CN117297988A - Amino acid facial cleanser and preparation method thereof - Google Patents
Amino acid facial cleanser and preparation method thereof Download PDFInfo
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- CN117297988A CN117297988A CN202311604833.4A CN202311604833A CN117297988A CN 117297988 A CN117297988 A CN 117297988A CN 202311604833 A CN202311604833 A CN 202311604833A CN 117297988 A CN117297988 A CN 117297988A
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- 230000001815 facial effect Effects 0.000 title claims abstract description 56
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 111
- 238000002156 mixing Methods 0.000 claims abstract description 96
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000000284 extract Substances 0.000 claims abstract description 62
- 238000010438 heat treatment Methods 0.000 claims abstract description 53
- 238000000498 ball milling Methods 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000003906 humectant Substances 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 229920002385 Sodium hyaluronate Polymers 0.000 claims abstract description 13
- 238000000605 extraction Methods 0.000 claims abstract description 13
- 229940065859 sodium cocoyl glycinate Drugs 0.000 claims abstract description 13
- 229940010747 sodium hyaluronate Drugs 0.000 claims abstract description 13
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims abstract description 13
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 claims abstract description 13
- 241000196324 Embryophyta Species 0.000 claims abstract description 9
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229940070765 laurate Drugs 0.000 claims abstract description 9
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims abstract description 9
- 229940079988 potassium cocoyl glycinate Drugs 0.000 claims abstract description 9
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims abstract description 9
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims abstract description 9
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims abstract description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 65
- 241000157835 Gardenia Species 0.000 claims description 56
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 238000004140 cleaning Methods 0.000 claims description 24
- 235000011187 glycerol Nutrition 0.000 claims description 23
- 230000005484 gravity Effects 0.000 claims description 20
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 12
- 241001673954 Magnolia sieboldii Species 0.000 claims description 11
- 241000221095 Simmondsia Species 0.000 claims description 11
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 11
- 229940072117 fennel extract Drugs 0.000 claims description 11
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 11
- 239000004386 Erythritol Substances 0.000 claims description 10
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 230000001276 controlling effect Effects 0.000 claims description 10
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 10
- 229940009714 erythritol Drugs 0.000 claims description 10
- 235000019414 erythritol Nutrition 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 claims description 9
- 239000004475 Arginine Substances 0.000 claims description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 9
- 229920002261 Corn starch Polymers 0.000 claims description 9
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims description 9
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 9
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 9
- 229960003237 betaine Drugs 0.000 claims description 9
- 229940071160 cocoate Drugs 0.000 claims description 9
- 239000008120 corn starch Substances 0.000 claims description 9
- 229940073499 decyl glucoside Drugs 0.000 claims description 9
- -1 dimethyl taurate Chemical compound 0.000 claims description 9
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 claims description 9
- 229940101267 panthenol Drugs 0.000 claims description 9
- 235000020957 pantothenol Nutrition 0.000 claims description 9
- 239000011619 pantothenol Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 239000011780 sodium chloride Substances 0.000 claims description 9
- 229940104261 taurate Drugs 0.000 claims description 9
- 230000006837 decompression Effects 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000013329 compounding Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 241000125183 Crithmum maritimum Species 0.000 claims description 4
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229940044591 methyl glucose dioleate Drugs 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- 238000010025 steaming Methods 0.000 claims description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 2
- 238000002137 ultrasound extraction Methods 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 13
- 230000003020 moisturizing effect Effects 0.000 abstract description 11
- 239000004480 active ingredient Substances 0.000 abstract description 4
- 239000008233 hard water Substances 0.000 abstract description 4
- 239000002537 cosmetic Substances 0.000 abstract description 3
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 240000001972 Gardenia jasminoides Species 0.000 abstract 2
- 238000012360 testing method Methods 0.000 description 43
- 230000000694 effects Effects 0.000 description 28
- 239000004519 grease Substances 0.000 description 17
- 238000005406 washing Methods 0.000 description 14
- 230000036564 melanin content Effects 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 239000003344 environmental pollutant Substances 0.000 description 8
- 231100000719 pollutant Toxicity 0.000 description 8
- 235000013336 milk Nutrition 0.000 description 7
- 239000008267 milk Substances 0.000 description 7
- 210000004080 milk Anatomy 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 239000000779 smoke Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 210000001061 forehead Anatomy 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 230000000622 irritating effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 230000005808 skin problem Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/82—Preparation or application process involves sonication or ultrasonication
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides an amino acid facial cleanser and a preparation method thereof, belonging to the technical field of cosmetics; the preparation process comprises the following steps: stirring and dispersing with water; adding a surfactant and a humectant to prepare a component A; heating in water bath to mix and prepare a component B; mixing with sodium hyaluronate to prepare component C; extracting gardenia for two times to prepare a gardenia composite extract; adding other plant extraction components, ball-milling and mixing to prepare a component D; the components were mixed and filled. The invention uses sodium cocoyl glycinate as main active ingredient, and after being compounded with surfactants of potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate, the hard water resistance of the prepared facial cleanser can be improved, a large amount of stable and fine foam can be produced, and the facial cleanser has excellent moisturizing and decontamination capacities.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to amino acid facial cleanser and a preparation method thereof.
Background
The face cleaning emulsion is a skin cleaning cosmetic, and is mainly used for cleaning face, removing dirt on skin, restoring skin activity, and keeping normal physiological state, so as to avoid some skin problems.
At present, the cleansing cream on the market can be divided into a soap base system, an amino acid system and the like, wherein the soap base system has excellent cleaning power, but has strong degreasing power, skin is dry and tight after cleaning, the skin is more irritative after long-term use, the amino acid system is mild and not irritative, and has good affinity with the skin, but has poor foamability and poor stability due to difficult thickening, and in addition, the cleaning power to the skin is limited, so that the better oil control effect cannot be achieved.
Therefore, the amino acid facial cleanser with rich and stable foam and good oil control effect and the preparation method thereof are provided.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide an amino acid facial cleanser and a preparation method thereof.
An amino acid facial cleanser comprises the following components:
23-25% of a first disperse phase, 0.4-0.6% of a second disperse phase, 5-7% of a third disperse phase, 2-4% of a fourth disperse phase, 0.2-0.4% of a fifth disperse phase, 14-16% of glycerin, 7.4-12.4% of a surfactant, 1.4-1.8% of a humectant, 0.4-0.6% of a thickener, 0.05-0.15% of arginine, 0.002-0.004% of sodium chloride, 0.01-0.03% of acetylated sodium hyaluronate, 0.008-0.01% of jojoba seed oil, 0.004-0.006% of gardenia complex extract, 0.002-0.004% of a fennel extract, 0.002-0.004% of magnolia sieboldii extract, and the balance of water;
wherein the first dispersed phase comprises sodium cocoyl glycinate and water;
the second disperse phase comprises sodium polyacryl dimethyl taurate, water, isohexadecane and PEG-7 glycerol cocoate;
the third dispersed phase comprises decyl glucoside and water;
the fourth dispersed phase comprises hydrolyzed corn starch and water;
the fifth disperse phase comprises polyquaternium-6 and water.
A preparation method of amino acid facial cleanser comprises the following steps:
s1: stirring and dispersing the mixture by using water,
stirring and dispersing sodium cocoyl glycinate, sodium polyacryl dimethyl taurate, isohexadecane, PEG-7 glycerol cocoate, decyl glucoside, hydrolyzed corn starch and polyquaternium-6 with water to obtain a first dispersed phase, a second dispersed phase, a third dispersed phase, a fourth dispersed phase and a fifth dispersed phase;
s2: adding a surfactant and a humectant to prepare a component A,
mixing the first disperse phase and the second disperse phase, mixing with 60% of glycerin by volume, adding surfactant and humectant, mixing, adding thickener, arginine and sodium chloride, adding water, and mixing uniformly to obtain component A;
s3: heating in water bath to mix and prepare the component B,
adding the third disperse phase, the fourth disperse phase and the fifth disperse phase into a first mixing tank, putting the first mixing tank into a water bath at 50-60 ℃ for water bath heating, stirring for 30-40min at the speed of 300-400r/min by a first stirrer, and uniformly mixing to obtain a component B;
s4: mixing with sodium hyaluronate to prepare component C,
adding the rest glycerol and the sodium hyaluronate into a second mixing tank together, and stirring at a speed of 150-250r/min for 20-30min by using a second stirrer to obtain a component C;
s5: extracting gardenia twice to prepare gardenia composite extract,
adding water into petals of gardenia, distilling under reduced pressure, collecting condensate, grinding residues of the petals after distillation, adding ethanol, performing ultrasonic extraction to prepare an extracting solution, mixing the condensate with the extracting solution, and concentrating to obtain a gardenia compound extract;
s6: adding other plant extraction components, ball milling and mixing to prepare a component D,
ball-milling and mixing the sea fennel extract, the magnolia sieboldii extract and the gardenia compound extract, adding jojoba seed oil, and continuing ball-milling and mixing to obtain a component D;
s7: the components are mixed and filled,
and adding the component B into the component A, heating, stirring and mixing, adding the component D, stopping heating, adding the component C, stirring and mixing, and then carrying out homogenizing mixing and filling to obtain the finished product of the facial cleanser.
Further, the stirring and dispersing with water in the step S1 specifically comprises the following steps:
s1.1: stirring and mixing sodium cocoyl glycinate and water according to a mass ratio (23-25) of 1, and uniformly dispersing to obtain a first dispersed phase;
s1.2: mixing and stirring poly (sodium acryl dimethyl taurate), water, isohexadecane and PEG-7 glycerol cocoate (46-48), (30-32), (15-17) and (5-7) according to the mass ratio, and uniformly dispersing to obtain a second dispersed phase;
s1.3: stirring and mixing decyl glucoside and water according to the mass ratio of (10-12) (8-9), and uniformly dispersing to obtain a third dispersed phase;
s1.4: mixing and stirring the hydrolyzed corn starch and water according to the mass ratio of (2-4) 1, and uniformly dispersing to obtain a fourth dispersed phase;
s1.5: and stirring and mixing the polyquaternium-6 and water according to the mass ratio of (1.4-1.6) to 1, and uniformly dispersing to obtain a fifth dispersed phase.
Further, the step S2 of adding the surfactant and the humectant to prepare the component A comprises the following steps:
s2.1: adding the first disperse phase prepared in the step S1.1 and the second disperse phase prepared in the step S1.2 into a stirrer together until a gravity sensor in the stirrer detects that the gravity in the stirrer is not increased any more, and sending a signal to a controller by the gravity sensor;
s2.2: after the controller receives the signal sent by the gravity sensor, controlling the hydraulic pump to pump 60% of the volume of the glycerol into the stirrer, and simultaneously controlling the stirrer to stir at a speed of 700-800r/min for 40-50min;
s2.3: adding the surfactant and the humectant into a stirrer together, regulating the stirring speed of the stirrer to 500-600r/min, and continuously stirring for 1-2h;
s2.4: adding thickener, arginine and sodium chloride into a stirrer, keeping stirring speed unchanged, stirring for 20-30min, and turning on a heater in the stirrer to heat at 70-80deg.C;
s2.5: pumping water into a stirrer at a constant speed through a water pump, adjusting the stirring speed of the stirrer to be 200-300r/min, heating and stirring for 1-2h, and uniformly mixing to obtain the component A.
Further, the preparation of the gardenia compound extract by extracting gardenia twice in the step S5 specifically comprises the following steps:
s5.1: selecting fresh and full gardenia, picking and cleaning petals, putting the petals into a decompression rotary steaming device, and adding water to submerge the petals;
s5.2: setting the heating temperature of a decompression rotary evaporator at 60-80 ℃ and the internal pressure at 0.05-0.07MPa, starting the decompression rotary evaporator, decompressing and distilling for 1-3h, and collecting condensate through a condenser;
s5.3: pouring the petal residues in the decompression rotary steamer into a grinder, and grinding for 30-40min to obtain petal slurry;
s5.4: pouring the petal slurry into an ultrasonic wave extraction instrument, adding ethanol into the ultrasonic wave extraction instrument, ultrasonically extracting for 1-2 hours at the power of 500-600W and the frequency of 30-40kHz, and filtering to obtain gardenia extract;
s5.5: adding the above Gardenia extractive solution and condensate together into a concentrator, heating and concentrating under stirring until the liquid is evaporated to dryness to obtain Gardenia compound extract.
Further, in step S6, other plant extraction components are added and ball-milled and mixed to prepare a component D, which specifically comprises the following steps:
s6.1: adding the gardenia composite extract prepared in the step S5.5 into a ball milling tank, adding the sea fennel extract and the magnolia sieboldii extract into the ball milling tank, and ball milling for 10-20min to obtain mixed extract powder;
s6.2: adding jojoba seed oil into a ball milling tank, continuously ball milling for 1-2h, and fully and uniformly mixing with the mixed extract powder to obtain a component D.
Further, the step S7 of mixing the components and filling specifically includes the following steps:
s7.1: restarting a heater in the stirrer, heating the component A prepared in the step S2.5 at 45-55 ℃, and simultaneously adding the component B prepared in the step S3 into the stirrer, and stirring and mixing at a speed of 400-600 r/min;
s7.2: keeping the heating temperature of the heater unchanged, adjusting the stirring speed of the stirrer to 700-800r/min, adding the component D prepared in the step S6.2 while stirring, and continuing stirring for 40-50r/min after the addition;
s7.3: turning off the heater, stopping heating, regulating the stirring speed of the stirrer to 200-350r/min, adding the component C prepared in the step S4 while stirring until the temperature sensor in the stirrer detects that the temperature in the stirrer is reduced to room temperature, and obtaining a precursor;
s7.4: the precursor is moved into a homogenizer, homogenized for 1 to 2 hours, and fully and uniformly mixed to obtain the facial cleanser;
s7.5: and filling the facial cleanser into a packaging can to obtain the finished facial cleanser.
Further, the surfactant is prepared by compounding potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate according to a mass ratio of 5-7:2-3:1:1.
Further, the humectant is compounded by erythritol, panthenol and betaine according to the mass ratio of (10-12): 1:1.
Further, the thickener is PEG-120 methylglucdioleate.
Compared with the prior art, the invention has at least the following beneficial effects:
1. the invention uses sodium cocoyl glycinate as main active ingredient, and after being compounded with surfactants of potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate, the hard water resistance of the prepared facial cleanser can be improved, a large amount of stable and fine foam can be produced, and the facial cleanser has excellent moisturizing and decontamination capacities.
2. According to the invention, natural plant extraction components such as jojoba seed oil, gardenia composite extract, fennel extract, magnolia sieboldii extract and the like are added, so that the facial cleanser can clean skin and simultaneously has an excellent oil control effect, and meanwhile, the moisturizing effect of the facial cleanser can be further improved.
3. According to the invention, petals of gardenia are firstly added with water for reduced pressure distillation, condensed liquid is collected by condensation, then ethanol is used for extracting petal residues again to prepare an extracting solution, and finally the condensed liquid and the extracting solution are mixed and concentrated to form the gardenia composite extract, so that not only can waste of gardenia resources be reduced, but also a synergistic effect can be generated after the condensed liquid and the extracting solution are compounded, and therefore, the cleaning and moisturizing effects of the facial cleanser are improved.
4. According to the invention, erythritol, panthenol and betaine are added as the humectant, so that the moisturizing effect of the facial cleanser can be further improved, the cleaning and decontamination effects of the surfactant can be further improved by cooperation of the erythritol, panthenol and betaine, and the oil control effect of the facial cleanser can be improved.
Drawings
The accompanying drawings, which are incorporated herein and form a part of the specification, illustrate embodiments of the present disclosure and, together with the description, further serve to explain the principles of the disclosure and to enable a person skilled in the pertinent art to make and use the disclosure.
FIG. 1 is a flow chart of a preparation method of an amino acid facial cleanser used in the embodiment of the invention;
FIG. 2 is a summary table of effect test results for examples 1, 2 and 3 of the present invention;
FIG. 3 is a summary of the results of the effect tests of example 1 and comparative example 1 of the present invention;
FIG. 4 is a summary of the results of the effect tests of example 1 and comparative example 2 of the present invention;
FIG. 5 is a summary of the results of the effect tests of example 1 and comparative example 3 of the present invention;
FIG. 6 is a summary of the results of the effect tests of example 1 and comparative example 4 of the present invention;
FIG. 7 is a summary of the results of the effect tests of example 1 and comparative example 5 of the present invention.
Detailed Description
The amino acid facial cleanser and the preparation method thereof provided by the invention are described in detail below with reference to the accompanying drawings and specific examples. While the invention has been described herein in terms of the preferred and preferred embodiments, the following embodiments are intended to be more illustrative, and may be implemented in many alternative ways as will occur to those of skill in the art; and the accompanying drawings are only for the purpose of describing the embodiments more specifically and are not intended to limit the invention specifically.
Example 1
The preparation method of the amino acid facial cleanser, as shown in fig. 1 and 2, comprises the following steps:
s1: stirring and dispersing the mixture by using water,
stirring and mixing sodium cocoyl glycinate and water according to a mass ratio of 23:1, uniformly dispersing to obtain a first dispersed phase, stirring and mixing sodium polyacryl dimethyl taurate, water, isohexadecane and PEG-7 glycerol cocoate according to a mass ratio of 46:30:15:5, uniformly dispersing to obtain a second dispersed phase, stirring and mixing decyl glucoside and water according to a mass ratio of 10:8, uniformly dispersing to obtain a third dispersed phase, stirring and mixing hydrolyzed corn starch and water according to a mass ratio of 2:1, uniformly dispersing to obtain a fourth dispersed phase, stirring and mixing polyquaternium-6 and water according to a mass ratio of 1.4:1, and uniformly dispersing to obtain a fifth dispersed phase;
s2: adding a surfactant and a humectant to prepare a component A,
adding the 23% first disperse phase and the 0.4% second disperse phase into a stirrer together until a gravity sensor in the stirrer detects that the gravity in the stirrer is not increased any more, sending a signal to a controller by the gravity sensor, after receiving the signal sent by the gravity sensor, controlling a hydraulic pump to pump 8.4% of glycerol into the stirrer, simultaneously controlling the stirrer to stir at a speed of 700r/min for 40min, then adding 7.4% of surfactant compounded by potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate according to a mass ratio of 5:2:1:1 and a humectant of 1.4% compounded by erythritol, panthenol and betaine according to a mass ratio of 10:1:1 into the stirrer together, adjusting the stirring speed of the stirrer to be 500r/min, continuously stirring for 1h, adding 0.4% of PEG-120 methylglucinolate, 0.05% of arginine and 0.002% of sodium chloride into the stirrer, keeping the stirring speed unchanged, opening the stirrer for 20min, heating the stirrer at a temperature of 70 ℃ for 1 min, uniformly heating the stirrer, and uniformly mixing the components in the stirrer to obtain a water after stirring for 200 h, and heating the stirrer;
s3: heating in water bath to mix and prepare the component B,
adding the 5% third disperse phase, the 2% fourth disperse phase and the 0.2% fifth disperse phase into a first mixing tank, putting the first mixing tank into a water bath pool with the temperature of 50 ℃ for water bath heating, stirring for 30min at the speed of 300r/min by a first stirrer, and uniformly mixing to obtain a component B;
s4: mixing with sodium hyaluronate to prepare component C,
adding the rest glycerol and 0.01% sodium hyaluronate together into a second mixing tank, and stirring at 150r/min with a second stirrer for 20min to obtain component C;
s5: extracting gardenia twice to prepare gardenia composite extract,
selecting fresh and full gardenia, picking petals, cleaning, putting the petals into a reduced pressure rotary evaporator, adding water, soaking the petals, setting the heating temperature of the reduced pressure rotary evaporator to 60 ℃ and the internal pressure to 0.05MPa, starting the reduced pressure rotary evaporator, distilling under reduced pressure for 1h, collecting condensate through a condenser, pouring petal residues in the reduced pressure rotary evaporator into a grinder, grinding for 30min to obtain petal slurry, pouring the petal slurry into an ultrasonic wave extractor, adding ethanol into the ultrasonic wave extractor, ultrasonically extracting for 1h at the power of 500W and the frequency of 30kHz, filtering to obtain gardenia extract, finally adding the gardenia extract and the condensate into the concentrator together, stirring, heating and concentrating until the liquid is evaporated to dryness, and obtaining the gardenia compound extract;
s6: adding other plant extraction components, ball milling and mixing to prepare a component D,
adding 0.004% of the gardenia composite extract into a ball milling tank, adding 0.002% of the fennel extract and 0.002% of the magnolia sieboldii extract into the ball milling tank, ball milling for 10min to obtain mixed extract powder, adding 0.008% of jojoba seed oil into the ball milling tank, continuing ball milling for 1h, and fully and uniformly mixing with the mixed extract powder to obtain a component D;
s7: the components are mixed and filled,
and (3) restarting a heater in the stirrer, heating the component A at 45 ℃, adding the component B into the stirrer, stirring and mixing at a speed of 400r/min, keeping the heating temperature of the heater unchanged, adjusting the stirring speed of the stirrer to 700r/min, adding the component D while stirring, continuing stirring for 40r/min after the addition, turning off the heater, stopping heating, adjusting the stirring speed of the stirrer to 200r/min, adding the component C while stirring until a temperature sensor in the stirrer detects that the temperature in the stirrer is reduced to room temperature, obtaining a precursor, then moving the precursor into a homogenizer, homogenizing for 1h, fully and uniformly mixing to obtain the facial cleanser, and finally filling the facial cleanser into a packaging can to obtain the finished facial cleanser.
And (3) effect test:
firstly, taking a square tested skin with a side length of 10cm, cleaning the surface of the square tested skin, placing the tested skin in a colored smoke environment with PM2.5 for 10min, taking out the square tested skin, testing the melanin content of the tested skin by a skin tester, marking the melanin content as A1, cleaning the tested skin subjected to smoke treatment by the prepared facial cleanser, naturally airing the tested skin, testing the melanin content of the tested skin again, marking the melanin content as A2, and calculating the pollutant clearance rate of the facial cleanser to be about 92.23 percent according to a formula of (1-A2/A1) multiplied by 100 percent;
then, selecting 5 healthy volunteers with the age of 20-45 years old as trial objects, selecting a region with the length of 2cm multiplied by 2cm at the same position of the forehead of the volunteer as a test region, firstly washing the face by using clear water, testing the skin moisture content before use by using a skin moisture tester after 0.5h, marking as B1, detecting the skin moisture content before use by using a skin grease test probe, marking as C1, then washing the face by using the prepared facial cleanser by using the volunteer, detecting the skin grease content after use again by using the skin grease test probe after 8h, marking as C2, testing the skin moisture content after use by using a skin moisture tester again after 24h, marking as B2, and calculating that the skin moisture content change is about +2.1% and the skin grease content change is about-31.4 according to test results;
finally, statistics of satisfaction scoring results of volunteers after trial, wherein the highest score is 10 and the lowest score is 0, and the results show that: the foam richness is 9.3 minutes, and the comfort level after washing is 9.4 minutes.
Example 2
The preparation method of the amino acid facial cleanser, as shown in fig. 1 and 2, comprises the following steps:
s1: stirring and dispersing the mixture by using water,
stirring and mixing sodium cocoyl glycinate and water according to a mass ratio of 24:1, uniformly dispersing to obtain a first dispersed phase, stirring and mixing sodium polyacryl dimethyl taurate, water, isohexadecane and PEG-7 glycerol cocoate according to a mass ratio of 47:31:16:6, uniformly dispersing to obtain a second dispersed phase, stirring and mixing decyl glucoside and water according to a mass ratio of 11:8.5, uniformly dispersing to obtain a third dispersed phase, stirring and mixing hydrolyzed corn starch and water according to a mass ratio of 3:1, uniformly dispersing to obtain a fourth dispersed phase, stirring and mixing polyquaternium-6 and water according to a mass ratio of 1.5:1, and uniformly dispersing to obtain a fifth dispersed phase;
s2: adding a surfactant and a humectant to prepare a component A,
adding the 24% first disperse phase and the 0.5% second disperse phase into a stirrer together until a gravity sensor in the stirrer detects that the gravity in the stirrer is not increased any more, sending a signal to a controller by the gravity sensor, controlling a hydraulic pump to pump 9.1% of glycerol into the stirrer after receiving the signal sent by the gravity sensor, simultaneously controlling the stirrer to stir at a speed of 750r/min for 45min, adding 9.9% of surfactant compounded by potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate according to a mass ratio of 6:2.5:1:1 and humectant compounded by erythritol, panthenol and betaine according to a mass ratio of 11:1:1 into the stirrer together, continuously stirring for 1.5h, adding 0.5% of PEG-120 methyl glucose dioleate, 0.1% of arginine and 0.003% of sodium chloride into the stirrer, keeping stirring for no longer, heating at a temperature of 75 ℃ in the stirrer for 75 h, uniformly heating the stirrer, and then heating the stirrer to obtain a uniform mixture, and heating the water in the stirrer for 250 h by the stirrer;
s3: heating in water bath to mix and prepare the component B,
adding the 6% of the third disperse phase, the 3% of the fourth disperse phase and the 0.3% of the fifth disperse phase into a first mixing tank, putting the first mixing tank into a water bath pool with the temperature of 55 ℃ for heating in a water bath, stirring for 35min at the speed of 350r/min by a first stirrer, and uniformly mixing to obtain a component B;
s4: mixing with sodium hyaluronate to prepare component C,
adding the rest glycerol and 0.02% of acetylated sodium hyaluronate into a second mixing tank, and stirring at 200r/min for 25min with a second stirrer to obtain component C;
s5: extracting gardenia twice to prepare gardenia composite extract,
selecting fresh and full gardenia, picking petals, cleaning, putting the petals into a reduced pressure rotary evaporator, adding water, soaking the petals, setting the heating temperature of the reduced pressure rotary evaporator to 70 ℃ and the internal pressure to 0.06MPa, starting the reduced pressure rotary evaporator, distilling under reduced pressure for 2 hours, collecting condensate through a condenser, pouring petal residues in the reduced pressure rotary evaporator into a grinder, grinding for 35 minutes to obtain petal slurry, pouring the petal slurry into an ultrasonic wave extractor, adding ethanol into the ultrasonic wave extractor, ultrasonically extracting for 1.5 hours at the power of 550W and the frequency of 35kHz, filtering to obtain gardenia extract, finally adding the gardenia extract and the condensate into the concentrator together, stirring, heating and concentrating until the liquid is evaporated to dryness, and obtaining the gardenia compound extract;
s6: adding other plant extraction components, ball milling and mixing to prepare a component D,
adding 0.005% of the gardenia composite extract into a ball milling tank, adding 0.003% of the fennel extract and 0.003% of the magnolia sieboldii extract into the ball milling tank, ball milling for 15min to obtain mixed extract powder, adding 0.009% of jojoba seed oil into the ball milling tank, continuing ball milling for 1.5h, and fully and uniformly mixing with the mixed extract powder to obtain a component D;
s7: the components are mixed and filled,
and (3) restarting a heater in the stirrer, heating the component A at 50 ℃, adding the component B into the stirrer, stirring and mixing at a speed of 500r/min, keeping the heating temperature of the heater unchanged, adjusting the stirring speed of the stirrer to 750r/min, adding the component D while stirring, continuing stirring for 45r/min after the addition, turning off the heater, stopping heating, adjusting the stirring speed of the stirrer to 275r/min, adding the component C while stirring until a temperature sensor in the stirrer detects that the temperature in the stirrer is reduced to room temperature to obtain a precursor, then moving the precursor into a homogenizer, homogenizing for 1.5h, fully and uniformly mixing to obtain the face cleaning milk, and finally filling the face cleaning milk into a packaging can to obtain the finished face cleaning milk.
And (3) effect test:
firstly, taking a square tested skin with a side length of 10cm, cleaning the surface of the square tested skin, placing the tested skin in a colored smoke environment with PM2.5 for 10min, taking out the square tested skin, testing the melanin content of the tested skin by a skin tester, marking the melanin content as A1, cleaning the tested skin subjected to smoke treatment by the prepared facial cleanser, naturally airing the tested skin, testing the melanin content of the tested skin again, marking the melanin content as A2, and calculating the pollutant clearance rate of the facial cleanser to be about 93.45 percent according to a formula of (1-A2/A1) multiplied by 100 percent;
then, selecting 5 healthy volunteers with the age of 20-45 years old as trial objects, selecting a region with the length of 2cm multiplied by 2cm at the same position of the forehead of the volunteer as a test region, firstly washing the face by using clear water, testing the skin moisture content before use by using a skin moisture tester after 0.5h, marking as B1, detecting the skin moisture content before use by using a skin grease test probe, marking as C1, then washing the face by using the prepared facial cleanser by using the volunteer, detecting the skin grease content after use again by using the skin grease test probe after 8h, marking as C2, testing the skin moisture content after use by using a skin moisture tester again after 24h, marking as B2, and calculating that the skin moisture content change is about +2.3% and the skin grease content change is about-30.6 according to test results;
finally, statistics of satisfaction scoring results of volunteers after trial, wherein the highest score is 10 and the lowest score is 0, and the results show that: the foam richness is 9.2 minutes, and the comfort level after washing is 9.5 minutes.
Example 3
The preparation method of the amino acid facial cleanser, as shown in fig. 1 and 2, comprises the following steps:
s1: stirring and dispersing the mixture by using water,
stirring and mixing sodium cocoyl glycinate and water according to a mass ratio of 25:1, uniformly dispersing to obtain a first dispersed phase, stirring and mixing sodium polyacryl dimethyl taurate, water, isohexadecane and PEG-7 glycerol cocoate according to a mass ratio of 48:32:17:7, uniformly dispersing to obtain a second dispersed phase, stirring and mixing decyl glucoside and water according to a mass ratio of 12:9, uniformly dispersing to obtain a third dispersed phase, stirring and mixing hydrolyzed corn starch and water according to a mass ratio of 4:1, uniformly dispersing to obtain a fourth dispersed phase, stirring and mixing polyquaternium-6 and water according to a mass ratio of 1.6:1, and uniformly dispersing to obtain a fifth dispersed phase;
s2: adding a surfactant and a humectant to prepare a component A,
adding the 25% first disperse phase and the 0.6% second disperse phase into a stirrer together until a gravity sensor in the stirrer detects that the gravity in the stirrer is not increased any more, sending a signal to a controller by the gravity sensor, controlling a hydraulic pump to pump 9.6% of glycerol into the stirrer after receiving the signal sent by the gravity sensor by the controller, simultaneously controlling the stirrer to stir at a speed of 800r/min for 50min, adding 12.4% of surfactant compounded by potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate according to a mass ratio of 7:3:1:1 and 1.8% of humectant compounded by erythritol, panthenol and betaine according to a mass ratio of 12:1:1 into the stirrer together, continuously stirring for 2h at a stirring speed of 600r/min, adding 0.6% of PEG-120 methylglucinolate, 0.15% of arginine and 0.004% of sodium chloride into the stirrer, keeping the stirring speed unchanged, opening the stirrer for 30min, heating the stirrer at a temperature of 80 ℃ and uniformly heating the stirrer, and uniformly heating the stirrer to obtain a water, and heating the stirrer to obtain a uniform mixture, and stirring the water by a pump for 300 h;
s3: heating in water bath to mix and prepare the component B,
adding the 7% third disperse phase, the 4% fourth disperse phase and the 0.4% fifth disperse phase into a first mixing tank, putting the first mixing tank into a water bath pool with the temperature of 50 ℃ for water bath heating, stirring for 40min at the speed of 400r/min by a first stirrer, and uniformly mixing to obtain a component B;
s4: mixing with sodium hyaluronate to prepare component C,
adding the rest glycerol and 0.03% of acetylated sodium hyaluronate into a second mixing tank, and stirring at 250r/min for 30min with a second stirrer to obtain component C;
s5: extracting gardenia twice to prepare gardenia composite extract,
selecting fresh and full gardenia, picking petals, cleaning, putting the petals into a reduced pressure rotary evaporator, adding water, soaking the petals, setting the heating temperature of the reduced pressure rotary evaporator to 80 ℃ and the internal pressure to 0.07MPa, starting the reduced pressure rotary evaporator, distilling under reduced pressure for 3 hours, collecting condensate through a condenser, pouring petal residues in the reduced pressure rotary evaporator into a grinder, grinding for 40 minutes to obtain petal slurry, pouring the petal slurry into an ultrasonic wave extractor, adding ethanol into the ultrasonic wave extractor, ultrasonically extracting for 2 hours at the power of 600W and the frequency of 40kHz, filtering to obtain gardenia extract, finally adding the gardenia extract and the condensate into the concentrator together, stirring, heating and concentrating until the liquid is evaporated to dryness, and obtaining the gardenia compound extract;
s6: adding other plant extraction components, ball milling and mixing to prepare a component D,
adding 0.006% of the gardenia composite extract into a ball milling tank, adding 0.004% of the fennel extract and 0.004% of the magnolia sieboldii extract into the ball milling tank, ball milling for 20min to obtain mixed extract powder, adding 0.01% of jojoba seed oil into the ball milling tank, continuing ball milling for 2h, and fully and uniformly mixing with the mixed extract powder to obtain a component D;
s7: the components are mixed and filled,
and (3) restarting a heater in the stirrer, heating the component A at 55 ℃, adding the component B into the stirrer, stirring and mixing at the speed of 600r/min, keeping the heating temperature of the heater unchanged, adjusting the stirring speed of the stirrer to 800r/min, adding the component D while stirring, continuing stirring for 50r/min after the addition, turning off the heater, stopping heating, adjusting the stirring speed of the stirrer to 350r/min, adding the component C while stirring until a temperature sensor in the stirrer detects that the temperature in the stirrer is reduced to the room temperature, obtaining a precursor, then moving the precursor into a homogenizer, homogenizing for 2h, fully and uniformly mixing to obtain the facial cleanser, and finally filling the facial cleanser into a packaging can to obtain the finished facial cleanser.
And (3) effect test:
firstly, taking a square tested skin with a side length of 10cm, cleaning the surface of the square tested skin, placing the tested skin in a colored smoke environment with PM2.5 for 10min, taking out the square tested skin, testing the melanin content of the tested skin by a skin tester, marking the melanin content as A1, cleaning the tested skin subjected to smoke treatment by the prepared facial cleanser, naturally airing the tested skin, testing the melanin content of the tested skin again, marking the melanin content as A2, and calculating the pollutant clearance rate of the facial cleanser to be about 91.87 according to a formula of = (1-A2/A1) ×100%;
then, selecting 5 healthy volunteers with the age of 20-45 years old as trial objects, selecting a region with the length of 2cm multiplied by 2cm at the same position of the forehead of the volunteer as a test region, firstly washing the face by using clear water, testing the skin moisture content before use by using a skin moisture tester after 0.5h, marking as B1, detecting the skin moisture content before use by using a skin grease test probe, marking as C1, then washing the face by using the prepared facial cleanser by using the volunteer, detecting the skin grease content after use again by using the skin grease test probe after 8h, marking as C2, testing the skin moisture content after use by using a skin moisture tester again after 24h, marking as B2, and calculating that the skin moisture content change is about +2.2% and the skin grease content change is about-32.7 according to test results;
finally, statistics of satisfaction scoring results of volunteers after trial, wherein the highest score is 10 and the lowest score is 0, and the results show that: the foam richness is 9.3 minutes, and the comfort level after washing is 9.2 minutes.
The effect test was carried out by referring to the experimental procedure of example 1 using a commercially available soap-based cleansing cream as an experimental subject, and the results showed that: the pollutant removal rate is about 94.68%, the skin moisture content is about-1.4%, the skin grease content is about-25.3%, the foam richness is 7.9 minutes, and the comfort after washing is 7.6 minutes.
As shown in fig. 3, it is apparent from the comparison of the effect test results of the above example 1 that the hard water resistance of the prepared cleansing milk can be increased by compounding the sodium cocoyl glycinate as a main active ingredient with the surfactants of potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate, and a large amount of stable and fine foam can be produced, and the cleansing milk has excellent moisturizing and detergency.
Comparative example 2
The effect test was carried out by referring to the experimental procedure of example 1 using a commercially available amino acid system cleanser as an experimental subject, and the results showed that: the pollutant removal rate is about 88.64%, the skin moisture content is about +0.02%, the skin grease content is about-9.6%, the foam richness is 7.1 minutes, and the comfort level after washing is 8.9 minutes.
As shown in fig. 4, it is apparent from the comparison of the effect test results of the above example 1 that the hard water resistance of the prepared cleansing milk can be increased by compounding the sodium cocoyl glycinate as a main active ingredient with the surfactants of potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate, and a large amount of stable and fine foam can be produced, and the cleansing milk has excellent moisturizing and detergency.
Comparative example 3
Referring to the preparation procedure of example 1, with other conditions unchanged, only steps S5 and S6 were removed, and referring again to the experimental procedure of example 1, effect tests were performed, and the results showed that: the pollutant removal rate is about 86.18%, the skin moisture content is about +1.3%, the skin grease content is about-13.6%, the foam richness is 9.0 minutes, and the comfort after washing is 9.2 minutes.
As shown in fig. 5, it is apparent from the comparison of the effect test results of the above example 1 that the addition of natural plant extracts such as jojoba seed oil, gardenia complex extract, fennel extract, magnolia sieboldii extract, etc. can provide excellent oil control effect while cleaning skin, and can further improve the moisturizing effect of the cleanser.
Comparative example 4
Referring to the preparation procedure of example 1, other conditions were not changed, and only the extract in step S5 was removed, namely, the gardenia extract was prepared by concentrating and evaporating only the condensate, and referring to the experimental procedure of example 1, the effect test was performed, and the results showed that: the pollutant removal rate is about 86.76%, the skin moisture content is about +1.8%, the skin grease content is about-29.8%, the foam richness is 9.2 minutes, and the comfort after washing is 9.3 minutes.
As shown in fig. 6, comparing the results of the effect test in the above example 1, it is known that the steps of distilling the petals of gardenia under reduced pressure by adding water, condensing and collecting condensate, extracting the petal residues again by using ethanol to prepare an extract, and finally mixing and concentrating the condensate with the extract to obtain a gardenia composite extract, so that not only can the waste of gardenia resources be reduced, but also the synergistic effect can be generated after the combination of the condensate and the extract, thereby improving the cleaning and moisturizing effects of the facial cleanser.
Comparative example 5
Referring to the preparation procedure of example 1, with the other conditions unchanged, the humectants erythritol, panthenol and betaine in step S2 were replaced with equal amounts of erythritol, and referring again to the experimental procedure of example 1, effect tests were performed, and the results showed that: the pollutant removal rate is about 82.16%, the skin moisture content is about +1.6%, the skin grease content is about-23.4%, the foam richness is 9.3 minutes, and the comfort after washing is 9.4 minutes.
As shown in fig. 7, it is apparent from the comparison of the effect test results of example 1 that the addition of erythritol, panthenol and betaine as the moisturizing agent can further improve the moisturizing effect of the cleansing cream, and the cooperation of the three can further improve the cleansing and detergency effects of the surfactant and the oil control effects of the cleansing cream.
The above embodiments are merely illustrative of the principles of the present invention and its effectiveness, and are not intended to limit the invention. Modifications and variations may be made to the above-described embodiments by those skilled in the art without departing from the spirit and scope of the invention. Accordingly, it is intended that all equivalent modifications and variations of the invention be covered by the claims, which are within the ordinary skill of the art, be within the spirit and scope of the present disclosure.
Claims (10)
1. An amino acid facial cleanser is characterized by comprising the following components:
23-25% of a first disperse phase, 0.4-0.6% of a second disperse phase, 5-7% of a third disperse phase, 2-4% of a fourth disperse phase, 0.2-0.4% of a fifth disperse phase, 14-16% of glycerin, 7.4-12.4% of a surfactant, 1.4-1.8% of a humectant, 0.4-0.6% of a thickener, 0.05-0.15% of arginine, 0.002-0.004% of sodium chloride, 0.01-0.03% of acetylated sodium hyaluronate, 0.008-0.01% of jojoba seed oil, 0.004-0.006% of gardenia complex extract, 0.002-0.004% of a fennel extract, 0.002-0.004% of magnolia sieboldii extract, and the balance of water;
wherein the first dispersed phase comprises sodium cocoyl glycinate and water;
the second disperse phase comprises sodium polyacryl dimethyl taurate, water, isohexadecane and PEG-7 glycerol cocoate;
the third dispersed phase comprises decyl glucoside and water;
the fourth dispersed phase comprises hydrolyzed corn starch and water;
the fifth disperse phase comprises polyquaternium-6 and water.
2. The preparation method of the amino acid facial cleanser is characterized by comprising the following steps of:
s1: stirring and dispersing the mixture by using water,
stirring and dispersing sodium cocoyl glycinate, sodium polyacryl dimethyl taurate, isohexadecane, PEG-7 glycerol cocoate, decyl glucoside, hydrolyzed corn starch and polyquaternium-6 with water to obtain a first dispersed phase, a second dispersed phase, a third dispersed phase, a fourth dispersed phase and a fifth dispersed phase;
s2: adding a surfactant and a humectant to prepare a component A,
mixing the first disperse phase and the second disperse phase, mixing with 60% of glycerin by volume, adding surfactant and humectant, mixing, adding thickener, arginine and sodium chloride, adding water, and mixing uniformly to obtain component A;
s3: heating in water bath to mix and prepare the component B,
adding the third disperse phase, the fourth disperse phase and the fifth disperse phase into a first mixing tank, putting the first mixing tank into a water bath at 50-60 ℃ for water bath heating, stirring for 30-40min at the speed of 300-400r/min by a first stirrer, and uniformly mixing to obtain a component B;
s4: mixing with sodium hyaluronate to prepare component C,
adding the rest glycerol and the sodium hyaluronate into a second mixing tank together, and stirring at a speed of 150-250r/min for 20-30min by using a second stirrer to obtain a component C;
s5: extracting gardenia twice to prepare gardenia composite extract,
adding water into petals of gardenia, distilling under reduced pressure, collecting condensate, grinding residues of the petals after distillation, adding ethanol, performing ultrasonic extraction to prepare an extracting solution, mixing the condensate with the extracting solution, and concentrating to obtain a gardenia compound extract;
s6: adding other plant extraction components, ball milling and mixing to prepare a component D,
ball-milling and mixing the sea fennel extract, the magnolia sieboldii extract and the gardenia compound extract, adding jojoba seed oil, and continuing ball-milling and mixing to obtain a component D;
s7: the components are mixed and filled,
and adding the component B into the component A, heating, stirring and mixing, adding the component D, stopping heating, adding the component C, stirring and mixing, and then carrying out homogenizing mixing and filling to obtain the finished product of the facial cleanser.
3. The method for preparing the amino acid facial cleanser according to claim 2, wherein the water stirring dispersion in the step S1 specifically comprises the following steps:
s1.1: stirring and mixing sodium cocoyl glycinate and water according to a mass ratio (23-25) of 1, and uniformly dispersing to obtain a first dispersed phase;
s1.2: mixing and stirring poly (sodium acryl dimethyl taurate), water, isohexadecane and PEG-7 glycerol cocoate (46-48), (30-32), (15-17) and (5-7) according to the mass ratio, and uniformly dispersing to obtain a second dispersed phase;
s1.3: stirring and mixing decyl glucoside and water according to the mass ratio of (10-12) (8-9), and uniformly dispersing to obtain a third dispersed phase;
s1.4: mixing and stirring the hydrolyzed corn starch and water according to the mass ratio of (2-4) 1, and uniformly dispersing to obtain a fourth dispersed phase;
s1.5: and stirring and mixing the polyquaternium-6 and water according to the mass ratio of (1.4-1.6) to 1, and uniformly dispersing to obtain a fifth dispersed phase.
4. The method for preparing the amino acid facial cleanser according to claim 3, wherein the surfactant and the humectant are added in the step S2 to prepare the component A, and the method specifically comprises the following steps:
s2.1: adding the first disperse phase prepared in the step S1.1 and the second disperse phase prepared in the step S1.2 into a stirrer together until a gravity sensor in the stirrer detects that the gravity in the stirrer is not increased any more, and sending a signal to a controller by the gravity sensor;
s2.2: after the controller receives the signal sent by the gravity sensor, controlling the hydraulic pump to pump 60% of the volume of the glycerol into the stirrer, and simultaneously controlling the stirrer to stir at a speed of 700-800r/min for 40-50min;
s2.3: adding the surfactant and the humectant into a stirrer together, regulating the stirring speed of the stirrer to 500-600r/min, and continuously stirring for 1-2h;
s2.4: adding thickener, arginine and sodium chloride into a stirrer, keeping stirring speed unchanged, stirring for 20-30min, and turning on a heater in the stirrer to heat at 70-80deg.C;
s2.5: pumping water into a stirrer at a constant speed through a water pump, adjusting the stirring speed of the stirrer to be 200-300r/min, heating and stirring for 1-2h, and uniformly mixing to obtain the component A.
5. The method for preparing amino acid facial cleanser according to claim 4, wherein the step S5 of extracting gardenia twice to prepare gardenia composite extract comprises the following steps:
s5.1: selecting fresh and full gardenia, picking and cleaning petals, putting the petals into a decompression rotary steaming device, and adding water to submerge the petals;
s5.2: setting the heating temperature of a decompression rotary evaporator at 60-80 ℃ and the internal pressure at 0.05-0.07MPa, starting the decompression rotary evaporator, decompressing and distilling for 1-3h, and collecting condensate through a condenser;
s5.3: pouring the petal residues in the decompression rotary steamer into a grinder, and grinding for 30-40min to obtain petal slurry;
s5.4: pouring the petal slurry into an ultrasonic wave extraction instrument, adding ethanol into the ultrasonic wave extraction instrument, ultrasonically extracting for 1-2 hours at the power of 500-600W and the frequency of 30-40kHz, and filtering to obtain gardenia extract;
s5.5: adding the above Gardenia extractive solution and condensate together into a concentrator, heating and concentrating under stirring until the liquid is evaporated to dryness to obtain Gardenia compound extract.
6. The method for preparing amino acid facial cleanser according to claim 5, wherein the step S6 comprises the steps of adding other plant extraction components, ball-milling and mixing to prepare the component D, and the method comprises the following steps:
s6.1: adding the gardenia composite extract prepared in the step S5.5 into a ball milling tank, adding the sea fennel extract and the magnolia sieboldii extract into the ball milling tank, and ball milling for 10-20min to obtain mixed extract powder;
s6.2: adding jojoba seed oil into a ball milling tank, continuously ball milling for 1-2h, and fully and uniformly mixing with the mixed extract powder to obtain a component D.
7. The method for preparing amino acid facial cleanser according to claim 6, wherein the step S7 comprises the steps of:
s7.1: restarting a heater in the stirrer, heating the component A prepared in the step S2.5 at 45-55 ℃, and simultaneously adding the component B prepared in the step S3 into the stirrer, and stirring and mixing at a speed of 400-600 r/min;
s7.2: keeping the heating temperature of the heater unchanged, adjusting the stirring speed of the stirrer to 700-800r/min, adding the component D prepared in the step S6.2 while stirring, and continuing stirring for 40-50r/min after the addition;
s7.3: turning off the heater, stopping heating, regulating the stirring speed of the stirrer to 200-350r/min, adding the component C prepared in the step S4 while stirring until the temperature sensor in the stirrer detects that the temperature in the stirrer is reduced to room temperature, and obtaining a precursor;
s7.4: the precursor is moved into a homogenizer, homogenized for 1 to 2 hours, and fully and uniformly mixed to obtain the facial cleanser;
s7.5: and filling the facial cleanser into a packaging can to obtain the finished facial cleanser.
8. The preparation method of the amino acid facial cleanser according to claim 4, wherein the surfactant is prepared by compounding potassium cocoyl glycinate, sodium lauroyl glutamate, cocoyl glutamate and polyglycerol-10 laurate according to a mass ratio of (5-7): (2-3): 1:1.
9. The method for preparing the amino acid facial cleanser according to claim 4, wherein the humectant is prepared by compounding erythritol, panthenol and betaine according to a mass ratio of (10-12) to 1:1.
10. The method for preparing amino acid facial cleanser of claim 6, wherein the thickener is PEG-120 methyl glucose dioleate.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505584A (en) * | 2015-12-03 | 2016-04-20 | 镇江市丹徒区南山溪园茶叶专业合作社 | Extraction method of cape jasmine flower essential oil |
| CN105997828A (en) * | 2016-07-22 | 2016-10-12 | 广州艾蓓生物科技有限公司 | Smearing type moistening and brightening essence liquid |
| CN106344464A (en) * | 2016-11-04 | 2017-01-25 | 王少琼 | Amino acid facial cleanser as well as preparation method and application thereof |
| CN106619302A (en) * | 2016-12-29 | 2017-05-10 | 广州市中通生化制品有限公司 | Mild allergy-relieving cleansing milk and preparation method thereof |
| CN112315845A (en) * | 2020-12-03 | 2021-02-05 | 广东嘉丹婷日用品有限公司 | Whitening and freckle removing cream and preparation method thereof |
| CN113230158A (en) * | 2021-05-26 | 2021-08-10 | 南京中医药大学 | Gardenia composite extract capable of improving antioxidant activity and application thereof |
| CN114903834A (en) * | 2022-06-30 | 2022-08-16 | 羽楠(广州)化妆品有限公司 | Cold-storable mild double-tube facial cleanser and preparation method thereof |
-
2023
- 2023-11-29 CN CN202311604833.4A patent/CN117297988A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505584A (en) * | 2015-12-03 | 2016-04-20 | 镇江市丹徒区南山溪园茶叶专业合作社 | Extraction method of cape jasmine flower essential oil |
| CN105997828A (en) * | 2016-07-22 | 2016-10-12 | 广州艾蓓生物科技有限公司 | Smearing type moistening and brightening essence liquid |
| CN106344464A (en) * | 2016-11-04 | 2017-01-25 | 王少琼 | Amino acid facial cleanser as well as preparation method and application thereof |
| CN106619302A (en) * | 2016-12-29 | 2017-05-10 | 广州市中通生化制品有限公司 | Mild allergy-relieving cleansing milk and preparation method thereof |
| CN112315845A (en) * | 2020-12-03 | 2021-02-05 | 广东嘉丹婷日用品有限公司 | Whitening and freckle removing cream and preparation method thereof |
| CN113230158A (en) * | 2021-05-26 | 2021-08-10 | 南京中医药大学 | Gardenia composite extract capable of improving antioxidant activity and application thereof |
| CN114903834A (en) * | 2022-06-30 | 2022-08-16 | 羽楠(广州)化妆品有限公司 | Cold-storable mild double-tube facial cleanser and preparation method thereof |
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Application publication date: 20231229 |