CN1270022A - 漂白角蛋白纤维的无水组合物 - Google Patents
漂白角蛋白纤维的无水组合物 Download PDFInfo
- Publication number
- CN1270022A CN1270022A CN00104637A CN00104637A CN1270022A CN 1270022 A CN1270022 A CN 1270022A CN 00104637 A CN00104637 A CN 00104637A CN 00104637 A CN00104637 A CN 00104637A CN 1270022 A CN1270022 A CN 1270022A
- Authority
- CN
- China
- Prior art keywords
- compositions
- alkyl
- bleaching
- polymer
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 134
- 238000004061 bleaching Methods 0.000 title claims abstract description 55
- 239000000835 fiber Substances 0.000 title claims abstract description 28
- 108010076876 Keratins Proteins 0.000 title claims abstract description 22
- 102000011782 Keratins Human genes 0.000 title claims abstract description 22
- 229920000642 polymer Polymers 0.000 claims abstract description 93
- 210000004209 hair Anatomy 0.000 claims abstract description 55
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 25
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 125000000129 anionic group Chemical group 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- -1 ethoxyl Chemical group 0.000 claims description 71
- 125000000217 alkyl group Chemical group 0.000 claims description 50
- 229920001577 copolymer Polymers 0.000 claims description 43
- 125000001931 aliphatic group Chemical group 0.000 claims description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 28
- 239000000178 monomer Substances 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 25
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 22
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 20
- 150000001768 cations Chemical class 0.000 claims description 20
- 229920002678 cellulose Polymers 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 150000001450 anions Chemical class 0.000 claims description 13
- 239000001913 cellulose Substances 0.000 claims description 13
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 9
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- 238000005660 chlorination reaction Methods 0.000 claims description 8
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
- 230000003252 repetitive effect Effects 0.000 claims description 8
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical group [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- 239000002453 shampoo Substances 0.000 claims description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 150000004291 polyenes Chemical class 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229920013818 hydroxypropyl guar gum Polymers 0.000 claims description 3
- XXQBGBUZLWZPKT-UHFFFAOYSA-N n-prop-2-enoylbuta-2,3-dienamide Chemical compound C=CC(=O)NC(=O)C=C=C XXQBGBUZLWZPKT-UHFFFAOYSA-N 0.000 claims description 3
- 239000003605 opacifier Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004641 Diallyl-phthalate Substances 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical group C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 238000011010 flushing procedure Methods 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 239000003979 granulating agent Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000012764 mineral filler Substances 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 230000008719 thickening Effects 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 101001031591 Mus musculus Heart- and neural crest derivatives-expressed protein 2 Proteins 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 229940056582 human hair preparation Drugs 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 abstract description 3
- 239000002585 base Substances 0.000 description 22
- 239000002253 acid Substances 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 235000010980 cellulose Nutrition 0.000 description 10
- 229920000768 polyamine Polymers 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 241001597008 Nomeidae Species 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N anhydrous methyl chloride Natural products ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 230000029936 alkylation Effects 0.000 description 5
- 238000005804 alkylation reaction Methods 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 5
- 229920001661 Chitosan Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 229920002907 Guar gum Polymers 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 229940092705 beclomethasone Drugs 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000665 guar gum Substances 0.000 description 4
- 235000010417 guar gum Nutrition 0.000 description 4
- 229960002154 guar gum Drugs 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- GRZMEERIPCJGSO-UHFFFAOYSA-N oxalic acid;sodium Chemical compound [Na].[Na].OC(=O)C(O)=O GRZMEERIPCJGSO-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- KFSQJVOLYQRELE-UHFFFAOYSA-N 2-ethyl-2-butenoic acid Chemical compound CCC(=CC)C(O)=O KFSQJVOLYQRELE-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical class NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 244000299461 Theobroma cacao Species 0.000 description 3
- 235000009470 Theobroma cacao Nutrition 0.000 description 3
- 241001080929 Zeugopterus punctatus Species 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 125000003282 alkyl amino group Chemical group 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- NBMKJKDGKREAPL-DVTGEIKXSA-N beclomethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(Cl)[C@@H]1[C@@H]1C[C@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O NBMKJKDGKREAPL-DVTGEIKXSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 229960001484 edetic acid Drugs 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical class O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 239000001836 Dioctyl sodium sulphosuccinate Substances 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229940048053 acrylate Drugs 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000001350 alkyl halides Chemical class 0.000 description 2
- 125000004414 alkyl thio group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000003944 halohydrins Chemical class 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 125000004193 piperazinyl group Chemical group 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 150000003335 secondary amines Chemical group 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical group 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- 150000003462 sulfoxides Chemical class 0.000 description 2
- 229940095064 tartrate Drugs 0.000 description 2
- 150000003512 tertiary amines Chemical group 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- RLEQVGMLDNITBW-UHFFFAOYSA-N 2,4,4-trimethylhexanedioic acid Chemical compound OC(=O)C(C)CC(C)(C)CC(O)=O RLEQVGMLDNITBW-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 1
- GKMQZRFBORPJNG-UHFFFAOYSA-N 3-(4-oxidomorpholin-4-ium-4-yl)propan-1-amine Chemical compound NCCC[N+]1([O-])CCOCC1 GKMQZRFBORPJNG-UHFFFAOYSA-N 0.000 description 1
- XROQZQBOVZIYSK-UHFFFAOYSA-N 3-aminopropyl-dimethyl-(3-methyl-2-oxobut-3-enyl)azanium Chemical compound CC(=C)C(=O)C[N+](C)(C)CCCN XROQZQBOVZIYSK-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 description 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 241001044369 Amphion Species 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- IZIKYDMEBJERRS-UHFFFAOYSA-N C(C=C)(=O)OC[N+](C)(C)CC.CCl Chemical compound C(C=C)(=O)OC[N+](C)(C)CC.CCl IZIKYDMEBJERRS-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 240000006685 Carthamus lanatus Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical group OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- VPMWDFRZSIMDKW-YJYMSZOUSA-N Salmefamol Chemical compound C1=CC(OC)=CC=C1C[C@@H](C)NC[C@H](O)C1=CC=C(O)C(CO)=C1 VPMWDFRZSIMDKW-YJYMSZOUSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- WGQKYBSKWIADBV-UHFFFAOYSA-O benzylaminium Chemical compound [NH3+]CC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-O 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- BZWQNMUGNDAMBX-UHFFFAOYSA-N butyl butane-1-sulfonate Chemical compound CCCCOS(=O)(=O)CCCC BZWQNMUGNDAMBX-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229940073642 ceteareth-30 Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 125000004427 diamine group Chemical group 0.000 description 1
- 150000004985 diamines Chemical group 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N dimethyl monosulfide Natural products CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 150000002009 diols Chemical group 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- VFNGKCDDZUSWLR-UHFFFAOYSA-L disulfate(2-) Chemical compound [O-]S(=O)(=O)OS([O-])(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- DSNUMCVVLPZLKT-UHFFFAOYSA-N ethyl-dimethyl-(3-methyl-2-oxobut-3-enyl)azanium Chemical compound CC[N+](C)(C)CC(=O)C(C)=C DSNUMCVVLPZLKT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000003370 grooming effect Effects 0.000 description 1
- 231100000640 hair analysis Toxicity 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000002461 imidazolidines Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical class CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 210000002752 melanocyte Anatomy 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 125000002757 morpholinyl group Chemical group 0.000 description 1
- ITFGZZGYXVHOOU-UHFFFAOYSA-N n,n-dimethylmethanamine;methyl hydrogen sulfate Chemical compound C[NH+](C)C.COS([O-])(=O)=O ITFGZZGYXVHOOU-UHFFFAOYSA-N 0.000 description 1
- AWDYCSUWSUENQK-UHFFFAOYSA-N n-decylprop-2-enamide Chemical compound CCCCCCCCCCNC(=O)C=C AWDYCSUWSUENQK-UHFFFAOYSA-N 0.000 description 1
- XQPVIMDDIXCFFS-UHFFFAOYSA-N n-dodecylprop-2-enamide Chemical compound CCCCCCCCCCCCNC(=O)C=C XQPVIMDDIXCFFS-UHFFFAOYSA-N 0.000 description 1
- SWPMNMYLORDLJE-UHFFFAOYSA-N n-ethylprop-2-enamide Chemical compound CCNC(=O)C=C SWPMNMYLORDLJE-UHFFFAOYSA-N 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical group CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229950001879 salmefamol Drugs 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E05—LOCKS; KEYS; WINDOW OR DOOR FITTINGS; SAFES
- E05D—HINGES OR SUSPENSION DEVICES FOR DOORS, WINDOWS OR WINGS
- E05D15/00—Suspension arrangements for wings
- E05D15/06—Suspension arrangements for wings for wings sliding horizontally more or less in their own plane
- E05D15/0621—Details, e.g. suspension or supporting guides
- E05D15/0626—Details, e.g. suspension or supporting guides for wings suspended at the top
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P43/00—Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
-
- E—FIXED CONSTRUCTIONS
- E05—LOCKS; KEYS; WINDOW OR DOOR FITTINGS; SAFES
- E05Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES E05D AND E05F, RELATING TO CONSTRUCTION ELEMENTS, ELECTRIC CONTROL, POWER SUPPLY, POWER SIGNAL OR TRANSMISSION, USER INTERFACES, MOUNTING OR COUPLING, DETAILS, ACCESSORIES, AUXILIARY OPERATIONS NOT OTHERWISE PROVIDED FOR, APPLICATION THEREOF
- E05Y2600/00—Mounting or coupling arrangements for elements provided for in this subclass
- E05Y2600/60—Mounting or coupling members; Accessories therefor
- E05Y2600/62—Bolts
-
- E—FIXED CONSTRUCTIONS
- E05—LOCKS; KEYS; WINDOW OR DOOR FITTINGS; SAFES
- E05Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES E05D AND E05F, RELATING TO CONSTRUCTION ELEMENTS, ELECTRIC CONTROL, POWER SUPPLY, POWER SIGNAL OR TRANSMISSION, USER INTERFACES, MOUNTING OR COUPLING, DETAILS, ACCESSORIES, AUXILIARY OPERATIONS NOT OTHERWISE PROVIDED FOR, APPLICATION THEREOF
- E05Y2600/00—Mounting or coupling arrangements for elements provided for in this subclass
- E05Y2600/60—Mounting or coupling members; Accessories therefor
- E05Y2600/626—Plates or brackets
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Emergency Medicine (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Cosmetics (AREA)
Abstract
本发明涉及漂白角蛋白纤维,尤其是头发的在适于漂白的介质中的无水组合物,涉及使用这些组合物,通过与水性过氧化氢组合物混合制备即用的漂白组合物,和涉及用这些无水组合物漂白头发的方法。所述的无水组合物含有至少一种碱性剂和至少一种过氧化的盐及下述聚合物的混合物;-至少一种含有至少一个脂肪链的阴离子和/或非离子两亲聚合物,-至少一种阳离子或两性直接聚合物。
Description
本发明涉及漂白角蛋白纤维,尤其是头发的无水组合物,该组合物包括含至少一个脂肪链的至少一种阴离子两亲聚合物和/或含至少一个脂肪链的至少一种非离子两亲聚合物及至少一种阳离子或两性直接聚合物的混合物;本发明涉及使用这些组合物制备即用的漂白组合物;本发明涉及使用这些组合物漂白角蛋白纤维的方法,和涉及包含该组合物的包装桶。
人体角蛋白纤维,尤其是头发的漂白通过黑素的氧化,使其溶解并部分或全部去除该颜料来完成的。
含有过氧化试剂如铵或碱金属过硫酸盐、过硼酸盐或过碳酸盐的漂白粉在使用时与水性过氧化氢组合物结合通常用于漂白头发。由于过氧化的盐和过氧化氢在酸性介质中相当稳定,需要在碱性pH值下将它们活化,以便产生足够的氧。因而通常在漂白粉中添加诸如胺和碱性硅酸盐的碱性化合物。
这种通过氧化和碱性试剂进行的化学处理常常是侵蚀性很大,并改变了角蛋白的化学结构。
这一点反映出头发的美发性差,如很难清理、感觉不舒服或头发粗糙、无光泽,特别是角蛋白纤维的降解。
纤维降解尤其是不希望的,因为它不可逆地破坏了头发的物理化学性能。头发变得更多孔并因此变得更难干,对各种诸如染料或永久卷发的其它头发处理方法更敏感,头发的机械性能和表面特性被不愉快地改变,这反映出如头发拉伸或断裂强度降低或头发摩擦系数增大。
为克服这些缺点,迄今已使用阳离子或两性直接聚合物。通过将这些聚合物应用在头发上,改善了头发的美发性能,即它们使头发变得更柔软、更有光泽和更易于清理,但并不能明显限制角蛋白纤维的降解。
本申请人惊奇地发现,通过将通常使用的阳离子或两性直接聚合物与含有至少一个脂肪链的一种或多种两亲聚合物,也是指如阴离子和/或非离子缔合聚合物相结合,可能明显限制角蛋白纤维的降解。
因此本发明的一个目的是提供一种漂白角蛋白纤维,尤其是人体角蛋白纤维的在适合漂白的介质中的无水组合物,包括:至少一种碱性试剂;至少一种过氧化的盐;并另外含有一混合物,该混合物含:
—至少一个脂肪链的至少一种阴离子和/或非离子两亲聚合物,和
—至少一种阳离子或两性直接聚合物。
本发明的目的还包括使用这种无水组合物制备即用的漂白组合物。
本发明的另一个目的是使用上述无水漂白组合物漂白角蛋白纤维的方法,以及包含该组合物的包装桶。
阅读本说明书和实施例后便会知道本发明的其它目的。
根据本发明与阳离子或两性直接的聚合物结合使用的含有至少一个脂肪链的阴离子两亲聚合物是交联或非交联共聚物,包含
—从一个或多个包含带自由羧酸官能团的烯属不饱和键的单体衍生的亲水单元,和
—从一个或多个包含带疏水侧链的烯属不饱和键的单体衍生的疏水单元,和非必须的
—从一个或多个多不饱和单体衍生的交联单元。
包含带羧酸基团的烯属不饱和键的单体选自乙基丙烯酸、甲基丙烯酸和丙烯酸,优选自甲基丙烯酸和丙烯酸及它们的混合物。
包含带有疏水侧链的烯属不饱和键的单体可以是(i)不饱和羧酸的脂肪烷基酯,或(ii)烯丙基脂肪烷基醚。
(i)不饱和羧酸的脂肪烷基酯选自例如C10-C30,优选C12-C22,乙基丙烯酸烷基酯、甲基丙烯酸烷基酯和/或丙烯酸烷基酯。
它们包括例如丙烯酸月桂基酯、丙烯酸硬脂基酯、丙烯酸癸基酯、丙烯酸异癸基酯和丙烯酸十二烷基酯,以及相应的甲基丙烯酸酯,即甲基丙烯酸月桂基酯、甲基丙烯酸硬脂基酯、甲基丙烯酸癸基酯、甲基丙烯酸异癸基酯和甲基丙烯酸十二烷基酯。
(ii)形成本发明阴离子两亲聚合物疏水单元的烯丙基脂肪烷基醚对应的通式为
(I)CH2=CR’CH2-O-Bn-R其中
R’表示氢原子或甲基,
B表示亚乙氧基,
n是0到100的整数,
R表示选自包含8到30个碳原子,优选10到24个碳原子,更优选12到18个碳原子的烷基、芳烷基、芳基、烷芳基和环烷基的烃基。
本发明优选的通式(I)的一个单元是其中R’表示氢原子、n等于10和R表示硬脂基(C18)的单元。
所述交联单体是含有至少两个非共轭可聚合双键的化合物。可提及的实例是邻苯二甲酸二烯丙基酯、(甲基)丙烯酸烯丙基酯、二乙烯基苯、二甲基丙烯酸(聚)乙二醇酯、亚甲基二丙烯酰胺、聚烯丙基蔗糖或聚烯丙基季戊四醇。
上述类型的阴离子两亲聚合物描述在例如美国专利3915921和4509949中((甲基)乙基丙烯酸与(甲基)乙基丙烯酸C10-C30烷基酯的共聚物),或描述在专利EP-0216479B2中((甲基)乙基丙烯酸与烯丙基脂肪醇醚的共聚物)。
可提及的优选聚合物的实例是:
—丙烯酸与丙烯酸C10-C30烷基酯的交联聚合物,如Goodrich公司以商品名Pemulen TR1、Pemulen TR2和Carbopol 1382销售的聚合物,
—丙烯酸与甲基丙烯酸C10-C30烷基酯的交联聚合物,如Goodrich公司销售的Carbopol ETD 2020,
—氧乙烯化甲基丙烯酸/丙烯酸乙酯/甲基丙烯酸硬脂基酯(55/35/10)的三元共聚物,
—氧乙烯化(25EO)的(甲基)丙烯酸/丙烯酸乙酯/甲基丙烯酸二十二烷基酯的三元共聚物,和
—交联的甲基丙烯酸/丙烯酸乙基酯/steareth-10烯丙基醚三元共聚物。
本发明可用的含有至少一个脂肪链的非离子两亲聚合物包括,例如:
—用含有至少一个脂肪链的基团改性的纤维素或羟烷基纤维素,所述基团如烷基、芳烷基或烷芳烷基,所含烷基优选为C8-C22的烷基,如产于Aqualon公司的产品Natrosol Plus Grade 330 CS、产于Berol Nobel公司的Bermocoll EHM 100或产于Hercules公司的Polysurf67;或用聚烷氧基化的烷基苯酚基团改性的纤维素或羟烷基纤维素,如产于Amerchol公司的产品Amercell Polymer HM-1500;
—用含有至少一个C8-C22脂肪链的基团改性的羟丙基瓜耳胶,诸如产于Lamberti公司的产品Esaflor HM 22(C22烷基链),或产于Rhone-Poulenc公司的Miracare XC95-3(C14烷基链)和RE205-1(C20烷基链);
—含有至少一个C8-C30烷基或链烯基型脂肪链的聚氨酯,诸如产于Servodelben公司的产品SER-AD FX 1100,或
—具有癸基端基的SMDI(饱和亚甲基二苯基二异氰酸酯)聚乙二醇共聚物;
—具有烷基(甲基/C18)端基与麦芽糖糊精基质混合的SMDI(饱和亚甲基二苯基二异氰酸酯)聚乙二醇共聚物;
—氧乙烯化(66 EO)和氧丙烯化(14 PO)的C10-C18醇的HMDI(1,6-己二异氰酸酯)二尿烷,由Akzo公司以商品名Elfacos T 212销售;
—乙烯基吡咯烷酮与含有脂肪链的疏水单体的共聚物,诸如产于ISP公司的产品Antaron V216或Ganex V216(聚(乙烯基吡咯烷酮/十六碳烯))、AntaronV220或GanexV220(聚(乙烯基吡咯烷酮/二十碳烯));
—(甲基)丙烯酸C1-C6烷基酯与含有至少一个脂肪链的两亲单体的共聚物;
—亲水(甲基)丙烯酸酯与含有至少一个脂肪链的疏水单体的共聚物,例如聚(聚甲基丙烯酸乙二醇酯/甲基丙烯酸月桂基酯)。
含有至少一个C10-C20烷基型脂肪链的聚氨酯和用含有至少一个C8-C22烷基的基团改性的羟乙基纤维素是尤其优选的。
无水组合物含有阴离子和/或非离子两亲聚合物,所述聚合物中所含的至少一个脂肪链的比例为0.03~30%(重量),优选0.3~15%(重量)。
在本发明的漂白组合物中,含有至少一个上述脂肪链的阴离子和/或非离子两亲聚合物与至少一种阳离子或两性直接聚合物的混合物。
在化妆品领域,术语“直接聚合物”表示聚合物能够依赖其对诸如头发的载体强亲和力,在载体上形成沉积物的聚合物。直接性能通常根据由Richard J.Crawford在Journal ofthe Society of Cosmetic Chemists,1980,31(5),第273-278页中描述的测试方法评价。
为达到本发明的目的,表述“阳离子聚合物”表示任何含有阳离子基团和/或可离子化为阳离子基团的基团的聚合物。
本发明可用的阳离子聚合物可选自任何本身已知用作改善头发的美发性能的聚合物,即尤其是在专利申请EP-A-337354和EP-A-557203中和在法国专利FR-2270846、2383660、2598611、2470596和2519863中描述的聚合物。
优选的阳离子聚合物选自那些含有带伯、仲、叔和/或季铵基团的单元的聚合物,该单元或者形成聚合物主链部分或者由直接连接在其上的侧取代基携带。
所用的阳离子聚合物通常具有约500到5×106,优选约103到3×106的数均分子量。
在可提及的阳离子聚合物中,更优选的是诸如聚胺、聚氨基酰胺和聚季铵的聚合物。
这些是公知的产品。它们尤其描述在法国专利2505348或2542997中。在所述聚合物中,可提及的是:
R3可以相同或不同,表示氢原子或CH3;
A可以相同或不同,表示1到6个碳原子,优选2或3个碳原子的线性或支链烷基,或1到4个碳原子的羟烷基;
R4、R5和R6可以相同或不同,表示含有1到18个碳原子的烷基或苄基,优选含有1到6个碳原子的烷基;
R1和R2可以相同或不同,表示氢或含有1到6个碳原子的烷基,优选甲基或乙基;
X表示从无机或有机酸衍生的阴离子,诸如甲基硫酸盐(methosulphate)阴离子或诸如氯或溴的卤素。
第(1)组的聚合物也可含有一个或多个从共聚单体衍生的单元,所述共聚单体可选自丙烯酰胺、甲基丙烯酰胺、双丙酮丙烯酰胺、用低级(C1-C4)烷基在氮上取代的丙烯酰胺和甲基丙烯酰胺、丙烯酸或甲基丙烯酸或它们的酯、诸如乙烯基吡咯烷酮或乙烯基己内酰胺的乙烯基内酰胺,以及乙烯基酯。
这样,在第(1)组的聚合物中,可提及的是:
—丙烯酰胺与用二甲基硫酸盐或二甲基卤化物季铵化的甲基丙烯酸二甲基氨乙基酯的共聚物,
—丙烯酰胺与氯化甲基丙烯酰氧乙基三甲基铵的共聚物,描述在例如专利申请EP-A-080976,
—丙烯酰胺与甲基丙烯酰氧乙基三甲基铵甲基硫酸盐的共聚物,
—季铵化或非季铵化的乙烯基吡咯烷酮/丙烯酸二烷基氨烷基酯或甲基丙烯酸二烷基氨烷基酯共聚物。这些聚合物详细描述在法国专利2077143和2393573中,
—甲基丙烯酸二甲基氨基乙基酯/乙烯基己内酰胺/乙烯基吡咯烷酮的三元共聚物,
—乙烯基吡咯烷酮/甲基丙烯酰氨丙基二甲基胺的共聚物,以及
—季铵化的乙烯基吡咯烷酮/二甲基氨丙基甲基丙烯酰胺的共聚物。
(2)含有季铵基团的纤维素醚衍生物,描述在法国专利1492597中。这些聚合物在CTFA词典中也被定义为已与被三甲基铵基取代的环氧化物反应的羟乙基纤维素的季铵。
(3)阳离子纤维素的衍生物,诸如用季铵的水溶性单体接枝的纤维素共聚物或纤维素衍生物,尤其是描述在美国专利41315%中的诸如羟烷基纤维素,如用尤其是甲基丙烯酰乙基三甲基铵、甲基丙烯酰氨丙基三甲基铵或二甲基二烯丙基铵盐接枝的羟甲基-、羟乙基-或羟丙基纤维素。
(4)尤其详细描述在美国专利3589578和4031307中的阳离子聚糖,诸如含有阳离子三烷基铵基团的瓜耳胶。例如使用由2,3-环氧丙基三甲基铵的盐(如氯化物)改性的瓜耳胶。
(5)由哌嗪单元和直链或支链的二价亚烷基或羟亚烷基构成的聚合物,以及这些聚合物的氧化和/或季铵化产物,所述直链或支链二价亚烷基或羟亚烷基可选择性插入氧、硫或氮原子或芳环或杂环。这些聚合物尤其描述在法国专利2162025和2280361中。
(6)尤其是通过酸性化合物与聚胺的缩聚制备的水溶性聚氨基酰胺(polyamino amide);这些聚氨基酰胺可与表卤代醇、双环氧化合物、双酐、不饱和双酐、双不饱和衍生物、双卤代醇、双氮杂环丁烷、双卤酰二胺、双烷基卤化物交联,或作为选择,双官能团化合物反应得到的低聚物交联,所述双官能团化合物可与双卤代醇、双氮杂环丁烷、双卤酰二胺、双烷基卤化物、表卤代醇、双环氧化合物或双不饱和衍生物反应;对于每一聚氨基酰胺的胺基团而言,交联剂的用量为0.025~0.35mol;这些聚氨基酰胺可烷基化,或者如果它们含有一个或多个叔胺官能团,它们也可以季铵化。这些聚合物尤其描述在法国专利2252840和2368508中。
(7)由聚亚烷基多胺与聚羧酸缩合,然后用双官能试剂烷基化得到的聚氨基酰胺衍生物。可提到的是例如己二酸/二烷基氨羟烷基二亚烷基三胺聚合物,其中烷基含有1到4个碳原子,优选甲基、乙基或丙基。这些聚合物尤其描述在法国专利1583363中。
在这些衍生物中,更尤其可提到的是由Sandoz公司以商品名“Cartaretine F、F4或F8”销售的己二酸/二甲基氨基羟丙基/二亚乙基三胺聚合物。
(8)由含有两个伯氨基和至少一个仲氨基的聚亚烷基多胺与选自二甘醇酸和具有3到8个碳原子的饱和脂族二羧酸的二羧酸反应得到的聚合物。聚亚烷基多胺与二羧酸的摩尔比在0.8∶1和1.4∶1之间;这样得到的聚氨基酰胺与表卤代醇反应,表卤代醇与聚氨基酰胺的仲胺基团的摩尔比在0.5∶1和1.8∶1之间。这些聚合物尤其描述在美国专利3227615和2961347中。
(9)烷基二烯丙基胺或二烷基二烯丙基铵的环聚物,诸如含有与通式(VI)或(VII)对应的单元、作为链的主要组成的均聚物或共聚物:其中符号k和t等于0或1,k+t的和等于1;R9代表氢原子或甲基;R7和R8各自相互独立地代表含有1到22个碳原子的烷基、其中的烷基具有优选为1到5个碳原子的羟烷基、或低级(C1-C4)酰氨基烷基,或者R7和R8与它们带有的氮原子一起可代表诸如哌啶基或吗啉基的杂环基;Y-是诸如溴化物、氯化物、乙酸盐、硼酸盐、柠檬酸盐、酒石酸盐、硫酸氢盐、亚硫酸氢盐、硫酸盐或磷酸盐的阴离子。这些聚合物尤其描述在法国专利2080759和在它的附加许可证2190406中。
(10)含有对应通式(VIII)的重复单元的季二铵聚合物:其中R10、R11、R12和R13可相同或不同,代表含有1到20个碳原子的脂族基、脂环基或芳脂族基,或低级羟烷基脂族基,或作为选择,R10、R11、R12和R13一起或单独,与它们所带的氮原子一起构成杂环,该杂环除氮原子外含或不含第二杂原子,或作为选择,R10、R11、R12和R13代表被腈、酯、酰或酰胺的基团或-CO-O-R14-D基或CO-NH-R14-D基取代的线性或支链的C1-C6烷基,其中R14是亚烷基和D是季铵基;
A1和B1代表含有2到20个碳原子的线性或支链、饱和或不饱和的聚亚甲基基团,所述基团含有与主链连接或嵌入主链的一个或多个芳族环,或一个或多个氧或硫原子或亚砜、砜、二硫化物、氨基、烷氨基、羟基、季铵基、脲基、酰胺基或酯基,以及
X-表示从无机或有机酸衍生的阴离子;
A1、R10和R12可与连接在其上的两个氮原子一起形成哌嗪环;另外,如果A1表示线性或支链、饱和或不饱和亚烷基或羟亚烷基,B1也可表示-(CH2)n-CO-D-OC-(CH2)n-基,其中D表示
a)通式-O-Z-O-的二醇残基,其中Z表示线性或支链烃基或下列通式之一对应的基团:
-(CH2-CH2-O)x-CH2-CH2-
-[CH2-CH(CH3)-O]y-CH2-CH(CH3)-其中x和y表示1到4的整数,代表确定的和唯一的聚合度,或表示从1到4的代表平均聚合度的任何值;
b)诸如哌嗪衍生物的双仲二胺残基;
c)通式为-NH-Y-NH-的双伯二胺残基,其中Y表示线性或支链烃基,或作为选择表示二价基团-CH2-CH2-S-S-CH2-CH2-;
d)通式为-NH-CO-NH-的1,3-亚脲基。
优选地,X-是诸如氯化物或溴化物的阴离子。
这些聚合物通常具有1000到100000的数均分子量。
该类型聚合物尤其描述在法国专利2320330、2270846、2316271、2336434和2413907,以及美国专利2273780、2375853、2388614、2454547、3206462、2261002、2271378、3874870、4001432、3929990、3966904、4005193、4025617、4025627、4025653、4026945和4027020中。
更优选可使用的聚合物是那些由以下通式(IX)对应的重复单元构成的聚合物:其中R15、R16、R17和R18可相同或不同,表示具有约1到4个碳原子的烷基或羟烷基,n和p是约2到20的整数,X-是从无机酸或有机酸衍生的阴离子。
R19、R20、R21和R22可相同或不同,代表氢原子或甲基、乙基、丙基、β-羟乙基、β-羟丙基或-CH2CH2(OCH2CH2)pOH基,其中p等于0或1到6的整数,
条件是R19、R20、R21和R22不同时代表氢原子,
r和s可相同或不同,是1到6的整数,
q等于0或1到34的整数,
X表示卤素原子,
A表示二卤化物基团,或优选代表-CH2-CH2-O-CH2-CH2-。
这些化合物尤其描述在专利申请EP-A-122324中。
(12)乙烯基吡咯烷酮或乙烯基咪唑的季聚合物。
(13)诸如CTFA词典中名称为聚乙二醇(15)牛脂聚胺的产品的聚胺。
(14)甲基丙烯酰氧(C1-C4)烷基三(C1-C4)烷基铵的交联聚合物,诸如这样的聚合物,即用氯代甲烷季铵化的甲基丙烯酸二甲基氨乙基酯均聚,或用丙烯酰胺与用氯代甲烷季铵化的甲基丙烯酸二甲基氨乙基酯共聚,均聚或共聚后将均聚物或共聚物用含烯属不饱和键的化合物,尤其是亚甲基二丙烯酰胺,交联得到的聚合物。更优选能以这样的分散体形式使用丙烯酰胺/氯化甲基丙烯酰氧基乙基三甲基铵(20/80(重量))交联共聚物,所述分散体分散在矿物油中,其中含有50%(重量)的上述共聚物。该分散体由Allied Colloids公司以商品名SalcareSC 92销售。也可以使用在矿物油或液体酯中含有约50%(重量)的甲基丙烯酰氧基乙基三甲基氯化铵交联均聚物。这些分散体由AlliedColloids公司以商品名SalcareSC 95和SalcareSC 96销售。也可使用甲基丙烯酰氧基乙基三甲基铵和甲基丙烯酰氧基乙基二甲基乙酰基铵的共聚物的甲基硫酸盐,由Rohm Gmbh公司以商品名Plex7525L销售(CTFA名:Polyquatemium-35)。
本发明可使用的其它阳离子聚合物是聚亚烷基亚胺,尤其是聚亚乙基亚胺、含有乙烯基吡啶或乙烯基吡啶嗡单元的聚合物、聚胺和表氯醇的缩合物、聚季1,3-亚脲基以及几丁质衍生物。
本发明可使用的两性聚合物可选自含有随机分散在聚合物链中的K和M单元的聚合物,其中K表示从含有至少一个碱性氮原子的单体衍生的单元,M表示从含有一个或多个羧基或磺基的酸性单体衍生的单元,或作为选择,K和M可表示从羧基甜菜碱或磺基甜菜碱两性离子单体衍生的基团。
K和M也可表示含有伯、仲、叔或季胺基团的阳离子聚合物链,其中至少一种胺基团带有通过烃基连接的羧基或磺基,或作为选择,K和M形成含有α,β-二羧酸亚乙基单元的聚合物链的一部分,其中一个羧基已与含有一个或多个伯或仲胺基团的聚胺反应。
更尤其优选上述定义的两性成膜聚合物选自以下聚合物:
(1)由从带有羧基的乙烯基化合物衍生的单体和从含有至少一个碱性原子的取代的乙烯基化合物衍生的碱性单体共聚得到的聚合物,所述带有羧基的乙烯基化合物衍生的单体更优选诸如丙烯酸、甲基丙烯酸、马来酸、α-氯代丙烯酸,所述含有至少一个碱性原子的取代的乙烯基化合物衍生的碱性单体更优选诸如甲基丙烯酸二烷基氨烷基酯和丙烯酸二烷基氨烷基酯、二烷基氨烷基甲基丙烯酰胺和二烷基氨烷基丙烯酰胺。这些化合物描述在美国专利No.3836537中。还可提及丙烯酸钠/氯化丙烯酰氨基丙基三甲基铵的共聚物。
乙烯基化合物也可以是诸如氯化二乙基二烯丙基铵的二烷基二烯丙基铵盐。
(2)含有这样的单元的聚合物,该单元衍生自:
a)至少一种选自氮上用烷基取代的丙烯酰胺和甲基丙烯酰胺的单体,
b)至少一种含有一个或多个反应性羧基的酸性共聚单体,和
c)至少一种碱性共聚单体,诸如含有丙烯酸和甲基丙烯酸的伯、仲、叔和季胺取代基的酯,以及用二甲基或二乙基硫酸盐对甲基丙烯酸二甲基氨乙基酯季铵化的产品。
本发明更优选的N-取代的丙烯酰胺或甲基丙烯酰胺是烷基含有2到12个碳原子的基团,更优选是N-乙基丙烯酰胺、N-叔丁基丙烯酰胺、N-叔辛基丙烯酰胺、N-辛基丙烯酰胺、N-癸基丙烯酰胺、N-十二烷基丙烯酰胺和相应的甲基丙烯酰胺。
酸性共聚单体更优选选自丙烯酸、甲基丙烯酸、巴豆酸、衣康酸、马来酸和富马酸,以及马来或富马酸的具有1到4个碳原子的烷基单酯或酸酐。
优选的碱性共聚单体是甲基丙烯酸氨乙基、丁基氨乙基、N,N’-二甲基氨乙基和N-叔丁基氨乙基酯。
尤其可使用CTFA(第4版,1991)名称为“辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁基氨乙基酯共聚物”的共聚物。
(3)部分地或全部地从通式(XI)的聚氨基酰胺衍生的交联和烷基化的聚氨基酰胺:其中R23代表从饱和二羧酸、含有烯属双键的单或二羧基脂肪酸、这些酸的具有1到6个碳原子的低级链烷醇的酯衍生的二价基团,或代表将任何一种所述酸加成到二(伯)或二(仲)胺中衍生出的基团,Z表示二(伯)、单或二(仲)聚亚烷基-聚胺基,优选地代表:
其中x=2、p=2或3,或作为选择,x=3和p=2,该基团衍生自二亚乙基三胺、三亚乙基四胺或二亚丙基三胺;
c)以0~20%(摩尔)的比例的基团-NH-(CH2)6-NH-,该基团衍生自六亚甲基二胺,这些聚氨基胺通过添加选自表卤代醇、双环氧化合物、双酐和双不饱和衍生物的双官能团交联剂进行交联,对于每个聚氨基酰胺的胺基,使用0.025~0.35摩尔交联剂,还可以通过丙烯酸、氯乙酸或链烷基磺内酯或它们的盐的作用烷基化。
饱和羧酸优选地选自具有6到10个碳原子的酸,例如己二酸、2,2,4-三甲基己二酸和2,4,4-三甲基己二酸、对苯二酸,含有烯属双键的酸,例如丙烯酸、甲基丙烯酸和衣康酸。
在烷基化中使用的链烷基磺内酯优选的是丙磺酸内酯或丁磺酸内酯,烷基化剂的盐优选的是钠盐或钾盐。
(4)含有通式(XIII)的两性离子单元的聚合物:其中R24表示可聚合的不饱和基,如丙烯酸酯基、甲基丙烯酸酯基、丙烯酰胺基或甲基丙烯酰胺基,y和z代表1到3的整数,R25和R26指氢原子、甲基、乙基或丙基,R27和R28指氢原子或R27和R28中碳原子的和不超过10的烷基。
含有这样的单元的聚合物还可以含有衍生自非两性离子单体的单元,所述非两性离子单体如丙烯酸二甲基-或二乙基氨乙基酯或甲基丙烯酸二甲基-或二乙基氨乙基酯,或丙烯酸烷基酯或甲基丙烯酸烷基酯、丙烯酰胺或甲基丙烯酰胺或乙酸乙烯基酯。
通过举例的方式,可提及的是甲基丙烯酸甲酯/二甲基羧甲基铵甲基乙基甲基丙烯酸酯(dimethylcarboxymethylammonio methyl ethylmethacrylate)的共聚物。
(5)衍生自含有对应于以下通式(XIV)、(XV)和(XVI)的单体单元的脱乙酰壳多糖的聚合物:单元XIV的量为0~30%,单元XV的量为5~50%,单元XVI的量为30~90%,当然,在单元F中,R29指通式为(XVII)的基团:其中
如果q=0,R30、R31和R32,可以相同或不同,各自指氢原子、甲基、羟基、乙酸基或氨基,可非必须地插入一个或多个氮原子和/或非必须地用一个或多个氨、羟基、羧基、烷基硫代或磺基取代的单烷基胺残基或二烷基胺残基,其中的烷基带有氨基残基的烷基硫代残基,在这种情况下R30、R31和R32至少一个基团是氢原子;
或,如果q=1,R30、R31和R32各自指氢原子,以及由这些化合物与碱或酸形成的盐。
(6)衍生自脱乙酰壳多糖的N-羧烷基化的聚合物,如N-羧甲基脱乙酰壳多糖或N-羧丁基脱乙酰壳多糖。
(7)与例如在法国专利1400366中描述的通式(XVIII)对应的聚合物:其中R33指氢原子、CH3O、CH3CH2O或苯基,R34指氢或诸如甲基或乙基的低级烷基,R35指氢或诸如甲基或乙基的低级烷基,R36指诸如甲基或乙基的低级烷基或对应通式:-R37-N(R35)2的基团,R37指-CH2-CH2-,-CH2-CH2-CH2-或-CH2-CH(CH3)-基,R35具有上述的意义,以及这些基较高的同系物并含有多达6个碳原子。
(8)类型-D-X-D-X的两性聚合物,选自:
a)通过氯乙酸或氯乙酸钠与含有至少一个通式(XIX)的单元的化合物作用得到的聚合物:
-D-X-D-X (XIX)其中D指基团X指符号E或E’,E或E’,可以相同或不同,指含有在主链上具有多达7个碳原子的直链或支链链的亚烷基的二价基,可以不被取代或用羟基取代,除含有氧、氮或硫原子外,还可含有1到3个芳族环和/或杂环;以醚、硫醚、亚砜、砜、锍、烷基胺或链烯胺基团、羟基、苄胺、氧化胺、季铵、酰胺、酰亚胺、醇、酯和/或聚氨酯基团的形式存在的氧、氮或硫原子;
b)通式为
-D-X-D-X- (XX)
的聚合物其中D指基团X指符号E或E’并至少一次E’;E具有上述意义,E’是具有在主链上含有多达7个碳原子的直链或支链链的亚烷基的二价基,可以不被取代或用一个或多个羟基取代,并含有一个或多个氮原子,氮原子被烷基链取代,烷基链非必须地插入氧原子和必须含有一个或多个羧基或一个或多个羟基官能团,并通过与氯乙酸或氯乙酸钠反应进行甜菜碱化。
(9)(C1-C5)烷基乙烯基醚/马来酸酐共聚物,尤其是用N,N-二烷基氨基烷基胺如N,N-二甲基氨丙基胺半酰胺化改性的共聚物,或用N,N-二链烷醇胺半酯化改性的共聚物。这些共聚物还含有其它乙烯基共聚单体如乙烯基己内酰胺。
阳离子或两性直接聚合物也可以带有疏水基团。
它们选自例如含有季铵基的纤维素衍生物和含有氨基侧基的聚丙烯酸酯,例如:
—含有季铵基的纤维素,用含有至少一个选自带至少8个碳原子的烷基、芳烷基和烷芳基或它们的混合的脂族链的基团改性,
—含有季铵基的羟乙基纤维素,用含有至少一个选自带至少8个碳原子的烷基、芳烷基和烷芳基或它们的混合的脂族链的基团改性,
—含有氨基侧基的聚丙烯酸酯,它们可以或不被季铵化,带有疏水基团。
上述含有季铵基的纤维素或羟乙基纤维素所带的烷基优选含有8到30个碳原子。
芳基优选指苯基、苄基、萘基或蒽基。
在本发明可使用的阳离子或两性直接聚合物中,尤其优选的是:
—由Merck公司以Merquat 100 Dry商品名销售的氯化二甲基二烯丙基铵均聚物;
—由Calgon公司以Merquat 2200商品名销售的氯化二甲基二烯丙基铵与丙烯酰胺的共聚物;
—在法国专利2270846中制备和描述的聚(季铵)型聚合物,由以下通式(XXII)的重复单元构成:尤其是通过凝胶渗透色谱法测得的重均摩尔量为约1200的聚合物;
—在美国专利4390689、4702906和4719282中描述的聚(季铵)型聚合物,由以下通式(XXIII)的重复单元构成:其中
p是1到6的整数,
D指单键或-(CH2)r-CO-,r是4或7,尤其是重均摩尔量小于100000,优选小于或等于50000的聚合物;
—以下两性共聚物:
—由Calgon公司以Merquat 280 Dry商品名销售的氯化二烯丙基二甲基铵/丙烯酸(80/20)的共聚物(CTFA名:Polyquaternium-22);
—由Calgon公司以Merquat 295 Dry商品名销售的氯化二烯丙基二甲基铵/丙烯酸(95/5)的共聚物(CTFA名:Polyquaternium-22);
—甲基丙烯酰氨基丙基氯化三铵与丙烯酸和/或丙烯酸甲酯的共聚物,由Calgon公司以Merquat 2001商品名销售(CTFA名:Polyquaternium-47);和
—丙烯酰胺/氯化二甲基二烯丙基铵/丙烯酸三元共聚物,由Calgon公司以Merquat Plus 3330 Dry商品名销售(CTFA名:Polyquaternium-39)。
在上述直接聚合物中,尤其最优选两性共聚物Polyquaternium-22、Polyquaternium-39和Polyquaternium-47(CTFA命名)。
无水漂白组合物含有阳离子或两性直接聚合物的量按无水组合物计为0.03~30%(重量),优选0.3~15%(重量)。
阴离子和/或非离子两亲聚合物与阳离子或两性直接聚合物的重量比通常为10/1至1/10,优选5/1至1/5。
如上所述,无水漂白组合物含有至少一种碱性剂和至少一种过氧化的盐。
所述碱性剂选自诸如氯化铵、硫酸铵、磷酸铵或硝酸铵的铵盐,碱金属或碱土金属的硅酸盐、磷酸盐或碳酸盐,尤其是碱金属硅酸盐。
过氧化的盐选自铵或碱金属过硫酸盐、过碳酸盐和过硼酸盐。
其中优选使用的过硫酸盐主要是过硫酸钠和过硫酸钾。
以无水组合物的总量为基准计,本发明组合物含有20~70%(重量),优选30~60%(重量)过氧化的盐。
本发明漂白组合物还含有任何在漂白组合物中常用的助剂,它们能有助于处理和使用,能提高组合物的储存性或效率,能提高被处理头发的美发性能。
这些助剂是例如,控制氧释放的试剂,如碳酸镁和氧化镁;诸如纤维素及其衍生物水溶性增稠和凝胶聚合物,如羟乙基纤维素、羟丙基纤维素和羟丙基甲基纤维素,淀粉及其衍生物,羟丙基瓜耳胶和瓜耳胶,藻酸盐,聚糖,聚乙烯基吡咯烷酮,羧甲基纤维素,合成生物聚合胶,阿拉伯胶,gatti胶,黄耆胶,聚丙烯酰胺和聚(丙烯酸);阴离子表面活性剂、非离子表面活性剂、阳离子表面活性剂、两性表面活性剂或两性离子表面活性剂以及它们的混合物;矿物油或植物油;蜡;成粒剂;粘合剂;诸如二氧化硅和粘土的矿物填料;诸如氧化钛的遮光剂;染料;螯合剂和香料。
不用说,本领域普通技术人员将会选择这个或这些非必要的添加物及其用量,使得与本发明漂白组合物本身相关的有益性能不会或不完全受到设想添加剂的负面影响。
本发明的组合物优选含有至少一种表面活性剂。
适合于本发明的表面活性剂尤其是如下的表面活性剂:
(i)阴离子表面活性剂:
作为本发明可以单独或混合使用的阴离子表面活性剂的实例,尤其可以提到如下化合物的盐(特别是碱金属盐,尤其钠盐、铵盐、胺盐、氨基醇盐或镁盐):烷基硫酸盐、烷基醚硫酸盐、烷氨基醚硫酸盐、烷芳基聚醚硫酸盐、单甘油酯硫酸盐;烷基磺酸盐、烷基磷酸盐、烷基酰胺磺酸盐、烷芳基磺酸盐、α-烯属磺酸盐、链烷烃磺酸盐;(C6-C24)烷基磺基琥珀酸盐、(C6-C24)烷基磺基醚琥珀酸盐、(C6-C24)烷基酰胺磺基琥珀酸盐;(C6-C24)烷基磺基乙酸盐;(C6-C24)酰基肌氨酸盐和(C6-C24)酰基谷氨酸盐。还可以使用(C6-C24)烷基聚苷羧酸酯,如烷基聚苷柠檬酸盐、烷基聚苷酒石酸盐和烷基聚苷磺基琥珀酸盐、alkyl sulphosuccinamates;酰基羟乙磺酸盐和N-酰基牛磺酸盐;所有这些不同化合物的烷基或酰基优选的含有12到20个碳原子,芳基优选指苯基或苄基。在这些可以使用的阴离子表面活性剂中,可提到脂肪酸盐,如油酸盐、蓖麻油酸盐、棕榈酸盐和硬脂酸盐、椰子油酸或氢化的椰子油酸;酰基带有8至20个碳原子的酰基乳酸化物(lactylates)。还可以使用alkyl D-galactosiduronic acid及其盐、聚氧亚烷基化的(C6-C24)烷基醚羧酸、聚氧亚烷基化的(C6-C24)烷基芳基醚羧酸和聚氧亚烷基化的(C6-C24)烷基氨基醚羧酸及其盐,尤其是含有2至50个烯化氧基的上述化合物,尤其是含有环氧乙烷基的化合物及其混合物。
(ii)非离子表面活性剂:
非离子表面活性剂是本身公知的化合物(参见Blackie & Son(Glasgow andLondon)出版的M.R.Porter的“表面活性剂手册”,1991,pp.116-178),在本发明中,其性质并不是重要的特征。它们可以选自聚乙氧基化或聚丙氧基化的脂肪酸、烷基苯酚、具有含如8至18个碳原子的脂族链的α-二醇或醇,环氧乙烷或环氧丙烷基的个数在2至50的范围内。可以提到环氧乙烷与环氧丙烷的共聚物,环氧乙烷和环氧丙烷与脂族醇的缩合产物;聚乙氧基化的脂肪酰胺,优选具有2至30摩尔的环氧乙烷、平均含有1至5、尤其1.5至4个甘油基的聚甘油化的脂肪酰胺;聚乙氧基化的脂肪胺,优选具有2至30摩尔的环氧乙烷;具有2至30摩尔环氧乙烷的脱水山梨醇的氧亚乙基化的脂肪酸酯;蔗糖的脂肪酸酯、聚乙二醇的脂肪酸酯、烷基聚苷、N-烷基葡糖胺衍生物、氧化胺如(C10-C14)烷基氧化胺或N-酰基氨丙基吗啉氧化物。值得注意的是非离子表面活性剂的烷基聚苷尤其适合用于本发明。
(iii)两性或两性离子表面活性剂:
两性或两性离子表面活性剂(在本发明中其性质并不是重要的特征)尤其可以是脂族仲或叔胺衍生物,其中脂族基是含有8到18个碳原子和至少一个水溶性阴离子基(如羧酸盐、磺酸盐、硫酸盐、磷酸盐或膦酸盐)的线性或支链链;可以提及(C8-C20)烷基甜菜碱、磺基甜菜碱、(C8-C20)烷基酰氨基(C1-C6)烷基甜菜碱或(C8-C20)烷基酰氨基(C1-C6)烷基磺基甜菜碱。
在胺衍生物中,可提及描述在美国专利2528378和2781354中的产品,在CTFA词典(第3版,1982出版)中分类在名称Amphocarboxyglycinates和Amphocarboxyproppioniates下,并分别具有以下结构:
R38-CONHCH2CH2-N(R39)(R40)(CH2COO-)其中:R38指衍生自存在于水解的可可油中的酸R38-COOH的烷基、庚基、壬基或十一烷基,R39指β-羟乙基和R40指羧甲基;
和
R38’-CONHCH2CH2-N(B)(C)
其中:
B指-CH2CH2OX’,
C指-(CH2)z-Y’,z=1或2,
X’指-CH2CH2-COOH基或氢原子,
Y’指-COOH或-CH2-CHOH-SO3H基,
R38’指在可可油或水解的亚麻子油中存在的酸R-COOH的烷基,烷基,尤其是C7、C9、C11或C13烷基,C17烷基及其异构形式,不饱和C17基。
这些化合物在CTFA词典(第5版,1993)中按以下名称分类:可可基两性二乙酸二钠、月桂基两性二乙酸二钠、癸酰基两性二乙酸二钠、辛基两性二乙酸二钠、可可基两性二丙酸二钠、月桂基两性二丙酸二钠、癸酰基两性二丙酸二钠辛基两性二丙酸二钠、月桂基两性二丙酸、可可基两性二丙酸。
(iv)阳离子表面活性剂:
在阳离子表面活性剂中,尤其可提及的是:选择性的聚氧亚烷基化的伯、仲或叔脂肪族胺盐;季铵盐,如四烷基铵、烷基酰氨基烷基三烷基铵、三烷基苄基铵、三烷基羟烷基铵或烷基吡啶嗡氯化物或溴化物;咪唑啉衍生物;或阳离子性质的氧化胺。
本发明组合物中表面活性剂的用量为组合物总重量的0.01~40%,优选0.1~30%。
无水漂白组合物可以是粉末形式,当与水性过氧化氢溶液混合后产生泥状物。还可以是含有可悬浮或分散在有机溶剂中的粉剂的无水漂白膏的形式,如在专利US4170637、DE3814356、DE3844956、EP0778020和DE19723538中描述的膏。
根据本发明,无水漂白组合物优选的为包覆、未包覆粉末或粉状颗粒的形式。
本发明的目的还包括漂白角蛋白纤维,尤其是人的毛发的方法。
该方法包括以下步骤:
—使用前立即将无水漂白组合物与水性过氧化氢组合物混合,所述无水漂白组合物含有至少一种碱性试剂、至少一种过氧化的盐及至少一种含有至少一个脂肪链的阴离子和/或非离子两亲聚合物与至少一种阳离子或两性直接聚合物的混合物,
—将该混合物施用于待漂白的角蛋白纤维部位,
—将混合物在纤维上滞留足够时间,以获得理想的漂白,该时间通常为10分钟至1小时,优选10到45分钟,和
—用水清洗以去除漂白混合物,然后用香波冲洗,然后干燥。
本发明的另一个目的是使用上述无水漂白组合物制备即用的漂白组合物。为此,将无水组合物与约0.5~10等效重量(equivalent by weight)的水性过氧化氢组合物混合,如浓度为2~12%(重量)的溶液、乳液或凝胶。必须在将产品施用到头发前立即进行混合。
即用的漂白组合物的pH值优选为7~12,更优选为8.5~11.5。
本发明的另一个目的是分几部分的包装装置,也公知为包装“桶”,包括至少两个部件,一个部件装有上述无水漂白组合物,另一个部件装有水性过氧化氢组合物。
下列实施例,仅用于描述而没有限制作用,将使本发明得到更清晰地理解。
实施例1到3
制备了下列A、B和C三种粉状形式的漂白组合物,:
用量(%重量) | |||
组合物A | 组合物B | 组合物C(本发明) | |
过硫酸钾 | 35 | 35 | 35 |
过硫酸钠 | 30 | 30 | 30 |
硅酸钠 | 14 | 14 | 14 |
氯化铵 | 5 | 5 | 5 |
亚乙基二胺四乙酸 | 1 | 1 | 1 |
二辛基磺基琥珀酸钠/苯甲酸钠 | 1 | 1 | 1 |
硬脂酸钙 | 1 | 1 | 1 |
二氧化硅 | 9 | 8 | 6.5 |
Polyquatemium-22* | 0 | 1 | 1 |
交联共聚物(丙烯酸/丙烯酸C10-30烷基酯)** | 0 | 0 | 1.5 |
瓜耳胶*** | 2 | 2 | 2 |
羟乙基纤维素 | 2 | 2 | 2 |
* 由Calgon公司销售的Merquat 280 Dry
**由Goodrich公司销售的Carbopol1382
***由Société Francaise des Colloides公司销售的Guargel D/15
还制备下列过氧化氢组合物D:
组合物D | |
(用量重量%) | |
Cetearyl alcohol/ceteareth-30 | 2.85 |
稳定剂 | 0.06 |
遮光剂 | 0.15 |
过氧化氢 | 9 |
磷酸 | 适量pH2 |
蒸馏水 | 适量100 |
漂白组合物A、B和C各8克与16克过氧化氢组合物D混合。
在3克染成枣红色的头发束上,各用一种即用的组合物AD、BD和CD,按以下约定进行三次连续的漂白循环:
将一束头发浸入每一种即用的组合物中,开始计时后,将头发在保持31℃恒温的盘子上以扇形散开。扇形散开的头发用一半混合物涂覆,然后停留20分钟。20分钟后,将头发迅速翻转,并涂覆剩下的混合物,然后再停留20分钟。暴露时间完成后,将头发用水彻底清洗直到水干净为止。用中和洗发香波除去头发上的氧化剂残留物。将头发用梳子整理并用电干燥器在60℃下干燥1小时,同时用纸巾保护头发。重新润湿头发,再用标准香波清洗一次。整理头发然后用电干燥器在60℃下重新干燥1小时。
漂白后,将每3克头发分成5份,每束0.6克,将每束头发进行以下描述的碱性溶解度测试。
将5束头发的每一束放在置于60℃烘箱中达30分钟的定型盘中;加热后将装有头发的定型盘称重(P0)。将头发从定型盘移开,对这些空盘称重(P1)。然后,将头发放回定型盘,将这些盘放入干燥器中24小时。
将40ml NaOH(0.1N)溶液放入50ml的锥形烧瓶中,将烧瓶置于水浴中保持65℃恒温。当温度稳定后,将待测头发浸入碱性溶液中30分钟,小心搅拌2到3次。移开头发,然后连续清洗3次,每次清洗包括将头发浸入100ml去离子水中15分钟,并时常轻微搅拌。然后将这样清洗的头发沥干,并置于预先校准的定型盘中(P1)。将定型盘和头发置于烘箱中,在105℃干燥24小时。在干燥器中冷却45分钟后,将装有头发的定型盘再称重(P2)。
测量头发的失重,碱性溶解度(AS)用%表示,用以下方法计算:
AS=(P0-P2)/(P0-P1-a)×100其中(P0-P2)表示发束在测试期间的失重,(P0-P1-a)表示发束的初始重量,a相当于发束附着物的重量(0.07g)。
头发的碱性溶解度测量使计量由于漂白造成的角蛋白纤维的降解成为可能。特别是,在漂白期间角蛋白的二硫化物桥氧化为磺酸基提高了待处理头发在碱性溶液中的溶解度。碱性溶解度越高,纤维的降解越强。
列于下表的这些碱性溶解度测试结果是5份头发测试结果的计算平均值。
碱性溶解度(%) | ||
平均值 | 标准偏差 | |
组合物AD | 54.5 | 3.1 |
组合物BD | 54.6 | 2.1 |
组合物CD(本发明) | 45.4 | 2.4 |
这些结果表明,与既不含直接聚合物又不含两亲聚合物的组合物(组合物AD)相比,单独使用两性直接聚合物(Polyquaternium-22)(组合物BD)不能限制纤维的降解。
另一方面,本发明将丙烯酸和丙烯酸C10-C30烷基酯的阴离子两亲共聚物(产于Goodrich公司的Carbopol 1382)与两性直接聚合物Polyquaternium-22混合物(组合物CD)显著减少了被漂白角蛋白纤维的碱性溶解度(约17%)。
实施例4
制备以下粉状形式的漂白组合物E(用量为重量%)过硫酸钾 38过硫酸钠 30硅酸钠 14氯化铵 5亚乙基二胺四乙酸 1二辛基磺基琥珀酸钠/苯甲酸钠 2二氧化硅 2Polyquaternium-22 1Hercules公司以商品名Polysurf 67销售的十六烷基羟 4基纤维素
将8克该组合物E与16克上述组合物D混合。将该混合物施用在待漂白头发上并保持45分钟。经清洗、洗香波和干燥后,得到均匀的漂白效果。纤维的状态是满意的,降解很有限。
实施例5
制备以下无水膏状形式的漂白组合物F(用量为重量%):棕榈酸异丙基酯 23矿物油 3过硫酸钾 27过硫酸钠 20硅酸钠 12氯化铵 4亚乙基二胺四乙酸 1含有25mol环氧乙烷的十六烷基硬脂醇 2粘土 1Polyquaternium-22 1SeradFX-1100 3氧化钛 1硬脂酸镁 2
将10克该组合物F与15克上述组合物D混合。将该混合物施用在待漂白头发上并保持45分钟。经清洗、洗香波和干燥后,得到均匀的漂白效果。纤维的状态是满意的,降解很有限。
Claims (28)
1、一种在适于漂白的介质中的漂白角蛋白纤维、尤其是人类角蛋白纤维的无水组合物,该组合物含有至少一种碱性剂和至少一种过氧化的盐,其特征在于另外还含有下述聚合物的混合物:
—至少一种含有至少一个脂肪链的阴离子和/或非离子两亲聚合物,和
—至少一种阳离子或两性直接聚合物
2、权利要求1的组合物,其特征在于含有至少一个脂肪链的阴离子两亲聚合物是共聚物,它包含
—含有衍生自带有羧酸官能团的烯属不饱和键的一个或多个单体的亲水单元,和
—含有衍生自带有疏水侧链的烯属不饱和键的一个或多个单体的疏水单元。
3、权利要求1或2的组合物,其特征在于含有带有羧酸官能团的烯属不饱和键的单体选自乙基丙烯酸、甲基丙烯酸和丙烯酸,优选选自甲基丙烯酸和丙烯酸及它们的混合物。
4、权利要求1到3的任一组合物,其特征在于含有带有疏水侧链的烯属不饱和键的单体选自乙基丙烯酸的、甲基丙烯酸的和/或丙烯酸的C10-C30,优选C12-C22的烷基酯。
5、权利要求1到3的任一组合物,其特征在于含有带有疏水侧链的烯属不饱和键的单体选自烯丙基脂肪烷基醚,对应的通式为
(I)CH2=CR’CH2-O-Bn-R其中
R’表示氢原子或甲基,
B表示亚乙氧基,
n是0到100的整数,
R表示选自包含8到30个碳原子、优选10到24个碳原子的烷基、芳烷基、芳基、烷芳基和环烷基的烃基。
6.根据上述任一项权利要求的组合物,其特征在于含有至少一个脂肪链的阴离子两亲聚合物还包括衍生自含有两个非共轭烯属双键的交联单体的单元。
7、权利要求6的无水组合物,其特征在于所述交联单体选自邻苯二甲酸二烯丙基酯、(甲基)丙烯酸烯丙基酯、二乙烯基苯、二甲基丙烯酸(聚)乙二醇酯、亚甲基二丙烯酰胺、聚烯丙基蔗糖或聚烯丙基季戊四醇。
8、权利要求1到7中任一项一的组合物,其特征在于含有至少一个脂肪链的阴离子两亲聚合物是丙烯酸与甲基丙烯酸C10-C30烷基酯的交联共聚物。
9、权利要求1的组合物,其特征在于所述含有至少一个脂肪链的非离子两亲聚合物选自
—用含有至少一个烷基、芳烷基或含有C8-C22烷基的烷芳烷基型脂肪链的基团,或用聚烷氧基化的烷基苯酚基团改性的纤维素或羟烷基纤维素;
—用含有至少一个C8-C22脂肪链的基团改性的羟丙基瓜耳胶;
—含有至少一个C8-C30烷基或链烯基型脂肪链的聚氨酯;
—乙烯基吡咯烷酮与含有脂肪链的疏水单体的共聚物;
—(甲基)丙烯酸C1-C6烷基酯与含有至少一个脂肪链的两亲单体的共聚物;
—亲水(甲基)丙烯酸酯与含有至少一个脂肪链的疏水单体的共聚物。
10、权利要求9的组合物,其特征在于含有至少一个脂肪链的非离子两亲聚合物是用含有至少一个C8-C22烷基的基团改性的羟乙基纤维素,或用至少一个C10-C20烷基链改性的聚氨酯。
11、上述任一项权利要求的组合物,其特征在于含有至少一个脂肪链的阴离子两亲聚合物和/或非离子两亲聚合物的含量相对无水组合物总量为0.03~30%(重量),优选0.3~15%(重量)。
12、上述任一项权利要求的组合物,其特征在于阳离子或两性直接聚合物是含有带伯、仲、叔和/或季铵基团的单元的聚合物,该单元或者形成聚合物主链部分或者由直接连接在其上的侧取代基携带,该聚合物具有500到5×106,优选103到3×106的数均分子量。
13、权利要求12的组合物,其特征在于所述直接聚合物选自季胺化纤维素衍生物和含有季胺化或非季胺化氨基侧基的聚丙烯酸酯。
14、权利要求13的组合物,其特征在于季胺化纤维素衍生物选自
—用选自含有至少8个碳原子的烷基、芳烷基和烷芳基,或它们的混合物的至少一个脂肪链的基团改性的季胺化纤维素,和
—用选自含有至少8个碳原子的烷基、芳烷基和烷芳基,或它们的混合物的至少一个脂肪链的基团改性的季胺化羟乙基纤维素。
15、权利要求12的组合物,其特征在于所述阳离子直接聚合物是氯化二甲基二烯丙基铵均聚物或二甲基二烯丙基铵与丙烯酰胺的共聚物。
17、权利要求12的组合物,其特征在于所述两性直接聚合物选自Polyquaternium-22、Polyquaternium-39和Polyquaternium-47。
18、上述任一项权利要求的组合物,其特征在于所述阳离子或两性直接聚合物的含量相对无水组合物总量为0.03~30%(重量),优选0.3~15%(重量)。
19、上述任一项权利要求的组合物,其特征在于阴离子和/或非离子两亲聚合物与阳离子或两性直接聚合物的重量比为10/1至1/10,优选5/1至1/5。
20、上述任一项权利要求的组合物,其特征在于所述碱性剂选自诸如氯化铵、硫酸铵、磷酸铵或硝酸铵的铵盐,和碱金属或碱土金属的硅酸盐、磷酸盐或碳酸盐,尤其是碱金属硅酸盐。
21、上述任一项权利要求的组合物,其特征在于所述过氧化的盐选自铵或碱金属过硫酸盐、过碳酸盐和过硼酸盐,尤其选自过硫酸钠和过硫酸钾。
22、权利要求21的组合物,其特征在于所述过氧化的盐的用量相对于无水组合物的总量为20~70%(重量),优选30~60%(重量)。
23、上述任一项权利要求的组合物,其特征在于该组合物还含有漂白助剂,所述助剂选自控制氧释放的试剂、增稠或凝胶聚合物、阴离子表面活性剂、非离子表面活性剂、阳离子表面活性剂、两性表面活性剂或两性离子表面活性剂以及它们的混合物、矿物油或植物油、蜡、成粒剂、粘合剂、矿物填料、诸如氧化钛的遮光剂、染料、螯合剂和香料的漂白助剂。
24、权利要求23的组合物,其特征在于该组合物含有0.01~40%(重量),优选0.1~30%(重量)的至少一种表明活性剂。
25、上述任一项权利要求的组合物,其特征在于该组合物以粉状、或无水有机液体介质中的粉末悬浮体或分散体的形式存在。
26、通过添加水性过氧化氢组合物来使用上述任一项权利要求的无水漂白组合物制备即用漂白组合物的用途。
27、漂白角蛋白纤维,尤其是人发的方法,包括以下步骤
—使用前立即将权利要求1到25中任一项权利要求定义的无水漂白组合物与水性过氧化氢组合物混合,
—将得到的混合物施用于待漂白的角蛋白纤维部位,
—将混合物在纤维上滞留足够时间,以获得理想的漂白效果,和
—用水清洗以去除漂白混合物,然后用香波冲洗,然后干燥。
28、漂白角蛋白纤维,尤其是诸如头发的人体角蛋白纤维的多部件装置或“桶”,其特征在于包括至少两个部件,一个部件装有权利要求1到25中任一项的无水组合物,另一个部件装有水性过氧化氢组合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR99/01054 | 1999-01-29 | ||
FR9901054A FR2788974B1 (fr) | 1999-01-29 | 1999-01-29 | Composition anhydre de decoloration des fibres keratiniques comprenant l'association de polymeres amphiphiles anioniques et/ou non ioniques comportant au moins une chaine grasse et de polymeres substantifs cationiques ou amphoteres |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1270022A true CN1270022A (zh) | 2000-10-18 |
Family
ID=9541405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN00104637A Pending CN1270022A (zh) | 1999-01-29 | 2000-01-29 | 漂白角蛋白纤维的无水组合物 |
Country Status (19)
Country | Link |
---|---|
US (1) | US6260556B1 (zh) |
EP (1) | EP1023891B1 (zh) |
JP (1) | JP2000239134A (zh) |
KR (1) | KR100363470B1 (zh) |
CN (1) | CN1270022A (zh) |
AR (1) | AR017492A1 (zh) |
AT (1) | ATE207338T1 (zh) |
AU (1) | AU728168B2 (zh) |
BR (1) | BR0000419A (zh) |
CA (1) | CA2297275C (zh) |
DE (1) | DE60000017T2 (zh) |
DK (1) | DK1023891T3 (zh) |
ES (1) | ES2161674T3 (zh) |
FR (1) | FR2788974B1 (zh) |
HU (1) | HUP0000363A3 (zh) |
PL (1) | PL338116A1 (zh) |
PT (1) | PT1023891E (zh) |
RU (1) | RU2200540C2 (zh) |
ZA (1) | ZA200000258B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1321626C (zh) * | 2003-01-16 | 2007-06-20 | 莱雅公司 | 即用漂白组合物、其制备方法以及漂白方法 |
CN1331457C (zh) * | 2003-01-16 | 2007-08-15 | 莱雅公司 | 即用漂白组合物、其制备方法以及漂白方法 |
Families Citing this family (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6540791B1 (en) * | 2000-03-27 | 2003-04-01 | The Procter & Gamble Company | Stable alkaline hair bleaching compositions and method for use thereof |
FR2816208B1 (fr) * | 2000-11-08 | 2003-01-03 | Oreal | Composition de teinture directe pour fibres keratiniques comprenant un polyurethane associatif cationique |
FR2816207B1 (fr) * | 2000-11-08 | 2003-01-03 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polyurethane associatif cationique |
FR2816210B1 (fr) * | 2000-11-08 | 2005-02-25 | Oreal | Composition pour la decoloration ou la deformation permanente des fibres keratiniques comprenant un polyurethane associatif cationique |
FR2816209B1 (fr) * | 2000-11-08 | 2005-02-25 | Oreal | Composition de decoloration pour fibres keratiniques comprenant un polyurethane associatif cationique |
FR2817467B1 (fr) * | 2000-12-04 | 2003-01-10 | Oreal | Composition de teinture pour fibres keratiniques comprenant un polymere associatif et un polymere a motifs acrylamide, halogenure de dialkyldiallylammonium et acide carboxylique vinylique |
FR2820312B1 (fr) * | 2001-02-02 | 2003-05-02 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
US6774175B2 (en) * | 2001-02-16 | 2004-08-10 | L'oreal S.A. | Stabilizing compositions comprising at least two anionic associative polymers, their use for stabilization of non-solid compositions, and compositions comprising at least one stabilizing composition |
US7070769B2 (en) * | 2001-02-16 | 2006-07-04 | L'oreal | Compositions comprising at least two anionic associative polymers and their use for stabilization of an oxidizing solution |
FR2824734B1 (fr) * | 2001-05-16 | 2003-06-27 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
FR2824735A1 (fr) * | 2001-05-16 | 2002-11-22 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
FR2830189B1 (fr) * | 2001-09-28 | 2004-10-01 | Oreal | Composition de teinture a effet eclaircissant pour fibres keratiniques humaines |
FR2831802B1 (fr) * | 2001-11-08 | 2004-10-15 | Oreal | Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations |
FR2831815B1 (fr) * | 2001-11-08 | 2004-08-06 | Oreal | Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831803B1 (fr) * | 2001-11-08 | 2004-07-30 | Oreal | Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations |
AU2002301803B2 (en) * | 2001-11-08 | 2004-09-09 | L'oreal | Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof |
FR2831808B1 (fr) * | 2001-11-08 | 2003-12-19 | Oreal | Composition de teinture pour fibres keratiniques comprenant une silicone aminee particuliere |
FR2831814B1 (fr) * | 2001-11-08 | 2004-09-10 | Oreal | Utilisations de silicones aminees particulieres en pre- ou post-traitement de decolorations de fibres keratiniques |
FR2831813B1 (fr) * | 2001-11-08 | 2004-10-01 | Oreal | Utilisation de silicones aminees particulieres en pre-traitement de colorations directes ou d'oxydation de fibres keratiniques |
FR2831809B1 (fr) * | 2001-11-08 | 2004-07-23 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831805B1 (fr) * | 2001-11-08 | 2004-08-06 | Oreal | Procede de deformation permanente des cheveux mettant en oeuvres des silicones aminees particulieres |
FR2831817B1 (fr) * | 2001-11-08 | 2003-12-19 | Oreal | Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831811B1 (fr) * | 2001-11-08 | 2004-07-23 | Oreal | Utilisation de silicones aminees particulieres en post traitement de colorations directes ou d'oxydation de fibres keratiniques |
FR2831804B1 (fr) * | 2001-11-08 | 2004-07-30 | Oreal | Procede de deformation permanente des cheveux mettant en oeuvre des silicones aminees particulieres |
FR2831818B1 (fr) * | 2001-11-08 | 2004-07-16 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
KR20030081848A (ko) * | 2002-04-13 | 2003-10-22 | 주식회사 비봉파인 | 과황산염을 함유하는 크림, 리니멘트, 연고, 파스타제형의 모발 탈색 촉진제 |
FR2842101B1 (fr) * | 2002-07-12 | 2005-10-28 | Pate anhydre pour la decoloration des fibres keratiniques humaines | |
FR2842099B1 (fr) * | 2002-07-12 | 2004-09-10 | Oreal | Pate anhydre pour la decoloration des fibres keratiniques humaines |
FR2842100B1 (fr) * | 2002-07-12 | 2004-09-10 | Oreal | Pate anhydre pour la decoloration des fibres keratiniques humaines |
US20040181883A1 (en) * | 2002-12-20 | 2004-09-23 | Frederic Legrand | Pasty anhydrous composition for simultaneously bleaching and dyeing human keratin fibers comprising at least one peroxygenated salt, at least one alkaline agent, at least one inert organic liquid and at least one cationic direct dye; process using such a compound; and kit comprising such a compound |
US7261744B2 (en) * | 2002-12-24 | 2007-08-28 | L'oreal S.A. | Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener |
US7226486B2 (en) | 2003-01-16 | 2007-06-05 | L'oreal S.A | Ready-to-use bleaching compositions, preparation process and bleaching process |
US7217298B2 (en) | 2003-01-16 | 2007-05-15 | L'oreal S.A. | Ready-to-use bleaching compositions, preparation process and bleaching process |
US7303588B2 (en) * | 2003-03-25 | 2007-12-04 | L'oreal S.A. | Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device |
US20050039270A1 (en) * | 2003-03-25 | 2005-02-24 | L'oreal S.A. | Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres |
US20050036970A1 (en) * | 2003-03-25 | 2005-02-17 | L'oreal S.A. | Reducing compositions for bleaching or permanently reshaping keratin fibres comprising polycarboxylic acids and salts thereof as complexing agents |
FR2852832B1 (fr) * | 2003-03-25 | 2008-06-27 | Oreal | Composition de coloration pour fibres keratiniques comprenant un acide hydroxycarboxilique ou un sel, composition prete a l'emploi la comprenant, procede de mise en oeuvre et dispositif |
US7195651B2 (en) * | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor |
US7195650B2 (en) * | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye |
US7204860B2 (en) * | 2003-04-01 | 2007-04-17 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof |
FR2853240A1 (fr) * | 2003-04-01 | 2004-10-08 | Oreal | Composition de coloration pour matieres keratiniques humaines comprenant un colorant fluorescent et un polymere associatif, procede et utilisation |
US7186278B2 (en) * | 2003-04-01 | 2007-03-06 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor |
US7303589B2 (en) | 2003-04-01 | 2007-12-04 | L'oreal S.A. | Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same |
US7147673B2 (en) | 2003-04-01 | 2006-12-12 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof |
US7198650B2 (en) * | 2003-04-01 | 2007-04-03 | L'oreal S.A. | Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor |
US7736631B2 (en) | 2003-04-01 | 2010-06-15 | L'oreal S.A. | Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing |
US7208018B2 (en) * | 2003-04-01 | 2007-04-24 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof |
US7192454B2 (en) * | 2003-04-01 | 2007-03-20 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof |
US7150764B2 (en) * | 2003-04-01 | 2006-12-19 | L'oreal S.A. | Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof |
US7250064B2 (en) * | 2003-04-01 | 2007-07-31 | L'oreal S.A. | Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof |
FR2864444B1 (fr) * | 2003-12-29 | 2006-02-03 | Oreal | Pate anhydre de decoloration comprenant au moins un compose de type ceramide et procede la mettant en oeuvre |
EP1713434A4 (en) * | 2004-01-29 | 2009-01-07 | Avlon Ind Inc | CONDITIONING HAIR ENHANCEMENT SYSTEM, COMPOSITIONS, METHOD AND SET THEREFOR |
US20060257339A1 (en) * | 2005-05-13 | 2006-11-16 | L'oreal | Use of conductive polymer nanofibers for treating keratinous surfaces |
US20070134191A1 (en) * | 2005-12-14 | 2007-06-14 | L'oreal | Hair styling compositions containing a nonionic amphiphilic polymer in combination with styling polymers and emulsifying agents |
DE102006005450A1 (de) | 2006-02-07 | 2007-08-09 | Henkel Kgaa | Haar-Colorationscreme auf Polymerbasis |
US7597719B2 (en) * | 2006-08-02 | 2009-10-06 | The Procter & Gamble Company | Polymer thickened hair colouring and bleaching compositions |
FR2917972B1 (fr) | 2007-06-29 | 2009-10-16 | Oreal | Composition anhydre sous forme de pate pour la decoloration des fibres keratiniques |
EP2022477A1 (en) * | 2007-08-07 | 2009-02-11 | KPSS-Kao Professional Salon Services GmbH | Bleaching/highlighting composition |
FR2920971B1 (fr) | 2007-09-14 | 2014-03-28 | Oreal | Composition cosmetique comprenant au moins un polymere cationique particulier, au moins un agent tensioactif, au moins un polymere cationique ou amphotere et au moins une particule minerale, et procede de traitement cosmetique. |
FR2925323B1 (fr) | 2007-12-21 | 2009-12-18 | Oreal | Procede de coloration en presence d'un agent oxydant et d'une amine organique particuliere et dispositif |
FR2925307B1 (fr) | 2007-12-21 | 2009-12-18 | Oreal | Procede de coloration directe eclaircissante ou d'oxydation en presence d'une amine organique particuliere et dispositif |
FR2925311B1 (fr) | 2007-12-21 | 2009-12-18 | Oreal | Procede d'eclaircissement de fibres keratiniques humaines mettant en oeuvre une composition anhydre et une amine organique particuliere et dispositif approprie |
CN101822619B (zh) | 2008-12-19 | 2014-03-26 | 莱雅公司 | 在无机碱存在下着色或色泽变淡的方法以及试剂盒 |
BRPI0907294A2 (pt) | 2008-12-19 | 2013-05-07 | Oreal | processo de clareamento ou de coloraÇço das fibras queratÍnicas e dispositivo com vÁrios compartimentos |
FR2940092B1 (fr) | 2008-12-19 | 2011-02-18 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras amide ou ester |
JP5826454B2 (ja) | 2008-12-19 | 2015-12-02 | ロレアル | モノエタノールアミン/塩基性アミノ酸混合物を含有する無水組成物を使用する、ヒトのケラチン繊維の明色化または染色、ならびにそのためのデバイス |
FR2940101B1 (fr) | 2008-12-19 | 2011-02-18 | Oreal | Composition de teinture d'oxydation de fibres keratiniques comprenant un corps gras et un derive 4,5-diaminopyrazole |
FR2940077B1 (fr) | 2008-12-19 | 2012-07-20 | Oreal | Procede de coloration eclaircissante de matieres keratiniques mettant en oeuvre une composition anhydre colorante comprenant un agent alcalin et une composition oxydante. |
FR2940100B1 (fr) | 2008-12-19 | 2011-02-18 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras et la n,n bis (beta-hydroxyethyl)-paraphenylene diamine |
FR2940055B1 (fr) | 2008-12-19 | 2015-03-27 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant le para-aminophenol, du dipropyleneglycol, et un precurseur de colorant additionnel. |
FR2940061B1 (fr) | 2008-12-19 | 2011-03-04 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras et un derive de diaminopyrazolone. |
FR2940104B1 (fr) | 2008-12-19 | 2011-08-19 | Oreal | Procede de traitement des cheveux mettant en oeuvre une emulsion directe comprenant un agent oxydant et une composition contenant un agent alcalin |
FR2940067B1 (fr) | 2008-12-19 | 2011-02-25 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant un polymere cationique, un amide gras et un agent-oxygene |
FR2940090B1 (fr) | 2008-12-19 | 2011-02-25 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant une huile, un alcool gras et un alcool gras oxyalkylene |
US7909888B2 (en) | 2008-12-19 | 2011-03-22 | L'oreal | Process for dyeing or lightening human keratin fibers using an anhydrous composition and a monoethanolamine/basic amino acid mixture, and suitable device therefor |
FR2940078B1 (fr) | 2008-12-19 | 2011-05-13 | Oreal | Composition comprenant un corps gras et un polymere cationique, procede de coloration la mettant en oeuvre et dispositifs |
FR2940102B1 (fr) | 2008-12-19 | 2016-03-11 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras, un epaississant et un precurseur de colorant d'oxydation |
FR2940106B1 (fr) | 2008-12-19 | 2013-04-12 | Oreal | Composition comprenant un corps gras et un silicate, procede de coloration la mettant en oeuvre et dispositifs |
JP5815205B2 (ja) | 2008-12-19 | 2015-11-17 | ロレアル | 有機アミン及び無機塩基の存在下で、淡色化し、あるいは淡色化直接染色し、あるいは酸化染色する方法、及びそのためのデバイス |
FR2940108B1 (fr) * | 2008-12-19 | 2011-04-29 | Oreal | Procede d'eclaircissement de matieres keratiniques mettant en oeuvre une composition anhydre comprenant un agent alcalin et une composition oxydante |
FR2940107B1 (fr) | 2008-12-19 | 2011-03-18 | Oreal | Procede d'eclaircissement de matieres keratiniques mettant en oeuvre une emulsion comprenant un agent alcalin et une composition oxydante |
FR2940103B1 (fr) | 2008-12-19 | 2011-06-10 | Oreal | Procede de coloration eclaircissante de matieres keratiniques mettant en oeuvre une emulsion comprenant un colorant et un agent alcalin et une composition oxydante |
FR2940105B1 (fr) | 2008-12-19 | 2011-04-08 | Oreal | Composition comprenant un corps gras et un tensioactif oxyethylene particulier, procede de coloration la mettant en oeuvre et dispositifs |
FR2940079B1 (fr) | 2008-12-19 | 2011-02-18 | Oreal | Composition comprenant au moins un alcool gras solide, procede de coloration la mettant en oeuvre et dispositifs |
US7927381B2 (en) | 2008-12-19 | 2011-04-19 | L'oreal S.A. | Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of an aqueous composition comprising at least one fatty substance, and device |
CN102137653B (zh) * | 2009-11-24 | 2014-09-10 | 宝洁公司 | 粉末状毛发着色和漂白组合物 |
EP2338570A1 (en) * | 2009-12-22 | 2011-06-29 | KPSS-Kao Professional Salon Services GmbH | Bleaching composition |
FR2954127B1 (fr) | 2009-12-22 | 2015-10-30 | Oreal | Agent de coloration et/ou de decoloration des fibres keratiniques en deux parties, comprenant un corps gras et un agent sequestrant. |
FR2954121B1 (fr) | 2009-12-22 | 2016-03-25 | Oreal | Agent de coloration et/ou de decoloration des fibres keratiniques en deux parties, comprenant un corps gras particulier et une reductone. |
FR2954160B1 (fr) * | 2009-12-22 | 2012-03-30 | Oreal | Composition de coloration ou d'eclaircissement comprenant un corps gras et un polymere amphotere |
FR2954159B1 (fr) | 2009-12-22 | 2012-02-10 | Oreal | Agent de coloration et/ou de decoloration des fibres keratiniques comprenant une composition comprenant un agent alcalinisant et une composition anhydre comprenant un oxydant, l'une ou l'autre des compositions pouvant contenir un corps gras |
EP2364751A1 (fr) * | 2010-03-09 | 2011-09-14 | L'Oréal | Procédé d'éclaircissement de matières kératiniques mettant en oeuvre une composition anhydre comprenant un agent alcalin et une composition oxydante |
DE102010039878A1 (de) * | 2010-08-27 | 2012-03-01 | Henkel Ag & Co. Kgaa | Blondierung mit reduktiver Vorbehandlung |
WO2014029656A2 (en) * | 2012-08-23 | 2014-02-27 | L'oreal | Keratin fibre bleaching composition in compressed form with persulfate and particular cationic polymer |
FR2994654A1 (fr) * | 2012-08-23 | 2014-02-28 | Oreal | Composition de decoloration des fibres keratiniques sous forme comprimee avec persulfate et polymere amphotere |
DE102012222768A1 (de) * | 2012-12-11 | 2014-06-12 | Henkel Ag & Co. Kgaa | Haarpflegemittel mit ausgewählten und/oder ausgewählten Oligopeptiden und/oder ausgewählten kationischen Proteinhydrolysaten und Silikonen enthaltend Zuckerstrukturen |
JP6515587B2 (ja) * | 2015-02-27 | 2019-05-22 | コニカミノルタ株式会社 | 液体現像剤 |
Family Cites Families (71)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2271378A (en) | 1939-08-30 | 1942-01-27 | Du Pont | Pest control |
US2273780A (en) | 1939-12-30 | 1942-02-17 | Du Pont | Wax acryalte ester blends |
US2261002A (en) | 1941-06-17 | 1941-10-28 | Du Pont | Organic nitrogen compounds |
US2388614A (en) | 1942-05-05 | 1945-11-06 | Du Pont | Disinfectant compositions |
US2375853A (en) | 1942-10-07 | 1945-05-15 | Du Pont | Diamine derivatives |
US2454547A (en) | 1946-10-15 | 1948-11-23 | Rohm & Haas | Polymeric quaternary ammonium salts |
US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
US2781354A (en) | 1956-03-26 | 1957-02-12 | John J Mccabe Jr | Imidazoline derivatives and process |
US2961347A (en) | 1957-11-13 | 1960-11-22 | Hercules Powder Co Ltd | Process for preventing shrinkage and felting of wool |
US3227615A (en) | 1962-05-29 | 1966-01-04 | Hercules Powder Co Ltd | Process and composition for the permanent waving of hair |
US3206462A (en) | 1962-10-31 | 1965-09-14 | Dow Chemical Co | Quaternary poly(oxyalkylene)alkylbis(diethylenetriamine) compounds |
FR1400366A (fr) | 1963-05-15 | 1965-05-28 | Oreal | Nouveaux composés pouvant être utilisés en particulier pour le traitement des cheveux |
FR1492597A (fr) | 1965-09-14 | 1967-08-18 | Union Carbide Corp | Nouveaux éthers cellulosiques contenant de l'azote quaternaire |
CH491153A (de) | 1967-09-28 | 1970-05-31 | Sandoz Ag | Verfahren zur Herstellung von neuen kationaktiven, wasserlöslichen Polyamiden |
DE1638082C3 (de) | 1968-01-20 | 1974-03-21 | Fa. A. Monforts, 4050 Moenchengladbach | Verfahren zum Entspannen einer zur Längenmessung geführten, dehnbaren Warenbahn |
SE375780B (zh) | 1970-01-30 | 1975-04-28 | Gaf Corp | |
IT1035032B (it) | 1970-02-25 | 1979-10-20 | Gillette Co | Composizione cosmetica e confezione che la contiente |
US3912808A (en) | 1970-02-25 | 1975-10-14 | Gillette Co | Hair waving and straightening process and composition containing water-soluble amino and quaternary ammonium polymers |
US3836537A (en) | 1970-10-07 | 1974-09-17 | Minnesota Mining & Mfg | Zwitterionic polymer hairsetting compositions and method of using same |
US4013787A (en) | 1971-11-29 | 1977-03-22 | Societe Anonyme Dite: L'oreal | Piperazine based polymer and hair treating composition containing the same |
LU64371A1 (zh) | 1971-11-29 | 1973-06-21 | ||
FR2280361A2 (fr) | 1974-08-02 | 1976-02-27 | Oreal | Compositions de traitement et de conditionnement de la chevelure |
GB1394353A (en) | 1972-06-29 | 1975-05-14 | Gillette Co | Hair treating composition |
US4189468A (en) | 1973-11-30 | 1980-02-19 | L'oreal | Crosslinked polyamino-polyamide in hair conditioning compositions |
FR2368508A2 (fr) | 1977-03-02 | 1978-05-19 | Oreal | Composition de conditionnement de la chevelure |
US4172887A (en) | 1973-11-30 | 1979-10-30 | L'oreal | Hair conditioning compositions containing crosslinked polyaminopolyamides |
LU68901A1 (zh) | 1973-11-30 | 1975-08-20 | ||
US3929990A (en) | 1973-12-18 | 1975-12-30 | Millmaster Onyx Corp | Microbiocidal polymeric quaternary ammonium compounds |
US4025627A (en) | 1973-12-18 | 1977-05-24 | Millmaster Onyx Corporation | Microbiocidal polymeric quaternary ammonium compounds |
US3874870A (en) | 1973-12-18 | 1975-04-01 | Mill Master Onyx Corp | Microbiocidal polymeric quarternary ammonium compounds |
DK659674A (zh) | 1974-01-25 | 1975-09-29 | Calgon Corp | |
US4217914A (en) | 1974-05-16 | 1980-08-19 | L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
NL180975C (nl) | 1974-05-16 | 1987-06-01 | Oreal | Werkwijze voor het bereiden van een cosmetisch preparaat voor het behandelen van menselijk haar. |
US3915921A (en) | 1974-07-02 | 1975-10-28 | Goodrich Co B F | Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers |
US4005193A (en) | 1974-08-07 | 1977-01-25 | Millmaster Onyx Corporation | Microbiocidal polymeric quaternary ammonium compounds |
US3966904A (en) | 1974-10-03 | 1976-06-29 | Millmaster Onyx Corporation | Quaternary ammonium co-polymers for controlling the proliferation of bacteria |
US4025617A (en) | 1974-10-03 | 1977-05-24 | Millmaster Onyx Corporation | Anti-microbial quaternary ammonium co-polymers |
US4026945A (en) | 1974-10-03 | 1977-05-31 | Millmaster Onyx Corporation | Anti-microbial quaternary ammonium co-polymers |
US4027020A (en) | 1974-10-29 | 1977-05-31 | Millmaster Onyx Corporation | Randomly terminated capped polymers |
US4001432A (en) | 1974-10-29 | 1977-01-04 | Millmaster Onyx Corporation | Method of inhibiting the growth of bacteria by the application thereto of capped polymers |
US4025653A (en) | 1975-04-07 | 1977-05-24 | Millmaster Onyx Corporation | Microbiocidal polymeric quaternary ammonium compounds |
AT365448B (de) | 1975-07-04 | 1982-01-11 | Oreal | Kosmetische zubereitung |
US4197865A (en) | 1975-07-04 | 1980-04-15 | L'oreal | Treating hair with quaternized polymers |
CH1669775A4 (zh) | 1975-12-23 | 1977-06-30 | ||
US4031307A (en) | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
LU76955A1 (zh) | 1977-03-15 | 1978-10-18 | ||
US4170637A (en) | 1977-05-16 | 1979-10-09 | Redken Laboratories, Inc. | Frosting bleach composition |
US4165367A (en) | 1977-06-10 | 1979-08-21 | Gaf Corporation | Hair preparations containing vinyl pyrrolidone copolymer |
CA1091160A (en) | 1977-06-10 | 1980-12-09 | Paritosh M. Chakrabarti | Hair preparation containing vinyl pyrrolidone copolymer |
LU78153A1 (fr) | 1977-09-20 | 1979-05-25 | Oreal | Compositions cosmetiques a base de polymeres polyammonium quaternaires et procede de preparation |
US4131576A (en) | 1977-12-15 | 1978-12-26 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of a water soluble monomer and polysaccharide employing a two-phase reaction system |
FR2470596A1 (fr) | 1979-11-28 | 1981-06-12 | Oreal | Composition destinee au traitement des fibres keratiniques a base de polymeres amphoteres et de polymeres cationiques |
FR2471777A1 (fr) | 1979-12-21 | 1981-06-26 | Oreal | Nouveaux agents cosmetiques a base de polymeres polycationiques, et leur utilisation dans des compositions cosmetiques |
FR2471997B1 (fr) | 1979-12-21 | 1987-08-28 | Oreal | Nouveaux polymeres polycationiques, leur preparation et leur utilisation |
LU83349A1 (fr) | 1981-05-08 | 1983-03-24 | Oreal | Composition sous forme de mousse aerosol a base de polymere cationique et de polymere anionique |
EP0080976B1 (de) | 1981-11-30 | 1986-09-24 | Ciba-Geigy Ag | Gemische aus quaternären, polymeren Ammoniumsalzen auf Acrylbasis, aus quaternären, mono- bis oligomeren Ammoniumsalzen und aus Tensiden, deren Herstellung und Verwendung in kosmetischen Mitteln |
LU83876A1 (fr) | 1982-01-15 | 1983-09-02 | Oreal | Composition cosmetique destinee au traitement des fibres keratiniques et procede de traitement de celles-ci |
LU84708A1 (fr) | 1983-03-23 | 1984-11-14 | Oreal | Composition epaissie ou gelifiee de conditionnement des cheveux contenant au moins un polymere cationique,au moins un polymere anionique et au moins une gomme de xanthane |
DE3375135D1 (en) | 1983-04-15 | 1988-02-11 | Miranol Inc | Polyquaternary ammonium compounds and cosmetic compositions containing them |
US4509949A (en) | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
US4719282A (en) | 1986-04-22 | 1988-01-12 | Miranol Inc. | Polycationic block copolymer |
LU86429A1 (fr) | 1986-05-16 | 1987-12-16 | Oreal | Compositions cosmetiques renfermant un polymere cationique et un polymere anionique comme agent epaississant |
MY105119A (en) | 1988-04-12 | 1994-08-30 | Kao Corp | Low irritation detergent composition. |
DE3814356A1 (de) | 1988-04-28 | 1988-09-08 | Schwarzkopf Gmbh Hans | Zweikomponenten-zubereitung bzw. auftragefaehige, breiartige zubereitung zum bleichen von humanhaaren |
FR2687570A1 (fr) | 1992-02-21 | 1993-08-27 | Oreal | Composition cosmetique a base d'agents tensio-actifs non-ioniques et de polymeres substantifs cationiques ou amphoteres et son utilisation comme support de teinture ou de decoloration. |
US5866107A (en) * | 1995-08-30 | 1999-02-02 | Cosmair, Inc. | Dust free bleach |
DE19545853A1 (de) | 1995-12-08 | 1997-06-12 | Wella Ag | Mittel zum Bleichen von Haaren |
FR2751533B1 (fr) | 1996-07-23 | 2003-08-15 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile non-ionique |
FR2753094B1 (fr) * | 1996-09-06 | 1998-10-16 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile anionique |
FR2753093B1 (fr) | 1996-09-06 | 1998-10-16 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile anionique |
DE19723538C1 (de) * | 1997-06-05 | 1998-09-17 | Wella Ag | Pastenförmiges Mittel zum Bleichen von Haaren |
-
1999
- 1999-01-29 FR FR9901054A patent/FR2788974B1/fr not_active Expired - Fee Related
-
2000
- 2000-01-20 DE DE60000017T patent/DE60000017T2/de not_active Expired - Lifetime
- 2000-01-20 DK DK00400148T patent/DK1023891T3/da active
- 2000-01-20 AU AU12512/00A patent/AU728168B2/en not_active Ceased
- 2000-01-20 ES ES00400148T patent/ES2161674T3/es not_active Expired - Lifetime
- 2000-01-20 EP EP00400148A patent/EP1023891B1/fr not_active Expired - Lifetime
- 2000-01-20 PT PT00400148T patent/PT1023891E/pt unknown
- 2000-01-20 AT AT00400148T patent/ATE207338T1/de not_active IP Right Cessation
- 2000-01-21 ZA ZA200000258A patent/ZA200000258B/xx unknown
- 2000-01-24 CA CA002297275A patent/CA2297275C/fr not_active Expired - Lifetime
- 2000-01-27 BR BR0000419-7A patent/BR0000419A/pt not_active IP Right Cessation
- 2000-01-28 AR ARP000100382A patent/AR017492A1/es not_active Application Discontinuation
- 2000-01-28 HU HU0000363A patent/HUP0000363A3/hu unknown
- 2000-01-28 RU RU2000102305/14A patent/RU2200540C2/ru not_active IP Right Cessation
- 2000-01-28 US US09/492,778 patent/US6260556B1/en not_active Expired - Fee Related
- 2000-01-28 PL PL00338116A patent/PL338116A1/xx not_active Application Discontinuation
- 2000-01-29 CN CN00104637A patent/CN1270022A/zh active Pending
- 2000-01-29 KR KR1020000004449A patent/KR100363470B1/ko not_active IP Right Cessation
- 2000-01-31 JP JP2000023189A patent/JP2000239134A/ja not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1321626C (zh) * | 2003-01-16 | 2007-06-20 | 莱雅公司 | 即用漂白组合物、其制备方法以及漂白方法 |
CN1331457C (zh) * | 2003-01-16 | 2007-08-15 | 莱雅公司 | 即用漂白组合物、其制备方法以及漂白方法 |
Also Published As
Publication number | Publication date |
---|---|
DE60000017D1 (de) | 2001-11-29 |
US6260556B1 (en) | 2001-07-17 |
EP1023891B1 (fr) | 2001-10-24 |
BR0000419A (pt) | 2001-05-02 |
RU2200540C2 (ru) | 2003-03-20 |
HU0000363D0 (en) | 2000-03-28 |
DK1023891T3 (da) | 2002-02-11 |
FR2788974B1 (fr) | 2001-03-30 |
AU728168B2 (en) | 2001-01-04 |
AU1251200A (en) | 2000-08-24 |
ATE207338T1 (de) | 2001-11-15 |
DE60000017T2 (de) | 2002-06-13 |
FR2788974A1 (fr) | 2000-08-04 |
PT1023891E (pt) | 2002-04-29 |
EP1023891A1 (fr) | 2000-08-02 |
AR017492A1 (es) | 2001-09-05 |
HUP0000363A3 (en) | 2001-06-28 |
HUP0000363A2 (hu) | 2000-11-28 |
KR20000076563A (ko) | 2000-12-26 |
ZA200000258B (en) | 2000-10-12 |
KR100363470B1 (ko) | 2002-12-05 |
PL338116A1 (en) | 2000-07-31 |
ES2161674T3 (es) | 2001-12-16 |
CA2297275C (fr) | 2006-11-28 |
JP2000239134A (ja) | 2000-09-05 |
CA2297275A1 (fr) | 2000-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1270022A (zh) | 漂白角蛋白纤维的无水组合物 | |
CN1195477C (zh) | 含阳离子聚合物和丙烯酸三元共聚物的化妆品组合物,该组合物护理角蛋白物质的应用 | |
CN1155361C (zh) | 洗涤美容护发组合物及其应用 | |
CN1063939C (zh) | 基于神经酰胺和含阳离子基聚合物的洗涤与处理毛发和皮肤的组合物 | |
CN1082805C (zh) | 头发用的洗涤化妆组合物及其应用 | |
CN1099281C (zh) | 用于定形及上光的化妆品组合物 | |
CN1192763C (zh) | 含有特定两性淀粉的洗涤化妆品组合物及其用途 | |
CN1263445C (zh) | 用于处理角蛋白纤维的含有特定的氨基硅氧烷的氧化组合物 | |
CN1104888C (zh) | 含有聚硅氧烷和二烷基醚的洗涤和调理组合物 | |
KR100296171B1 (ko) | 모발보호용세제화장조성물및이의용도 | |
CN1399950A (zh) | 含有单甘油化或多甘油化脂肪醇和特定多元醇,用于角蛋白纤维的氧化染色的组合物 | |
CN1950062A (zh) | 染色、漂白或烫发后用于改善毛发调理的方法和组件套盒 | |
CN1404812A (zh) | 含有甲基丙烯酸共聚物和油的化妆品组合物及其用途 | |
CN1853610A (zh) | 含有阳离子、阳离子聚合物、固体化合物和淀粉的化妆品组合物及化妆处理的方法 | |
CN1138450A (zh) | 含碱性氨基酸和阳离子聚合物的还原性组合物 | |
CN1404814A (zh) | 包含甲基丙烯酸共聚物、硅氧烷和阳离子聚合物的化妆品组合物及其用途 | |
CN1460015A (zh) | 含有阳离子聚乙烯基内酰胺的角质纤维氧化染色组合物 | |
CN1404816A (zh) | 含有甲基丙烯酸共聚物、硅氧烷和阳离子聚合物的化妆品组合物及其应用 | |
CN1229103C (zh) | 包含特定氨基(聚)硅氧烷的用于处理角蛋白纤维的还原组合物 | |
CN1312066A (zh) | 含有乙烯聚二甲硅氧烷/聚二甲硅氧烷共聚物和阳离子聚合物的化妆组合物及其应用 | |
CN1305801A (zh) | 含两性淀粉和阳离子调理剂的化妆品组合物及其用途 | |
CN1281693A (zh) | 洗涤化妆品组合物及其应用 | |
CN1183897C (zh) | 包含特定的氨基硅氧烷的用于处理角蛋白纤维的还原组合物 | |
CN1292256A (zh) | 用于洗涤角蛋白材料的组合物 | |
CN1270020A (zh) | 漂白角蛋白纤维的即用的水性组合物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |