CN1269855C - 含有在4－、5－、6－或7－位被甲硅烷氧基或甲锗烷氧基取代的茚基部分的金属茂催化剂 - Google Patents

含有在4－、5－、6－或7－位被甲硅烷氧基或甲锗烷氧基取代的茚基部分的金属茂催化剂 Download PDF

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Publication number
CN1269855C
CN1269855C CNB028154010A CN02815401A CN1269855C CN 1269855 C CN1269855 C CN 1269855C CN B028154010 A CNB028154010 A CN B028154010A CN 02815401 A CN02815401 A CN 02815401A CN 1269855 C CN1269855 C CN 1269855C
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China
Prior art keywords
catalyst
group
ligand
indenyl
ring
Prior art date
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Expired - Fee Related
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CNB028154010A
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English (en)
Chinese (zh)
Other versions
CN1538975A (zh
Inventor
彼得·埃克霍尔姆
亨德里克·卢蒂克赫德
詹尼·马拉南
安蒂·彭宁坎格斯
卡尔－埃里克·威伦
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Borealis Technology Oy
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Borealis Technology Oy
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Publication date
Priority claimed from GB0115370A external-priority patent/GB0115370D0/en
Priority claimed from GB0117629A external-priority patent/GB0117629D0/en
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Publication of CN1538975A publication Critical patent/CN1538975A/zh
Application granted granted Critical
Publication of CN1269855C publication Critical patent/CN1269855C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB028154010A 2001-06-22 2002-06-21 含有在4－、5－、6－或7－位被甲硅烷氧基或甲锗烷氧基取代的茚基部分的金属茂催化剂 Expired - Fee Related CN1269855C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB0115370A GB0115370D0 (en) 2001-06-22 2001-06-22 Catalysts
GB0115370.9 2001-06-22
GB0117629.6 2001-07-19
GB0117629A GB0117629D0 (en) 2001-07-19 2001-07-19 Catalysts

Publications (2)

Publication Number Publication Date
CN1538975A CN1538975A (zh) 2004-10-20
CN1269855C true CN1269855C (zh) 2006-08-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028154010A Expired - Fee Related CN1269855C (zh) 2001-06-22 2002-06-21 含有在4－、5－、6－或7－位被甲硅烷氧基或甲锗烷氧基取代的茚基部分的金属茂催化剂

Country Status (9)

Country Link
US (1) US7074863B2 (https=)
EP (1) EP1401880B1 (https=)
JP (1) JP2004532346A (https=)
KR (1) KR100626258B1 (https=)
CN (1) CN1269855C (https=)
AT (1) ATE487744T1 (https=)
BR (1) BR0210607B1 (https=)
DE (1) DE60238256D1 (https=)
WO (1) WO2003000744A1 (https=)

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GB0118010D0 (en) * 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
AU2003260370B2 (en) 2002-08-05 2008-05-22 Silence Therapeutics Gmbh Further novel forms of interfering RNA molecules
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
GB0419851D0 (en) * 2004-09-07 2004-10-13 Borealis Tech Oy Catalysts
KR20060056712A (ko) * 2004-11-22 2006-05-25 삼성전자주식회사 포토리소그래피에 사용되는 바텀 레지스트용 폴리머 및 그제조 방법
US7446216B2 (en) * 2004-12-16 2008-11-04 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1739103A1 (en) * 2005-06-30 2007-01-03 Borealis Technology Oy Catalyst
DE602005013376D1 (de) 2005-08-09 2009-04-30 Borealis Tech Oy Siloxy substituierte Metallocenkatalysatoren
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7763562B2 (en) 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
JP2010529253A (ja) 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
CN101815727B (zh) 2007-08-27 2013-05-15 保瑞利斯科技公司 催化剂
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US7544825B1 (en) 2008-06-12 2009-06-09 Basell Polyolefine Gmbh Preparation of siloxy-bridged metallocenes
EP2330135B1 (en) 2009-12-02 2012-11-07 Borealis AG Process for producing polyolefins
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
JP6645969B2 (ja) * 2014-08-20 2020-02-14 株式会社ブリヂストン 末端変性共役ジエン重合体の製造方法、末端変性共役ジエン重合体、ゴム組成物及びタイヤ

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Publication number Priority date Publication date Assignee Title
ATE286918T1 (de) 1991-10-15 2005-01-15 Basell Polyolefine Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
WO1993011258A1 (fr) * 1991-11-29 1993-06-10 Bioxytech Procede de dosage de l'activite sod utilisant un compose autoxydable, necessaire pour sa mise en ×uvre, composes autoxydables et leur preparation
ATE198207T1 (de) 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
JP3626186B2 (ja) 1993-05-25 2005-03-02 エクソンモービル・ケミカル・パテンツ・インク オレフィンの重合用の担持されたメタロセン触媒系、その製造法及び使用
DE4330661A1 (de) 1993-09-10 1995-03-16 Basf Ag Kälteschlagzähe Propylenpolymerisate
KR100378973B1 (ko) 1994-06-24 2003-08-19 엑손모빌 케미칼 패턴츠 인코포레이티드 중합촉매시스템, 이의 제조방법 및 용도
FI104975B (fi) 1995-04-12 2000-05-15 Borealis As Menetelmä katalyyttikomponenttien valmistamiseksi
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US5723632A (en) 1996-08-08 1998-03-03 Mgi Pharma, Inc. Total synthesis of antitumor acylfulvenes
FI971565A7 (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä

Also Published As

Publication number Publication date
JP2004532346A (ja) 2004-10-21
EP1401880B1 (en) 2010-11-10
US7074863B2 (en) 2006-07-11
KR100626258B1 (ko) 2006-09-21
ATE487744T1 (de) 2010-11-15
EP1401880A1 (en) 2004-03-31
CN1538975A (zh) 2004-10-20
KR20040007747A (ko) 2004-01-24
US20040152882A1 (en) 2004-08-05
DE60238256D1 (de) 2010-12-23
BR0210607B1 (pt) 2011-06-28
BR0210607A (pt) 2004-09-28
WO2003000744A1 (en) 2003-01-03

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Granted publication date: 20060816

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