CN115028362A - 一种高性能日用细瓷彩色釉 - Google Patents
一种高性能日用细瓷彩色釉 Download PDFInfo
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- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 56
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 30
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 21
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 19
- 239000004927 clay Substances 0.000 claims abstract description 16
- 239000010453 quartz Substances 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 16
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000005751 Copper oxide Substances 0.000 claims abstract description 15
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 15
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims abstract description 15
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 238000010304 firing Methods 0.000 abstract description 8
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 abstract description 3
- 230000008859 change Effects 0.000 abstract description 3
- 239000010459 dolomite Substances 0.000 abstract description 3
- 229910000514 dolomite Inorganic materials 0.000 abstract description 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 3
- 239000000454 talc Substances 0.000 abstract description 3
- 229910052623 talc Inorganic materials 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000009966 trimming Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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Abstract
本发明涉及一种高性能日用细瓷彩色釉,包括以下份数的原料:石英10‑20份、钾长石40‑50份、高温膨胀熔块20‑30份、粘土5‑8份、工业氧化锌2‑4份、方解石8‑10份、瓷粉5‑10份、硅酸锆6‑8份、氧化钕2‑3份、氧化镨4‑5份、氧化铜0.5‑0.8份、氧化铁4‑6份和氧化锰5‑8份。该高性能日用细瓷彩色釉,通过采用熔块取代部分方解石、白云石、滑石和碳酸钡,减少了气体发生对釉面光泽度和针孔的影响,提高了釉面平整光泽度,又选用优质稀土元素着色后提高了色釉的耐温性,发色鲜艳稳定,提高了抗火焰气氛变化能力,烧成温度可达到1330‑1340℃,可适用高性能日用细瓷产品上,从而有效的提高高性能日用细瓷产品的烧制质量。
Description
技术领域
本发明涉及陶瓷技术领域,具体为一种高性能日用细瓷彩色釉。
背景技术
陶瓷是中华文明史的一个重要的组成部分,随着陶瓷文化的发展及制备工艺的改进,以及人们生活水平的不断提高,对作为生活中重要组成部分的陶瓷制品的需要,已从过往单一的要求无毒,无害的高性能日用细瓷彩色釉,向色彩多元化、无毒和无害的高性能日用细瓷彩色釉转变。
现有的高性能日用细瓷彩色釉采用普通石英、钾钠长石、粘土、方解石、工业氧化锌、废瓷粉、硅酸锆和人工合成色剂进行混合研磨,混研万孔筛细度为0.01~0.03%,青坯施釉比重:1.45-1.55,再经过1300-1320℃的温度烧制而成,这样的加工方法细度偏粗,青坯施釉密度大,缺陷多,人工合成色剂温度在1270-1290℃,釉烧高温时(大于1300℃),色相发生分解变色,制得的产品釉面质量差,针孔多且粗糙,烧成温差窄,波动大与高性能日用细瓷适配性差,进而大大的降低了高性能日用细瓷烧制后成品的质量,故而提出一种高性能日用细瓷彩色釉。
发明内容
针对现有技术的不足,本发明提供了一种高性能日用细瓷彩色釉,具备有效提高高性能日用细瓷彩色釉的产品质量等优点,解决了现有的高性能日用细瓷彩色釉加工方法细度偏粗,青坯施釉密度大,缺陷多,人工合成色剂温度在1270-1290℃,釉烧高温时(大于1300℃),色相发生分解变色,制得的产品釉面质量差,针孔多且粗糙,烧成温差窄,波动大与高性能日用细瓷适配性差,进而大大的降低了高性能日用细瓷烧制后成品的质量的问题。
为实现上述目的,本发明提供如下技术方案:一种高性能日用细瓷彩色釉,包括以下份数的原料:石英10-20份、钾长石40-50份、高温膨胀熔块20-30份、粘土5-8份、工业氧化锌2-4份、方解石8-10份、瓷粉5-10份、硅酸锆6-8份、氧化钕2-3份、氧化镨4-5份、氧化铜0.5-0.8份、氧化铁4-6份和氧化锰5-8份。
进一步,所述石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份。
进一步,所述石英15份、钾长石45份、高温膨胀熔块25份、粘土6.5份、工业氧化锌3份、方解石9份、瓷粉7.5份、硅酸锆7份、氧化钕2.5份、氧化镨4.5份、氧化铜0.65份、氧化铁5份和氧化锰6.5份。
进一步,所述石英20份、钾长石50份、高温膨胀熔块30份、粘土8份、工业氧化锌4份、方解石10份、瓷粉10份、硅酸锆8份、氧化钕3份、氧化镨5份、氧化铜0.8份、氧化铁6份和氧化锰8份。
进一步,所述瓷粉5-10份的细度为100-140目。
与现有技术相比,本申请的技术方案具备以下有益效果:
该高性能日用细瓷彩色釉,通过采用熔块取代部分方解石、白云石、滑石和碳酸钡,减少了气体发生对釉面光泽度和针孔的影响,提高了釉面平整光泽度,又选用优质稀土元素着色后提高了色釉的耐温性,发色鲜艳稳定,提高了抗火焰气氛变化能力,烧成温度可达到1330-1340℃,可适用高性能日用细瓷产品上,从而有效的提高高性能日用细瓷产品的烧制质量。
具体实施方式
下面将结合本发明的实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例一,一种高性能日用细瓷彩色釉,包括以下份数的原料:石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份。
瓷粉5-10份的细度为100-140目。
一种高性能日用细瓷彩色釉,其制备方法包括以下步骤:
1)将制备需要的原料严格按照配方称量好备用;
2)将称取好的石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份装入球磨机,按照一定的料球水比例研磨至240目标准筛,原料筛余量为0.05-0.12%,经过筛,除铁,榨泥,炼制制成泥条或化浆制成泥浆备用;
3)将步骤2中备用的泥条滚压和塑压成所需器型或泥浆注浆成所需器型,得生坯,取坯干燥24~48小时,精修坯,经过洗水后对胚体进行干燥12-24小时,直到测得坯体的含水率小于3%,制得合格生坯;
4)将步骤3中的生坯装窑一次烧成,保温20~30分钟,再降温停窑,即得高性能日用细瓷彩色釉。
实施例二,一种高性能日用细瓷彩色釉,包括以下份数的原料:石英15份、钾长石45份、高温膨胀熔块25份、粘土6.5份、工业氧化锌3份、方解石9份、瓷粉7.5份、硅酸锆7份、氧化钕2.5份、氧化镨4.5份、氧化铜0.65份、氧化铁5份和氧化锰6.5份。
瓷粉5-10份的细度为100-140目。
一种高性能日用细瓷彩色釉,其制备方法包括以下步骤:
1)将制备需要的原料严格按照配方称量好备用;
2)将称取好的石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份装入球磨机,按照一定的料球水比例研磨至240目标准筛,原料筛余量为0.05-0.12%,经过筛,除铁,榨泥,炼制制成泥条或化浆制成泥浆备用;
3)将步骤2中备用的泥条滚压和塑压成所需器型或泥浆注浆成所需器型,得生坯,取坯干燥24~48小时,精修坯,经过洗水后对胚体进行干燥12-24小时,直到测得坯体的含水率小于3%,制得合格生坯;
4)将步骤3中的生坯装窑一次烧成,保温20~30分钟,再降温停窑,即得高性能日用细瓷彩色釉。
实施例三,一种高性能日用细瓷彩色釉,包括以下份数的原料:石英20份、钾长石50份、高温膨胀熔块30份、粘土8份、工业氧化锌4份、方解石10份、瓷粉10份、硅酸锆8份、氧化钕3份、氧化镨5份、氧化铜0.8份、氧化铁6份和氧化锰8份。
瓷粉5-10份的细度为100-140目。
一种高性能日用细瓷彩色釉,其制备方法包括以下步骤:
1)将制备需要的原料严格按照配方称量好备用;
2)将称取好的石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份装入球磨机,按照一定的料球水比例研磨至240目标准筛,原料筛余量为0.05-0.12%,经过筛,除铁,榨泥,炼制制成泥条或化浆制成泥浆备用;
3)将步骤2中备用的泥条滚压和塑压成所需器型或泥浆注浆成所需器型,得生坯,取坯干燥24~48小时,精修坯,经过洗水后对胚体进行干燥12-24小时,直到测得坯体的含水率小于3%,制得合格生坯;
4)将步骤3中的生坯装窑一次烧成,保温20~30分钟,再降温停窑,即得高性能日用细瓷彩色釉。
本发明的有益效果是:
通过采用熔块取代部分方解石、白云石、滑石和碳酸钡,减少了气体发生对釉面光泽度和针孔的影响,提高了釉面平整光泽度,又选用优质稀土元素着色后提高了色釉的耐温性,发色鲜艳稳定,提高了抗火焰气氛变化能力,烧成温度可达到1330-1340℃,可适用高性能日用细瓷产品上,从而有效的提高高性能日用细瓷产品的烧制质量。
需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。
Claims (5)
1.一种高性能日用细瓷彩色釉,其特征在于,包括以下份数的原料:石英10-20份、钾长石40-50份、高温膨胀熔块20-30份、粘土5-8份、工业氧化锌2-4份、方解石8-10份、瓷粉5-10份、硅酸锆6-8份、氧化钕2-3份、氧化镨4-5份、氧化铜0.5-0.8份、氧化铁4-6份和氧化锰5-8份。
2.根据权利要求1所述的一种高性能日用细瓷彩色釉,其特征在于:所述石英10份、钾长石40份、高温膨胀熔块20份、粘土5份、工业氧化锌2份、方解石8份、瓷粉5份、硅酸锆6份、氧化钕2份、氧化镨4份、氧化铜0.5份、氧化铁4份和氧化锰5份。
3.根据权利要求1所述的一种高性能日用细瓷彩色釉,其特征在于:所述石英15份、钾长石45份、高温膨胀熔块25份、粘土6.5份、工业氧化锌3份、方解石9份、瓷粉7.5份、硅酸锆7份、氧化钕2.5份、氧化镨4.5份、氧化铜0.65份、氧化铁5份和氧化锰6.5份。
4.根据权利要求1所述的一种高性能日用细瓷彩色釉,其特征在于:所述石英20份、钾长石50份、高温膨胀熔块30份、粘土8份、工业氧化锌4份、方解石10份、瓷粉10份、硅酸锆8份、氧化钕3份、氧化镨5份、氧化铜0.8份、氧化铁6份和氧化锰8份。
5.根据权利要求1所述的一种高性能日用细瓷彩色釉,其特征在于:所述瓷粉5-10份的细度为100-140目。
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