CN114958472A - 一种绿色轮胎用st/ut钢帘线拉拔用润滑液 - Google Patents

一种绿色轮胎用st/ut钢帘线拉拔用润滑液 Download PDF

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CN114958472A
CN114958472A CN202210520441.9A CN202210520441A CN114958472A CN 114958472 A CN114958472 A CN 114958472A CN 202210520441 A CN202210520441 A CN 202210520441A CN 114958472 A CN114958472 A CN 114958472A
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steel cord
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黄河
倪自飞
王文凯
严淑君
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Nanjing Vocational University of Industry Technology NUIT
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Abstract

本发明公开了一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,包括以下组分:原料组成:摩擦特性改进剂6‑12份、复合羧酸6‑11份、偶合剂10‑15份、表面活性剂4‑8份、二亚油酸棕榈酸甘油酯25‑36份、油酸三乙醇胺20‑30份、异噻唑啉酮10‑14份、聚丙烯酰胺5‑8份、三聚氰胺14‑18份、抗氧化剂2‑6份、水基润滑剂10‑20份、甲基纤维素10‑25份、醋酸丁脂15‑25份、醋酸钠5‑10份和离子水10‑20份。本发明通过设置摩擦特性改进剂、复合羧酸、偶合剂、表面活性剂的成分,使润滑液的润滑性能周期长、生产稳定、耐高压、高温和冷却效果好的目的,再通过二亚油酸棕榈酸甘油酯、油酸三乙醇胺、异噻唑啉酮、聚丙烯酰胺和三聚氰胺,使润滑液具备良好的耐燃性和的降解能力效果。

Description

一种绿色轮胎用ST/UT钢帘线拉拔用润滑液
技术领域
本发明涉及润滑液技术领域,具体为一种绿色轮胎用ST/UT钢帘线拉拔用润滑液。
背景技术
ST/UT钢帘线由优质高碳钢经表面镀层、拉拔、加捻制成,是轮胎主要骨架材料之一,ST/UT钢帘线在加工时需要通过金属拉拔步骤,金属拉拔是金属的一种常见的成型方式,且属于无切削的成型方式,可以获得高精度、高光泽度的成型产品,在金属拉拔时,需要较好的润滑油来保证拉丝精度,而润滑液在使用时容易出现异味,同时ST/UT钢帘线拉拔用润滑液的润滑度较差,在拉拔时与模具摩擦力较大,损毁拉拔模具。
发明内容
为解决上述背景技术中提出的问题,本发明的目的在于提供一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,具备可以保证润滑度的优点,解决了ST/UT钢帘线拉拔用润滑液无法保证润滑度的问题。
为实现上述目的,本发明提供如下技术方案:一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,包括以下组分:
原料组成:摩擦特性改进剂6-12份、复合羧酸6-11份、偶合剂10-15份、表面活性剂4-8份、二亚油酸棕榈酸甘油酯25-36份、油酸三乙醇胺20-30份、异噻唑啉酮10-14份、聚丙烯酰胺5-8份、三聚氰胺14-18份、抗氧化剂2-6份、水基润滑剂10-20份、甲基纤维素10-25份、醋酸丁脂15-25份、醋酸钠5-10份和离子水10-20份。
作为本发明优选的,所述原料组成,摩擦特性改进剂为甲酰胺磷酸盐和乙二胺磷酸盐其中的一种与鲸蜡醇磷酸酯和脂肪醇醚磷酸酯其中的一种的混合而成。
作为本发明优选的,所述原料组成,复合羧酸为妥尔油和精制妥尔油其中的一种与二聚酸和米糠油酸其中一种的混合而成。
作为本发明优选的,所述原料组成,偶合剂为甘油和聚合甘油混合而成。
作为本发明优选的,所述原料组成,表面活性剂为油醇聚氧乙烯醚或者脂肪胺聚氧乙烯醚。
作为本发明优选的,所述原料组成,抗氧化剂为二叔丁基对甲酚、硫代双苯硫酚、二叔丁基酚和烷基二苯胺中的两种或多种的混合而成。
作为本发明优选的,所述原料组成,水基润滑剂为石油硫磺盐或者有机硅制成。
作为本发明优选的,包括以下步骤:
S1:使用者准备一个加温混合装置,通过先将离子水倒入加温混合装置的内部,通过加温混合装置将温度加温到75℃,边搅拌边依次加入摩擦特性改进剂、复合羧酸、偶合剂和表面活性剂,维持75-80℃搅拌反应90min,然后执行S2;
S2:准备一个混合器,将二亚油酸棕榈酸甘油酯和油酸三乙醇胺倒入进行混合,完成后将二亚油酸棕榈酸甘油酯和油酸三乙醇胺混合物抽出,再将异噻唑啉酮、聚丙烯酰胺和三聚氰胺倒入混合器的内部进行混合,完成后将异噻唑啉酮、聚丙烯酰胺和三聚氰胺混合物抽出,然后执行S3;
S3:将抗氧化剂、水基润滑剂、甲基纤维素、醋酸丁脂和醋酸钠倒入加温混合器的内部,使抗氧化剂、水基润滑剂、甲基纤维素、醋酸丁脂和醋酸钠与摩擦特性改进剂、复合羧酸、偶合剂和表面活性剂混合,然后将二亚油酸棕榈酸甘油酯和油酸三乙醇胺混合物与异噻唑啉酮、聚丙烯酰胺和三聚氰胺混合物倒入加温混合装置,维持75-80℃搅拌反应100min,形成润滑剂。
与现有技术相比,本发明的有益效果如下:
本发明通过设置摩擦特性改进剂、复合羧酸、偶合剂、表面活性剂的成分,使润滑液的润滑性能周期长、生产稳定、耐高压、高温和冷却效果好的目的,再通过二亚油酸棕榈酸甘油酯、油酸三乙醇胺、异噻唑啉酮、聚丙烯酰胺和三聚氰胺,使润滑液具备良好的耐燃性和的降解能力效果,抗氧化剂、水基润滑剂、甲基纤维素、醋酸丁脂、醋酸钠份和离子水的成分,使润滑剂被环保的效果,防止润滑剂污染周围环境,从而达到了可以保证润滑度的效果,该绿色轮胎用ST/UT钢帘线拉拔用润滑液,具备可以保证润滑度的优点,解决了ST/UT钢帘线拉拔用润滑液无法保证润滑度的问题,润滑液在使用时不会出现异味,同时ST/UT钢帘线拉拔用润滑液的润滑度较好,在拉拔时与模具摩擦力小,不会损毁拉拔模具。
具体实施方式
下面将结合本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例一
一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,包括以下组分:
原料组成:摩擦特性改进剂6份、复合羧酸6份、偶合剂10份、表面活性剂4份、二亚油酸棕榈酸甘油酯25份、油酸三乙醇胺20份、异噻唑啉酮10份、聚丙烯酰胺5份、三聚氰胺14份、抗氧化剂2份、水基润滑剂10份、甲基纤维素10份、醋酸丁脂15份、醋酸钠5份和离子水10份。
实施例二
一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,包括以下组分:
原料组成:摩擦特性改进剂9份、复合羧酸8.5份、偶合剂12.5份、表面活性剂6份、二亚油酸棕榈酸甘油酯30.5份、油酸三乙醇胺25份、异噻唑啉酮12份、聚丙烯酰胺6.5份、三聚氰胺16份、抗氧化剂4份、水基润滑剂15份、甲基纤维素17.5份、醋酸丁脂20份、醋酸钠8份和离子水15份。
实施例三
一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,包括以下组分:
原料组成:摩擦特性改进剂12份、复合羧酸11份、偶合剂15份、表面活性剂8份、二亚油酸棕榈酸甘油酯36份、油酸三乙醇胺30份、异噻唑啉酮14份、聚丙烯酰胺8份、三聚氰胺18份、抗氧化剂6份、水基润滑剂20份、甲基纤维素25份、醋酸丁脂25份、醋酸钠10份和离子水20份。
需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。

Claims (8)

1.一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:包括以下组分:
原料组成:摩擦特性改进剂6-12份、复合羧酸6-11份、偶合剂10-15份、表面活性剂4-8份、二亚油酸棕榈酸甘油酯25-36份、油酸三乙醇胺20-30份、异噻唑啉酮10-14份、聚丙烯酰胺5-8份、三聚氰胺14-18份、抗氧化剂2-6份、水基润滑剂10-20份、甲基纤维素10-25份、醋酸丁脂15-25份、醋酸钠5-10份和离子水10-20份。
2.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,摩擦特性改进剂为甲酰胺磷酸盐和乙二胺磷酸盐其中的一种与鲸蜡醇磷酸酯和脂肪醇醚磷酸酯其中的一种的混合而成。
3.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,复合羧酸为妥尔油和精制妥尔油其中的一种与二聚酸和米糠油酸其中一种的混合而成。
4.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,偶合剂为甘油和聚合甘油混合而成。
5.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,表面活性剂为油醇聚氧乙烯醚或者脂肪胺聚氧乙烯醚。
6.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,抗氧化剂为二叔丁基对甲酚、硫代双苯硫酚、二叔丁基酚和烷基二苯胺中的两种或多种的混合而成。
7.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液,其特征在于:所述原料组成,水基润滑剂为石油硫磺盐或者有机硅制成。
8.根据权利要求1所述的一种绿色轮胎用ST/UT钢帘线拉拔用润滑液的制备方法,其特征在于:包括以下步骤:
S1:使用者准备一个加温混合装置,通过先将离子水倒入加温混合装置的内部,通过加温混合装置将温度加温到75℃,边搅拌边依次加入摩擦特性改进剂、复合羧酸、偶合剂和表面活性剂,维持75-80℃搅拌反应90min,然后执行S2;
S2:准备一个混合器,将二亚油酸棕榈酸甘油酯和油酸三乙醇胺倒入进行混合,完成后将二亚油酸棕榈酸甘油酯和油酸三乙醇胺混合物抽出,再将异噻唑啉酮、聚丙烯酰胺和三聚氰胺倒入混合器的内部进行混合,完成后将异噻唑啉酮、聚丙烯酰胺和三聚氰胺混合物抽出,然后执行S3;
S3:将抗氧化剂、水基润滑剂、甲基纤维素、醋酸丁脂和醋酸钠倒入加温混合器的内部,使抗氧化剂、水基润滑剂、甲基纤维素、醋酸丁脂和醋酸钠与摩擦特性改进剂、复合羧酸、偶合剂和表面活性剂混合,然后将二亚油酸棕榈酸甘油酯和油酸三乙醇胺混合物与异噻唑啉酮、聚丙烯酰胺和三聚氰胺混合物倒入加温混合装置,维持75-80℃搅拌反应100min,形成润滑剂。
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