

Also Published As

Publication number Publication date
WO1998030601A2 (en) 1998-07-16
KR20000070015A (ko) 2000-11-25
KR100504055B1 (ko) 2005-07-27
US20030149208A1 (en) 2003-08-07
EP0951485A2 (en) 1999-10-27
CN1824655A (zh) 2006-08-30
BR9807104A (pt) 2000-04-25
EP0951485B1 (en) 2003-04-02
DE69829588D1 (de) 2005-05-04
JP2001508485A (ja) 2001-06-26
DE69829588T2 (de) 2006-01-19
CN1249759A (zh) 2000-04-05
CA2277164A1 (en) 1998-07-16
DE69812885D1 (de) 2003-05-08
WO1998030601A3 (en) 1998-12-03
US6271340B1 (en) 2001-08-07
US20020061989A1 (en) 2002-05-23
AU750626B2 (en) 2002-07-25
CA2277164C (en) 2005-11-08
AU6022998A (en) 1998-08-03
DE69812885T2 (de) 2004-01-29

Similar Documents

Publication Publication Date Title
CN1280314C (zh) 控制聚合物分子量和结构的方法
CN1240725C (zh) 接枝聚合物的合成
CN1200953C (zh) 受控自由基聚合方法
US6455706B2 (en) Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
CN1082965C (zh) 烯丙基链转移剂
US6624306B2 (en) 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
CN1241577A (zh) 在一种稳定的自由基存在下乳液聚合法
CN1293106C (zh) 用于除去聚合物链端的二硫代基的方法
CN1252813A (zh) 大单体的合成方法
CN1308363C (zh) 嵌段共聚物的制备方法
CN1303396A (zh) 聚合方法
US6388004B1 (en) Method of controlling polymer molecular weight and structure
CN1507432A (zh) 水溶性二硫酯及其聚合方法
EP1178010B1 (en) Colorless aqueous ammonium sulfide solution
HK1027581B (en) Controlled free radical polymerization process
CN1688592A (zh) 由β－磷酸化氮氧化物形成的烷氧基胺及其在自由基聚合中的应用
MXPA99006330A (en) Method of controlling polymer molecular weight and structure
HK1068144A (en) The in situ polymerization of monoethylenically unsaturated monomers with oligomeric or polymeric secondary amines

Legal Events

Date Code Title Description
C06 Publication
C10 Entry into substantive examination
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee