CN115302876A - 一种防钻绒保暖防水羽绒服面料及制备方法 - Google Patents

一种防钻绒保暖防水羽绒服面料及制备方法 Download PDF

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CN115302876A
CN115302876A CN202210978878.7A CN202210978878A CN115302876A CN 115302876 A CN115302876 A CN 115302876A CN 202210978878 A CN202210978878 A CN 202210978878A CN 115302876 A CN115302876 A CN 115302876A
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CN115302876B (zh
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张传贵
吴昆明
刘昌甲
赵传书
金宇霞
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Gaofan Zhejiang Information Technology Co Ltd
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Abstract

本发明涉及一种防钻绒保暖防水羽绒服面料，通过利用羊毛和竹炭纤维交错制成锁绒层，并在锁绒层的内表面均匀分布椭球状的凹陷部，一方面增强了锁绒层在空间上的弹性，当凹陷部的短径方向延伸并瞬间释放的弹力时候，在锁绒面料的表面产生相对冲击力，该弹力会使得均匀分布在锁绒面料内侧表面的羽绒发生蓬松，通过仿照“弹棉花原理”，使得长久穿戴的羽绒服内部的羽绒蓬松，大大增强其保暖效果，而凹陷部的内部均匀分布有超细竹炭纤维，方便羽绒的根部附着在超细竹炭纤维上，能进一步阻止位于内胆内的羽绒飘出，而位于荆棘状的超细竹炭纤维处的羽绒，形成了整体保暖加厚层，在保证保暖的同时，整体的钻绒效果好。

Description

一种防钻绒保暖防水羽绒服面料及制备方法
技术领域
本发明属于羽绒服面料技术领域，具体涉及一种防钻绒保暖防水羽绒服面料及制备方法。
背景技术
羽绒服内充羽绒填料的上衣，外形庞大圆润；羽绒服一般鸭绒量占一半以上，同时可以混杂一些细小的羽毛，将鸭绒清洗干净，经高温消毒，之后填充在衣服中就是羽绒服了；羽绒服保暖性最好；多为寒冷地区的人们穿着，也为极地考察人员所常用。
其中，羽绒服面料的性能直接决定着羽绒服的整体效果，在使用者穿戴过程中，起到至关重要的作用，另外，羽绒填充物同样非常重要，羽绒服中的填充物最常见的是鹅绒和鸭绒，羽绒为三维结构，羽绒相对比其他填充材料是非常蓬松的，因此相同重量的羽绒可以比其他材质固定更多的空气，大量的羽绒细丝交错在一起固定住空气，并形成隔热的保护层，从而实现良好的保暖性能。
羽绒蓬松细软，容易穿过面料飞扬而去，因此对于羽绒服面料要求也逐渐提高，羽绒服的面料需要具有防钻绒功能和保暖功能，同时还需兼顾轻便透气功能，以便于减轻衣物重量，也便于穿着和清洗，但现有技术中保暖防钻绒功能和轻便透气功能难以同时具备。
发明内容
本发明的目的就在于为了解决上述问题而提供一种防钻绒保暖防水羽绒服面料及制备方法。
本发明通过以下技术方案来实现上述目的：
一种防钻绒保暖防水羽绒服面料，由外而内依次包括防水层、保温层、透气层和锁绒层，所述锁绒层包括由羊毛以及竹炭纤维制成的锁绒面料，
羊毛的质地柔软，且保暖效果好，热一点的水就会使蛋白部分凝固，所以会出现缩水现象，通过设置有竹炭纤维能有效的缓解上述缩水的状态，同时竹炭纤维可去除异味，能释放微量元素，具有弱导电性，起到防静电作用，可放射远红外线，波长适合人体吸收，加快血液循环，改善人体内环境，通过由羊毛以及竹炭纤维制成的锁绒面料舒适度强，且易于保暖效果好，能有效的缓解羊毛带来的缩水效果；
所述锁绒面料的内表面设有椭球状的凹陷部，凹陷部在锁绒面料的内表面均匀分布，椭球状的凹陷部在空间上存在有长径方向和短径方向，一方面增强了锁绒层在空间上的弹性，另一方面，当凹陷部的短径方向延伸并瞬间释放的弹力时候，凹陷部的短径方向会发生快速的复位，并在锁绒面料的表面产生相对弹力，该弹力会使得均匀分布在锁绒面料内侧表面的羽绒发生蓬松，通过仿照“弹棉花原理”，使得长久穿戴的羽绒服内部的羽绒蓬松，大大增强其保暖效果；
椭球状的凹陷部的内部设有若干组呈锥形结构的超细竹炭纤维，超细竹炭纤维通过机械分丝、软化脱胶、开松梳理、化学纺丝、一端捻压并断切1-2mm获得；
所述银纳米颗粒以纯亲水无规共聚物poly的水相自组装体为模板，并加入纳米二氧化锗和橡胶混合制成的添加剂，搅拌并通过原位还原法制得的，其中，需要说明的是：银纳米颗粒经过处理形成的带有纳米银离子的溶液，纳米二氧化锗能快速增强与纳米银离子的溶液之间的吸附力，另外通过加入橡胶，一方面，大大增强了银纳米颗粒与超细竹炭纤维之间粘性粘附力，避免由于清洗揉搓，造成银纳米颗粒的流失，另一方面，大大增大了锁绒层整体的延展性，锁绒层的弹性好，另外银纳米颗粒抗菌效果好，再一方面银纳米颗粒能在锁绒层的内侧上形成抗菌网层，整体羽绒服面料不易发生霉变，羽绒的抗菌性好，当模板处于低pH值时，纯亲水无规共聚物poly形成微孔棒状及棒状的二级自组装体(球状或立方体状)的稳定结构；随着银还原率的提高，银纳米颗粒从球状或立方体状解体为小球状；
椭球状的凹陷部的内部设有若干组呈锥形结构的超细竹炭纤维，一方面，由于超细竹炭纤维设置有若干组，在相邻的超细竹炭纤维之间交错形成荆棘状，羽绒的根部容易附着在荆棘状上，羽绒容易在荆棘状的超细竹炭纤维处起到阻挡作用，能有效的进一步阻止位于内胆内的羽绒飘出，而位于荆棘状的超细竹炭纤维处的羽绒，形成了整体保暖加厚层，在保证保暖的同时，整体的钻绒效果好；另一方面，超细竹炭纤维的内部设有球状的银纳米颗粒，银纳米颗粒的抗菌效果好，能有效的进一步的消除羽绒携带的细菌，整体的舒适度，抗菌性好；再一方面，凹陷部与下述热膨胀颗粒相匹配，当热膨胀颗粒受热膨胀时，促使凹陷部处于平整状态，此时凹陷部内的超细竹炭纤维向内张开，方便释放超细竹炭纤维处的羽绒，便于在清洗时，快速清洗凹陷部内的羽绒，避免产生清洗死角，造成局部霉变。
所述透气层包括由苎麻纤维以及涤纶纤维制成的透气面料，所述透气面料的内表面设有凸起部，所述透气面料与锁绒面料之间的对立面上设有热膨胀颗粒。
利用苎麻纤维以及涤纶纤维编织而成的透气面料，苎麻纤维以及涤纶纤维之间的孔隙大，并填充有热膨胀颗粒，热膨胀颗粒采用热膨胀冷收缩材料，便于与椭球状的凹陷部相匹配，在遇冷时收缩，此时羽绒快速填充在椭球状的凹陷部内，起到保温的作用，另一方面，预热膨胀时，此时，凹陷部处于平整状态，位于超细竹炭纤维上的羽绒间距会增大，便于起到快速透气的作用。
作为本发明的进一步优化方案，所述防水层由在聚酯纤维外表面喷涂有防水涂层获得，所述防水层的内表面设有褶皱面，防水层的防水效果好，且易于延展。
作为本发明的进一步优化方案，所述保温层包括由羊毛纤维和棉纤维编织而成的保温面料，所述保温面料的内表面设有椭球凸起点，羊毛纤维和棉纤维的保暖效果好，能大幅度的降低热量的损耗。
一种制备上述防钻绒保暖防水羽绒服面料的方法，其制备方法包括：
S1：将超细竹炭纤维浸泡在搅拌容器中，并分批次定量添加银纳米颗粒，放入由羊毛以及竹炭纤维制成的锁绒面料，搅拌、晾干和整理制得锁绒层；
S2：将透气面料浸泡在带有热膨胀颗粒的溶液中，加热搅拌，晾干制得透气层；
S3：取带有椭球凸点的模板，热压在保温面料的表面，并形成带有椭球凸起点的保温面料，即获得保温层；
S4：利用热压技术将由在聚酯纤维外表面喷涂有防水涂层获得的防水层、保温层、透气层和锁绒层形成防钻绒保暖防水羽绒服面料；在热压过程中，透气层内的热膨胀颗粒受热膨胀，并形成熔融状态，并透过防水层和透气层，大大增强防水层、保温层和透气层之间的粘附力度，使得该防钻绒保暖防水羽绒服面料的整体性好，并且当热膨胀颗粒遇冷收缩时，会缩小透气面料整体的内部孔隙，一方面避免热量的流失，同时具有良好的防钻绒效果，使得透气层与防水层、保温层和锁绒层之间协同效果好。
作为本发明的进一步优化方案，在步骤S1中，所述银纳米颗粒至少分三批递加式添加，且前一次添加的用量是后一次添加用量的1.5倍，通过分批次的加入银纳米颗粒，使得银纳米颗粒和超细竹炭纤维的吸附更加的均匀，避免银纳米颗粒一次性投入，大量的银纳米颗粒会附着在超细竹炭纤维的外表面，难以进一步的渗透至超细竹炭纤维的内部，一方面导致上下层的超细竹炭纤维吸附不均，另一方面加大了搅拌负担，影响超细竹炭纤维和银纳米颗粒的吸附效果。
作为本发明的进一步优化方案，在步骤S2中，所述加热温度区间范围在100-150℃，所述搅拌转速1500-2000r/S。
作为本发明的进一步优化方案，在步骤S3中，所述热压温度区间范围为90-120℃。
本发明的有益效果在于：该防钻绒保暖防水羽绒服面料，通过利用羊毛和竹炭纤维交错制成锁绒层，竹炭纤维能有效的缓解上述缩水的状态，同时竹炭纤维可去除异味，能释放微量元素，具有弱导电性，起到防静电作用，可放射远红外线，波长适合人体吸收，加快血液循环，改善人体内环境，通过由羊毛以及竹炭纤维制成的锁绒面料舒适度强，且易于保暖效果好，能有效的缓解羊毛带来的缩水效果。
进一步，凹陷部在锁绒面料的内表面均匀分布，椭球状的凹陷部在空间上存在有长径方向和短径方向，一方面增强了锁绒层在空间上的弹性，另一方面，当椭球状的凹陷部的短径方向延伸并瞬间释放的弹力时候，椭球状的凹陷部的短径方向会发生快速的复位，并在锁绒面料的表面产生相对冲击力，该冲击力会使得均匀分布在锁绒面料内侧表面的羽绒发生蓬松，通过仿照“弹棉花原理”，使得长久穿戴的羽绒服内部的羽绒蓬松，大大增强其保暖效果。
椭球状的凹陷部的内部设有若干组呈锥形结构的超细竹炭纤维，一方面，由于超细竹炭纤维设置有若干组，在相邻的超细竹炭纤维之间交错形成荆棘状，羽绒的根部容易附着在荆棘状上，羽绒容易在荆棘状的超细竹炭纤维处起到阻挡作用，能有效的进一步阻止位于内胆内的羽绒飘出，而位于荆棘状的超细竹炭纤维处的羽绒，形成了整体保暖加厚层，在保证保暖的同时，整体的钻绒效果好；另一方面，超细竹炭纤维的内部设有球状的银纳米颗粒，银纳米颗粒的抗菌效果好，能有效的进一步的消除羽绒携带的细菌，整体的舒适度，抗菌性好；再一方面，凹陷部与下述热膨胀颗粒相匹配，当热膨胀颗粒受热膨胀时，促使凹陷部处于平整状态，此时凹陷部内的超细竹炭纤维向内张开，方便释放超细竹炭纤维处的羽绒，便于在清洗时，快速清洗凹陷部内的羽绒，避免产生清洗死角，造成局部霉变。
附图说明
图1是本发明的主视剖面结构示意图；
图2是本发明的图1中A处放大结构示意图；
图3是本发明的锁绒层遇冷状主视剖面结构示意图；
图4是本发明的保温层侧视结构示意图。
图中：1、防水层；2、保温层；21、保温面料；22、椭球凸起点；3、透气层；31、透气面料；32、凸起部；33、热膨胀颗粒；4、锁绒层；41、锁绒面料；42、凹陷部；43、超细竹炭纤维；44、银纳米颗粒；5、褶皱面。
具体实施方式
下面结合附图对本申请作进一步详细描述，有必要在此指出的是，以下具体实施方式只用于对本申请进行进一步的说明，不能理解为对本申请保护范围的限制，该领域的技术人员可以根据上述申请内容对本申请作出一些非本质的改进和调整。
实施例
如图1-2所示，一种防钻绒保暖防水羽绒服面料，由外而内依次包括防水层1、保温层2、透气层3和锁绒层4，所述锁绒层4包括由羊毛以及竹炭纤维制成的锁绒面料41；
羊毛的质地柔软，且保暖效果好，热一点的水就会使蛋白部分凝固，所以会出现缩水现象，通过设置有竹炭纤维能有效的缓解上述缩水的状态，同时竹炭纤维可去除异味，能释放微量元素，具有弱导电性，起到防静电作用，可放射远红外线，波长适合人体吸收，加快血液循环，改善人体内环境，通过由羊毛以及竹炭纤维制成的锁绒面料41舒适度强，且易于保暖效果好，能有效的缓解羊毛带来的缩水效果；
所述锁绒面料41的内表面设有椭球状的凹陷部42，凹陷部42在锁绒面料41的内表面均匀分布，椭球状的凹陷部42在空间上存在有长径方向和短径方向，一方面增强了锁绒层4在空间上的弹性，另一方面，当椭球状的凹陷部42的短径方向延伸并瞬间释放的弹力时候，椭球状的凹陷部42的短径方向会发生快速的复位，并在锁绒面料41的表面产生相对冲击力，该冲击力会使得均匀分布在锁绒面料41内侧表面的羽绒发生蓬松，通过仿照“弹棉花原理”，使得长久穿戴的羽绒服内部的羽绒蓬松，大大增强其保暖效果。
椭球状的凹陷部42的内部设有若干组呈锥形结构的超细竹炭纤维43，其中，呈锥形结构的超细竹炭纤维通过机械分丝、软化脱胶、开松梳理、化学纺丝、一端捻压并断切1-2mm获得，所述超细竹炭纤维43的内部设有球状的银纳米颗粒44，其中，需要说明的是：银纳米颗粒以纯亲水无规共聚物poly的水相自组装体为模板，并加入纳米二氧化锗和橡胶混合制成的添加剂，搅拌并通过原位还原法制得的，其中，需要说明的是：银纳米颗粒经过处理形成的带有纳米银离子的溶液，纳米二氧化锗能快速增强与纳米银离子的溶液之间的吸附力，另外通过加入橡胶，一方面，大大增强了银纳米颗粒与超细竹炭纤维之间粘性粘附力，避免由于清洗揉搓，造成银纳米颗粒的流失，另一方面，大大增大了锁绒层整体的延展性，锁绒层的弹性好，另外银纳米颗粒抗菌效果好，再一方面银纳米颗粒能在锁绒层的内侧上形成抗菌网层，整体羽绒服面料不易发生霉变，羽绒的抗菌性好，当模板处于低pH值时，纯亲水无规共聚物poly形成微孔棒状及棒状的二级自组装体(球状或立方体状)的稳定结构；随着银还原率的提高，银纳米颗粒从球状或立方体状解体为小球状；
椭球状的凹陷部42的内部设有若干组呈锥形结构的超细竹炭纤维43，一方面，由于超细竹炭纤维43设置有若干组，在相邻的超细竹炭纤维43之间交错形成荆棘状，羽绒的根部容易附着在荆棘状上，羽绒容易在荆棘状的超细竹炭纤维43处起到阻挡作用，能有效的进一步阻止位于内胆内的羽绒飘出，而位于荆棘状的超细竹炭纤维43处的羽绒，形成了整体保暖加厚层，在保证保暖的同时，整体的钻绒效果好；另一方面，超细竹炭纤维43的内部设有球状的银纳米颗粒44，银纳米颗粒44的抗菌效果好，能有效的进一步的消除羽绒携带的细菌，整体的舒适度，抗菌性好；再一方面，凹陷部42与下述热膨胀颗粒33相匹配，当热膨胀颗粒33受热膨胀时，促使凹陷部42处于平整状态，此时凹陷部42内的超细竹炭纤维43向内张开，方便释放超细竹炭纤维43处的羽绒，便于在清洗时，快速清洗凹陷部42内的羽绒，避免产生清洗死角，造成局部霉变。
所述透气层3包括由苎麻纤维以及涤纶纤维制成的透气面料31，所述透气面料31的内表面设有凸起部32，所述透气面料31与锁绒面料41之间的对立面上设有热膨胀颗粒33。
利用苎麻纤维以及涤纶纤维编织而成的透气面料31，苎麻纤维以及涤纶纤维之间的孔隙大，并填充有热膨胀颗粒33，热膨胀颗粒33采用热膨胀冷收缩材料，便于与椭球状的凹陷部42相匹配，在遇冷时收缩，此时羽绒快速填充在椭球状的凹陷部42内，起到保温的作用，另一方面，预热膨胀时，此时，凹陷部42处于平整状态，位于超细竹炭纤维43上的羽绒间距会增大，便于起到快速透气的作用。
如图3所示，所述防水层1由在聚酯纤维外表面喷涂有防水涂层获得，所述防水层1的内表面设有褶皱面5，防水层1的防水效果好，且易于延展。
如图4所示，所述保温层2包括由羊毛纤维和棉纤维编织而成的保温面料21，所述保温面料21的内表面设有椭球凸起点22，羊毛纤维和棉纤维的保暖效果好，能大幅度的降低热量的损耗。
一种制备上述防钻绒保暖防水羽绒服面料的方法，其制备方法包括：
S1：将超细竹炭纤维43浸泡在搅拌容器中，并分批次定量添加银纳米颗粒44，放入由羊毛以及竹炭纤维制成的锁绒面料41，搅拌、晾干和整理制得锁绒层4；
S2：将透气面料31浸泡在带有热膨胀颗粒33的溶液中，加热搅拌，晾干制得透气层3；
S3：取带有椭球凸点的模板，热压在保温面料21的表面，并形成带有椭球凸起点22的保温面料21，即获得保温层2；
S4：利用热压技术将由在聚酯纤维外表面喷涂有防水涂层获得的防水层1、保温层2、透气层3和锁绒层4形成防钻绒保暖防水羽绒服面料；在热压过程中，透气层3内的热膨胀颗粒33受热膨胀，并形成熔融状态，并透过防水层1和透气层3，大大增强防水层1、保温层2和透气层3之间的粘附力度，使得该防钻绒保暖防水羽绒服面料的整体性好，并且当热膨胀颗粒33遇冷收缩时，会缩小透气面料31整体的内部孔隙，一方面避免热量的流失，同时具有良好的防钻绒效果，使得透气层3与防水层1、保温层2和锁绒层4之间协同效果好。
在步骤S1中，所述银纳米颗粒44至少分三批递加式添加，且前一次添加的用量是后一次添加用量的1.5倍，通过分批次的加入银纳米颗粒44，使得银纳米颗粒44和超细竹炭纤维43的吸附更加的均匀，避免银纳米颗粒44一次性投入，大量的银纳米颗粒44会附着在超细竹炭纤维43的外表面，降低其还原率，难以进一步的渗透至超细竹炭纤维43的内部，一方面导致上下层的超细竹炭纤维43吸附不均，另一方面加大了搅拌负担，影响超细竹炭纤维43和银纳米颗粒44的吸附效果。
在步骤S2中，所述加热温度区间范围在100℃，所述搅拌转速1500r/S。
在步骤S4中，所述热压温度区间范围为100℃。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。

Claims (10)

1.一种防钻绒保暖防水羽绒服面料，其特征在于：该面料由外而内依次包括防水层(1)、保温层(2)、透气层(3)和锁绒层(4)，所述锁绒层(4)包括由羊毛以及竹炭纤维制成的锁绒面料(41)，所述锁绒面料(41)的内表面设有椭球状的凹陷部(42)，凹陷部(42)的内部设有若干组呈锥形结构的超细竹炭纤维(43)，所述超细竹炭纤维(43)的内部设有球状的银纳米颗粒(44)。
2.根据权利要求1所述的一种防钻绒保暖防水羽绒服面料，其特征在于：所述超细竹炭纤维(43)通过机械分丝、软化脱胶、开松梳理、化学纺丝、一端捻压并断切1-2mm获得。
3.根据权利要求1所述的一种防钻绒保暖防水羽绒服面料，其特征在于：所述银纳米颗粒(44)以纯亲水无规共聚物poly的水相自组装体为模板，并加入纳米二氧化锗和橡胶混合制成的添加剂，搅拌并通过原位还原法制得的。
4.根据权利要求1所述的一种防钻绒保暖防水羽绒服面料，其特征在于：所述透气层(3)包括由苎麻纤维以及涤纶纤维制成的透气面料(31)，所述透气面料(31)的内表面设有凸起部(32)，所述透气面料(31)与锁绒面料(41)之间的相对面上设有热膨胀颗粒(33)。
5.根据权利要求1所述的一种防钻绒保暖防水羽绒服面料，其特征在于：所述保温层(2)包括由羊毛纤维和棉纤维编织而成的保温面料(21)，所述保温面料(21)的内表面设有椭球凸起点(22)。
6.根据权利要求1所述的一种防钻绒保暖防水羽绒服面料，其特征在于：所述防水层(1)由在聚酯纤维外表面喷涂有防水涂层获得，所述防水层(1)的内表面设有褶皱面(5)。
7.一种制备如权利要求1-6任一所述的防钻绒保暖防水羽绒服面料的方法，其特征在于：包括以下步骤：
S1：将超细竹炭纤维(43)浸泡在搅拌容器中，并分批次定量添加银纳米颗粒(44)，放入由羊毛以及竹炭纤维制成的锁绒面料(41)，搅拌、晾干和整理制得锁绒层(4)；
S2：将透气面料(31)浸泡在带有热膨胀颗粒(33)的溶液中，加热搅拌，晾干制得透气层(3)；
S3：取带有椭球凸点的模板，热压在保温面料(21)的表面，并形成带有椭球凸起点(22)的保温面料(21)，即获得保温层(2)；
S4：利用热压技术将由在聚酯纤维外表面喷涂有防水涂层获得的防水层(1)、保温层(2)、透气层(3)和锁绒层(4)形成防钻绒保暖防水羽绒服面料。
8.根据权利要求7所述的一种制备防钻绒保暖防水羽绒服面料的方法，其特征在于：在步骤S1中，所述银纳米颗粒(44)至少分三批递加式添加，且前一次添加的用量是后一次添加用量的1.5倍。
9.根据权利要求7所述的一种制备防钻绒保暖防水羽绒服面料的方法，其特征在于：在步骤S2中，所述加热温度为100-150℃，所述搅拌转速1500-2000r/S。
10.根据权利要求7所述的一种制备防钻绒保暖防水羽绒服面料的方法，其特征在于：在步骤S4中，所述热压温度为90-120℃。
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