CN106010758A - 一种汽车机械齿轮润滑油及其制备方法 - Google Patents

一种汽车机械齿轮润滑油及其制备方法 Download PDF

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CN106010758A
CN106010758A CN201610470686.XA CN201610470686A CN106010758A CN 106010758 A CN106010758 A CN 106010758A CN 201610470686 A CN201610470686 A CN 201610470686A CN 106010758 A CN106010758 A CN 106010758A
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于秀涛
介石磊
孙玉凤
王雪
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Huanghe Jiaotong University
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Abstract

本发明提供了一种汽车机械齿轮润滑油，由基础油80‑120份、抗氧化剂4‑12份、十二烷基苯磺酸钠1‑3份、高碳润滑石墨1‑12份、抗结胶添加剂3‑4份、清洁添加剂3‑4份、2，6‑二叔丁基对甲酚2‑8份、柠檬酸钠1‑9份、盐酸2‑8份、硫酸丁辛醇锌盐1‑6份、烯基二丁酸1‑3份、牛脂4‑9份、妥尔油8‑15份、硼酸脂5‑8份、土耳其油6‑11份、磷酸二氢钾3‑9份、二氯甲烷2‑10份、单丁二酰亚胺3‑8份、失水山梨醇单油酸酯1‑3份、三乙醇胺3‑9份和防锈剂4‑12份制成。该润滑油具有良好的抗氧化防腐性、防锈性、高温稳定性、抗乳化性、生物可降解性好、价格相对传统润滑油较低的特点。

Description

一种汽车机械齿轮润滑油及其制备方法
技术领域
本发明属于石油化工技术领域，具体涉及一种汽车机械齿轮润滑油及其制备方法。
背景技术
润滑油是用在各种类型汽车、机械设备上以减少摩擦，保护机械及加工件的液体或半固体润滑剂，主要起润滑、冷却、防锈、清洁、密封和缓冲等作用。
近年来，随着我国经济的高速发展，润滑油已成为交通运输及工业机械设备必不可免的“保护液”。同时，机械齿轮油是以矿物基础油或合成基础油为主，加入抗磨剂和油性剂调制而成的一种重要的润滑油，用于各种齿轮传动装置，以防止齿面磨损、擦伤、烧结等，延长其使用寿命，提高传递功率效率，减少功率损失。齿轮油应具有良好的抗磨、耐负荷性能和合适的粘度。此外，还应具有良好的热氧化安定性、抗泡性、水分离性能和防锈性能，即使在很高的操作温度和负荷下，仍能保证传动系统的各个部件不受磨损。行业的高速发展与环保对润滑油性能提出了更加苛刻的要求。
发明内容
为此，本发明提供了一种汽车机械齿轮润滑油，以解决现有技术中存在的问题。
具体的，本发明提供的汽车机械齿轮润滑油，由以下重量份数计的原料制成：基础油80-120份、抗氧化剂4-12份、十二烷基苯磺酸钠1-3份，高碳润滑石墨1-12份，抗结胶添加剂3-4份、清洁添加剂3-4份、2，6-二叔丁基对甲酚2-8份、柠檬酸钠1-9份、盐酸2-8份、硫酸丁辛醇锌盐1-6份、烯基二丁酸1-3份、牛脂4-9份，妥尔油8-15份，硼酸脂5-8份，土耳其油6-11份、磷酸二氢钾3-9份、二氯甲烷2-10份、单丁二酰亚胺3-8份、失水山梨醇单油酸酯1-3份、三乙醇胺3-9份、防锈剂4-12份。
优选地，所述基础油为聚а-烯烃、聚醚、硅油和磷酸酯的混合物。
更优选地，所述抗结胶添加剂和清洁添加剂的重量比为1:1，有效改善高温下或高负荷下，润滑油的抗磨性和抗乳化性。
更优选地，本发明提供的汽车机械齿轮润滑油，由以下重量份数计的原料制成：基础油120份、抗氧化剂12份、十二烷基苯磺酸钠3份，高碳润滑石墨12份，抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚8份、柠檬酸钠9份、盐酸8份、硫酸丁辛醇锌盐6份、烯基二丁酸3份、牛脂9份，妥尔油15份，硼酸脂8份，土耳其油11份、磷酸二氢钾9份、二氯甲烷10份、单丁二酰亚胺8份、失水山梨醇单油酸酯3份、三乙醇胺9份、防锈剂12份；
其中，所述基础油由聚а-烯烃100份、聚醚5份、硅油5份、磷酸酯15份组成。
更优选地，本发明提供的汽车机械齿轮润滑油，由以下重量份数计的原料制成：基础油80份、抗氧化剂4份、十二烷基苯磺酸钠1份，高碳润滑石墨1份，抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚2份、柠檬酸钠1份、盐酸2份、硫酸丁辛醇锌盐1份、烯基二丁酸1份、牛脂4份，妥尔油8份，硼酸脂5份，土耳其油6份、磷酸二氢钾3份、二氯甲烷2份、单丁二酰亚胺3份、失水山梨醇单油酸酯1份、三乙醇胺3份、防锈剂4份；
其中，所述基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
更优选地，本发明提供的汽车机械齿轮润滑油，由以下重量份数计的原料制成：基础油100份、抗氧化剂7份、十二烷基苯磺酸钠2份，高碳润滑石墨5份，抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚5份、柠檬酸钠6份、盐酸5份、硫酸丁辛醇锌盐3份、烯基二丁酸2份、牛脂5份，妥尔油9份，硼酸脂7份，土耳其油7份、磷酸二氢钾6份、二氯甲烷5份、单丁二酰亚胺6份、失水山梨醇单油酸酯2份、三乙醇胺5份、防锈剂7份；
其中，所述基础油由聚а-烯烃82份、聚醚4份、硅油4份、磷酸酯10份组成。
更优选地，本发明提供的汽车机械齿轮润滑油，由以下重量份数计的原料制成：基础油80份、抗氧化剂5份、十二烷基苯磺酸钠2份，高碳润滑石墨2份，抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚3份、柠檬酸钠2份、盐酸3份、硫酸丁辛醇锌盐2份、烯基二丁酸2份、牛脂4份，妥尔油10份，硼酸脂5份，土耳其油6份、磷酸二氢钾5份、二氯甲烷4份、单丁二酰亚胺4份、失水山梨醇单油酸酯2份、三乙醇胺4份、防锈剂5份；
其中，所述基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
本发明提供的汽车机械齿轮润滑油的制备方法，包括如下步骤：
将配方量的基础油转入反应釜中，升温至40℃，匀速搅拌；然后依次加入配方量的抗氧化剂、十二烷基苯磺酸钠，高碳润滑石墨，抗结胶添加剂、清洁添加剂、2，6-二叔丁基对甲酚、柠檬酸钠、盐酸、硫酸丁辛醇锌盐、烯基二丁酸、牛脂，妥尔油，硼酸脂，土耳其油、磷酸二氢钾、二氯甲烷、单丁二酰亚胺、失水山梨醇单油酸酯、三乙醇胺和防锈剂，升温至50℃，匀速搅拌30mi n。
本发明提供的汽车机械齿轮润滑油，具有良好的抗氧化防腐性、防锈性、抗磨、减摩、承载、高扭矩、高温稳定性、抗乳化性、换油周期长、减少废油、废气和颗粒物排放、生物可降解性好、价格相对传统润滑油较低的特点，能使齿轮在高速、低速、重载、高扭矩或冲击负荷下，迅速形成耐磨、耐高温、耐挤压的边界润滑油膜，防止齿面发生磨损、擦伤、胶合、点蚀等破坏现象，以延长重负荷工业齿轮的使用寿命。
具体实施方式
为了使本领域技术人员更好地理解本发明的技术方案能予以实施，下面结合具体实施例对本发明作进一步说明，但所举实施例不作为对本发明的限定。
本发明以下实施例中所用到的各种原料皆可在市场购买得到。
实施例1
一种汽车机械齿轮润滑油，具体由以下重量份数计的原料制成：基础油80份、抗氧化剂4份、十二烷基苯磺酸钠1份、高碳润滑石墨1份、抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚2份、柠檬酸钠1份、盐酸2份、硫酸丁辛醇锌盐1份、烯基二丁酸1份、牛脂4份、妥尔油8份、硼酸脂5份、土耳其油6份、磷酸二氢钾3份、二氯甲烷2份、单丁二酰亚胺3份、失水山梨醇单油酸酯1份、三乙醇胺3份、防锈剂4份。
其中，基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
该汽车机械齿轮润滑油的制备方法为：将组成基础油的组分混合均匀，转入反应釜中，升温至40℃，匀速搅拌，依次加入抗氧化剂、十二烷基苯磺酸钠、高碳润滑石墨、抗结胶添加剂、清洁添加剂、2，6-二叔丁基对甲酚、柠檬酸钠、盐酸、硫酸丁辛醇锌盐、烯基二丁酸、牛脂、妥尔油、硼酸脂、土耳其油、磷酸二氢钾、二氯甲烷、单丁二酰亚胺、失水山梨醇单油酸酯、三乙醇胺、防锈剂，升温至50℃，匀速搅拌30分钟。
实施例2
一种汽车机械齿轮润滑油，具体由以下重量份数计的原料制成：基础油120份、抗氧化剂12份、十二烷基苯磺酸钠3份、高碳润滑石墨12份、抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚8份、柠檬酸钠9份、盐酸8份、硫酸丁辛醇锌盐6份、烯基二丁酸3份、牛脂9份、妥尔油15份、硼酸脂8份、土耳其油11份、磷酸二氢钾9份、二氯甲烷10份、单丁二酰亚胺8份、失水山梨醇单油酸酯3份、三乙醇胺9份、防锈剂12份。
其中，基础油由聚а-烯烃100份、聚醚5份、硅油5份、磷酸酯15份组成。
该汽车机械齿轮润滑油的制备方法同实施例1。
实施例3：
一种汽车机械齿轮润滑油，具体由以下重量份数计的原料制成：基础油100份、抗氧化剂7份、十二烷基苯磺酸钠2份、高碳润滑石墨5份、抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚5份、柠檬酸钠6份、盐酸5份、硫酸丁辛醇锌盐3份、烯基二丁酸2份、牛脂5份、妥尔油9份、硼酸脂7份、土耳其油7份、磷酸二氢钾6份、二氯甲烷5份、单丁二酰亚胺6份、失水山梨醇单油酸酯2份、三乙醇胺5份、防锈剂7份。
其中，基础油由聚а-烯烃82份、聚醚4份、硅油4份、磷酸酯10份组成。
该汽车机械齿轮润滑油的制备方法同实施例1。
实施例4
一种汽车机械齿轮润滑油，具体由以下重量份数计的原料制成：基础油80份、抗氧化剂5份、十二烷基苯磺酸钠2份、高碳润滑石墨2份、抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚3份、柠檬酸钠2份、盐酸3份、硫酸丁辛醇锌盐2份、烯基二丁酸2份、牛脂2份、妥尔油10份、硼酸脂5份、土耳其油6份、磷酸二氢钾5份、二氯甲烷4份、单丁二酰亚胺4份、失水山梨醇单油酸酯2份、三乙醇胺4份、防锈剂5份。
其中，基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
该汽车机械齿轮润滑油的制备方法同实施例1。
本发明实施例1-4提供的汽车机械齿轮润滑油不仅具有良好的抗氧化防腐性、防锈性、高温稳定性、抗乳化性、换油周期长、减少废油、废气和颗粒物排放、生物可降解性好、价格相对传统润滑油较低的特点；同时，具有极好的极压抗磨性能，承载能力高，可配置较重负荷车辆齿轮油，也可用于重负荷和中负荷工业齿轮油。
以上所述实施例仅是为充分说明本发明而所举的较佳的实施例，其保护范围不限于此。本技术领域的技术人员在本发明基础上所作的等同替代或变换，均在本发明的保护范围之内，本发明的保护范围以权利要求书为准。

Claims (8)

1.一种汽车机械齿轮润滑油，其特征在于，由以下重量份数计的原料制成：
基础油80-120份、抗氧化剂4-12份、十二烷基苯磺酸钠1-3份、高碳润滑石墨1-12份、抗结胶添加剂3-4份、清洁添加剂3-4份、2，6-二叔丁基对甲酚2-8份、柠檬酸钠1-9份、盐酸2-8份、硫酸丁辛醇锌盐1-6份、烯基二丁酸1-3份、牛脂4-9份、妥尔油8-15份、硼酸脂5-8份、土耳其油6-11份、磷酸二氢钾3-9份、二氯甲烷2-10份、单丁二酰亚胺3-8份、失水山梨醇单油酸酯1-3份、三乙醇胺3-9份、防锈剂4-12份。
2.根据权利要求1所述的汽车机械齿轮润滑油，其特征在于，所述基础油为聚а-烯烃、聚醚、硅油和磷酸酯中的一种或他们的混合物。
3.根据权利要求2所述的汽车机械齿轮润滑油，其特征在于，所述抗结胶添加剂和清洁添加剂的重量比为1：1。
4.根据权利要求3所述的汽车机械齿轮润滑油，其特征在于，由以下重量份数计的原料制成：
基础油120份、抗氧化剂12份、十二烷基苯磺酸钠3份、高碳润滑石墨12份、抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚8份、柠檬酸钠9份、盐酸8份、硫酸丁辛醇锌盐6份、烯基二丁酸3份、牛脂9份、妥尔油15份、硼酸脂8份、土耳其油11份、磷酸二氢钾9份、二氯甲烷10份、单丁二酰亚胺8份、失水山梨醇单油酸酯3份、三乙醇胺9份、防锈剂12份；
其中，所述基础油由聚а-烯烃100份、聚醚5份、硅油5份、磷酸酯15份组成。
5.根据权利要求3所述的汽车机械齿轮润滑油，其特征在于，由以下重量份数计的原料制成：
基础油80份、抗氧化剂4份、十二烷基苯磺酸钠1份、高碳润滑石墨1份、抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚2份、柠檬酸钠1份、盐酸2份、硫酸丁辛醇锌盐1份、烯基二丁酸1份、牛脂4份、妥尔油8份、硼酸脂5份、土耳其油6份、磷酸二氢钾3份、二氯甲烷2份、单丁二酰亚胺3份、失水山梨醇单油酸酯1份、三乙醇胺3份、防锈剂4份；
其中，所述基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
6.根据权利要求3所述的汽车机械齿轮润滑油，其特征在于，由以下重量份数计的原料制成：
基础油100份、抗氧化剂7份、十二烷基苯磺酸钠2份、高碳润滑石墨5份、抗结胶添加剂4份、清洁添加剂4份、2，6-二叔丁基对甲酚5份、柠檬酸钠6份、盐酸5份、硫酸丁辛醇锌盐3份、烯基二丁酸2份、牛脂5份、妥尔油9份、硼酸脂7份、土耳其油7份、磷酸二氢钾6份、二氯甲烷5份、单丁二酰亚胺6份、失水山梨醇单油酸酯2份、三乙醇胺5份、防锈剂7份；
其中，所述基础油由聚а-烯烃82份、聚醚4份、硅油4份、磷酸酯10份组成。
7.根据权利要求3所述的汽车机械齿轮润滑油，其特征在于，由以下重量份数计的原料制成：
基础油80份、抗氧化剂5份、十二烷基苯磺酸钠2份、高碳润滑石墨2份、抗结胶添加剂3份、清洁添加剂3份、2，6-二叔丁基对甲酚3份、柠檬酸钠2份、盐酸3份、硫酸丁辛醇锌盐2份、烯基二丁酸2份、牛脂4份、妥尔油10份、硼酸脂5份、土耳其油6份、磷酸二氢钾5份、二氯甲烷4份、单丁二酰亚胺4份、失水山梨醇单油酸酯2份、三乙醇胺4份、防锈剂5份；
其中，所述基础油由聚а-烯烃68份、聚醚3份、硅油3份、磷酸酯6份组成。
8.根据权利要求1所述的汽车机械齿轮润滑油的制备方法，其特征在于，包括如下步骤：
将配方量的基础油转入反应釜中，升温至40℃，匀速搅拌；然后依次加入配方量的抗氧化剂、十二烷基苯磺酸钠、高碳润滑石墨、抗结胶添加剂、清洁添加剂、2，6-二叔丁基对甲酚、柠檬酸钠、盐酸、硫酸丁辛醇锌盐、烯基二丁酸、牛脂、妥尔油、硼酸脂、土耳其油、磷酸二氢钾、二氯甲烷、单丁二酰亚胺、失水山梨醇单油酸酯、三乙醇胺和防锈剂，升温至50℃，匀速搅拌30min。
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CN107460029A (zh) * 2017-08-18 2017-12-12 马鞍山中粮生物化学有限公司 一种复合型环保润滑油及其制备方法
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CN108410551A (zh) * 2018-02-05 2018-08-17 合肥欧仕嘉机电设备有限公司 一种机械设备用抗腐蚀润滑油及其制备方法
CN114085695A (zh) * 2021-09-26 2022-02-25 希玛石油制品（镇江）有限公司 一种用于高速运动组件的防锈润滑专用油及其制备工艺
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* Cited by examiner, † Cited by third party
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CN107460029A (zh) * 2017-08-18 2017-12-12 马鞍山中粮生物化学有限公司 一种复合型环保润滑油及其制备方法
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CN114085695A (zh) * 2021-09-26 2022-02-25 希玛石油制品（镇江）有限公司 一种用于高速运动组件的防锈润滑专用油及其制备工艺
CN114958472A (zh) * 2022-05-13 2022-08-30 南京工业职业技术大学 一种绿色轮胎用st/ut钢帘线拉拔用润滑液

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