CN114983917A - Soothing deep moisturizing emulsion and preparation method thereof - Google Patents
Soothing deep moisturizing emulsion and preparation method thereof Download PDFInfo
- Publication number
- CN114983917A CN114983917A CN202111661594.7A CN202111661594A CN114983917A CN 114983917 A CN114983917 A CN 114983917A CN 202111661594 A CN202111661594 A CN 202111661594A CN 114983917 A CN114983917 A CN 114983917A
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- CN
- China
- Prior art keywords
- soothing
- skin
- stirring
- emollient
- deep moisturizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000003756 stirring Methods 0.000 claims abstract description 61
- 239000003974 emollient agent Substances 0.000 claims abstract description 35
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- 239000002562 thickening agent Substances 0.000 claims abstract description 18
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- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229920000370 gamma-poly(glutamate) polymer Polymers 0.000 description 1
- 235000020710 ginseng extract Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 230000036548 skin texture Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/99—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from microorganisms other than algae or fungi, e.g. protozoa or bacteria
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- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A61K8/37—Esters of carboxylic acids
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A61K8/67—Vitamins
- A61K8/673—Vitamin B group
- A61K8/675—Vitamin B3 or vitamin B3 active, e.g. nicotinamide, nicotinic acid, nicotinyl aldehyde
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- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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Abstract
The invention relates to the technical field of cosmetics, and discloses a soothing deep moisturizing milk with an IPC (International patent medicine) classification number of A61K and a preparation method thereof, wherein the soothing deep moisturizing milk comprises the following preparation raw materials in percentage by weight: 8% of emollient, 6% of skin conditioner, 0.3% of emollient, 0.05% of essence, 10% of humectant, 0.5% of preservative, 0.0001% of pigment, 0.1% of thickener, 0.1% of neutralizer, 0.2% of emulsifier and the balance of water to 100%. The soothing deep moisturizing emulsion is prepared by mixing, stirring and homogenizing water, a humectant, a thickening agent, an emollient, a neutralizer, an emulsifier, a softening agent, a skin conditioner, essence, a pigment and a preservative, has excellent physicochemical stability, can deeply moisturize skin, repair damaged skin cells, improve skin elasticity and recover skin luster, simultaneously forms a breathable and permeable protective film on the surface of the skin, prolongs the moisturizing effect of the moisturizing emulsion, and has the effects of long-term moisturizing and soothing of the skin, and is fresh and cool in use without rubbing mud feel.
Description
Technical Field
The invention relates to the technical field of cosmetics, has an IPC classification number of A61K, and particularly relates to a soothing deep moisturizing milk and a preparation method thereof.
Background
The moisture factor content of the skin cuticle is reduced along with the change of the external temperature, the moisture content of oil and fat in the skin is reduced, the water and oil balance is broken, the surface layer of the skin has the phenomena of drying crack, wrinkle, relaxation, wrinkle and the like, a skin care product suitable for the skin is selected, the skin barrier can be reconstructed, the skin texture is repaired, the skin is kept moist and smooth, the skin moisture is increased, the moisture loss on the surface of the skin is prevented, and a moisture retention film is formed outside the skin to lock the moisture.
Patent CN201910335650.4 discloses a multifunctional plant extract lotion and a preparation method thereof, wherein the preparation raw materials include an emollient, a humectant, an emulsion thickener, an antioxidant, functional components and the like, and the prepared lotion has the effects of moisturizing, repairing skin barrier, whitening and the like, but has poor long-acting moisturizing effect.
Patent CN201811493126.1 discloses a peanut skin procyanidin winter skin cream and a preparation method thereof, the preparation raw materials comprise peanut skin procyanidin, stearic acid, liquid paraffin, lanolin, vaseline, glyceryl monostearate and the like, and the prepared skin cream has good moisturizing effect, is safe and does not irritate skin, the production cost is low, but the physicochemical stability is poor.
Therefore, the development of the moisturizing cream which can maintain the long-acting moistening of the skin and has stable physicochemical properties has an important effect on keeping the moisture of the skin.
Disclosure of Invention
The invention provides a soothing deep moisturizing milk, which comprises the following raw materials in percentage by weight: 8-15% of an emollient, 6-8% of a skin conditioner, 0.3-0.7% of an emollient, 0.05-0.12% of an essence, 10-15% of a humectant, 0.5-1.2% of a preservative, 0.0001-0.0005% of a pigment, 0.1-0.5% of a thickener, 0.1-0.5% of a neutralizer, 0.2-0.8% of an emulsifier, and the balance of water to 100%.
Preferably, the emollient comprises one or more of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, dimethicone/vinyl dimethicone crosspolymer, squalane, hydrolyzed protein, isooctyl palmitate, isopropyl myristate, and wheat germ oil;
further preferably, the emollient is a compound of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and squalane, and the mass ratio of the glycerol tri (ethyl hexanoate), the petrolatum, caprylic propyl heptyl ester, the polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and the squalane is 2-4: 0.3-1: 2-4: 4-6: 0.3-0.7;
preferably, the skin conditioning agent comprises one or more of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, OPUNTIA FICUS-INDICA (Opuntia FICUS-INDICA) stem extract, beta-glucan, sodium hyaluronate, lactobacillus/soy milk fermentation product filtrate, nicotinamide, shea butter, ginseng extract, and gentian extract;
further preferably, the skin conditioning agent is PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, stem extract of Opuntia FICUS-INDICA (Opuntia INDICA), beta-glucan, sodium hyaluronate, and a complex formulation of lactobacillus/soymilk fermentation product filtrate, wherein the mass ratio of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, stem extract of Opuntia FICUS-INDICA (Opuntia us INDICA), beta-glucan, sodium hyaluronate, lactobacillus/soymilk fermentation product filtrate is 0.4-0.7: 0.3-0.7: 0.05-0.3: 0.05-0.3: 0.1-0.4: 0.4-0.8: 0.05-0.3: 0.8-1.5: 1-1.5: 0.05-0.3: 0.5-1.2;
preferably, the emollient comprises one of isostearic acid, triglyceride, phospholipid, and isopropyl lanolate;
further preferably, the emollient is isostearic acid;
preferably, the essence is one of orchid essence, jasmine essence and lavender essence;
preferably, the humectant comprises one or more of butanediol, propylene glycol, dipropylene glycol, glycerol, caprylyl glycol, glycerol acrylate/acrylic acid copolymer, rhamnose, mannose, sorbitol and gamma-sodium polyglutamate;
preferably, the humectant is a compound of butanediol, propylene glycol, dipropylene glycol, glycerol, caprylyl glycol and a glycerol acrylate/acrylic acid copolymer, and the mass ratio of the butanediol, the propylene glycol, the dipropylene glycol, the glycerol, the caprylyl glycol and the glycerol acrylate/acrylic acid copolymer is 1-3: 1-3: 2-4: 1-3: 0.1-0.3: 2-4;
preferably, the preservative comprises one of phenoxyethanol, propyl paraben, imidazolidinyl urea and DMDM hydantoin;
preferably, the pigment is CI 75470;
preferably, the thickening agent comprises one or more of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, acryloyl dimethyl ammonium taurate/VP copolymer, PEG-55 propylene glycol oleate, PEG-150 pentaerythritol tetrastearate and PEG-200 glyceryl stearate;
more preferably, the thickener is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and acryloyl dimethyl taurate/VP copolymer, and the mass ratio of the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer to the acryloyl dimethyl taurate/VP copolymer is 0.1-0.3: 0.05-0.2;
preferably, the neutralizing agent comprises one of triethanolamine, potassium hydroxide and aminomethyl propanol;
preferably, the emulsifier comprises one or more of sodium acrylate/sodium acryloyldimethyl taurate copolymer, ceteareth-12, ceteareth-20, cetearyl glucoside, coco alcohol, coco glucoside and sorbitan monostearate;
further preferably, the emulsifier is a sodium acrylate/sodium acryloyldimethyl taurate copolymer.
The second aspect of the invention provides a preparation method of a soothing deep moisturizing milk, which comprises the following steps:
(1) adding water, humectant and thickener into a reaction device, mixing and stirring, homogenizing, continuously heating in the stirring and homogenizing process, stopping heating and keeping the temperature when the temperature in the reaction device reaches 75-85 ℃, and preparing a mixture a;
(2) adding the emollient, the neutralizer, the emulsifier and the emollient into another reaction device, stirring and heating, continuously heating in the stirring process, continuing stirring for 25-35min when the temperature of the reaction device is raised to 75-85 ℃, and then stopping stirring and preserving heat to prepare a mixture b;
(3) adding the mixture b into the mixture a, mixing and stirring, then adjusting the stirring speed, continuing stirring, and carrying out homogenization treatment to obtain a mixture c;
(4) and (5) adding the skin conditioner, the essence, the pigment and the preservative into the mixture c, mixing, stirring, homogenizing, regulating the stirring speed, continuing to stir uniformly, cooling to room temperature, and stopping stirring to obtain the skin conditioner.
Has the beneficial effects that:
(1) according to the invention, water, the humectant and the thickening agent are mixed to obtain a mixture a, the emollient, the neutralizer, the emulsifier and the emollient are mixed to obtain a mixture b, and the mixtures a and b are mixed with the skin conditioner, the essence, the pigment and the preservative to prepare the soothing deep moisturizing emulsion which has excellent physicochemical stability, can deeply moisturize the skin, repair damaged skin cells, improve the elasticity of the skin and restore the gloss of the skin, and meanwhile, a breathable and permeable protective film is formed on the surface of the skin to prolong the moisturizing effect of the moisturizing emulsion, so that the moisturizing emulsion has the effects of long-acting moistening and soothing of the skin, and is fresh and cool in use without rubbing the skin.
(2) The applicant finds that by adding the emollient, the complex formulation of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, dimethicone/vinyl dimethicone crosspolymer and squalane, the mass ratio of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, dimethicone/vinyl dimethicone crosspolymer and squalane is 2-4: 0.3-1: 2-4: 4-6: 0.3-0.7, wherein the skin conditioner is PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, stem extract of Opuntia FICUS-INDICA (OPUNTIA FICUS-INDICA), beta-glucan, sodium hyaluronate, and the complex formulation of lactobacillus/soybean milk fermentation product filtrate, and the mass ratio of the PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, stem extract of Opuntia FICUS-INDICA (OPUNTIA US-INDICA), beta-glucan, sodium hyaluronate, lactobacillus/soybean milk fermentation product filtrate is 0.4-0.7: 0.3-0.7: 0.05-0.3: 0.05-0.3: 0.1-0.4: 0.4-0.8: 0.05-0.3: 0.8-1.5: 1-1.5: 0.05-0.3: 0.5-1.2, the humectant is a compound of butanediol, propylene glycol, dipropylene glycol, glycerol, octylene glycol and a glycerol acrylate/acrylic acid copolymer, and the mass ratio of the butanediol, the propylene glycol, the dipropylene glycol, the glycerol, the octylene glycol and the glycerol acrylate/acrylic acid copolymer is 1-3: 1-3: 2-4: 1-3: 0.1-0.3: 2-4, the prepared soothing deep moisturizing emulsion has excellent physicochemical stability, active groups among long and short chain structure molecules in the emollient, the skin conditioner and the moisturizing agent can be tightly coated and combined through intermolecular force to form an aggregation structure, the physicochemical stability of the prepared soothing deep moisturizing emulsion is increased, when the moisturizing emulsion acts on the skin, the active ingredients are synergistic, the active ingredients permeate into the skin, the skin is moisturized deeply, damaged skin cells are repaired, the elasticity of the skin is improved, the skin luster is restored, and the skin is moisturized deeply, so that the skin is kept fine and smooth.
(3) According to the invention, water, a humectant and a thickening agent are mixed, stirred and homogenized to obtain a mixture a, the emollient, a neutralizer, an emulsifier and a softening agent are mixed, stirred and mixed to obtain a mixture b, the mixtures a and b are mixed, stirred and homogenized with a skin conditioner, essence, a pigment and a preservative to prepare the soothing deep moisturizing emulsion which has excellent physicochemical stability, can deeply moisturize skin, repair damaged skin cells, improve skin elasticity and restore skin luster, simultaneously forms a breathable and permeable protective film on the surface of the skin, prolongs the moisturizing effect of the moisturizing emulsion, is especially suitable for being used in autumn and winter, has the long-acting moisturizing and soothing effects, and is fresh and free of rubbing feeling when used.
Detailed Description
Example 1
Embodiment 1 provides a soothing deep moisturizing milk, which comprises the following preparation raw materials in percentage by weight: 8% of an emollient, 6% of a skin conditioner, 0.3% of a softening agent, 0.05% of an essence, 10% of a humectant, 0.5% of a preservative, 0.0001% of a pigment, 0.1% of a thickening agent, 0.1% of a neutralizing agent, 0.2% of an emulsifier, and the balance of water to 100%.
The emollient is a compound of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and squalane, and the mass ratio of the glycerol tri (ethyl hexanoate), the petrolatum, the caprylic propyl heptyl ester, the polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and the squalane is 2: 0.3: 2: 4: 0.3, Triglycerol (ethyl hexanoate) is available from Yihui International trade Co., Ltd, petrolatum CAS number 8009-03-8, propylheptyl octanoate is available from COGNIS, dimethicone/vinyl dimethicone crosspolymer is available from Guangzhou Maxim Fine chemical Co., Ltd, squalane CAS number 111-01-3;
the skin conditioner is a compound of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, biogel-1, cactus (Opuntiaficus-INDICA) stem extract, beta-glucan, sodium hyaluronate and lactobacillus/soybean milk fermentation product filtrate, and the mass ratio of the PEG-60 glyceryl isostearate, the phytosterol/octyldodecanol lauroyl glutamate, the allantoin, the tranexamic acid, the panthenol, the bisabolol, the biogel-1, the cactus (Opuntiaficus-INDICA) stem extract, the beta-glucan, the sodium hyaluronate and the lactobacillus/soybean milk fermentation product filtrate is 0.4: 0.3: 0.05: 0.05: 0.1: 0.4: 0.05: 0.8: 1: 0.05: 0.5 PEG-60 glyceryl isostearate, available from NIHON EMULSION, phytosterol/octyldodecanol lauroyl glutamate, available from AJINOMOTO Co., Inc., allantoin CAS No. 97-59-6, tranexamic CAS No. 701-54-2, panthenol CAS No. 16485-10-2, bisabolol CAS No. 515-69-5, bioglycan-1 available from mibellel AG, cactus (OPUNTIA FICUS-INDICA) stem extract available from Guangzhou leads trade, Cactus latin, named Opuntiasatricta (Haw.) Haw.var.dillenii (Ker-Gawl.) Benson, beta-glucan available from SK BIOLAND, sodium hyaluronate CAS No. 9067-32-7, and lactobacillus/fermentation product filtrate available from Biyan;
the emollient is isostearic acid, and the CAS number of the isostearic acid is 22890-21-7;
the essence is orchid essence, and the orchid essence is purchased from France Aiqile essence and spice companies;
the humectant is a compound of butanediol, propylene glycol, dipropylene glycol, glycerol, caprylyl glycol and a glycerol acrylate/acrylic acid copolymer, and the mass ratio of the butanediol, the propylene glycol, the dipropylene glycol, the glycerol, the caprylyl glycol and the glycerol acrylate/acrylic acid copolymer is 1: 1: 2: 1: 0.1: 2, butanediol CAS No. 19132-06-0, propylene glycol CAS No. 57-55-6, dipropylene glycol CAS No. 110-98-5, glycerol CAS No. 56-81-5, octylene glycol CAS No. 1117-86-8, glycerol acrylate/acrylic acid copolymer available from Ashland;
the preservative is phenoxyethanol, and the CAS number of the phenoxyethanol is 122-99-6;
the PIGMENT is CI 75470, CI 75470 is purchased from TOSHHIKI PIGMENT CO., LTD.;
the thickening agent is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and an ammonium acryloyl dimethyl taurate/VP copolymer, and the mass ratio of the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer to the ammonium acryloyl dimethyl taurate/VP copolymer is 0.1: 0.05, acrylic/C10-30 alkanol acrylate crosspolymer from Noveon, ammonium acryloyldimethyltaurate/VP copolymer from Guangzhou brocade chemical trade company Limited;
the neutralizer is triethanolamine which is purchased from BP CHEMICALS;
the emulsifier is sodium acrylate/sodium acryloyldimethyl taurate copolymer, and the sodium acrylate/sodium acryloyldimethyl taurate copolymer is purchased from SEPPIC.
The second aspect of the invention provides a preparation method of a soothing deep moisturizing milk, which comprises the following steps:
(1) adding water, humectant and thickener into the reaction device, mixing and stirring for 40min at the stirring speed of 4000r/min, homogenizing for 4min, continuously heating during stirring and homogenizing, and stopping heating and heat preservation when the temperature in the reaction device reaches 75 ℃ to obtain a mixture a;
(2) adding the emollient, the neutralizer, the emulsifier and the emollient into another reaction device, stirring and heating at the stirring speed of 400r/min, continuously heating during stirring, and stopping stirring and keeping the temperature after continuously stirring for 15min when the temperature of the reaction device rises to 75 ℃ to obtain a mixture b;
(3) adding the mixture b into the mixture a, mixing and stirring at the stirring speed of 400r/min for 15min, then adjusting the stirring speed to 4000r/min, continuing stirring for 25min, and then homogenizing for 7min to obtain a mixture c;
(4) and (3) when the temperature of the mixture c is reduced to 40 ℃, adding a skin conditioner, an essence, a pigment and a preservative, adjusting the stirring speed to 3000r/min, continuously stirring for 15min, homogenizing for 4min, adjusting the stirring speed to 400r/min, continuously stirring for 15min, cooling to room temperature, and stopping stirring to obtain the skin conditioner, essence, pigment and preservative.
Example 2
Embodiment 2 provides a soothing deep moisturizing milk, which is prepared from the following raw materials in percentage by weight: 12% of emollient, 5.2% of skin conditioner, 0.5% of emollient, 0.08% of essence, 12.2% of humectant, 0.8% of preservative, 0.0002% of pigment, 0.3% of thickener, 0.2% of neutralizer, 0.5% of emulsifier and the balance of water to 100%.
The emollient is a compound of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and squalane, and the mass ratio of the glycerol tri (ethyl hexanoate), the petrolatum, the caprylic propyl heptyl ester, the polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer and the squalane is 3: 0.5: 3: 5: 0.5, Triglycerol (ethyl hexanoate) is available from Yihui International trade Co., Ltd, petrolatum CAS number 8009-03-8, propylheptyl octanoate is available from COGNIS, dimethicone/vinyl dimethicone crosspolymer is available from Guangzhou Maxim Fine chemical Co., Ltd, squalane CAS number 111-01-3;
the skin conditioner is a compound of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, biogel-1, cactus (Opuntiaficus-INDICA) stem extract, beta-glucan, sodium hyaluronate and lactobacillus/soybean milk fermentation product filtrate, and the mass ratio of the PEG-60 glyceryl isostearate, the phytosterol/octyldodecanol lauroyl glutamate, the allantoin, the tranexamic acid, the panthenol, the bisabolol, the biogel-1, the cactus (Opuntiaficus-INDICA) stem extract, the beta-glucan, the sodium hyaluronate and the lactobacillus/soybean milk fermentation product filtrate is 0.4: 0.3: 0.1: 0.1: 0.2: 0.6: 0.1: 1: 1.2: 0.1: 0.8 PEG-60 glyceryl isostearate, available from NIHON EMULSION, phytosterol/octyldodecanol lauroyl glutamate, available from AJINOMOTO Co., Inc., allantoin CAS No. 97-59-6, tranexamic CAS No. 701-54-2, panthenol CAS No. 16485-10-2, bisabolol CAS No. 515-69-5, biosaccharide gum-1 available from mibellele AG, Opuntia FICUS-INDICA stem extract available from Guangzhou trade company, Opuntia Lactuca having Opuntias tricta (Haw.) Haw.var.dilleii (Ker-Gawl.) Benson, beta-glucan available from SK BIOLAND, sodium hyaluronate CAS No. 9067-32-7, Lactobacillus lactis/fermented product filtrate available from French Biyan juice;
the emollient is isostearic acid, and the CAS number of the isostearic acid is 22890-21-7;
the essence is orchid essence, and the orchid essence is purchased from France Aiqile essence and spice company;
the humectant is a compound of butanediol, propylene glycol, dipropylene glycol, glycerol, caprylyl glycol and a glycerol acrylate/acrylic acid copolymer, and the mass ratio of the butanediol, the propylene glycol, the dipropylene glycol, the glycerol, the caprylyl glycol and the glycerol acrylate/acrylic acid copolymer is 2: 2: 3: 2: 0.2: 3, butanediol CAS No. 19132-06-0, propylene glycol CAS No. 57-55-6, dipropylene glycol CAS No. 110-98-5, glycerol CAS No. 56-81-5, octylene glycol CAS No. 1117-86-8, glycerol acrylate/acrylic acid copolymer available from Ashland;
the preservative is phenoxyethanol, and the CAS number of the phenoxyethanol is 122-99-6;
the PIGMENT is CI 75470, CI 75470 is purchased from TOSHIKI PIGMENT CO., LTD.;
the thickening agent is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and an ammonium acryloyl dimethyl taurate/VP copolymer, and the mass ratio of the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer to the ammonium acryloyl dimethyl taurate/VP copolymer is 0.2: 0.1, acrylic/C10-30 alkanol acrylate crosspolymer from Noveon, Acryloyldimethyl ammonium taurate/VP copolymer from Guangzhou brocade chemical trade, Inc.;
the neutralizer is triethanolamine which is purchased from BP CHEMICALS;
the emulsifier is sodium acrylate/sodium acryloyldimethyl taurate copolymer, and the sodium acrylate/sodium acryloyldimethyl taurate copolymer is purchased from SEPPIC.
The second aspect of the invention provides a preparation method of a soothing deep moisturizing milk, which comprises the following steps:
(1) adding water, humectant and thickener into the reaction device, mixing and stirring for 45min at a stirring speed of 6000r/min, homogenizing for 6min, continuously heating during stirring and homogenizing, and stopping heating and heat preservation when the temperature in the reaction device reaches 80 ℃ to obtain a mixture a;
(2) adding the emollient, the neutralizer, the emulsifier and the emollient into another reaction device, stirring and heating at the stirring speed of 550r/min, continuously heating during stirring, and stopping stirring and keeping the temperature after continuously stirring for 25min when the temperature of the reaction device rises to 80 ℃ to obtain a mixture b;
(3) adding the mixture b into the mixture a, mixing and stirring at the stirring speed of 550r/min for 25min, then adjusting the stirring speed to 5000r/min, continuing stirring for 35min, and then homogenizing for 9min to obtain a mixture c;
(4) and when the temperature of the mixture c is reduced to 50 ℃, adding a skin conditioner, an essence, a pigment and a preservative, adjusting the stirring speed to 4500r/min, continuously stirring for 20min, homogenizing for 6min, adjusting the stirring speed to 500r/min, continuously stirring for 20min, cooling to room temperature, and stopping stirring to obtain the skin conditioner, essence, pigment and preservative.
Comparative example 1
The specific implementation mode is the same as that of example 2, except that the emollient is a compound of glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, polydimethylsiloxane/vinyl polydimethylsiloxane crosspolymer and squalane, and the mass ratio of the glycerol tri (ethyl hexanoate), petrolatum, caprylic propyl heptyl ester, the polydimethylsiloxane/vinyl polydimethylsiloxane crosspolymer and squalane is 0.5: 0.3: 2: 0.4: 0.1, Triglycerol (ethyl hexanoate) is available from Yihui International trade company, Inc., petrolatum CAS number 8009-03-8, propylheptyl octanoate is available from COGNIS, polydimethylsiloxane/vinyl polydimethylsiloxane crosspolymer is available from Guangzhou Maxim Fine chemical Co., Ltd., squalane CAS number 111-01-3.
Comparative example 2
The specific implementation manner is the same as that of example 2, except that the skin conditioner is a mixture of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, bioglycan-1, cactus (Opuntia FICUS-INDICA) stem extract, beta-glucan, sodium hyaluronate, and lactobacillus/soybean milk fermentation product filtrate, and the mass ratio of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, biogan-1, cactus (Opuntia FICUS-INDICA) stem extract, beta-glucan, sodium hyaluronate, lactobacillus/soybean milk fermentation product filtrate is 0.1: 0.3: 0.05: 0.02: 0.1: 0.2: 0.05: 0.2: 1: 0.05: 0.2 PEG-60 glyceryl isostearate, available from NIHON EMULSION, phytosterol/octyldodecanol lauroyl glutamate, available from AJINOMOTO Co., Inc., allantoin CAS No. 97-59-6, tranexamic CAS No. 701-54-2, panthenol CAS No. 16485-10-2, bisabolol CAS No. 515-69-5, bioglycan gum-1 available from mibellel AG, cactus (Opuntiaficus-INDICA) stem extract available from Guangzhou trade, Opuntiasatricta (Haw.) Haw.var.dillenii (Ker-wl.) Benson, beta-glucan available from SKBIOLAND, sodium hyaluronate CAS No. 9067-32-7, and Lactobacillus/fermented product filtrate available from Bijie bean milk.
Comparative example 3
The specific implementation manner is the same as that in example 2, except that the humectant is a mixture of butylene glycol, propylene glycol, dipropylene glycol, glycerin, caprylyl glycol and a glycerin acrylate/acrylic acid copolymer, and the mass ratio of the butylene glycol, the propylene glycol, the dipropylene glycol, the glycerin, the caprylyl glycol and the glycerin acrylate/acrylic acid copolymer is 1: 0.2: 0.3: 0.5: 0.1: 0.5, butanediol CAS No. 19132-06-0, propylene glycol CAS No. 57-55-6, dipropylene glycol CAS No. 110-98-5, glycerol CAS No. 56-81-5, octylene glycol CAS No. 1117-86-8, and glycerol acrylate/acrylic acid copolymer available from Ashland.
And (3) performance testing: physical and chemical stability, and skin hydration degree
1. Physical and chemical properties:
the emulsions prepared in examples 1-2 and comparative examples 1-3 were tested for cold stability, heat stability, appearance, pH according to the standard GB _ T29665-.
2. Skin hydration and transdermal water loss (Note: please supplement the following efficacy test results)
Taking 50 volunteers aged 17-40 and having close skin color L value, dividing into 5 groups, marking as the first to fifth groups, 10 people in each group, examples 1-2 and comparative examples 1-3, preparing 10 parts in parallel, using the soothing deep moisturizing milk prepared in example 1 by the first group of volunteers, repeating until the fifth group of volunteers uses the soothing deep moisturizing milk prepared in example 3, coating the moisturizing milk on cheeks of each group of volunteers to avoid the skin around eyes, using the moisturizing milk once in the morning and at night for 4 weeks, testing the skin hydration degree by a technician by a Corneometer CM85, testing the initial skin hydration degree before the moisturizing milk is used by each group of volunteers (taking the average value of the initial skin hydration degree before the moisturizing milk is used by each group of volunteers), and testing the skin hydration degree after the moisturizing milk is continuously used by each group of volunteers for 4 weeks (taking the average value of the initial skin hydration degree after the moisturizing milk is used by each group of volunteers), the test result shows that the moisturizing cream prepared in the embodiment 1-2 has excellent moisturizing effect and can obviously improve the skin hydration degree.
25 volunteers aged 17-40 years and having skin color L value close to each other were divided into 5 groups and recorded as the first to fifth groups, 5 individuals in each group, examples 1-2 and comparative examples 1-3, 5 parts of the soothing deep moisturizing cream prepared in example 1 was prepared in parallel, the soothing deep moisturizing cream prepared in example 1 was used by the first volunteer, the soothing deep moisturizing cream prepared in example 3 was used by the fifth volunteer, the moisturizing cream was applied to the cheek of each group of volunteer, the initial skin moisture content before the moisturizing cream was used by each group of volunteer was measured by a VaporMeter transdermal loss moisture tester and recorded as A 1 After each group of volunteers used the moisturizing cream for 10h, the skin water was testedThe content (average value of skin moisture content of each group of volunteers after using the moisturizing cream for 10 hours) is recorded as A 2 From the formula (A) 1 -A 2 )/A 1 The transdermal water loss (%) was calculated as 100%.
Claims (10)
1. The soothing deep moisturizing milk is characterized by comprising the following preparation raw materials in percentage by weight: 8-15% of emollient, 6-8% of skin conditioner, 0.3-0.7% of emollient, 0.05-0.12% of essence, 10-15% of humectant, 0.5-1.2% of preservative, 0.0001-0.0005% of pigment, 0.1-0.5% of thickener, 0.1-0.5% of neutralizer, 0.2-0.8% of emulsifier and the balance of water to 100%.
2. A soothing deep moisturizing emulsion according to claim 1, wherein the emollient comprises one or a combination of glycerol tri (ethyl hexanoate), petrolatum, propyl heptyl caprylate, dimethicone/vinyl dimethicone crosspolymer, squalane.
3. A soothing deep moisturizing milk according to claims 1 and 2, wherein the skin conditioning agent comprises one or more of PEG-60 glyceryl isostearate, phytosterol/octyldodecanol lauroyl glutamate, allantoin, tranexamic acid, panthenol, bisabolol, biosaccharide-1, opuntia ficus indica stem extract, β -glucan, sodium hyaluronate, lactobacillus/soy milk fermentation product filtrate.
4. A soothing deep moisturizing emulsion as in claim 1, wherein the emollient comprises one of isostearic acid, triglycerides, phospholipids, isopropyl lanolate.
5. The soothing deep moisturizing emulsion of claim 1, wherein the moisturizer comprises one or more of butylene glycol, propylene glycol, dipropylene glycol, glycerol, caprylyl glycol, glycerol acrylate/acrylic acid copolymer, rhamnose, mannose, sorbitol, and gamma-polyglutamate.
6. A soothing deep moisturizing lotion as claimed in claim 1, wherein the thickener comprises one or more of acrylic acid/C10-30 alkyl acrylate crosspolymer, ammonium acryloyldimethyl taurate/VP copolymer, PEG-55 propylene glycol oleate, PEG-150 pentaerythritol tetrastearate, PEG-200 glyceryl stearate.
7. The soothing deep moisturizing lotion of claim 1, wherein the neutralizing agent comprises one of triethanolamine, potassium hydroxide, aminomethyl propanol.
8. A soothing deep moisturizing milk according to claim 1, wherein the emulsifier comprises one or a combination of sodium acrylate/sodium acryloyldimethyl taurate copolymer, ceteareth-12, ceteareth-20, cetearyl glucoside, coco alcohol, coco glucoside, sorbitan monostearate.
9. A soothing deep moisturizing milk according to claim 8, wherein the emulsifier is a compound of sodium acrylate/sodium acryloyl dimethyl taurate copolymer, coco glucoside and cocol alcohol, and the mass ratio of the sodium acrylate/sodium acryloyl dimethyl taurate copolymer, the coco glucoside and the cocol alcohol is 1: 0.5-0.8: 0.2-0.4.
10. A method of preparing a soothing deep moisturizing milk according to any of claims 1-9 comprising the steps of:
(1) adding water, humectant and thickener into a reaction device, mixing and stirring, homogenizing, continuously heating in the stirring and homogenizing process, stopping heating and keeping the temperature when the temperature in the reaction device reaches 75-85 ℃, and preparing a mixture a;
(2) adding the emollient, the neutralizer, the emulsifier and the emollient into another reaction device, stirring and heating, continuously heating in the stirring process, continuously stirring for 25-35min when the temperature of the reaction device is raised to 75-85 ℃, and then stopping stirring and preserving heat to prepare a mixture b;
(3) adding the mixture b into the mixture a, mixing and stirring, then adjusting the stirring speed, continuing stirring, and carrying out homogenization treatment to obtain a mixture c;
(4) adding skin conditioner, essence, pigment, and antiseptic into the mixture c, mixing, stirring, homogenizing, adjusting stirring speed, stirring, cooling to room temperature, and stopping stirring.
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CN116602895A (en) * | 2023-06-26 | 2023-08-18 | 彭氏(惠州)实业发展有限公司 | Repairing emulsion and preparation method thereof |
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