CN1197934C - Pearlite for culturing plant and its use - Google Patents

Pearlite for culturing plant and its use Download PDF

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CN1197934C
CN1197934C CN 01143467 CN01143467A CN1197934C CN 1197934 C CN1197934 C CN 1197934C CN 01143467 CN01143467 CN 01143467 CN 01143467 A CN01143467 A CN 01143467A CN 1197934 C CN1197934 C CN 1197934C
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pearlstone
soil
fertilizer
plant
perlite
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CN1393123A (en
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朴炫俊
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Samson Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00758Uses not provided for elsewhere in C04B2111/00 for agri-, sylvi- or piscicultural or cattle-breeding applications

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
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  • Cultivation Of Plants (AREA)
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Abstract

The invention provides a functional pearlite for plant culturing and application thereof, the functional pearlite is obtained by mixing clay mineral containning lossal by harmless binder to cover swelling pearlite. The functional pearlite has advantages of pearlite and also increases advantages of nutrient retention and high hardness of particles, so can be used by self or mixed with artifical soil for kinds of plant. Moreover, coving with fertilizer without need adding other organic or inorganic fertilizer, regualting component of fertilizer according need of plant for afforesting light soil on upper of artifical building, covering regent, roof, terrace, drain, oxygen tube of trees, artifical soil of bedding soil for growing seed, potted flower soil and soil amendment.

Description

Plant growing perlite and uses thereof
Technical field
The present invention relates to plant growing perlite and uses thereof.Both used the caking agent harmless to plant on perlitic surface, the clay mineral that CEC (cation exchange capacity (CEC)) is high mixes the back with the foster liquid composition that is suitable for plant-growth and covers on it, existing perlitic shortcoming-be nutrient is possessed the power difference and granule strength is low thereby overcome, the CEC and the liquid fertilizer that are suitable for dissimilar plant-growths simultaneously in the energy regulated at will perlite constitute, and needn't add the plant growing perlite of other liquid fertilizer again.Perlite of the present invention can use and be used for the artificial soil of plant growing.
Background technology
Pearlstone is mainly used in agricultural gardening and makes the scape artificial soil, the sound-absorbing ceramic tile that light weight aggregate for building and interior and exterior finishes are used, macromolecular material filling etc.But, because the pearlstone of every kind of purposes all has its shortcoming separately, so in order to remedy its shortcoming, the inventor has proposed pearlstone is covered, and improves the invention of its function.
Now, domestic also not relevant therewith technology.Abroad, only for building or industry with former pair of material in, in order to remedy shortcoming such as the low and water-absorbent difference of pearlstone intensity, later on the pearlstone surface quality was carried out improved research and development since 1970.
No. 4255489 patent of the U.S. and No. 4183980 patent disclosure mainly cover on it with the lyophobic dust polysiloxane, make it have hydrophobicity, and this method mainly is applicable to macromolecular material (coating and pigment).No. 4889747 patent of the U.S. announced the method that use silicane caking agent, buffer reagent cover, No. 5964934 patent has been announced the method that covers with silane compound, No. 3769065 patent has been announced the method that covers with acetate and water glass, this method applicable object is plastics, infill panel, internal and external ornament sound-absorbing ceramic tile etc.
Have the shortcoming that lower nutrient is possessed power and intensity at the pearlstone that is used for agricultural gardening and makes scape, up to the present also do not hear promising solution, overcome its shortcoming and the effort done.
On the other hand, pearlstone has the physical property of the plant-growth of being well suited for, and both voidage was higher than 70% air permeability, and coefficient of permeability is higher than 10 -3The drainage of cm/sec, the needed moisture content of plant---available water (0.03--15 air pressure) value are higher than 40% high-moisture and possess power; And, space and higher surface area (500m that 10um is inside and outside 2/ g) provide good environment than the breeding of giving microorganism.Therefore, when plant-growth, pearlstone and plant symbiosis are deposited, can around plant root, be formed with the useful matter and the good growing environment that are beneficial to microbial reproduction.
But because pearlstone is as noncrystalline matter mineral, its surface does not have insulating covering agent, and it is low that nutrient is possessed power, CEC (cation exchange capacity (CEC)) almost approaches 0, so can not keep the required nutrient of plant-growth, and the pearlstone surface is frangible, has the shortcoming that micro mist disorderly looses.
On the other hand, when trees are transplanted, do not form plant-growth required nutrient supply in period,, occurred trees kind and the withered situation of state again so trees surviving rate reduces.Need the trees of nutrient supply opposite with early growth period, the flowers and plants class colored situation occurred not tying because of not having to form the nutrient supply that continues.
Summary of the invention
In view of the foregoing, the purpose of this invention is to provide a kind of plant growing perlite and uses thereof that plant growing ground nutrient is possessed power and granule strength that improves.
In order to realize this goal of the invention, the present invention by the following technical solutions: a kind of plant growing perlite, it is to cover clay mineral and adhesive solution on pearlstone.
Described pearlstone is meant that pitchstone, black credit rock, perlite are heated to the material that draws after 1000 degree expand; Or silicate, glass are heated to the material that draws after 1000 degree expand; The material that draws after the described expansion is the mesopore spheroid that comprises bubble.Described 1000ml pearlstone is coated with clay mineral 15-400g, the adhesive solution 50-400ml of 5-50%.Described caking agent is the organic or inorganic caking agent, and described organic adhesive is more than one organic adhesives of selecting in vinylacetate system, aqueous acrylic acid series, three polymeric amide system, aqueous vinyl Mono Chloro Acetic Acid system, water-based ammonia ester system, polyethenol series, epoxy resin and synthetic rubber, the natural rubber class; Inorganic adhesive refers to water glass or polyphosphoric acid aluminum dihydrogen, phosphoric acid hydrogen two aluminium, aluminum phosphate, aluminum pyrophosphate, aluminium metaphosphate, aluminium dihydrogen phosphate, aluminium triphosphate.Described clay mineral is meant the material of selecting more than one loess, zeolite, wilkinite and snake aragonite more than 10cmolc/kg, peridotites, the pyroxene mineral.Add fertilizer in described adhesive solution or the clay mineral.Described fertilizer is inorganic or organic fertilizer or various plant growth regulating substance; Described mineral manure is that saltpetre, nitrocalcite, ammonium nitrate, sal epsom, ethylenediamine tetraacetic acid (EDTA) are ferrous, manganous sulfate, copper sulfate, zinc sulfate chemical substance and with this blended compound manure; Described organic fertilizer is that amino acid, wood vinegar, plant extractum are basic fertilizer.
Utilize plant growing of the present invention can make the greening of artificial structure top and use insulating covering agent with light weight soil and potted flower with perlite.Utilize plant growing of the present invention can make trees with perlite, the lawn, the flowers and plants class greening light weight soil on artificial structure top, trees are used oxygen hose, grow seedlings with bed soil, and potted flower is used various plant growings artificial soil and soil improvement agents such as soil.
The contriver is in the process that solves the problem that exists when pearlstone is applicable to plant growing such as flowers and plants, when finding that CEC is high, clay mineral is added behind the harmless caking agent of plant, after injection covers the pearlstone surface, CEC can regulate, and strengthened granule strength, optionally add fertilizer again.When regulating the addition of nutrient, can play effect quick-acting and slow release nutrient.
This pearlite for culturing plant is of many uses, can use with artificial mixing with soil separately or with various plant growings.Be mainly used in insulating covering agent and roof, balcony, the greening light weight soil on artificial structure tops such as water drain treatment plant, trees are used oxygen hose, grow seedlings with bed soil, and potted flower is used various plant growings artificial soil and soil improvement agents such as soil.
Description of drawings
Fig. 1 is when making product of the present invention-covering perlite, the cumulative water-oil ratio table of clay mineral mud
Fig. 2 is the covering perlite mixed soil of making according to the present invention, the embodiment sectional view that is used to plant arbor or shrub
Fig. 3 is the covering perlite mixed soil of making according to the present invention, is used for the embodiment sectional view of turf plant
Symbol is detailed among the figure:
11,111-concrete water-proof layer
12,112-polypropylene-base draining porous disc
13,113-synthon sheet
14-draining pearlstone
15,115-mixes the covering perlite and grows seedlings and use pearlstone soil
The specific embodiment of the invention
Of the present invention being described in detail as follows:
Because perlite is not with negatively charged ion, promptly CEC almost approaches 0, in order to separate the shortcoming that must not keep nutrient, uses clay mineral, for example, and the high clay minerals of CEC such as loess, zeolite, wilkinite, snake aragonite.
Above clay mineral has the CEC height, and quality is more stable, buys easily, and is difficult for producing the advantage of decomposing.
The clay mineral that such CEC is high covers on the pearlstone, just can produce to have and can regulate CEC, can regulate the recoverable amount of nutrient and the pearlstone of nutrient.Can also add the organic fertilizer with slow effect as required and make pearlite, proportion is 0.20-0.30g/cm 2Similar to perlite, so there is not particle size separation, need not specific engineering and can add fertilizer, and cover on the pearlstone after fertilizer directly is added on clay mineral or caking agent, play the effect of uniform distribution fertilizer, and can select quick-acting, controlled-release fertilizer, also have the strength ratio pearlstone strong, so rerum natura is with low uncertainty, patience is fine, can also guarantee stable quality.Regulate to cover perlitic addition, the addition of the nutrient during covering and nutrient kind can be produced the mixing prod of plant and different applicable objects.With small amount of clay matter mineral high CEC can be arranged.
The perlitic making of above-mentioned covering is only used clay mineral mud, also can cover.For the caking agent that adds in order to improve bonding efficient, in the choice, not only bonding force wants outstanding, also harmless to plant.
The selection of caking agent is undertaken by following experiment:
(1) selection of organic/inorganic caking agent experiment
The present invention is developed to the pearlite of plant growing ground usefulness with pearlstone, wherein will use caking agent, thus having/selection of inorganic adhesive on, not only the sticking criticality of caking agent wants outstanding, also harmless to plant.
In the selection experiment of caking agent, cover the back bonding force and its weather resistance, weathering resistance are tested according to the KSM5000 standard, compared water-intake rate again, percentage of germination and plant-growth.Selected plant harmless, and the organic/inorganic caking agent that can cover with pearlstone.
The concentration that covers organic/inorganic adhesive is 20%, and the weight ratio of caking agent and loess is 2: 1, and the volume ratio of caking agent and pearlstone is 1: 10.Last moisture content (VOL%) when water-intake rate refers to exert pressure with PF1.5.Fraction of coverage is meant that difference that the water-intake rate of pearlstone deducts the water-intake rate that covers the pearlstone behind organic/inorganic adhesive is again divided by the per-cent of the water-intake rate of pearlstone.Percentage of germination refers to Chinese sorghum, capsicum, the cucumber 30ml, the seed of Chinese cabbage, sowing is on the mu dish of 50 tools, temperature is controlled at 25 degree, humidity 70%, and guarantee under the moisture-resistant situation of temperature resistance, it is germinateed, then the later quantity of germinateing is removed the per-cent that obtains in 50 (seed number of sowing).The cultivation of plant be temperature be 25 the degree, humidity is 30%, illuminance is under the condition of 150000LUx (12 hours), the back of germinateing in the place of growth provided and once supports liquid and organic/inorganic caking agent 1% in per 3 days, cultivate after 30 days its growth conditions is divided into best maintenance, maintenance, generally, bad reaches five very bad stages and represent.
1-1) the experimental result of organic adhesive selection
When selecting organic adhesive, water tolerance, weathering resistance are not unusual, and fraction of coverage is more than 70%, and pH value approaches neutrality, and percentage of germination is more than 80%, plant grew well.This only is the selectivity experiment of organic bonding agent and oneself is not to be limited in to add organic adhesive.
The experimental result of concrete organic adhesive please be seen table 1.
[table 1]
Organic adhesive (20%) The water tolerance weathering resistance Water-intake rate (vol%) Fraction of coverage (%) PH before dry Dry back PH Percentage of germination (%) Plant-growth
Pearlstone 67 - Neutral Neutral 92 Bad
EVA No abnormal 10 85 Neutral Neutral 95 Very good
Water soluble acrylic acid No abnormal 18 73 Neutral Neutral 90 Well
Three polymeric amide No abnormal 5 93 Alkalescence Neutral 88 Well
The aqueous vinyl Mono Chloro Acetic Acid No abnormal 15 78 Slightly acidic Neutral 94 Well
Water-based ammonia ester No abnormal 18 73 Alkalescence Neutral 89 Well
PVA No abnormal 14 79 Neutral Neutral 95 Very good
1-2) inorganic adhesive is selected experimental result for use
Belong to the water glass and the phosphoric acid alkali of inorganic adhesive, though be suitable for water tolerance, weathering resistance, fraction of coverage etc. cover perlitic physical property standard, because of the approaching alkalescence of pH value or acid, are not suitable for biological standard.In order to address these problems, add lime treatment when using phosphoric acid alkali, use nitronic acid when using water glass, phosphoric acid, use middleization such as yellow acid back.This is the experimental result of selecting for use of inorganic adhesive, and the kind of adding inorganic adhesive is not limited to this.
Concrete outcome is as shown in table 2.
[table 2]
Inorganic adhesive (20%) The water tolerance weathering resistance Water-intake rate (vol%) Fraction of coverage (%) PH before handling Handle back PH Percentage of germination (%) Plant-growth
Pearlstone (EP1) 67 - Neutral Neutral 92 Bad
Water glass No abnormal 23 75 Alkalescence Neutral 82 Well
Phosphoric acid alkali No abnormal 10 85 Acid Neutral 85 Well
More than experiment, organic adhesive has used vinylacetate, water soluble acrylic acid, three polymeric amide, the aqueous vinyl Mono Chloro Acetic Acid, water-based ammonia ester, polyvinyl alcohol, inorganic adhesive has used water glass, phosphoric acid alkali.Mix with clay mineral, cover on the pearlstone with inorganic adhesive.
(2) pearlstone covers experiment
The method that covers pearlstone has 3 kinds.First kind is the method that is injected in the surface of pearlstone after mixing adhesive solution in the clay mineral mud.Second kind is after spraying adhesive solution in the pearlstone, the method for spraying clay mineral again.The third is that clay mineral and pearlstone mix the method that adhesive solution is sprayed in the back.These 3 kinds of methods all are applicable to continous way, the collocation type mode of production, but first method is the most favourable in the continous way mode of production, and three kinds of methods can in the collocation type mode of production.These three kinds of methods caking agent concentration when covering plays an important role, can regulated at will caking agent concentration from 5-50%, the first method that is fit to the continous way mode of production (can carry out double mass production), because viscosity plays vital role when making mud, so selected experiment of mud and the selected experiment of proportioning have been carried out.This does not mean that the covering method of clay mineral only is defined in first kind.
2-1) the clay mineral mud viscosity is selected
Select to ask the size ratio and the liquid limit of each clay mineral earlier before the viscosity of mud, make mud by 5 kinds of functions between saturated soil that is higher than liquid limit and the supersaturation soil than (with reference to Fig. 1) after, try to achieve the function ratio that is suitable for covering most.
As clay mineral, loess, zeolite, wilkinite, snake aragonite are like table 3, and the fluidity limitation of each argillaceous mineral ratio, size ratio is different.Because all clay minerals are non-plasticity-in the granularity below 35#, measured liquid limit in the granularity more than 100#.Based on its result, after in the product of liquid limit more than 150%, adding the 5 kinds of mud of moisture (10%EVA) making more than the liquid limit, measure the viscosity of (using the viscosimetric analysis device) various mud, cover pearlstone, try to achieve proportion after the drying, water-intake rate (moisture content in pf1.5), fraction of coverage, below 20%, fraction of coverage is a benchmark more than 70% with water-intake rate, has selected best mud function ratio.During covering, the volume of the pearlstone of input is with 10 times of calculating of moisture content volume.For example, when the moisture content of the clay mineral of 100g is 190% (190ml), use the pearlstone of 1900ml, when the moisture content of 100g clay mineral is 210% (210ml), used the pearlstone of 2100ml.
[table 3]
Order No Liquid limit (%)
Loess Zeolite Wilkinite The snake aragonite
100 65 129 83 45
150 123 167 137 104
200 168 242 228 176
325 227 303 274 239
2-1-1) loess mud
Granularity is the moisture content ratio of 200 purpose loess and 10%EVA mud, drying back proportion, water-intake rate and fraction of coverage such as table 4.
[table 4]
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
180 2100 0.254 22 67 The nozzle ejection difficulty
190 1570 0.287 13 80
200 1140 0.290 7 90
210 880 0.284 12 82
220 410 0.247 24 64
From the result of last table 4 as can be known, clay mineral uses under the situation of granularity as 200# loess, during moisture content 190-210% weight, produces the viscosity, proportion, water-intake rate and the fraction of coverage that are fit to.
In addition, use the determination of moisture result such as the table 5 of the clay of 325# loess.
[table 5]
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
240 2300 0.263 18 73 The nozzle ejection difficulty
250 1680 0.298 11 83
260 1250 0.315 5 92
270 980 0.284 10 85
280 4901 0.268 16 76
From the result of last table 5 as can be known, during the granularity 325# of loess, the moisture content of adjusting clay with 250-270% is optimum.
2-1-2) zeolite clay
Measured the moisture content ratio of zeolite and 10%EVA clay, dry back proportion, water-intake rate, fraction of coverage is shown in table 6-8.[table 6]
Granularity is zeolite+10% EVA of 150#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
180 2010 0.233 19 71
190 1450 0.262 12 82
200 1030 0.271 6 91
210 740 0.268 10 85
220 350 0.225 18 73
[table 7]
Granularity is zeolite+10%EVA of 200#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
260 2250 0.254 21 63 The nozzle ejection difficulty
270 1770 0.287 11 81
280 1480 0.302 5 93
290 980 0.279 9 86
300 470 0.257 16 76
[table 8]
Granularity is zeolite+10%EVA of 325#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
310 3500 - - - The nozzle ejection failure
320 2540 0.258 31 53 N nozzle ejection difficulty
330 1850 0.305 13 80
340 1680 0.327 4 94
350 1160 0.303 8 88
From the result of table 6-8 as can be known, during the most suitable covering, the clay moisture content of zeolite is: 190-210% in 150#, 270-290% among the 200#, 330-350% among the 325#.
2-1-3) POLARGEL NF
Measured the moisture content ratio of wilkinite and 10%EVA clay, dry back proportion, water-intake rate, fraction of coverage is shown in table 9 and 10.
[table 9]
Granularity is wilkinite+10%EVA of 200#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
240 2050 0.263 27 59 The nozzle ejection difficulty
250 1470 0.277 11 83
260 1280 0.289 6 91
270 780 0.275 13 80
280 370 0.251 23 65
[table 10]
Granularity is wilkinite+10%EVA of 325#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
290 2420 0.283 36 56 The nozzle ejection difficulty
300 1850 0.295 11 83
310 1350 0.311 7 90
320 1080 0.287 10 85
330 690 0.278 24 64
Can learn that from the result of table 9 and 10 during the most suitable covering, bentonitic clay moisture content is: 300-320% among 250-270%, the 325# in 200#.
2-1-4) snake aragonite clay
Measured the moisture content ratio that pastes the civilian heart and 1 sail EVA clay, dry back proportion, water-intake rate, fraction of coverage is as table 11 and 12.[table 11]
Granularity is snake aragonite+10%EVA of 200#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
190 2130 0.232 34 59 The nozzle ejection difficulty
200 1520 0.265 17 74
210 1240 0.278 12 82
220 680 0.261 15 77
230 310 0.228 23 65
[table 12]
Granularity is snake aragonite+10%EVA of 325#
Moisture content (weight %) Viscosity (CP) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Relatively
250 2290 0.251 29 56 The nozzle ejection difficulty
260 1580 0.278 16 76
270 1350 0.301 9 86
280 820 0.272 13 80
290 390 0.241 21 68
Can learn that from the result of table 11 and 12 during the most suitable covering, the moisture content of the clay of snake aragonite is: 200-220% in 200#, 260-280% among the 325#.
Can know the most suitable covering between 500-2000CP time of the viscosity number of clay mineral clay from above 12 experimental results.But this to be fraction of coverage be 60% experimental result when above, also having some to need fraction of coverage is product 60% below, so the viscosity of interpolation clay mineral clay is not restricted to this.
2-2) proportioning is selected
Under the situation of same granularity, the viscosity ratio of clay mineral (loess, zeolite, wilkinite, snake aragonite) is that zeolite>wilkinite>loess>snake aragonite reduces in proper order.And because the color (lightness) of loess utilizes the loess of 200# than being easier to, in EVA concentration, EVA and pearlstone change, and carry out pearlstone and cover the selected experiment of proportioning.
The concentration of organic adhesive EVA is with 10,20,30%, and the amount of having made viscosity and be the loess of using when loess mud between the 500-2000CP is made mud EVA concentration of interpolation when making is directly proportional.This is because EVA disperses when adding gradually.
The covering proportioning of pearlstone: the volume ratio of EVA and pearlstone is with 1: 50, and 1: 20,1: 102: 5, be benchmark cover at 1: 2.
Finish after the loess covering, measure dry back proportion, water-intake rate, fraction of coverage (conversion of water-intake rate), color (Munsell color table) (annotate: this is a name), with water-intake rate below 20%, fraction of coverage is a benchmark more than 70%, has selected the concentration of suitable organic adhesive, the cooperation volume ratio of EVA and pearlstone, and whether be suitable for plant-growth usefulness in order to confirm, measured CEC (cation exchange capacity (CEC)).
Concrete experiment condition and result are as table 13-15.
[table 13]
[table 13]
EVA concentration (%) Loess mud (EVA: loess, ml:g) EVA: pearlstone (ml: ml) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Lightness CEC (cmol/kg)
10 100∶30 50∶1000 Can not form mud (liquid is strong)
100∶1000
400∶1000
100∶40 20∶1000 Because of water deficient, cover bad
50∶1000 0.211 20 70 5 7.32
100∶1000 0.235 13 80 4 8.19
400∶1000 0.233 18 74 5 7.54
500∶1000 Because of excess moisture, cover bad
100∶50 20∶1000 Because of water deficient, cover bad
50∶1000 0.205 27 59 6 6.13
100∶1000 0.269 7 89 4 8.28
400∶1000 0.223 17 74 5 7.17
500∶ 1000 Because of excess moisture, cover bad
100∶60 20∶1000 Because of water deficient, cover bad
50∶1000 0.218 3l 53 7 6.34
100∶1000 0.27l 10 85 4 8.66
400∶1000 0.234 13 80 4 8.15
500∶1000 Because of water deficient, cover bad
100∶70 50∶1000 Can not form mud (expansion)
100∶1000
400∶1000
[table 14]
EVA concentration (%) Loess mud (EVA: loess, ml:g) EVA: pearlstone (ml: ml) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Lightness CEC (cmol/kg)
20 100∶40 50∶1000 Can not form mud (liquid is strong)
100∶1000
400∶1000
100∶50 20∶1000 Because of water deficient, cover bad
50∶1000 0.235 21 62 6 7.72
100∶1000 0.289 9 86 4 8.47
400∶1000 0.233 17 74 5 7.82
500∶1000 Because of excess moisture, cover bad
100∶60 20∶1000 Because of water deficient, cover bad
50∶1000 0.247 12 59 6 6.19
100∶1000 0.292 6 91 3 8.32
400∶1000 0.242 13 80 4 7.89
500∶1000 Because of excess moisture, cover bad
100∶70 20∶1000 Because of water deficient, cover bad
50∶1000 0.235 23 65 6 6.34
100∶1000 0.296 9 86 4 8.99
400∶1000 0.247 11 83 4 7.37
500∶1000 Because of water deficient, cover bad
100∶80 50∶1000 Can not form mud (expansion)
100∶1000
400∶1000
[table 15]
EVA concentration (%) Loess mud (EVA: loess, ml:g) EVA: pearlstone (ml: ml) Dry back proportion (g/ml) Water-intake rate (%) Fraction of coverage (%) Lightness CEC (cmol/kg)
30 100∶50 50∶1000 Can not form mud (liquid is strong)
100∶1000
400∶1000
100∶60 20∶1000 Because of water deficient, cover bad
50∶1000 0.252 14 79 5 7.82
100∶1000 0.308 4 95 3 9.12
400∶1000 0.285 13 80 4 7.87
500∶1000 Because of excess moisture, cover bad
100∶70 20∶1000 Because of water deficient, cover bad
50∶1000 0.275 12 82 4 8.75
100∶1000 0.311 7 89 4 9.05
400∶1000 0.283 11 83 4 8.81
500∶1000 Because of excess moisture, cover bad
100∶80 20∶1000 Because of water deficient, cover bad
50∶1000 0.271 12 82 4 8.71
100∶1000 0.324 10 85 4 8.89
400∶1000 0.279 12 82 4 7.38
500∶1000 Because of water deficient, cover bad
100∶90 50∶1000 Can not form mud (expansion)
100∶1000
400∶1000
In the experiment of last table 13-15, used proportion to be 0.135-0.155g/ml, granularity 0.5-3mm, the pearlstone of water-intake rate (moisture content in the long power of the moisture of pf0) 60-70%.This is for no other reason than that the big pearlstone fraction of coverage of granularity, and the color ratio is easier to, and does not mean that the kind of pearlstone only is defined in this.
Granule strength is measured with compression resistivity (the compression resistivity is according to the laboratory method of abundant Li Te institute), and the experiment utensil is by compression strength tester, trial jar, fringing ring flange, formations such as test portion compressor.Half test portion of having prepared of dress after the test portion compressor is installed trial jar, strikes about 25 times in trial jar.Aim at the fringing ring flange above the trial jar, add test portion, make it highly reach 1/2 of fringing ring flange and strike again about 25 times afterwards.Remove the fringing ring flange, utilize ruler to remove covering perlite above the trial jar height again.The trial jar of dress test portion is that unit claims with the gram, and this weight can be used at bulk density (bulk density, g/cm 3=test portion weight, g/ trial jar volume, cm 3) mensuration.Trial jar is placed on the compressive strength test apparatus, puts compressed rod above the test portion, no longer falls down as compressed rod, locks auxiliary valve behind the door, compresses test portion (1 time/4-5 second) at leisure, when piston is represented 1 cun (2.54cm), reads instantaneous pressure (kg) by forcer.Thereby produce the compression resistivity.
Compression resistivity (kg/cm 2)=(1 cun compression pressure, kg+ compressed rod weight, kg)/and trial jar area (45.8), cm 2
Measured the characteristic that covers perlite and pearlstone in order to last method.As table 16
[table 16]
Take this as the standard and drawn dry back proportion more than 0.25, water-intake rate is below 20%, the proportioning of fraction of coverage more than 70%, its result is for after mixing the EVA aqueous solution of 10-30% in the mud that adds loess 40-80g, is that the amount covering of 5-40ml is the most suitable with the content of the EVA aqueous solution in the 100ml pearlstone.
Experimental result when above result just is suitable for making fraction of coverage and being 70% above goods with the continous way mode of production, during in conjunction with actual production, because need the adjusting fraction of coverage, so mud viscosity, EVA concentration etc. is not limited to this.
On the other hand, for CEC, pearlstone covers has different positively charged ions with clay mineral, when mixing use as suitably cooperating, can obtain the color that is consistent with CEC that needs.
The CEC mean value of various clay minerals is: loess 10 ± 2cmol/kg, and zeolite 100 ± 10cmol/kg, wilkinite 50 ± 5cmol/kg, about snake aragonite 30 ± 5cmol/kg, but according to the place of production of mineral, mining period, their value has difference.
CEC is: loess covers perlite 10cmol/kg, about by volume 3cmol/l; Zeolite covers perlite 100cmol/kg, about by volume 30cmol/l; Wilkinite covers perlite 50cmol/kg, about by volume 15Cmol/l, and the snake aragonite covers perlite 30cmol/kg, the about 9cmol/l of volume ratio.And clay mineral covers the multiple CEC that perlite can have 10-100cmol/kg, also can regulate CBC according to proportioning, and the scope of volume ratio is 3-30cmol/l.
(annotate: 10cmol/kg* bulk density (0.3kg/l) is that the 3cmol/l back is also like this)
(3) interpolation of fertilizer
As above, can cover the clay mineral that adds adhesive solution in the pearlstone, the perlite that does not from then on keep the nutrient ability has also had reservation nutrient ability one CEC capacity, is suitable for cultivated plant.
But the required amount that needs nutrient of each plant is different.Therefore, optionally add necessary fertilizer inside the adhesive solution of the present invention.
The amount of fertilizer can arbitrarily be adjusted according to the content of the specific nutrient of each plant needs, and its example such as table 17. but this just illustrate, and the formation of adding fertilizer is not limited to this.
[table 17]
Fertilizer amount (g/m 3): to the weight of pearlstone volume
Multiple amount element
The kind of aa Fertilizer design 1 Fertilizer design 2 Fertilizer design 3 Fertilizer design 4 Fertilizer design 5
KNO 3 242.6 950 506 607 809
Ca(NO 3) 2·4H 2O 566.9 810 1181 944 709
NH 4H 2PO 4 92.0 500 136 272 409
MgSO 4·7H 2O 197.2 155 493 246 493
Trace element
Fe-EDTA 15`25 15`25 15`25 15`25 15`25
H 3BO 3 3 3 3 3 3
MnSO 4·4H 2O 2 2 2 2 2
CuSO 4·5H 2O 0.05 0.22 0.08 0.22 0.22
ZnSO 4·7H 2O 0.22 0.05 0.22 0.05 0.05
Na 2MoO 4·2H 2O 0.22 0.02 0.02 0.02 0.02
After the fertilizer that has designed is added on adhesive solution or is blended in clay mineral, spray and cover on the pearlstone, just can produce pearlite of the present invention.
The scope of the proper content of the perlitic main nutrient of covering that so draws is when being benchmark to cover perlite lL, as table 18
Nutrient The other proper content of the form of nutrient
Nitrogen NO 3-N 30~800mg
NO 4-N 50~150mg
P2O5 Available state 300 ~ 100mg
K 2O Tradable 150 ~ 200mg
CaO Tradable 200 ~ 400mg
MgO Tradable 25 ~ 50mg
SiO 2 More than the available state 15mg
B Available state 8 ~ 20ppm
Mn Tradable 40 ~ 80ppm
Fe Tradable 80 ~ 100ppm
Zn Solubility 80 ~ 400ppm
Cu Solubility 8 ~ 15ppm
Mo Available state 0.5 ~ 4ppm
Different types of farm crop, the useful properties of fertilizer is shown in table 19.This table is only for reference.
Table 19
Nutrient (me/l) EC(dSm -1)
NO 3-N P K Ca Mg
Cucumber 13 3 6 7 4 2.0
Muskmelon 13 4 6 7 3 2.0
Watermelon 13 1.5 6 7 1.5 1.6
Tomato 7 2 4 3 2 1.1
Capsicum 9 2.5 6 3 2 1.3
Eggplant 10 3 7 3 2 1.5
The grass enzyme 5 1.5 3 2 1 0.7
Romaine lettuce 6 1.5 4 2 1 0.8
aaa 7 2 3 4 2 1.1
From above situation as can be known, the nutrient characteristic difference that different crops was suitable for, after regulating the kind and content of its fertilizer, add adhesive solution or clay mineral, cover pearlstone, so, there is not the interpolation of other liquid fertilizer, also can be used for tree, the lawn, showy flowers of herbaceous plants classes etc. are only with a kind of plant that is difficult to as artificial soil of pearlstone.
(4) cultivate experiment
Cover perlitic trees fertility test in order to finish, as the roof of Fig. 2 at concrete structure, with the four directions is the polypropylene-base draining porous disc 12 (300*300*25mm) of open configuration, with 1m is to have connected the cubic water port place that is arranged on the roof afterwards at interval, cover with synthon sheet 13 above, spread draining pearlstone light weight soil 14 with the thickness of 100m.After all preparation works were ready, blended covered perlite and grows seedlings with pearlstone 15.Spread with 400mm thickness, suitably plant pine tree, the mountain is red etc. forever, observes the state after 1 year.In order to observe fertility status, utilize trees vigor degree determinator to measure the vigor degree of trees, be benchmark with the pine tree that is planted in pearlstone routine tests district again, contrast.Spring and autumn are applied fertilizer each in once by pearlstone routine tests district, and its rate of fertilizer application is consistent with the amount that is included in the fertilizer that covers perlite bulk testing district, does not pour water, and has only utilized natural precipitation.[table 20]
Distinguish Cover perlite bulk testing district
1 2 3 4 5 6 7
Fertility status Trees vigor degree (k Ω) 9 8.5 9.2 10.1 11.2 9.7 8.2
Distinguish Pearlstone routine tests district
1 2 3 4 5 6 7
Fertility status Trees vigor degree (k Ω) 17.5 19.2 16.7 18.5 20.3 19.8 18.9
(notes)
Record to above table 20:
Bulk testing district 1: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 18: 18: 18 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 1: 9 mixed.
Bulk testing district 2: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 20: 9: 20 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 1.5: 8.5 mixed.
Bulk testing district 3: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 17: 10: 27 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 2: 8 mixed.
Bulk testing district 4: loess 60g and 20%EVA Lip river liquid 100ml, after N-P-K regulates by 16: 8: 32 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 2.5: 7.5 mixed.
Bulk testing district 5: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 14: 10: 34 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 3: 7 mixed.
Bulk testing district 6: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 11: 12: 33 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 3.5: 6.5 mixed.
Bulk testing district 7: loess 60g and 20%EVA solution 100ml, after N-P-K regulates by 11: 8: 34 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 4: 6 mixed.
Pearlstone routine tests district 1: use the pearlstone test site growing seedlings, the soil that the content of N-P-K is regulated with 18: 18: 18 ratio in the fertilizer.
Pearlstone routine tests district 2: the soil that the content of N-P-K is regulated with 20: 9: 20 ratio in growing seedlings with pearlstone test site, fertilizer.
Pearlstone routine tests district 3: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 17: 10: 27 ratio.
Pearlstone routine tests district 4: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 16: 8: 32 ratio.
Pearlstone routine tests district 5: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 14: 10: 34 ratio.
Pearlstone routine tests district 6: the soil of regulating with 11: 12: 33 ratio at the content of using pearlstone test site, fertilizer to tremble N-P-K of growing seedlings.
Pearlstone routine tests district 7: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 11: 8: 34 ratio.
The arboreal growth result, the surviving rate that covers perlite bulk testing district is 8.2-11.2, well-grown; The value in pearlstone routine tests district is 16.7-20.3, reduces than covering perlite mixing zone trees surviving rate.
And covering perlitic lawn growth test in order to finish, as the roof of Fig. 3 at concrete structure, is the polypropylene-based draining porous disc (300*300*25mm, 12) of open configuration with the four directions, is to have connected the four directions at interval with 1m.The water port on roof is set afterwards, covers with synthon 113 above, will and grow seedlings by the covering perlite of 4: 6 mixed again, spread, plant closely knit lawn, observed the state after 1 year with 150mm thickness with pearlstone 115.At this moment do not carry out any pouring water, only utilized natural precipitation, and behind the condition bedding pearlstone light weight soil with same state, remove lawn seed, observe the germination situation.Pearlstone routine tests district is at the blue sky, and autumn, each applied fertilizer once, and its amount is the same with amount of the fertilizer that covering perlite bulk testing district comprises.
Its result such as table 21.
[table 21]
Distinguish Cover perlite bulk testing district
1 2 3 4 5 6 7
Percentage of germination (%) The lawn 72 80 83 84 71 76 79
Fertility status Leaf length (cm) 7.8 7.5 8.5 8.3 8.8 9.1 9.2
The weight of lawn root (g) 148 163 167 167 144 157 161
Distinguish Pearlstone routine tests district
1 2 3 4 5 6 7
Percentage of germination (%) The lawn 71 73 74 53 66 69 71
Fertility status Leaf length (cm) 4.2 3.7 4.9 4.8 4.5 5.3 4
The weight of lawn root (g) 117 121 124 91 100 102 102
Record to last table 21:
Bulk testing district 1: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 18: 18: 18 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 1: 9 mixed.
Bulk testing district 2: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 20: 9: 20 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 1.5: 8.5 mixed.
Bulk testing district 3: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 17: 130: 27 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 2: 8 mixed.
Bulk testing district 4: loess 70g and 30%EVA Lip river liquid 100ml, after N-P-K regulates by 16: 8: 32 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 2.5: 7.5 mixed.
Bulk testing district 5: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 14: 10: 34 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 3: 7 mixed.
Bulk testing district 6: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 11: 12: 33 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 3.5: 6.5 mixed.
Bulk testing district 7: loess 70g and 30%EVA solution 100ml, after N-P-K regulates by 11: 8: 34 content ratio in the fertilizer, cover on the pearlstone of 1000ml, then the goods after covering and the soil of usefulness pearlstone of growing seedlings with 4: 6 mixed.
Pearlstone routine tests district 1: use the pearlstone test site growing seedlings, the soil that the content of N-P-K is regulated with 18: 18: 18 ratio in the fertilizer.
Pearlstone routine tests district 2: the soil that the content of N-P-K is regulated with 20: 9: 20 ratio in growing seedlings with pearlstone test site, fertilizer.
Pearlstone routine tests district 3: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 17: 10: 27 ratio.
Pearlstone routine tests district 4: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 16: 8: 32 ratio.
Pearlstone routine tests district 5: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 14: 10: 34 ratio.
Pearlstone routine tests district 6: the soil of regulating with 11: 12: 33 ratio at the content of using pearlstone test site, fertilizer to tremble N-P-K of growing seedlings.
Pearlstone routine tests district 7: use the pearlstone test site growing seedlings, the soil that the content of fertilizer N-P-K is regulated with 11: 8: 34 ratio.
Plant the result of lawn seed investigation germination, percentage of germination average out to 78% of the present invention, the percentage of germination on average about 67% in pearlstone routine tests district.Observe the result of developmental process thereafter, the present invention is after 30 days, and the leaf mean length is about 8cm, than pearlstone routine tests head of district 3cm, has shown good fertility condition.
1 year result with " Invest, Then Investigate " lawn root is the most vigorous in the root prosperity on the lawn of test site of the present invention.The lawn root in pearlstone routine tests district is flourishing in covering perlite bulk testing of the present invention district.
Can see that in fertility test effect covering perlitic test site by the mixing of above invention manufacturing has better growth result than pearlstone test site to trees and lawn.Pearlite of the present invention in other words goes for insulating covering agent and various roof, balcony, following water is to the artificial domain light weight soil of treatment plant etc., and trees are used oxygen hose, grow seedlings with bed soil, flowerpot with the various plant growings of soil etc. with soil and soil improvement agent.
Can draw from above detailed description, the present invention selects the caking agent harmless to plant for use, after the clay mineral that comprises loess mixes, covers on the pearlstone and the pearlite of making.Both had perlitic advantage, and increased the advantage of reservation nutrient again, thereby can use with artificial mixing with soil separately or with various plant growings.Outside, organic and inorganic fertilizer that does not add other when covering together with fertilizer etc. also can be according to the plant needs, regulate and be used in insulating covering agent and roof after fertilizer constitutes, balcony, the greening light weight soil on artificial structure tops such as water drain treatment plant, trees are used oxygen hose, grow seedlings with bed soil, and potted flower is used various plant growings artificial soil and soil improvement agents such as soil.
This pearlite for culturing plant is of many uses, can be used as insulating covering agent and various roof, balcony, following water is to the artificial domain light weight soil of treatment plant etc., trees are used oxygen hose, grow seedlings with bed soil, flowerpot with the various plant growings of soil etc. with soil and soil improvement agent.

Claims (8)

1, a kind of plant growing perlite is characterized in that: it is to cover clay mineral and adhesive solution on pearlstone.
2, plant growing perlite according to claim 1 is characterized in that: described pearlstone is meant that pitchstone, black credit rock, perlite are heated to the material that draws after 1000 degree expand; Or silicate, glass are heated to the material that draws after 1000 degree expand; The material that draws after the described expansion is the mesopore spheroid that comprises bubble.
3, plant growing perlite according to claim 1 is characterized in that: described 1000ml pearlstone is coated with clay mineral 15-400g, the adhesive solution 50-400ml of 5-50%.
4, plant growing perlite according to claim 1, it is characterized in that: described caking agent is the organic or inorganic caking agent, and described organic adhesive is more than one organic adhesives of selecting in vinylacetate system, aqueous acrylic acid series, three polymeric amide system, aqueous vinyl Mono Chloro Acetic Acid system, water-based ammonia ester system, polyethenol series, epoxy resin and synthetic rubber, the natural rubber class; Inorganic adhesive refers to water glass or polyphosphoric acid aluminum dihydrogen, phosphoric acid hydrogen two aluminium, aluminum phosphate, aluminum pyrophosphate, aluminium metaphosphate, aluminium dihydrogen phosphate, aluminium triphosphate.
5, plant growing perlite according to claim 1 is characterized in that: described clay mineral is meant the material of selecting more than one loess, zeolite, wilkinite and snake aragonite more than 10cmolc/kg, peridotites, the pyroxene mineral.
6, plant growing perlite according to claim 1 is characterized in that: add fertilizer in described adhesive solution or the clay mineral.
7, plant growing perlite according to claim 6 is characterized in that: described fertilizer is inorganic or organic fertilizer or various plant growth regulating substance; Described mineral manure is that saltpetre, nitrocalcite, ammonium nitrate, sal epsom, ethylenediamine tetraacetic acid (EDTA) are ferrous, manganous sulfate, copper sulfate, zinc sulfate chemical substance and with this blended compound manure; Described organic fertilizer is that amino acid, wood vinegar, plant extractum are basic fertilizer.
8, the perlitic purposes of the described plant growing of claim 1 is characterized in that: utilize the described plant growing of claim 1 with perlite make trees, lawn, flowers and plants class with the greening on artificial structure top with light weight soil, trees with oxygen hose, grow seedlings with bed soil, potted flower with soil and soil improvement agent.
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