CN114870056A - Antibacterial deodorant and preparation method thereof - Google Patents
Antibacterial deodorant and preparation method thereof Download PDFInfo
- Publication number
- CN114870056A CN114870056A CN202210610921.4A CN202210610921A CN114870056A CN 114870056 A CN114870056 A CN 114870056A CN 202210610921 A CN202210610921 A CN 202210610921A CN 114870056 A CN114870056 A CN 114870056A
- Authority
- CN
- China
- Prior art keywords
- preparation
- parts
- antibacterial
- antibacterial deodorant
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 claims abstract description 9
- 229940100530 zinc ricinoleate Drugs 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- 230000003449 preventive effect Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 8
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 7
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 8
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 241000894006 Bacteria Species 0.000 abstract description 5
- 238000004332 deodorization Methods 0.000 abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000006459 hydrosilylation reaction Methods 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- 206010059866 Drug resistance Diseases 0.000 abstract description 2
- 239000003899 bactericide agent Substances 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 210000004877 mucosa Anatomy 0.000 abstract description 2
- 230000001850 reproductive effect Effects 0.000 abstract description 2
- 230000000638 stimulation Effects 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 210000002683 foot Anatomy 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000009569 green tea Nutrition 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 2
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 2
- 235000012141 vanillin Nutrition 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- MCCACAIVAXEFAL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-2-[(2,4-dichlorophenyl)methoxy]ethyl]imidazole;nitric acid Chemical compound O[N+]([O-])=O.ClC1=CC(Cl)=CC=C1COC(C=1C(=CC(Cl)=CC=1)Cl)CN1C=NC=C1 MCCACAIVAXEFAL-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 241000723436 Chamaecyparis obtusa Species 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 208000014770 Foot disease Diseases 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229960005040 miconazole nitrate Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
- 201000004647 tinea pedis Diseases 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- -1 zinc ester Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/90—Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention relates to the field of macromolecules, in particular to an antibacterial deodorant and a preparation method thereof; the method provides the existing chemical deodorization technology, and generally can not effectively inhibit the reproductive metabolism of bacteria; the antibacterial agent adopted by the invention has strong capability of killing bacteria, broad spectrum, high efficiency, stable chemical property, low toxicity, no stimulation to skin mucosa, good combination with other types of bactericides and no damage to sterilized articles; the sterilization process is rapid, no harmful substance is generated, and no selective sterilization mode exists, so that the bacteria can not generate drug resistance; in addition, the macromolecular silicon-based odor removing agent prepared by carrying out hydrosilylation reaction on 1, 1-dimethyl silicon-based iron, diallyl dimethyl ammonium chloride and zinc ricinoleate has high temperature resistance and high humidity resistance, is suitable for being used in the south with damp and warm water, and has lasting use effect.
Description
Technical Field
The invention relates to the field of polymers, in particular to an antibacterial deodorant and a preparation method thereof.
Background
At present, the foot hygiene products on the market are more, and can be generally divided into direct soaking liquid, water-soluble powder, ointment for treating tinea pedis and a pad body placed in a shoe. The commonly used products generally adopt miconazole nitrate as a main raw material, and some products are also prepared into foot care products by adopting Chinese medicinal preparations. These products have the following problems: the foot care product is used for treating foot diseases, is easy to decompose and has short time effect; the use process is complex; can not be treated by shoe materials and socks; the paste must be applied to the affected part; has no function of deodorizing and decomposing foreign odor molecules.
CN 200610018259.4: the invention relates to an antibacterial deodorant for shoes and socks, which can effectively kill the growth of bacterial microorganisms in the shoes and socks so as to eliminate the peculiar smell of the shoes and socks. An antibacterial deodorant for shoes and socks comprises the following components in percentage by weight: and (3) chitosan: 0.1-5%, acetic acid: 10-40%, betaine: 0.2-4%, thymol: 0.05-2%, tween-80: 10-40%, essence: 0.1-4%, deionized water: the balance, the sum of all the components is 100 percent. The main raw materials selected by the invention are all from green organisms, and the invention has the characteristics of no toxicity, environmental protection, low cost, good sterilization effect and long effective time.
CN 200710017892.6: the invention relates to a preparation method of a biological antibacterial deodorant, which has the advantages of simple preparation method, low cost, obvious deodorization and sterilization effects, no toxicity, no corrosion and difficult secondary pollution. The invention is prepared from the following raw materials in parts by weight: one or more of citric acid, malic acid and lactic acid, the content of which is more than or equal to 1 weight part; water, the content of which is less than or equal to 990 weight portions; filtering the above components on a copper net, aseptically mixing with water at room temperature, fully dissolving, and standing to obtain the antibacterial deodorant.
CN 200910230771.9: the invention discloses a nano composite micro-emulsion type antibacterial deodorant, which comprises the following raw materials of water, chamaecyparis obtusa, vanillin, water-based polyurethane resin, span-80 and nano antibacterial powder dispersion liquid, wherein the proportioning relation of the raw materials is as follows: water: 1000 ml; hinoki fragrance: 55ml to 125 ml; vanillin: 55ml to 125 ml; aqueous polyurethane resin: 11.2ml to 12.8 ml; span-80: 5.58ml to 6.28 ml; nano antibacterial powder dispersion liquid: 40ml to 60 ml. Compared with the prior art, the nano composite micro emulsion type antibacterial deodorant has the following functions: 1) the use amount is small, the cost is low, the adhesive force is strong, and no toxic or side effect exists; 2) has the functions of no decomposition and long-acting sterilization; 3) has the functions of decomposing foreign odor molecules and releasing fragrance.
The above patents and prior art generally adopt chemical deodorizing techniques, which convert the odor functional group in the odor substance into a non-odor substance by a series of chemical reactions such as acid-base neutralization, oxidation-reduction, etc. between the deodorizing component and the odor molecule; the chemical deodorization technology can decompose and recombine odor molecules, and meanwhile, the deodorization effect is rapid and obvious, so that the technology is a thorough deodorization technology; the disadvantage is that the bacterial reproductive metabolism is generally not effectively inhibited.
Disclosure of Invention
In order to solve the problems, the invention provides an antibacterial deodorant and a preparation method thereof, and the preparation method comprises the following operation steps:
according to the mass parts, 25-35 parts of antibacterial agent, 40-60 parts of odor removing agent, 5-7 parts of mildew preventive, 1-4 parts of additive, 0.5-1 part of essence and 100-120 parts of water are fully stirred and mixed under the aseptic condition at room temperature, and then the mixture is stood to obtain the antibacterial deodorant.
The invention also provides a preparation method of the odor removing agent, which comprises the following steps:
according to the mass parts, 30-60 parts of 1, 1-dimethyl silicon-based iron, 20-35 parts of diallyl dimethyl ammonium chloride, 5-12 parts of zinc ricinoleate and 0.02-0.6 part of Kanster platinum catalyst (CAS: 68478-92-2) are heated to 40-50 ℃, and stirred for reaction for 100-180min to obtain the odor removing agent.
Further, the mildew preventive is methylisothiazolinone, 3-iodine-2-propynyl butyl carbamate or p-hydroxybenzoate.
Further, the additive is ethanol.
Further, the essence is mint-flavored essence or green tea-flavored essence.
Further, the stirring time is 10-30 min.
Further, the stirring speed is 600-
Further, the standing time is 2-5 h.
The invention also provides a preparation method of the antibacterial agent, which comprises the following steps:
the antibacterial agent is obtained by fully stirring and mixing 16-20 parts of benzalkonium chloride, 8-12 parts of ethanol and 3-7 parts of isopropanol according to the parts by weight.
Further, it is characterized in that: the stirring time is 10-15 min.
The innovation points of the invention are as follows:
the 1, 1-dimethyl silicon-based iron, diallyl dimethyl ammonium chloride and zinc ricinoleate undergo hydrosilylation reaction to obtain the odor removing agent with the synergistic effect of silicon base and zinc ester.
The invention has the beneficial effects that:
the invention relates to an antibacterial deodorant and a preparation method thereof, and the antibacterial deodorant has the following obvious beneficial effects:
(1) the adopted antibacterial agent has strong capability of killing bacteria, broad spectrum, high efficiency, stable chemical property, low toxicity, no stimulation to skin mucosa, good compounding property with other types of bactericides and no damage to sterilized articles; the sterilization process is rapid, no harmful substance is generated, and no selective sterilization mode exists, so that the bacteria can not generate drug resistance.
(2) The macromolecular silicon-based odor removing agent prepared by carrying out hydrosilylation reaction on 1, 1-dimethyl silicon-based iron, diallyl dimethyl ammonium chloride and zinc ricinoleate has high temperature resistance and high humidity resistance, is suitable for being used in the south with humidity and warmth, and has lasting use effect.
Detailed Description
The invention is further illustrated by the following specific examples:
the odor content determination method adopts GB/T14675-93 to perform determination; the antibacterial effect is measured by GB/T20944.1.2.
Example 1
An antibacterial deodorant and a preparation method thereof comprise the following operation steps:
the antibacterial deodorant is prepared by mixing 25g of antibacterial agent, 40g of odor removing agent, 5g of mildew preventive, 1g of additive, 0.5g of essence and 100g of water under sterile conditions at room temperature, stirring thoroughly, and standing.
The invention also provides a preparation method of the odor removing agent, which comprises the following steps:
heating 30g of 1, 1-dimethyl silicon-based iron, 20g of diallyl dimethyl ammonium chloride, 5g of zinc ricinoleate and 0.02g of Kastet platinum catalyst (CAS: 68478-92-2) to 40 ℃, and stirring for reaction for 100min to obtain the odor removing agent.
Further, the mildew preventive is methylisothiazolinone.
Further, the additive is ethanol.
Further, the essence is mint-flavored essence.
Further, the stirring time is 10 min.
Further, the stirring speed is 600r/min
Further, the standing time is 2 hours.
The invention also provides a preparation method of the antibacterial agent, which comprises the following steps:
the antibacterial agent is obtained by mixing 16g of benzalkonium chloride, 8g of ethanol and 3g of isopropanol under stirring.
Further, it is characterized in that: the stirring time is 10 min.
Example 2
An antibacterial deodorant and a preparation method thereof comprise the following operation steps:
28g of antibacterial agent, 45g of odor removing agent, 6g of mildew preventive, 2g of additive, 0.6g of essence and 105g of water are fully stirred and mixed under the aseptic condition at room temperature, and then are kept stand to obtain the antibacterial deodorant.
The invention also provides a preparation method of the odor removing agent, which comprises the following steps:
40g of 1, 1-dimethyl silicon-based iron and 25g of diallyl dimethyl ammonium chloride, 7g of zinc ricinoleate and 0.1g of Kastet platinum catalyst (CAS: 68478-92-2) are heated to 44 ℃, and stirred to react for 120min to obtain the odor removing agent.
Further, the mildew preventive is 3-iodine-2-propynyl butyl carbamate.
Further, the additive is ethanol.
Further, the essence is mint-flavored essence.
Further, the stirring time is 15 min.
Further, the stirring speed is 700r/min
Further, the standing time is 3 hours.
The invention also provides a preparation method of the antibacterial agent, which comprises the following steps:
the antibacterial agent was obtained by thoroughly mixing 17g of benzalkonium chloride, 9g of ethanol, and 4g of isopropyl alcohol.
Further, it is characterized in that: the stirring time is 12 min.
Example 3
An antibacterial deodorant and a preparation method thereof comprise the following operation steps:
32g of antibacterial agent, 55g of odor removing agent, 6g of mildew preventive, 3g of additive, 0.8g of essence and 115g of water are stirred and mixed fully under the aseptic condition at room temperature, and then the mixture is kept stand to obtain the antibacterial deodorant.
The invention also provides a preparation method of the odor removing agent, which comprises the following steps:
50g of 1, 1-dimethyl silicon-based iron, 30g of diallyl dimethyl ammonium chloride, 10g of zinc ricinoleate and 0.4g of Kaste platinum catalyst (CAS: 68478-92-2) are heated to 48 ℃, stirred and reacted for 160min to obtain the odor removing agent.
Further, the mildew preventive is 3-iodine-2-propynyl butyl carbamate.
Further, the additive is ethanol.
Further, the essence is green tea flavor essence.
Further, the stirring time is 25 min.
Further, the stirring speed is 900r/min
Further, the standing time is 4 hours.
The invention also provides a preparation method of the antibacterial agent, which comprises the following steps:
the antibacterial agent was obtained by thoroughly mixing 19g of benzalkonium chloride, 11g of ethanol, and 6g of isopropyl alcohol.
Further, it is characterized in that: the stirring time is 14 min.
Example 4
An antibacterial deodorant and a preparation method thereof comprise the following operation steps:
and (2) fully stirring and mixing 35g of antibacterial agent, 60g of odor removing agent, 7g of mildew preventive, 4g of additive, 1g of essence and 120g of water under the aseptic condition at room temperature, and standing to obtain the antibacterial deodorant.
The invention also provides a preparation method of the odor removing agent, which comprises the following steps:
60g of 1, 1-dimethyl silicon-based iron, 35g of diallyl dimethyl ammonium chloride, 12g of zinc ricinoleate and 0.6g of Kaste platinum catalyst (CAS: 68478-92-2) are heated to 48 ℃, stirred and reacted for 160min to obtain the odor removing agent.
Further, the mildew preventive is p-hydroxybenzoate.
Further, the additive is ethanol.
Further, the essence is green tea flavor essence.
Further, the stirring time is 30 min.
Further, the stirring rotating speed is 1000r/min
Further, the standing time is 5 hours.
The invention also provides a preparation method of the antibacterial agent, which comprises the following steps:
20g of benzalkonium chloride, 12g of ethanol and 7g of isopropanol are fully stirred and mixed to obtain the antibacterial agent.
Further, it is characterized in that: the stirring time is 15 min.
Comparative example 1
The same procedure as in example 3 was repeated except that 1, 1-dimethylsilyloxy iron was not added;
comparative example 2
The procedure is as in example 3 except that diallyldimethylammonium chloride is not added; comparative example 3
Benzalkonium chloride was not added, as in example 3;
Claims (10)
1. an antibacterial deodorant and a preparation method thereof, the operation steps are as follows:
according to the mass parts, 25-35 parts of antibacterial agent, 40-60 parts of odor removing agent, 5-7 parts of mildew preventive, 1-4 parts of additive, 0.5-1 part of essence and 100-120 parts of water are fully stirred and mixed under the aseptic condition at room temperature, and then the mixture is stood to obtain the antibacterial deodorant.
2. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the preparation method of the odor removing agent comprises the following steps:
according to the mass parts, 30-60 parts of 1, 1-dimethyl silicon-based iron, 20-35 parts of diallyl dimethyl ammonium chloride, 5-12 parts of zinc ricinoleate and 0.02-0.6 part of Kanster platinum catalyst (CAS: 68478-92-2) are heated to 40-50 ℃, and stirred for reaction for 100-180min to obtain the odor removing agent.
3. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the mildew preventive is methylisothiazolinone, 3-iodine-2-propynyl butyl carbamate or p-hydroxybenzoate.
4. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the additive is ethanol.
5. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the essence is mint-flavored essence or green tea-flavored essence.
6. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the stirring time is 10-30 min.
7. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the stirring speed is 600-1000 r/min.
8. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the standing time is 2-5 h.
9. The antibacterial deodorant and the preparation method thereof according to claim 1, wherein: the preparation method of the antibacterial agent comprises the following steps:
and (2) fully stirring and mixing 16-20 parts of benzalkonium chloride, 8-12 parts of ethanol and 3-7 parts of isopropanol according to the parts by mass to obtain the antibacterial agent.
10. The antibacterial deodorant and the preparation method thereof according to claim 9, characterized in that: the stirring time is 10-15 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210610921.4A CN114870056B (en) | 2022-05-31 | 2022-05-31 | Antibacterial deodorant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210610921.4A CN114870056B (en) | 2022-05-31 | 2022-05-31 | Antibacterial deodorant and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114870056A true CN114870056A (en) | 2022-08-09 |
| CN114870056B CN114870056B (en) | 2023-02-14 |
Family
ID=82680570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210610921.4A Active CN114870056B (en) | 2022-05-31 | 2022-05-31 | Antibacterial deodorant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114870056B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116445216A (en) * | 2023-03-30 | 2023-07-18 | 广东铭康香精香料有限公司 | Essence capable of efficiently removing peculiar smell and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003230623A (en) * | 2001-12-04 | 2003-08-19 | Nippon Soda Co Ltd | Composition for deodorization |
| JP2004049435A (en) * | 2002-07-18 | 2004-02-19 | Kawaken Fine Chem Co Ltd | Deodorizing base agent comprising polyvalent metal ricinoleate and manufacturing method therefor |
| CN102639549A (en) * | 2009-10-19 | 2012-08-15 | Cbz化学品有限公司 | Process for the synthesis of silylferrocene compounds |
| CN105875621A (en) * | 2016-05-11 | 2016-08-24 | 于文 | Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof |
| CN106719771A (en) * | 2016-12-28 | 2017-05-31 | 于文 | Footgear antibacterial deodorizing agent and preparation method thereof |
| CN107321170A (en) * | 2017-07-04 | 2017-11-07 | 广州市拓新化工科技有限公司 | A kind of odor scavenging agent and preparation method thereof |
| CN108404186A (en) * | 2018-05-04 | 2018-08-17 | 东莞御容宫日化有限公司 | A kind of vehicle-mounted type space air purifying preparation |
| US20190040338A1 (en) * | 2017-08-04 | 2019-02-07 | Vinay Bhalchandra PARANJPE | Deodorant formulation and uses thereof |
| CN112675914A (en) * | 2020-12-19 | 2021-04-20 | 浙江锦华新材料股份有限公司 | Preparation method of catalyst for synthesizing vinyl tributyroximo silane |
| CN113115789A (en) * | 2021-04-01 | 2021-07-16 | 青岛广恩技术研发有限公司 | Disinfecting deodorant and preparation method thereof |
-
2022
- 2022-05-31 CN CN202210610921.4A patent/CN114870056B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003230623A (en) * | 2001-12-04 | 2003-08-19 | Nippon Soda Co Ltd | Composition for deodorization |
| JP2004049435A (en) * | 2002-07-18 | 2004-02-19 | Kawaken Fine Chem Co Ltd | Deodorizing base agent comprising polyvalent metal ricinoleate and manufacturing method therefor |
| CN102639549A (en) * | 2009-10-19 | 2012-08-15 | Cbz化学品有限公司 | Process for the synthesis of silylferrocene compounds |
| CN105875621A (en) * | 2016-05-11 | 2016-08-24 | 于文 | Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof |
| CN106719771A (en) * | 2016-12-28 | 2017-05-31 | 于文 | Footgear antibacterial deodorizing agent and preparation method thereof |
| CN107321170A (en) * | 2017-07-04 | 2017-11-07 | 广州市拓新化工科技有限公司 | A kind of odor scavenging agent and preparation method thereof |
| US20190040338A1 (en) * | 2017-08-04 | 2019-02-07 | Vinay Bhalchandra PARANJPE | Deodorant formulation and uses thereof |
| CN108404186A (en) * | 2018-05-04 | 2018-08-17 | 东莞御容宫日化有限公司 | A kind of vehicle-mounted type space air purifying preparation |
| CN112675914A (en) * | 2020-12-19 | 2021-04-20 | 浙江锦华新材料股份有限公司 | Preparation method of catalyst for synthesizing vinyl tributyroximo silane |
| CN113115789A (en) * | 2021-04-01 | 2021-07-16 | 青岛广恩技术研发有限公司 | Disinfecting deodorant and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| FELIX MÜLLER ET AL.: "TEGO SORB 吸味剂的分子动态分析", 《环球科技》 * |
| 姚永丽等: "蓖麻醇酸锌在除臭方面的应用", 《中国洗涤用品工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116445216A (en) * | 2023-03-30 | 2023-07-18 | 广东铭康香精香料有限公司 | Essence capable of efficiently removing peculiar smell and preparation method thereof |
| CN116445216B (en) * | 2023-03-30 | 2023-11-21 | 广东铭康香精香料有限公司 | Essence capable of efficiently removing peculiar smell and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114870056B (en) | 2023-02-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108404186A (en) | A kind of vehicle-mounted type space air purifying preparation | |
| CN101455849A (en) | Air purification agent | |
| JPH07330505A (en) | Antimicrobial composition | |
| CN114870056B (en) | Antibacterial deodorant and preparation method thereof | |
| CN108042562A (en) | Disposable disinfectant of the compound alcohol of gel-type and preparation method thereof | |
| CN109569287A (en) | A kind of quick-acting air purifying preparations and preparation method thereof | |
| CN113349201A (en) | Ethanol-gel-free no-wash disinfectant and preparation method thereof | |
| CN107510857A (en) | Antibacterial deodorant | |
| CN111346124A (en) | Formula and preparation method of skin disinfection cleaning solution | |
| CN107496260A (en) | A kind of complexing agent containing Tea Polyphenols and preparation method thereof | |
| CN109675429A (en) | It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation | |
| CN109362782A (en) | A kind of antibacterial air freshener except formaldehyde | |
| CN110665355A (en) | Deodorant composition containing woody plant essential oil and preparation method thereof | |
| CN112716820A (en) | Antibacterial skin-care lotion and preparation method thereof | |
| CN112999202A (en) | Antibacterial and deodorant film-forming spray liquid and preparation method thereof | |
| CN110742845B (en) | Wet tissue and preparation method thereof | |
| JP2951341B2 (en) | Food deodorant and food deodorizing method | |
| CN113144058A (en) | Skin-moistening refreshing wash-free disinfection gel and preparation method thereof | |
| CN102309773A (en) | Biological deodorizing composition and preparation method thereof | |
| CN111493082A (en) | Foam type household disinfectant and preparation method thereof | |
| CN112972282A (en) | Natural deodorant and preparation method and application thereof | |
| CN112263513A (en) | Water-based mosquito repellent and preparation method thereof | |
| JP3031026U (en) | Polyurethane foam | |
| CN114569473B (en) | Environment-friendly wash-free antibacterial gel and preparation method thereof | |
| CN117005190B (en) | Mildew-proof antibacterial agent for textiles and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An antibacterial and deodorizing agent and its preparation method Granted publication date: 20230214 Pledgee: Zhejiang Dongyang Rural Commercial Bank Co.,Ltd. Weishan Sub branch Pledgor: Zhejiang Weihua jujiu Technology Co.,Ltd. Registration number: Y2024980001431 |