CN1198687C - 多孔高度氟化酸性聚合物催化剂及其制备方法 - Google Patents

多孔高度氟化酸性聚合物催化剂及其制备方法 Download PDF

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Publication number
CN1198687C
CN1198687C CNB00803057XA CN00803057A CN1198687C CN 1198687 C CN1198687 C CN 1198687C CN B00803057X A CNB00803057X A CN B00803057XA CN 00803057 A CN00803057 A CN 00803057A CN 1198687 C CN1198687 C CN 1198687C
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CN
China
Prior art keywords
polymer
polymkeric substance
highly fluorinated
solid acid
acid catalyst
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Expired - Fee Related
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CNB00803057XA
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English (en)
Chinese (zh)
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CN1337891A (zh
Inventor
R·B·劳埃德
E·G·霍瓦德
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/032—Impregnation of a formed object with a gas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CNB00803057XA 1999-01-29 2000-01-28 多孔高度氟化酸性聚合物催化剂及其制备方法 Expired - Fee Related CN1198687C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11769999P 1999-01-29 1999-01-29
US60/117,699 1999-01-29

Publications (2)

Publication Number Publication Date
CN1337891A CN1337891A (zh) 2002-02-27
CN1198687C true CN1198687C (zh) 2005-04-27

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CNB00803057XA Expired - Fee Related CN1198687C (zh) 1999-01-29 2000-01-28 多孔高度氟化酸性聚合物催化剂及其制备方法

Country Status (6)

Country Link
US (1) US6200924B1 (https=)
EP (1) EP1152830B1 (https=)
JP (1) JP4589533B2 (https=)
CN (1) CN1198687C (https=)
DE (1) DE60041436D1 (https=)
WO (1) WO2000044495A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100360239C (zh) * 2005-07-14 2008-01-09 上海交通大学 大孔交联聚苯乙烯混合酸离子交换树脂及其制备方法

Families Citing this family (17)

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DE19956568A1 (de) 1999-01-30 2000-08-17 Roland Kreutzer Verfahren und Medikament zur Hemmung der Expression eines vorgegebenen Gens
DE10100586C1 (de) 2001-01-09 2002-04-11 Ribopharma Ag Verfahren zur Hemmung der Expression eines Ziegens
US7193113B2 (en) 2000-12-15 2007-03-20 Japan Science And Technology Corporation Arylbis(perfluoroalkylsulfonyl) methane and metallic salt thereof, and methods for producing the same
US7423142B2 (en) 2001-01-09 2008-09-09 Alnylam Pharmaceuticals, Inc. Compositions and methods for inhibiting expression of anti-apoptotic genes
US7767802B2 (en) 2001-01-09 2010-08-03 Alnylam Pharmaceuticals, Inc. Compositions and methods for inhibiting expression of anti-apoptotic genes
JP3773824B2 (ja) * 2001-03-12 2006-05-10 独立行政法人科学技術振興機構 高分子担持型アリールビス（パーフルオロアルキルスルホニル）メタン
JP4712223B2 (ja) * 2001-05-22 2011-06-29 オルガノ株式会社 固体酸触媒
US6677269B2 (en) 2001-05-17 2004-01-13 George A Olah Environmentally safe alkylation of aliphatic and aromatic hydrocarbons with olefins using solid HF-equivalent catalysts
US6924407B2 (en) * 2001-08-27 2005-08-02 The University Of Kansas Pressure-tuned solid catalyzed heterogeneous chemical reactions
AU2003260370B2 (en) 2002-08-05 2008-05-22 Silence Therapeutics Gmbh Further novel forms of interfering RNA molecules
CN102228841B (zh) * 2011-05-11 2013-04-10 凯瑞化工股份有限公司 一种耐高温含氟树脂催化剂及其制备方法
AU2012260598A1 (en) * 2011-05-23 2014-01-16 Exonomer Pty Ltd Expanded ionomers and their uses
KR101358940B1 (ko) 2012-06-01 2014-02-06 한국과학기술연구원 다공성 표면층을 가지는 나피온 막 및 그 제조 방법
KR101719293B1 (ko) 2015-01-13 2017-03-23 한국과학기술연구원 다공성 나피온 막 및 그 제조 방법
CN112808310B (zh) * 2019-11-18 2022-09-06 六盘水师范学院 一种两亲性有机多孔聚合物固体酸催化剂及其制备方法和应用
CN113999337A (zh) * 2020-07-27 2022-02-01 上海漫关越水处理有限公司 一种超大孔含氟超强酸催化树脂及其合成方法
CN112436167B (zh) * 2020-11-17 2021-10-12 中国科学院兰州化学物理研究所 一种直接式多醚类化合物燃料电池及系统

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
JPS52154862A (en) * 1976-06-17 1977-12-22 Sumitomo Electric Industries Method of producing porous material
US4180695A (en) * 1976-03-04 1979-12-25 Shell Oil Company Isoparaffin alkylation process using an unsupported perfluorinated polymer catalyst
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5094995A (en) 1989-08-02 1992-03-10 E. I. Du Pont De Nemours And Company Supported perfluorinated ion-exchange polymers
JP3360286B2 (ja) * 1992-06-25 2002-12-24 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー 多孔質ポリテトラフルオロエチレン及び製造法
AU6531994A (en) * 1993-05-21 1994-12-20 E.I. Du Pont De Nemours And Company Porous polytetrafluoroethylene and preparation
US5824622A (en) * 1994-01-12 1998-10-20 E. I. Du Pont De Nemours And Company Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process
US5830923A (en) * 1996-05-22 1998-11-03 E. I. Du Pont De Nemours And Company Foamed fluoropolymer
JP3667005B2 (ja) * 1996-06-13 2005-07-06 旭化成エレクトロニクス株式会社 ゲル系電解質および電気化学素子の製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100360239C (zh) * 2005-07-14 2008-01-09 上海交通大学 大孔交联聚苯乙烯混合酸离子交换树脂及其制备方法

Also Published As

Publication number Publication date
WO2000044495A1 (en) 2000-08-03
DE60041436D1 (de) 2009-03-12
JP2002535137A (ja) 2002-10-22
US6200924B1 (en) 2001-03-13
CN1337891A (zh) 2002-02-27
JP4589533B2 (ja) 2010-12-01
EP1152830B1 (en) 2009-01-21
EP1152830A1 (en) 2001-11-14

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Granted publication date: 20050427

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