CN1150230C - 阻光性和抗冲击强度改善的耐气候树脂组合物 - Google Patents

阻光性和抗冲击强度改善的耐气候树脂组合物 Download PDF

Info

Publication number
CN1150230C
CN1150230C CNB998056650A CN99805665A CN1150230C CN 1150230 C CN1150230 C CN 1150230C CN B998056650 A CNB998056650 A CN B998056650A CN 99805665 A CN99805665 A CN 99805665A CN 1150230 C CN1150230 C CN 1150230C
Authority
CN
China
Prior art keywords
matrix
monomer
grafted
grafting
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB998056650A
Other languages
English (en)
Chinese (zh)
Other versions
CN1299381A (zh
Inventor
M・C・O・常
M·C·O·常
奥克莱尔
R·M·奥克莱尔
萨诺基
R·A·萨诺基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arlanxeo Canada Inc
Original Assignee
Bayer Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Corp filed Critical Bayer Corp
Publication of CN1299381A publication Critical patent/CN1299381A/zh
Application granted granted Critical
Publication of CN1150230C publication Critical patent/CN1150230C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
CNB998056650A 1998-05-01 1999-04-27 阻光性和抗冲击强度改善的耐气候树脂组合物 Expired - Fee Related CN1150230C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/071,089 1998-05-01
US09/071,089 US6187862B1 (en) 1998-05-01 1998-05-01 Weatherable resinous composition having improved opacity and impact strength

Publications (2)

Publication Number Publication Date
CN1299381A CN1299381A (zh) 2001-06-13
CN1150230C true CN1150230C (zh) 2004-05-19

Family

ID=22099182

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998056650A Expired - Fee Related CN1150230C (zh) 1998-05-01 1999-04-27 阻光性和抗冲击强度改善的耐气候树脂组合物

Country Status (12)

Country Link
US (1) US6187862B1 (enExample)
EP (1) EP1084166B1 (enExample)
JP (1) JP2002513825A (enExample)
KR (1) KR100593347B1 (enExample)
CN (1) CN1150230C (enExample)
AU (1) AU3766699A (enExample)
BR (1) BR9910096A (enExample)
CA (1) CA2329985C (enExample)
DE (1) DE69923449T2 (enExample)
ES (1) ES2235482T3 (enExample)
TW (1) TW402622B (enExample)
WO (1) WO1999057168A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100626954B1 (ko) * 2004-08-19 2006-09-20 주식회사 엘지화학 열가소성 투명수지 조성물 및 그 제조방법
KR100815995B1 (ko) 2006-06-08 2008-03-21 제일모직주식회사 저온 및 상온 내충격성과 착색성 및 내후성이 우수한ａｓａ 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물
KR100998875B1 (ko) 2008-10-29 2010-12-08 제일모직주식회사 저광 특성이 우수한 내후성 열가소성 수지 및 그 제조 방법
EP2308906A1 (en) 2009-10-07 2011-04-13 Styron Europe GmbH Impact-modified monovinylidene aromatic polymer having low rubber crosslinking
KR101286503B1 (ko) * 2009-12-31 2013-07-16 제일모직주식회사 저광 특성이 우수한 내후성 열가소성 수지 조성물 및 그 제조 방법
EP2341090B1 (en) 2009-12-31 2012-09-12 Cheil Industries Inc. Weatherable thermoplastic resin having excellent low gloss characteristic and method of preparing the same
KR20120076301A (ko) 2010-12-29 2012-07-09 제일모직주식회사 내열성과 내후성이 우수한 저광 열가소성 수지 조성물
KR101469263B1 (ko) 2011-12-22 2014-12-05 제일모직주식회사 열가소성 수지 조성물 및 그 성형품
JP5905115B2 (ja) * 2012-10-11 2016-04-20 エルジー・ケム・リミテッド 低温衝撃強度が向上したアルキルアクリレート−芳香族ビニル化合物−シアン化ビニル化合物共重合体及びそれを含むポリカーボネート組成物
CN103254365B (zh) * 2013-05-17 2015-03-25 合肥工业大学 一种采用水溶性氧化还原引发剂低温制备asa共聚物胶乳的方法
EP3000845A4 (en) * 2013-05-23 2016-06-29 Asahi Kasei Chemicals Corp THERMOPLASTIC RESIN COMPOSITION AND ARTICLES THEREOF
JP6322000B2 (ja) * 2014-03-11 2018-05-09 旭化成株式会社 熱可塑性樹脂組成物、その成形体、及びその製造方法
MX2021000725A (es) * 2018-07-24 2021-04-12 Ineos Styrolution Group Gmbh Copolimero de caucho de injerto de poliacrilato y composicion de moldeo termoplastica.

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL99388C (enExample) 1956-09-28
DE1260135B (de) 1965-01-05 1968-02-01 Basf Ag Schlagfeste thermoplastische Formmassen
DE1911882B2 (de) 1969-03-08 1975-04-17 Basf Ag, 6700 Ludwigshafen Schlagfeste thermoplastische Massen
JPS5953513A (ja) 1982-09-22 1984-03-28 Japan Synthetic Rubber Co Ltd 熱可塑性樹脂の製造方法
DE3421353A1 (de) 1984-06-08 1985-12-12 Bayer Ag, 5090 Leverkusen Pfropfpolymerisate mit matter oberflaeche
DE3447249A1 (de) 1984-12-22 1986-07-03 Bayer Ag, 5090 Leverkusen Kerbschlagzaehe thermoplastformmassen
DE3629150A1 (de) 1986-08-27 1988-03-10 Basf Ag Thermoplastische formmasse auf basis von abs
GB9007199D0 (en) * 1990-03-30 1990-05-30 Tioxide Group Plc Preparation of polymeric particles
DE4131728A1 (de) 1991-09-24 1993-03-25 Basf Ag Teilchenfoermiges pfropfcopolymerisat mit kern/schale-aufbau
DE69510093T3 (de) 1995-02-01 2005-07-07 Bayer Antwerpen N.V. Polymerblends mit verbesserter Färbbarkeit
DE19503545A1 (de) * 1995-02-03 1996-08-08 Basf Ag Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit
JP2853987B2 (ja) 1996-01-29 1999-02-03 奇美実業股▲分▼有限公司 スチレン系樹脂の製造方法

Also Published As

Publication number Publication date
AU3766699A (en) 1999-11-23
EP1084166A1 (en) 2001-03-21
TW402622B (en) 2000-08-21
CA2329985A1 (en) 1999-11-11
JP2002513825A (ja) 2002-05-14
ES2235482T3 (es) 2005-07-01
DE69923449D1 (de) 2005-03-03
BR9910096A (pt) 2000-12-26
US6187862B1 (en) 2001-02-13
KR20010043189A (ko) 2001-05-25
DE69923449T2 (de) 2005-12-29
CA2329985C (en) 2008-03-25
KR100593347B1 (ko) 2006-06-26
EP1084166B1 (en) 2005-01-26
CN1299381A (zh) 2001-06-13
WO1999057168A1 (en) 1999-11-11

Similar Documents

Publication Publication Date Title
JP2794032B2 (ja) スチレン系樹脂用のコアーシェル型耐衝撃性改良剤
JP2921612B2 (ja) 粒子状グラフトポリマー及びそれよりなる成形材料
CN1150230C (zh) 阻光性和抗冲击强度改善的耐气候树脂组合物
EP1010725A2 (en) Thermoplastic polycarbonate composition
AU3535099A (en) Resin composition containing multilayered graft polymer
US5932655A (en) Weatherable resinous composition having improved opacity and impact strength
JPH06157688A (ja) 粒状物のグラフト重合体および該グラフト重合体を含有する成形材料
CN1205240C (zh) 热塑性树脂及其制备方法
CN1168754C (zh) 具有改进尺寸稳定性和低光泽度的热塑性模塑组合物
EP1312641B1 (en) Transparent impact-resistant thermoplastic resin composition
TW200418917A (en) Transparent anti-shock resistant thermoplastic resin composition
JP2003335827A (ja) ゴム強化熱可塑性樹脂及びゴム強化熱可塑性樹脂組成物
US4886857A (en) Styrene based resin composition
JPS6173755A (ja) 熱可塑性樹脂組成物
JP3286550B2 (ja) ゴム変性スチレン系樹脂組成物
JP2648179B2 (ja) 耐衝撃性に優れたメタクリル樹脂キャスト板及びその製造方法
US5990240A (en) Rubber-containing resin composition and styrene resin composition containing the same
JP3625566B2 (ja) 熱可塑性樹脂組成物
HK1037649A (en) Weatherable resinous composition having improved opacity and impact strength
JPS6225176B2 (enExample)
JPH10298375A (ja) ゴム変性耐熱性スチレン系樹脂組成物
JPH09316138A (ja) ゴム状重合体ラテックス、ゴム強化ビニル系重合体、および熱可塑性重合体組成物
US20050154127A1 (en) Impact-resistant thermoplastic resin composition
US6072002A (en) Weatherable resinous composition
JPH0354134B2 (enExample)

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1037649

Country of ref document: HK

ASS Succession or assignment of patent right

Owner name: LANXESS CORPORATION

Free format text: FORMER OWNER: BAYER CORP., USA

Effective date: 20080328

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20080328

Address after: American Pennsylvania

Patentee after: Lanxess Inc.

Address before: American Pennsylvania

Patentee before: Miles Inc.

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20040519

Termination date: 20110427