CN116648476A - 热膨胀性微囊、发泡性母料及发泡成形体 - Google Patents

热膨胀性微囊、发泡性母料及发泡成形体 Download PDF

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Publication number
CN116648476A
CN116648476A CN202280008926.8A CN202280008926A CN116648476A CN 116648476 A CN116648476 A CN 116648476A CN 202280008926 A CN202280008926 A CN 202280008926A CN 116648476 A CN116648476 A CN 116648476A
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Prior art keywords
thermally expandable
expandable microcapsule
volume
monomer
weight
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Pending
Application number
CN202280008926.8A
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English (en)
Chinese (zh)
Inventor
川上健
松洼龙也
内山裕作
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Publication of CN116648476A publication Critical patent/CN116648476A/zh
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/06Making microcapsules or microballoons by phase separation
    • B01J13/14Polymerisation; cross-linking
    • B01J13/18In situ polymerisation with all reactants being present in the same phase
    • B01J13/185In situ polymerisation with all reactants being present in the same phase in an organic phase
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • C08J9/20Making expandable particles by suspension polymerisation in the presence of the blowing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/06Making microcapsules or microballoons by phase separation
    • B01J13/14Polymerisation; cross-linking
    • B01J13/18In situ polymerisation with all reactants being present in the same phase
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • C08J9/232Forming foamed products by sintering expandable particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03Extrusion of the foamable blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/22Expandable microspheres, e.g. Expancel®
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CN202280008926.8A 2021-08-06 2022-08-03 热膨胀性微囊、发泡性母料及发泡成形体 Pending CN116648476A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2021130096 2021-08-06
JP2021-130096 2021-08-06
JP2022008513A JP7128371B1 (ja) 2021-08-06 2022-01-24 熱膨張性マイクロカプセル、発泡性マスターバッチ及び発泡成形体
JP2022-008513 2022-01-24
PCT/JP2022/029818 WO2023013682A1 (ja) 2021-08-06 2022-08-03 熱膨張性マイクロカプセル、発泡性マスターバッチ及び発泡成形体

Publications (1)

Publication Number Publication Date
CN116648476A true CN116648476A (zh) 2023-08-25

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ID=83103204

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CN202280008926.8A Pending CN116648476A (zh) 2021-08-06 2022-08-03 热膨胀性微囊、发泡性母料及发泡成形体

Country Status (6)

Country Link
US (1) US20250002667A1 (https=)
EP (1) EP4382554A4 (https=)
JP (2) JP7128371B1 (https=)
KR (1) KR20240042579A (https=)
CN (1) CN116648476A (https=)
WO (1) WO2023013682A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7121210B1 (ja) * 2021-08-11 2022-08-17 積水化学工業株式会社 発泡成形用マスターバッチ及び発泡成形体
TW202506899A (zh) * 2023-06-05 2025-02-16 日商積水化學工業股份有限公司 成形體
DE102024110058A1 (de) 2024-04-11 2025-10-16 Fraunhofer Gesellschaft zur Förderung der angewandten Forschung e.V. Mit Schmiermittel gefüllte Mikrokapseln aus Polyharnstoff
KR20260040251A (ko) * 2024-09-10 2026-03-24 세키스이가세이힝코교가부시키가이샤 중공 수지 입자, 그 제조 방법, 및 그 용도

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102203205A (zh) * 2008-11-07 2011-09-28 积水化学工业株式会社 热膨胀性微囊和发泡成形体
CN105722788A (zh) * 2014-01-29 2016-06-29 三菱综合材料株式会社 合成非晶质二氧化硅粉末及其制造方法
WO2020158613A1 (ja) * 2019-02-01 2020-08-06 積水化学工業株式会社 熱膨張性マイクロカプセル及び発泡成形用組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4027100B2 (ja) * 2001-01-18 2007-12-26 積水化学工業株式会社 熱膨張性マイクロカプセルの製造方法
JP2004323854A (ja) * 2003-04-11 2004-11-18 Matsumoto Yushi Seiyaku Co Ltd 熱膨張性マイクロカプセル及びその製造方法
JP6668067B2 (ja) 2015-12-21 2020-03-18 株式会社クレハ マイクロスフェアー、これを含む熱発泡性樹脂組成物、構造部材、および成形体
WO2018012415A1 (ja) 2016-07-15 2018-01-18 松本油脂製薬株式会社 樹脂組成物およびその利用
JP7583537B2 (ja) * 2019-06-27 2024-11-14 積水化学工業株式会社 熱膨張性マイクロカプセル、成形用樹脂組成物及び発泡成形体

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102203205A (zh) * 2008-11-07 2011-09-28 积水化学工业株式会社 热膨胀性微囊和发泡成形体
CN105722788A (zh) * 2014-01-29 2016-06-29 三菱综合材料株式会社 合成非晶质二氧化硅粉末及其制造方法
WO2020158613A1 (ja) * 2019-02-01 2020-08-06 積水化学工業株式会社 熱膨張性マイクロカプセル及び発泡成形用組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
佚名: "Advancell EM系列热膨胀微球", Retrieved from the Internet <URL:https://www.sekisui.co.jp/cs/products/1270513_25825.html> *

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Publication number Publication date
KR20240042579A (ko) 2024-04-02
EP4382554A4 (en) 2025-09-10
TW202313812A (zh) 2023-04-01
JPWO2023013682A1 (https=) 2023-02-09
JP7128371B1 (ja) 2022-08-30
US20250002667A1 (en) 2025-01-02
WO2023013682A1 (ja) 2023-02-09
EP4382554A1 (en) 2024-06-12
JP2023024247A (ja) 2023-02-16

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