CN1255361C - Humic acid solid fertilizer - Google Patents
Humic acid solid fertilizer Download PDFInfo
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- CN1255361C CN1255361C CN 200410020960 CN200410020960A CN1255361C CN 1255361 C CN1255361 C CN 1255361C CN 200410020960 CN200410020960 CN 200410020960 CN 200410020960 A CN200410020960 A CN 200410020960A CN 1255361 C CN1255361 C CN 1255361C
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- active
- weathered coal
- humic acids
- humic acid
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Abstract
The present invention relates to a solid fertilizer, more specifically to a solid humic acid fertilizer, which is measured by 100 parts and prepared from components of the following composition by weight: 4 to 40 parts of nitrogen, 3 to 35 parts of phosphorus, 3 to 40 parts of potassium, 0 to 6.5 parts of secondary elements, 0 to 1.5 parts of microelements, 15 to 30 parts of active humic acid and 0 to 1.0 part of water soluble chitosan, wherein the active humic acid is provided by active weathered coal containing active humic acid. Active weathered coal is made by the following method that under the condition of agitation, 30 to 50 parts by weight of water and 4 to 7 parts by weight of active agent are added into 30 to 60 parts by weight of weathered coal, evenly agitated and then added with 2 to 10 parts by weight of catalyzed oxidation agent to simultaneously react for 3 to 30 minutes at a temperature of 10 to 60 DEG C at an agitation speed faster than 200 r/min, be dried at a temperature of 20 to 90 DEG C and pulverized into granules larger than or equal to 20 meshes to obtain active weathered coal containing active humic acid. The present invention has the advantages of high fertilizer effect, low preparation cost, no environmental pollution, etc.
Description
Technical field
The present invention relates to solid fertilizer, is a kind of humic acids solid fertilizer specifically.
Background technology
China farmland is because a large amount of chemical fertilizer of long-term application, harm such as soil compaction, salinification, pollution have been caused, and the quality taste of crop products becomes worse and worse, nitrate content severe overweight in the vegetables, threaten HUMAN HEALTH, for this reason, people advocate energetically and carry out the tangerine bar also measure such as field so that increase the amount of application of fertilizer, but the raw material of objectively producing fertilizer is very limited, does not also satisfy the needs in big area farmland.
The exploitation of humic acid fertilizer and application, increased fertilizer source channel, chemical fertilizer and fertilizer shortcoming have separately been remedied simultaneously also more satisfactoryly, that is: (1) humic acids of having activated combines with element chelatings such as the nutrient nitrogen of crop, phosphorus, potassium and chemical physics effectively, and make humic acid fertilizer promptly have quick-acting, slow and ion exchange are arranged again; (2) contain a large amount of organic matters such as humic acids in the humic acid fertilizer, play and reduce soil compaction, salinification, improve the soil, increase the effect of soil and fertilizer; (3) improve the crop and fruit quality, can make the crop and fruit quality reach the above level of pollution-free green food A level.
Relevant humic acid fertilizer documents and materials a lot (as: CN 1152564A, CN1176242A, CN1216759A, CN1212249A), domestic humic acids factory is quite a few, what " humic acids association " put on record family just arranged more than 50, but most manufacturer production technologies fall behind, be simply equipped, on activation humic acids technology, expend energy height, environmental pollution is serious, does not possess modern production technology and scale.
Summary of the invention
The object of the present invention is to provide a kind of non-environmental-pollution, fertilizer efficiency height, the humic acids solid fertilizer that preparation cost is low.
For achieving the above object, the technical scheme taked of the present invention is:
A kind of humic acids solid fertilizer, in 100 parts, its weight consists of: 4～40 parts in nitrogen, 3～35 parts in phosphorus, 3～40 parts in potassium, 0～6.5 part of moderate-element, 0～1.5 part of trace element, 15～30 parts of activated humic acids (HA), water-soluble chitosan are 0～1.0 part.
Described nitrogen is the available nitrogen content in the nitrogenous source, and nitrogenous source is urea, ammonium nitrate, ammonium sulfate, bicarbonate of ammonia and/or Dyhard RU 100; Phosphorus is the available phosphorus content in the phosphorus source, and the phosphorus source is ammonium hydrogen phosphate, potassium hydrogen phosphate, calcium superphosphate and/or double superhosphate; Potassium is the effective potassium content in the potassium source, and the potassium source is vitriolate of tartar, Repone K and/or saltpetre; Described moderate-element is Ca, Mg and/or S, and trace element is, Cu, Fe, Zn, Mo, Mn, B and/or Cl;
Described activated humic acid is provided by the active weathered coal that contains activated humic acid, active weathered coal is made by following method: under agitation condition, to parts by weight is to add the water of 30～50 parts of parts by weight, 4～7 parts activator in 30～60 parts the weathered coal, after stirring, the catalytic oxidant that adds 2～10 parts again, simultaneously with 〉=200 rev/mins stirring velocity, under 10～60 ℃ of priming reaction temperature, reacted 3～30 minutes, then, dry under 20～90 ℃, be crushed to 〉=20 purpose particles, promptly get the active weathered coal that contains activated humic acid;
The granularity of described weathered coal is more than 〉=60 orders, wherein humic acids content 〉=50%; Activator is NaOH, KOH, Na
2CO
3, K
2CO
3, NH
4HCO
3And/or NH
4OH, described catalytic oxidant is hydrogen peroxide, SPC-D, antihypo and/or percarbonic acid hydrogen ammonium; When activator is Na
2CO
3, K
2CO
3And/or NH
4HCO
3The time, the drying temperature of activated humic acid preparation process is a normal temperature.
When the priming reaction temperature is 25～35 ℃, when stirring velocity was 200～500 rev/mins, effect was preferable.
The preparation of humic acids solid fertilizer can be adopted ordinary method, promptly pressing the weight of humic acids solid fertilizer forms, respectively with nitrogenous source, phosphorus source and potassium source material and activated humic acid, in, trace element and water-soluble chitosan place stirred vessel, stirred 15～40 minutes, and can obtain the humic acids solid fertilizer pulvis of taupe.This fertilizer pulvis can be made into the particle that granularity is 3.35～5.6mm through extrusion machine.
The present invention has the following advantages:
1. fertilizer efficiency height.The present invention adopts the natural weathered coal that has than high humic acid content (HA content 〉=50%), use activator, Preparation of Catalyst to go out to activate humic acids, not only effectively raise the humic acids activation rate, and the humic acids that has highly activated and the needed nutritive element of plant growth (nitrogen, phosphorus, zinc, iron, manganese, copper, molybdenum, boron etc.) form chelating and binding substances, make it have slow certain controlled release ability of having immediate effect property again, significantly improved the assimilated efficiency and the utilising efficiency of fertilizer.
2. cut down the consumption of energy, non-environmental-pollution, preparation cost is low.The preparation of activation weathered coal in the humic acids solid fertilizer of the present invention, owing to adopt new production technique, promptly in priming reaction, added catalytic oxidant, feasible reaction can be carried out at normal temperatures, (priming reaction of prior art needs to carry out under 60～100 ℃), thereby the energy consumption of greatly reducing, in addition, with basic carbonate such as Na
2CO
3, K
2CO
3, NH
4HCO
3Deng being in the humic acids priming reaction of activator, because the great amount of carbon dioxide gas that generates in the reaction process makes reactant can form the porous expander, the utmost point is beneficial to the seasoning at normal temperatures of activation weathered coal, not only save the energy, reduce cost, even exempted environmental pollution.
3. effect is good, can improve crop yield, improves crop quality.Because the present invention adds chitosan (chitosan) in fertilizer, it and humic acids act synergistically, further strengthened the vigor of the intravital plurality of enzymes of crop, improved cold-resistant, the drought-resistant moisture-preserving of crop and suppressed anti-adversity ability such as harmful germ, thereby improved the output of crop; In addition, in the humic acids solid fertilizer of the present invention, owing to contain a large amount of organic matters such as humic acids, the normal phase uses, can not only play and reduce soil compaction, salinification, improve the soil, increase the effect of soil and fertilizer, and help to improve the crop and fruit quality, can make the crop and fruit quality reach the above level of pollution-free green food A level.
Embodiment
Embodiment 1
1. contain the preparation of the active weathered coal of activated humic acid
Take by weighing following material and put into the priming reaction jar:
(1) water (tap water or underground well water all can) 35kg, 20 ℃ of water temps;
(2) K
2CO
3(content 98.5%) 4.5kg;
(3) weathered coal 50kg (from colliery, Huo Lin river, HA content is 60.1%, more than granularity 60 orders);
Low whipping speed is under 50 rev/mins the condition, after above-mentioned material stirred 15 minutes, in the priming reaction jar, add hydrogen peroxide 5kg (its weight percentage is 29%) again, simultaneously stirring velocity being risen to is 200 rev/mins, 27 ℃ of down about 5 minutes of reactions, treat that material forms the porous varicosity after, be poured on the seasoning of airing field, pulverize, sieve (20 order) promptly gets evengranular activated humic acid content and is 61.3% active weathered coal.
2. the preparation of humic acids solid fertilizer
Low whipping speed is under 50 rev/mins the condition, to take by weighing following material, puts into mixing tank.
(1) active weathered coal 35.0kg (above-mentioned steps 1 is prepared)
(2) urea 29.0kg
(3) monoammonium phosphate 15.0kg
(4) vitriolate of tartar 19.0kg
(5) boric acid 0.6kg
(6) zinc sulfate 1.1kg
(7) ammonium molybdate 0.11kg
(8) manganous sulfate 0.10kg
(9) water-soluble chitosan 0.09kg
In mixing tank, stir and got final product discharging in 20 minutes, get humic acids solid fertilizer of the present invention.
Humic acids solid fertilizer with above-mentioned preparation carries out brooder application tests such as tomato, eggplant, strawberry, grape.With equivalent chemical fertilizer controlled trial in, make trial crops increase output 19～51% with this product, its crop and fruit quality be improved significantly, sugar, Vc content all obviously increase, and nitrate content reduces.Mouthfeel is significantly better than to fertilize crop and fruit.
Embodiment 2 contains the preparation of the active weathered coal of activated humic acid
The weathered coal 50Kg of granularity 100 orders, humic acids content 50% in the priming reaction jar, is started stirring, and its speed is 50 rev/mins, adds the water of 40Kg, the K of 4.5Kg respectively
2CO
3, stir after 20 minutes, add 7Kg H again
2O
2, stirring velocity is risen to 300 rev/mins simultaneously, under 35 ℃, reacted 5 minutes, reaction product natural drying 8 hours after the drying, sieves through slightly rolling in (20 order), promptly forms evengranular active weathered coal.Wherein the weight percentage of activated humic acid is 80.60% after testing.
Embodiment 3 contains the preparation of the active weathered coal of activated humic acid
The weathered coal 50Kg of granularity 100 orders, humic acids content 50% in the priming reaction jar, is started stirring, and its speed is 50 rev/mins, adds 30Kg water, 3.5Kg Na respectively
2CO
3, 2KgNH
4HCO
3, stir after 20 minutes, add 1Kg antihypo and 4Kg H again
2O
2, stirring velocity is risen to 500 rev/mins simultaneously, under 25 ℃, reacted 5 minutes, promptly become varicosity, reactant is poured out and is moved on the airing field, and seasoning was sieved through slightly rolling in (20 order) after 5 hours, promptly formed evengranular active weathered coal.Wherein the weight percentage of activated humic acid is 74.0% after testing.
The preparation of embodiment 4 humic acids solid fertilizers (fertilizer special for watermelon)
Under agitation condition, material listed in the table 1 is added respectively in the mixing tank, fully stirred 15 minutes, promptly obtain taupe humic acids solid fertilizer pulvis, its pH value is 6.3.It is applied on the melonry, compares with the melonry of using the equivalent chemical fertilizer, increasing yield of water melons is more than 28%, and melon is big, and flesh is crisp and sweet, and the shelf-time increases more than 10 days.
Table 1
| Name of material | Urea | Monoammonium phosphate | Vitriolate of tartar | Zinc sulfate | Manganous sulfate | Ammonium molybdate | Boric acid | Chitosan | Active weathered coal * |
| Quantity (Kg) | 24.2 | 10.0 | 18.0 | 1.0 | 0.05 | 0.1 | 0.45 | 0.1 | 46.2 |
*Active weathered coal selects for use embodiment 2 made
The preparation of embodiment 5 humic acids solid fertilizers (dedicated fertilizer for soybean)
Under agitation condition, material listed in the table 2 is added respectively in the mixing tank, fully stirred 15 minutes, promptly obtain taupe humic acids solid fertilizer pulvis, make the particle of φ 3mm, long 5mm then with Squeezinggranulator, its pH value is 7.3.It is applied to the soybean field, compares with the soybean field of using the equivalent chemical fertilizer, soybean yield-increasing is more than 16%, and its seed is even, big and full.
Table 2
| Name of material | Urea | Double superhosphate | Vitriolate of tartar | Repone K | Sal epsom | Manganous sulfate | Ferrous sulfate | Ammonium molybdate | Active weathered coal * |
| Quantity (Kg) | 29.0 | 15.0 | 6.7 | 5.0 | 2.0 | 0.58 | 0.40 | 0.12 | 40.1 |
*Active weathered coal selects for use embodiment 1 made
The preparation of embodiment 6 humic acids solid fertilizers (floral special-purpose fertilizer)
Under agitation condition, material listed in the table 3 is added respectively in the mixing tank, fully stirred 20 minutes, promptly obtain taupe humic acids solid fertilizer pulvis, its pH value is 6.0.It is applied in the poinsettia flowerpot, compares with the flower of using the equivalent chemical fertilizer, longer blooming period is more than 10 days, and the color of flower is especially bright-coloured.
Table 3
| Name of material | Ammonium nitrate | Urea | Monoammonium phosphate | Repone K | Sal epsom | Ferrous sulfate |
| Quantity (Kg) | 25.1 | 10.9 | 11.0 | 8.3 | 0.37 | 0.25 |
| Name of material | Zinc sulfate | Manganous sulfate | Ammonium molybdate | Boric acid | Chitosan | Active weathered coal ( *) |
| Quantity (Kg) | 0.03 | 0.11 | 0.02 | 0.12 | 0.1 | 43.58 |
*Active weathered coal selects for use embodiment 3 made
Claims (5)
1. humic acids solid fertilizer, it is characterized in that: in 100 parts, its weight consists of: 4～40 parts in nitrogen, 3～35 parts in phosphorus, 3～40 parts in potassium, 0～6.5 part of moderate-element, 0～1.5 part of trace element, 15～30 parts of activated humic acids, water-soluble chitosan are 0～1.0 part; Described activated humic acid is provided by the active weathered coal that contains activated humic acid, active weathered coal is made by following method: under agitation condition, to parts by weight is to add the water of 30～50 parts of parts by weight, 4～7 parts activator in 30～60 parts the weathered coal, after stirring, the catalytic oxidant that adds 2～10 parts again, simultaneously with 〉=200 rev/mins stirring velocity, under 10～35 ℃, reacted 3～30 minutes, then, seasoning, drying temperature is a normal temperature, be crushed to 〉=20 purpose particles, promptly get the active weathered coal that contains activated humic acid;
Described activator is Na
2CO
3, K
2CO
3And/or NH
4HCO
3Described catalytic oxidant is hydrogen peroxide, SPC-D and/or antihypo.
2. according to the described humic acids solid fertilizer of claim 1, it is characterized in that: described nitrogen is the available nitrogen content in the nitrogenous source, and nitrogenous source is urea, ammonium nitrate, ammonium sulfate, bicarbonate of ammonia and/or Dyhard RU 100; Phosphorus is the available phosphorus content in the phosphorus source, and the phosphorus source is ammonium hydrogen phosphate, potassium hydrogen phosphate, calcium superphosphate and/or double superhosphate; Potassium is the effective potassium content in the potassium source, and the potassium source is vitriolate of tartar, Repone K and/or saltpetre.
3. according to the described humic acids solid fertilizer of claim 1, it is characterized in that: described moderate-element is Ca, Mg and/or S, and trace element is Cu, Fe, Zn, Mo, Mn, B and/or Cl.
4. according to the described humic acids solid fertilizer of claim 1, it is characterized in that: the granularity of described weathered coal is 〉=60 orders, wherein humic acids content 〉=50%.
5. according to the described humic acids solid fertilizer of claim 1, tool is characterised in that: described temperature of reaction is 25～35 ℃, and stirring velocity is 200～500 rev/mins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410020960 CN1255361C (en) | 2004-07-12 | 2004-07-12 | Humic acid solid fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410020960 CN1255361C (en) | 2004-07-12 | 2004-07-12 | Humic acid solid fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1594235A CN1594235A (en) | 2005-03-16 |
| CN1255361C true CN1255361C (en) | 2006-05-10 |
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|---|---|---|---|
| CN 200410020960 Expired - Fee Related CN1255361C (en) | 2004-07-12 | 2004-07-12 | Humic acid solid fertilizer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101811900A (en) * | 2010-01-22 | 2010-08-25 | 西北农林科技大学 | Organic total nutrient fertilization method |
| CN102772704A (en) * | 2012-08-15 | 2012-11-14 | 殷广全 | Medicament for treating geriatric disease |
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2004
- 2004-07-12 CN CN 200410020960 patent/CN1255361C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101811900A (en) * | 2010-01-22 | 2010-08-25 | 西北农林科技大学 | Organic total nutrient fertilization method |
| CN101811900B (en) * | 2010-01-22 | 2012-11-14 | 西北农林科技大学 | Organic total nutrient fertilization method |
| CN102772704A (en) * | 2012-08-15 | 2012-11-14 | 殷广全 | Medicament for treating geriatric disease |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1594235A (en) | 2005-03-16 |
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