CN116004012B - 一种柔性储热相变复合材料及其制备方法 - Google Patents
一种柔性储热相变复合材料及其制备方法 Download PDFInfo
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- CN116004012B CN116004012B CN202211668706.6A CN202211668706A CN116004012B CN 116004012 B CN116004012 B CN 116004012B CN 202211668706 A CN202211668706 A CN 202211668706A CN 116004012 B CN116004012 B CN 116004012B
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- 239000002131 composite material Substances 0.000 title claims abstract description 127
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- 239000000463 material Substances 0.000 claims abstract description 56
- 239000004020 conductor Substances 0.000 claims abstract description 55
- 239000012782 phase change material Substances 0.000 claims abstract description 44
- 239000003094 microcapsule Substances 0.000 claims abstract description 29
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 26
- 238000003756 stirring Methods 0.000 claims abstract description 21
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 239000004944 Liquid Silicone Rubber Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 37
- 238000002156 mixing Methods 0.000 claims description 32
- HUYMWPVMPWHALT-UHFFFAOYSA-N aluminum magnesium zinc oxygen(2-) Chemical compound [O-2].[Zn+2].[Al+3].[Mg+2] HUYMWPVMPWHALT-UHFFFAOYSA-N 0.000 claims description 24
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 239000010439 graphite Substances 0.000 claims description 20
- 229910002804 graphite Inorganic materials 0.000 claims description 20
- 238000000498 ball milling Methods 0.000 claims description 18
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 18
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 18
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000001354 calcination Methods 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 11
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 239000012188 paraffin wax Substances 0.000 claims description 10
- 238000005507 spraying Methods 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 10
- 235000021355 Stearic acid Nutrition 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 8
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 claims description 8
- 239000008117 stearic acid Substances 0.000 claims description 8
- 238000000137 annealing Methods 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- 159000000003 magnesium salts Chemical class 0.000 claims description 6
- 150000003751 zinc Chemical class 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- -1 phenolic aldehyde Chemical class 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 238000011068 loading method Methods 0.000 abstract description 4
- 239000004945 silicone rubber Substances 0.000 abstract description 4
- 238000012546 transfer Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000741 silica gel Substances 0.000 description 8
- 229910002027 silica gel Inorganic materials 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 238000004146 energy storage Methods 0.000 description 5
- 238000011049 filling Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000017525 heat dissipation Effects 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- 230000008569 process Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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Abstract
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CN116497470B (zh) * | 2023-06-21 | 2023-09-19 | 相变储能(北京)科技有限公司 | 一种相变调温纤维及其制备方法与相变调温织物 |
CN116640366A (zh) * | 2023-06-27 | 2023-08-25 | 广东力王新材料有限公司 | 一种橡胶相变材料及其制备工艺 |
Citations (10)
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CN1727303A (zh) * | 2005-06-29 | 2006-02-01 | 上海大学 | Mg、Ti共掺的Al2O3晶体材料及其透明激光陶瓷的制备方法 |
CN103773322A (zh) * | 2014-02-08 | 2014-05-07 | 中国电子科技集团公司第三十三研究所 | 一种相变微胶囊导热材料及其制备方法 |
JP2014196380A (ja) * | 2013-03-29 | 2014-10-16 | 大阪ガスケミカル株式会社 | 被覆蓄熱マイクロカプセルの製造方法、蓄熱材の製造方法、蓄熱機能付吸着材 |
CN105348797A (zh) * | 2015-10-21 | 2016-02-24 | 中国科学院宁波材料技术与工程研究所 | 一种石墨烯基导热硅胶相变复合材料及其制备方法 |
CN107129281A (zh) * | 2017-04-28 | 2017-09-05 | 华东理工大学 | 一种钛酸镁掺杂氧化铝微波介质陶瓷 |
CN107793671A (zh) * | 2017-11-03 | 2018-03-13 | 常州市万昌化工有限公司 | 一种导热阻燃软质聚氯乙烯的制备方法 |
CN109913178A (zh) * | 2019-03-19 | 2019-06-21 | 北京服装学院 | 一种石墨烯改性相变微胶囊材料的制备方法 |
CN111430709A (zh) * | 2020-03-09 | 2020-07-17 | 深圳航美新材料科技有限公司 | 一种相变控温式电极及其制备方法与锂离子电池 |
CN114222906A (zh) * | 2019-08-01 | 2022-03-22 | 罗伯特·博世有限公司 | 用于检测在测量气体室中的测量气体的颗粒的传感器元件 |
CN115491181A (zh) * | 2022-09-15 | 2022-12-20 | 中国科学院合肥物质科学研究院 | 兼具优异导热和储热性能的PW@PS/BNNSs相变微胶囊及其制备方法 |
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- 2022-12-24 CN CN202211668706.6A patent/CN116004012B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1727303A (zh) * | 2005-06-29 | 2006-02-01 | 上海大学 | Mg、Ti共掺的Al2O3晶体材料及其透明激光陶瓷的制备方法 |
JP2014196380A (ja) * | 2013-03-29 | 2014-10-16 | 大阪ガスケミカル株式会社 | 被覆蓄熱マイクロカプセルの製造方法、蓄熱材の製造方法、蓄熱機能付吸着材 |
CN103773322A (zh) * | 2014-02-08 | 2014-05-07 | 中国电子科技集团公司第三十三研究所 | 一种相变微胶囊导热材料及其制备方法 |
CN105348797A (zh) * | 2015-10-21 | 2016-02-24 | 中国科学院宁波材料技术与工程研究所 | 一种石墨烯基导热硅胶相变复合材料及其制备方法 |
CN107129281A (zh) * | 2017-04-28 | 2017-09-05 | 华东理工大学 | 一种钛酸镁掺杂氧化铝微波介质陶瓷 |
CN107793671A (zh) * | 2017-11-03 | 2018-03-13 | 常州市万昌化工有限公司 | 一种导热阻燃软质聚氯乙烯的制备方法 |
CN109913178A (zh) * | 2019-03-19 | 2019-06-21 | 北京服装学院 | 一种石墨烯改性相变微胶囊材料的制备方法 |
CN114222906A (zh) * | 2019-08-01 | 2022-03-22 | 罗伯特·博世有限公司 | 用于检测在测量气体室中的测量气体的颗粒的传感器元件 |
CN111430709A (zh) * | 2020-03-09 | 2020-07-17 | 深圳航美新材料科技有限公司 | 一种相变控温式电极及其制备方法与锂离子电池 |
CN115491181A (zh) * | 2022-09-15 | 2022-12-20 | 中国科学院合肥物质科学研究院 | 兼具优异导热和储热性能的PW@PS/BNNSs相变微胶囊及其制备方法 |
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Address after: 100000 East Side of 1st Floor, Building 1, No. 3 Yuncheng Street, Beijing Economic and Technological Development Zone, Daxing District, Beijing Patentee after: Beijing Chuangyingguang Medical Technology Co.,Ltd. Country or region after: China Address before: 102600 east side, 1st floor, building 1, No.3 Yuncheng street, Beijing Economic and Technological Development Zone, Daxing District, Beijing Patentee before: BEIJING TRUWIN OPTOELECTRONIC MEDICAL CO.,LTD. Country or region before: China |
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