CN106719771A - Footgear antibacterial deodorizing agent and preparation method thereof - Google Patents

Footgear antibacterial deodorizing agent and preparation method thereof Download PDF

Info

Publication number
CN106719771A
CN106719771A CN201611236964.1A CN201611236964A CN106719771A CN 106719771 A CN106719771 A CN 106719771A CN 201611236964 A CN201611236964 A CN 201611236964A CN 106719771 A CN106719771 A CN 106719771A
Authority
CN
China
Prior art keywords
footgear
weight portions
antibacterial deodorizing
deodorizing agent
peculiar smell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611236964.1A
Other languages
Chinese (zh)
Inventor
于文
雷敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XI'AN KAIMI CO Ltd
Original Assignee
XI'AN KAIMI CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XI'AN KAIMI CO Ltd filed Critical XI'AN KAIMI CO Ltd
Priority to CN201611236964.1A priority Critical patent/CN106719771A/en
Publication of CN106719771A publication Critical patent/CN106719771A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44Guanidine; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/12Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions

Abstract

The present invention relates to footgear antibacterial deodorizing agent and preparation method thereof, it is made up of following components:Solvent, antiseptic, peculiar smell removal agent, mould inhibitor, other auxiliary materials, deionized water.Footgear antibacterial deodorizing agent of the invention is a liquid spray type product, carry, it is easy to use;Shoes, socks and the shoe chest of all kinds of materials are applied to, bacterial micro-organism growth in footgear can be effectively killed, footgear peculiar smell is eliminated;Delicate fragrance is left, keeps footgear salubrious, do not pollute vamp;With nontoxic non-stimulated, easily biological-degradable, the features such as safety and environmental protection.

Description

Footgear antibacterial deodorizing agent and preparation method thereof
Technical field
The present invention relates to a kind of peculiar smell removal agent, and in particular to a kind of footgear antibacterial deodorizing agent and preparation method thereof.
Background technology
Arch of the foot is every square centimeter about 620 sweat glands, and the same area in other positions of body only has 143~339, due to Arch of the foot is more than the sweat gland at other positions, increase when people's activity, weather is sultry, it is nervous, when eat pungent blanching food, Sweat will largely be secreted.Humidity and acid or alkali environment after perspiration in footwear provide a suitable growth ring to bacterium Border, adds the enough nutrition that dermonecrotic cuticula brings to bacterium, bacterium amount reproduction is decomposed keratoprotein And mix the urea in sweat, lactic acid and produce unpleasant stink.Stink overflows not only makes individual be in awkward circumstances, and instead The presence of a large amount of bacterial micro-organisms, infringement foot health are reflected.Although focusing on, foot is cleaned and changing footgear can subtract peculiar smell It is weak, but solved not from origin, only accomplish to kill and suppress bacterial reproduction, just can be thoroughly deodorant.
The product of presently commercially available removal footgear stink, the technology of use has following several respects:A. solids versions deodorant, Antibromic shoe pads, this kind of product uses the less effective that eliminated the unusual smell after a period of time;B. solution-type peculiar smell removal agent, more using in footwear The method for spraying aroma substance, it is intended to cover stink with fragrance physics, this scheme can not effectively suppress the growth of bacterium Breeding, this kind of product do not solve to the origin of stink, can not effective antibacterial;C. antiseptic, such as salicylic acid are used(It is high It is unstable under temperature, there is the general character of acid, skin can be stimulated, it is corrosive), arhat pitch(Price is high), formalin and glycerine coordinates (Formalin is volatile and poisonous), triclocarban(It has been proposed and has prohibitted the use of), chlorohexidene(Chlorhexidine, to aquatic Thing biology is poisonous, influences water body environment), or even have the nonylphenol class material containing biological degradability difference in formula, it is easy to environment Pollute.
The content of the invention
The footgear antibacterial good it is an object of the invention to provide a kind of anti-microbial property, deodorant speed is fast, holding footgear is salubrious is removed Peculiar smell agent and preparation method thereof, has antibacterial, deodorant two kinds of effects concurrently, at the same it is gentle it is non-stimulated, do not pollute footgear, safety and environmental protection, It is easy to use.
The technical solution adopted in the present invention is:
Footgear antibacterial deodorizing agent, it is characterised in that:
It is made up of following components:
Solvent 3-30 weight portions;
Antiseptic 0.05-5 weight portions;
Peculiar smell removal agent 0.05-5 weight portions;
Mould inhibitor 0.02-2 weight portions;
Other auxiliary materials 0.05-2 weight portions;
Deionized water surplus;
The parts by weight summation of each component is 100.
Described solvent is the mixture of one or more in PEG400, propane diols, ethanol.
Described antiseptic is at least one of benzalkonium chloride, parachlorometaxylenol, polyhexamethylene hydrochloric acid bisguanides.
Described peculiar smell removal agent is at least one of castor oil acid zinc salt, 4- ethyl -4- soybean-based ethyl-sulfate morpholines.
Described mould inhibitor is iodopropynyl butyl formate.
Other described auxiliary materials be essence, or essence and pigment mixing.
The preparation method of footgear antibacterial deodorizing agent, it is characterised in that:
Comprise the following steps:
Step 1:Got the raw materials ready according to formula as below:
Solvent 3-30 weight portions;
Antiseptic 0.05-5 weight portions;
Peculiar smell removal agent 0.05-5 weight portions;
Mould inhibitor 0.02-2 weight portions;
Other auxiliary materials 0.05-2 weight portions;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, solvent is added in deionized water, after being uniformly mixed, add other auxiliary materials, continue to stir To being uniformly dissolved, solution A is obtained;
Step 3:Antiseptic is added in solution A, is uniformly mixed, obtain solution B;
Step 4:Peculiar smell removal agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Mould inhibitor is added in solution C, is stirred to being uniformly dissolved, obtain transparency liquid, be made footgear antibacterial deodorizing Agent.
Described solvent is the mixture of one or more in PEG400, propane diols, ethanol;
Described antiseptic is at least one of benzalkonium chloride, parachlorometaxylenol, polyhexamethylene hydrochloric acid bisguanides;
Described peculiar smell removal agent is at least one of castor oil acid zinc salt, 4- ethyl -4- soybean-based ethyl-sulfate morpholines;
Described mould inhibitor is iodopropynyl butyl formate;
Other described auxiliary materials be essence, or essence and pigment mixing.
The present invention has advantages below:
1st, main active of the polyhexamethylene hydrochloric acid bisguanides as bactericide is employed, it has the energy of extremely strong killing bacterium Power, wide spectrum, efficiently and with long-term bacteriostasis, it is soluble in water, it is non-volatile to thermally-stabilised.It is bactericide compounded with other types Property is good;Compare with quaternary ammonium salt sterilization component, smell and foam have and largely reduce;LD50>5000 mg/ Kg, belong to Actual nontoxic level product, milder safety;Sterilization process is rapid and does not produce any harmful substance, while the sterilized work without selection With mode, will not make bacterial resistance occurred.
2nd, the 4- ethyl -4- soybean-based ethyl-sulfate morpholines selected as peculiar smell removal agent chief active thing, it is a kind of Unique cationic surfactant, the organic molecule for having peculiar smell by coordination or neutralization, reduces odor molecules concentration, realizes The effect for eliminating the unusual smell.It is good with antiseptic compatibility;It is completely soluble, it is not necessary to any additional solubilizer;To various different Taste(Amyl hydrosulfide, butyric acid, tobacco flavor, musty etc.)It is all effective;It is biodegradable, safety and environmental protection.
3rd, evaporation rate of the present invention is fast, basic noresidue vestige, does not result in the glutinous soapy feeling of footgear and feels, will not pollute footgear, Raw materials used equal free from extraneous odour, harmless, production technology environmental protection, safe operation is simple.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Footgear antibacterial deodorizing agent of the present invention, is made up of following components:
Solvent 3-30 weight portions;
Antiseptic 0.05-5 weight portions;
Peculiar smell removal agent 0.05-5 weight portions;
Mould inhibitor 0.02-2 weight portions;
Other auxiliary materials 0.05-2 weight portions;
Deionized water surplus;
The parts by weight summation of each component is 100.
Described solvent is the mixture of one or more in PEG400, propane diols, ethanol.It is preferred that various etc. Amount mixing, it is 5-25 that dosage is more excellent, and after further prioritization scheme, it is 8-20 that dosage is more excellent.
Described antiseptic is at least one of benzalkonium chloride, parachlorometaxylenol, polyhexamethylene hydrochloric acid bisguanides.It is excellent Various mixed in equal amounts are selected, it is 0.1-3 that dosage is more excellent, after further prioritization scheme, it is 0.5-1.5 that dosage is more excellent.
Described peculiar smell removal agent is at least one of castor oil acid zinc salt, 4- ethyl -4- soybean-based ethyl-sulfate morpholines.It is excellent Various mixed in equal amounts are selected, it is 0.1-3 that dosage is more excellent, after further prioritization scheme, it is 0.5-1.5 that dosage is more excellent.
Described mould inhibitor is iodopropynyl butyl formate.It is 0.05-1.0 that dosage is more excellent, further optimization side After case, it is 0.08-0.8 that dosage is more excellent.
Other described auxiliary materials be essence, or essence and pigment mixing.It is preferred that various mixed in equal amounts, dosage is more excellent to be 0.1-1.0。
The preparation method of above-mentioned footgear antibacterial deodorizing agent, comprises the following steps:
Step 1:Get the raw materials ready;
Step 2:Under normal temperature, solvent is added in deionized water, after being uniformly mixed, add other auxiliary materials, continue to stir To being uniformly dissolved, solution A is obtained;
Step 3:Antiseptic is added in solution A, is uniformly mixed, obtain solution B;
Step 4:Peculiar smell removal agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Mould inhibitor is added in solution C, is stirred to being uniformly dissolved, obtain transparency liquid, be made footgear antibacterial deodorizing Agent.
It is below the performance test explanation of footgear antibacterial deodorizing agent involved in the present invention:
Experiment 1:
Test the contrivance and contrast of the commercial products in terms of evaporation rate.
(1) prepare the glass plate of a block specifications 40cm*60cm, clean up, with distilled water flushing three times, horizontal positioned is dried in the air Dry, distilled water volatilizees completely.Four area identical regions are divided in glass pane surface, numbering is standby.
(2) contrivance and commercial products are poured into model, specification identical spray bottle respectively, consumption 30ml, point Record is not numbered, the numbering of spray bottle is corresponding with glass sheet areas numbering, recorded in order to phenomenon.
(3) it is uniform to spraying by the advance pressed several times of spray bottle of (2) middle dress sample, then by each sample pressing twice, It is even to be sprayed to glass plate corresponding region, stopwatch is pressed immediately, until sample volatilizees completely, stop timing.Furthermore it is ensured that sample is waved Hair is to carry out naturally at ambient temperature.
Evaluation result record is as follows:
Experiment 2:
Test the contrivance and contrast of the commercial products in terms of remaining trace.
The operation of experiment 2 is identical with experiment 1, is observed from different directions after after sample volatilization completely, asking 5 people to evaluate group The remaining trace situation of sample, the evaluation that 5 staff are given after conscientiously examining is consistent, and its result is as follows:
The remaining trace of this 4 groups of samples is preserved, after 24 h are stood at room temperature, then is observed in the same way, it is as a result as follows:
Present disclosure is not limited to cited by embodiment, and those of ordinary skill in the art are right by reading description of the invention Any equivalent conversion that technical solution of the present invention is taken, is claim of the invention and is covered.

Claims (8)

1. footgear antibacterial deodorizing agent, it is characterised in that:
It is made up of following components:
Solvent 3-30 weight portions;
Antiseptic 0.05-5 weight portions;
Peculiar smell removal agent 0.05-5 weight portions;
Mould inhibitor 0.02-2 weight portions;
Other auxiliary materials 0.05-2 weight portions;
Deionized water surplus;
The parts by weight summation of each component is 100.
2. footgear antibacterial deodorizing agent according to claim 1, it is characterised in that:
Described solvent is the mixture of one or more in PEG400, propane diols, ethanol.
3. footgear antibacterial deodorizing agent according to claim 1, it is characterised in that:
Described antiseptic is at least one of benzalkonium chloride, parachlorometaxylenol, polyhexamethylene hydrochloric acid bisguanides.
4. footgear antibacterial deodorizing agent according to claim 1, it is characterised in that:
Described peculiar smell removal agent is at least one of castor oil acid zinc salt, 4- ethyl -4- soybean-based ethyl-sulfate morpholines.
5. footgear antibacterial deodorizing agent according to claim 1, it is characterised in that:
Described mould inhibitor is iodopropynyl butyl formate.
6. footgear antibacterial deodorizing agent according to claim 1, it is characterised in that:
Other described auxiliary materials be essence, or essence and pigment mixing.
7. the preparation method of footgear antibacterial deodorizing agent, it is characterised in that:
Comprise the following steps:
Step 1:Got the raw materials ready according to formula as below:
Solvent 3-30 weight portions;
Antiseptic 0.05-5 weight portions;
Peculiar smell removal agent 0.05-5 weight portions;
Mould inhibitor 0.02-2 weight portions;
Other auxiliary materials 0.05-2 weight portions;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, solvent is added in deionized water, after being uniformly mixed, add other auxiliary materials, continue to stir To being uniformly dissolved, solution A is obtained;
Step 3:Antiseptic is added in solution A, is uniformly mixed, obtain solution B;
Step 4:Peculiar smell removal agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Mould inhibitor is added in solution C, is stirred to being uniformly dissolved, obtain transparency liquid, be made footgear antibacterial deodorizing Agent.
8. the preparation method of footgear antibacterial deodorizing agent according to claim 7, it is characterised in that:
Described solvent is the mixture of one or more in PEG400, propane diols, ethanol;
Described antiseptic is at least one of benzalkonium chloride, parachlorometaxylenol, polyhexamethylene hydrochloric acid bisguanides;
Described peculiar smell removal agent is at least one of castor oil acid zinc salt, 4- ethyl -4- soybean-based ethyl-sulfate morpholines;
Described mould inhibitor is iodopropynyl butyl formate;
Other described auxiliary materials be essence, or essence and pigment mixing.
CN201611236964.1A 2016-12-28 2016-12-28 Footgear antibacterial deodorizing agent and preparation method thereof Pending CN106719771A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611236964.1A CN106719771A (en) 2016-12-28 2016-12-28 Footgear antibacterial deodorizing agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611236964.1A CN106719771A (en) 2016-12-28 2016-12-28 Footgear antibacterial deodorizing agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106719771A true CN106719771A (en) 2017-05-31

Family

ID=58924898

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611236964.1A Pending CN106719771A (en) 2016-12-28 2016-12-28 Footgear antibacterial deodorizing agent and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106719771A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107583087A (en) * 2017-09-07 2018-01-16 中山富士化工有限公司 A kind of deodorizing composition and spray for refreshing air
CN109777647A (en) * 2019-03-04 2019-05-21 广东欧蝶兰高新科技日用品有限公司 A kind of clothing removes peculiar smell composition
CN110313492A (en) * 2019-05-20 2019-10-11 安徽启威生物科技有限公司 A kind of footgear deodorizing antibiotic composition and preparation method thereof
CN110742062A (en) * 2019-11-18 2020-02-04 浙江绿岛科技有限公司 Refreshing type shoe and sock disinfection aerosol and preparation method thereof
CN114870056A (en) * 2022-05-31 2022-08-09 浙江巍华巨久科技有限公司 Antibacterial deodorant and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1947518A (en) * 2006-11-07 2007-04-18 林贤荣 Antimicrobial agent for leather-shoes
CN105875621A (en) * 2016-05-11 2016-08-24 于文 Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1947518A (en) * 2006-11-07 2007-04-18 林贤荣 Antimicrobial agent for leather-shoes
CN105875621A (en) * 2016-05-11 2016-08-24 于文 Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107583087A (en) * 2017-09-07 2018-01-16 中山富士化工有限公司 A kind of deodorizing composition and spray for refreshing air
CN109777647A (en) * 2019-03-04 2019-05-21 广东欧蝶兰高新科技日用品有限公司 A kind of clothing removes peculiar smell composition
CN110313492A (en) * 2019-05-20 2019-10-11 安徽启威生物科技有限公司 A kind of footgear deodorizing antibiotic composition and preparation method thereof
CN110742062A (en) * 2019-11-18 2020-02-04 浙江绿岛科技有限公司 Refreshing type shoe and sock disinfection aerosol and preparation method thereof
CN114870056A (en) * 2022-05-31 2022-08-09 浙江巍华巨久科技有限公司 Antibacterial deodorant and preparation method thereof
CN114870056B (en) * 2022-05-31 2023-02-14 浙江巍华巨久科技有限公司 Antibacterial deodorant and preparation method thereof

Similar Documents

Publication Publication Date Title
CN105875621A (en) Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof
CN106719771A (en) Footgear antibacterial deodorizing agent and preparation method thereof
CN109432470A (en) A kind of footgear deodorant compositions and preparation method thereof containing Caulis Sacchari sinensis extract
CN111714543A (en) Herbal essential oil with sterilization effect and preparation method and application thereof
CN109497093A (en) A kind of thimerosal
JP7003186B2 (en) Composition containing meso-2,3-butanediol
CN103813799A (en) Disinfecting formulations and uses thereof
CN109497094A (en) A kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate
CN104862152A (en) Mosquito-repelling toilet soap
CN106955639A (en) A kind of compound surfactant and preparation method thereof
CN104080343A (en) Method for disinfecting a surface
KR20200028557A (en) Eco-friendly mist fog and cloud spread agent with sterilization and insecticidal effect
CN107233249A (en) Plant extraction for one kind and nourish shower cream and preparation method thereof
CN103585057B (en) Mint compound essential oil
CN107753489B (en) Beriberi treating preparation and its preparation method
CN106106439A (en) Footgear deodorization and sterilization spraying reagent and preparation method thereof
CN102309773A (en) Biological deodorizing composition and preparation method thereof
JP6763613B2 (en) Prescription of grass scent and its use
CN104397042B (en) Disinfecting towel and its production method in footwear
CN110934157A (en) Natural herbal disinfectant for deodorizing and sterilizing surfaces of objects in refrigerator
CN109805044A (en) Plant source extraction deodorant and preparation method thereof
CN103585060B (en) Cedar compound essential oil
KR20060026362A (en) Composition for antimicrobial and deodorizing agents with functional materials
CN107674790A (en) A kind of degerming soap of antibacterial and preparation method thereof
TWI551679B (en) Mittel zur reinigung des innenraumes von schuhen

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531