CN109675429A - It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation - Google Patents
It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation Download PDFInfo
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- CN109675429A CN109675429A CN201910115566.1A CN201910115566A CN109675429A CN 109675429 A CN109675429 A CN 109675429A CN 201910115566 A CN201910115566 A CN 201910115566A CN 109675429 A CN109675429 A CN 109675429A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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Abstract
It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation, it by weight mainly include following components: 0.5 ~ 5 part of gel powder, 0.1 ~ 1.5 part of gel auxiliary agent, 2 ~ 15 parts of solubilizer, 1 ~ 5 part of carboxymethyl chitosan, 0.2 ~ 1 part of cinnamaldehyde diethylacetal, 2 ~ 4 parts of glutamic acid, 0.2 ~ 0.5 part of laruyl alcohol, 0.1 ~ 0.3 part of graphene oxide solution, 0.1 ~ 0.5 part of natural essential oil, 0.1 ~ 0.5 part of sterilization antiseptic, 0.05 ~ 0.1 part of other auxiliary agents, 40 ~ 60 parts of deionized water, the present invention is using solid pharmaceutical preparation as carrier, the pernicious gases such as formaldehyde are thoroughly eliminated by chemically reacting, has the effect of fresh air simultaneously, it is easily achieved and easy to use.
Description
Technical field
The invention belongs to daily-use chemical industry technical fields, and in particular to a kind of automobile-used except formaldehyde solid pharmaceutical preparation.
Background technique
China starts formally to implement " Air Quality Evaluation guide in passenger car " in March, 2012, and clear stipulaties are related
Benzene, dimethylbenzene, toluene, ethylbenzene, styrene, formaldehyde, acetaldehyde, 8 kinds of methacrylaldehyde common interior volatile organic matter concentration limit
Value successively supervises Automobile Enterprises to pay attention to product quality, reduces vehicle air pollution.
Formaldehyde is widely used, is a kind of simple production process, the public chemical products of raw material supply abundance, in chemical industry, wood
The fields such as material, weaving all generally use;But formaldehyde can generate stimulation to application on human skin mucous membrane, be greater than 0.08mg/m3Concentration
Can cause to be envious, eye is itched, throat discomfort or the adverse reactions such as pain, uncomfortable in chest, asthma, dermatitis, concentration of formaldehyde is excessively high also to be drawn
Play acute poisoning.
200 vehicles were once detected in Chinese interior decoration association air monitering center, as a result, it has been found that, if referring to Interior Space
Gas quality standard, all there is in-vehicle air formaldehyde or benzene content excessive problem in nearly 90% automobile, and most of vehicle formaldehyde is super
Mark is all at five or six times or more, and wherein the air quality of new car car is worst;External research test is even more to show: new car goes out
It is the volatilization time sustainable 6 months or more of harmful gas in vehicle concentration, interior in the meantime after factory, it can lead to passenger's body
Discomfort is also possible to cause traffic accident when serious, and therefore, the product for researching and developing a kind of formaldehyde that can effectively remove car is even more important.
Under the development of current science and technology, various purifying formaldehyde materials also occur in succession, similar with adsorbent materials such as active carbons
Based on adsorbent, using titanium dioxide and noble metal as the catalyst of representative, it is various release fragrance cover methanol peculiar smell skies
Gas freshener etc., product form is also varied, non-woven fabrics charcoal bag, air purifier, spray, coagulator etc..
Application No. is the patents of CN107185020A to disclose a kind of solid freshener for purifying in-vehicle air, main component
For aluminum sulfate, active carbon, extraction of essential oil liquid etc., gas with foreign flavor is mainly adsorbed by way of absorption and fragrant cover is different
Taste, but " volume " of program adsorbed gas is limited, it is easy to it fails, and nothing pointedly adsorbs pernicious gas, clean-up effect
It is not strong;Application No. is the patents of CN105749479A to disclose a kind of new house except formaldehyde formulations, if by spray be sprayed on furniture,
Ground, woven face can effectively absorb the harmful elements such as formaldehyde, benzene homologues on metope, have a long-term effect, but the technical solution
The form of spray clearly not applys to the car of facility compact complexity.
Summary of the invention
In view of the above problems, it is automobile-used except formaldehyde solid pharmaceutical preparation that the object of the present invention is to provide one kind, with solid system
Agent is carrier, is thoroughly eliminated the pernicious gases such as formaldehyde by chemically reacting, while having the effect of fresh air, it is easy to accomplish
And it is easy to use.
To achieve the goals above, technical scheme is as follows:
It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation, in parts by weight, including following components: 0.5 ~ 5 part of gel powder, gel auxiliary agent
0.1 ~ 1.5 part, 2 ~ 15 parts of solubilizer, 1 ~ 5 part of carboxymethyl chitosan, 0.2 ~ 1 part of cinnamaldehyde diethylacetal, 2 ~ 4 parts of glutamic acid, the moon
0.2 ~ 0.5 part of cinnamic alcohol, 0.1 ~ 0.3 part of graphene oxide solution, 0.1 ~ 0.5 part of natural essential oil, 0.1 ~ 0.5 part of sterilization antiseptic,
0.05 ~ 0.1 part of other auxiliary agents, 40 ~ 60 parts of deionized water.
Preferably, the solid pharmaceutical preparation is in parts by weight, including following components: 0.6 ~ 3 part of gel powder, gel helps
0.3 ~ 1.0 part of agent, 2 ~ 8 parts of solubilizer, 1 ~ 5 part of carboxymethyl chitosan, 0.5 ~ 1 part of cinnamaldehyde diethylacetal, 2 ~ 4 parts of glutamic acid,
0.2 ~ 0.3 part of laruyl alcohol, 0.1 ~ 0.3 part of graphene oxide solution, 0.1 ~ 0.5 part of natural essential oil, sterilization antiseptic 0.2 ~ 0.4
Part, 0.05 ~ 0.1 part of other auxiliary agents, 40 ~ 60 parts of deionized water.
Above scheme, gel powder, gel auxiliary agent, deionized water, the prepared composition that sterilization antiseptic is solid pharmaceutical preparation;Naturally
Essential oil, solubilizer are auxiliary additive, and natural essential oil is common plants essential oil such as tea tree ethereal oil, eucalyptus oil etc., and solubilizer is used
In the solubility of increase natural essential oil in water;Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol, oxidation stone
Black alkene solution is functional additive, and there is carboxymethyl chitosan "-OH " electrophilic addition reaction elimination methanol can occur with formaldehyde,
Cinnamaldehyde diethylacetal can then occur to eliminate methanol through aldehyde condensation reaction with formaldehyde, and glutamic acid has "-NH2" can be with methanol
Affine addition reaction occurs, laruyl alcohol can promote graphene oxide when working with graphene oxide solution one well
Solution and other compositions are dissolved each other;It is obtained except formaldehyde solid pharmaceutical preparation be gel-type, can make in solid pharmaceutical preparation except formaldehyde at
Divide and continue slow release, action time is longer;The solid pharmaceutical preparation also have the function of common solid freshener fresh air and
It is easy to place, advantage easy to use.
Carried out by preferably, the gel powder be carragheen, gellan gum, agar any or two or more mixture.
Above-mentioned gel powder is preferably the mixing of one or both of carragheen and gellan gum arbitrary proportion, and carragheen is one
Kind Qinshui gelling agent, gellan gum is a kind of novel microbial exocellular polysaccharide, and both the natural hydrophilic gel in source, can answer
For in grocery trade, property to be excellent and safety coefficient is high.
Preferably, the gel auxiliary agent is any or two or more mixture of calcium lactate, sodium citrate, it is excellent
It is selected as calcium lactate.
Preferably, the solubilizer is Tween-80, rilanit special is any or two or more mixtures, it is excellent
It is selected as rilanit special.
Preferably, the sterilization antiseptic is one or more of sodium benzoate, methylisothiazolinone
Mixture, preferably methylisothiazolinone.
The solid pharmaceutical preparation is prepared by following processing step: (1) first sufficiently being stirred gel powder in 90 ~ 95 DEG C of hot water
It mixes to clear solution, gel auxiliary agent is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, insulated and stirred obtains liquid a;(2) will
Natural essential oil, solubilizer are mixed evenly, and obtain liquid b;(3) carboxymethyl will be added after graphene oxide solution ultrasonic disperse
Chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol, are uniformly mixed, and obtain liquid c;(4) liquid b, c are mixed and is stirred
It is then added in liquid a and is mixed after mixing uniformly, sterilization antiseptic, other auxiliary agents is then added, stirs evenly, filtering and discharging
Filling finished product.
Preferably, other auxiliary agents are that universaling components, the kinds such as light stabilizer, antioxidant, pigment do not do specific limit
System.
Preferably, the solid pharmaceutical preparation is also added with 1 ~ 5 part of polyethylene glycol.
Polyethylene glycol has preferable stablizing effect to integral system, can assist in the above-mentioned formaldehyde substance that removes and plays a role,
Polyethylene glycol is preferably polyethylene glycol 400.
In conclusion the invention has the following advantages:
It selects gel solids preparation as the carrier for removing formaldehyde components, can make effectively, longer to discharge except formaldehyde components, be applicable in
Complicated, narrow space the special circumstances in automobile equipment remove formaldehyde formulations ratio with tradition, and product is sustainable except formaldehyde acts on 20 days
More than, function and effect are good and the duration is long;Not only smell faint scent is natural and has bacteriostasis efficacy for the product;Product used
Journey is more environmentally-friendly, healthy, conveniently, safely, meets consumer's green, pure and fresh, natural requirement to air.
Specific embodiment
Embodiment 1
According to the formulation content of table 1, for preparing embodiment 1 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by carragheen
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, calcium lactate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, heat preservation
Stirring, obtains liquid a;(2) tea tree ethereal oil, solubilizer rilanit special are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, methylisothiazolinone, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Embodiment 2
According to the formulation content of table 1, for preparing embodiment 1 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by carragheen
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, calcium lactate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, heat preservation
Stirring, obtains liquid a;(2) tea tree ethereal oil, solubilizer rilanit special are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, methylisothiazolinone, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Embodiment 3
According to the formulation content of table 1, for preparing embodiment 3 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by carragheen
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, calcium lactate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, heat preservation
Stirring, obtains liquid a;(2) tea tree ethereal oil, solubilizer rilanit special are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, methylisothiazolinone, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Table 1 is the automobile-used formula composition except formaldehyde solid pharmaceutical preparation of embodiment 1 ~ 3:
Table 1
Embodiment 4
According to the formulation content of table 2, for preparing embodiment 4 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by gellan gum
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, sodium citrate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, protects
Temperature stirring, obtains liquid a;(2) eucalyptus oil, solubilizer Tween-80 are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, sodium benzoate, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Embodiment 5
According to the formulation content of table 2, for preparing embodiment 5 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by gellan gum
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, sodium citrate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, protects
Temperature stirring, obtains liquid a;(2) eucalyptus oil, solubilizer Tween-80 are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, sodium benzoate, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Embodiment 6
According to the formulation content of table 2, for preparing embodiment 6 removes formaldehyde solid pharmaceutical preparation, and preparation method is: (1) first by gellan gum
It is stirred well to clear solution in 90 ~ 95 DEG C of hot water, sodium citrate is added, stirring sufficiently, is then cooled to 60 ~ 65 DEG C, protects
Temperature stirring, obtains liquid a;(2) eucalyptus oil, solubilizer Tween-80 are mixed evenly, obtain liquid b;It (3) will oxidation
Carboxymethyl chitosan, cinnamaldehyde diethylacetal, glutamic acid, laruyl alcohol are added after graphene solution ultrasonic disperse, is stirred
It is even, obtain liquid c;(4) it is then added in liquid a and is mixed after liquid b, c being mixed evenly, poly- second two is then added
Alcohol 400, sodium benzoate, antioxidant, pigment stir evenly, the filling finished product of filtering and discharging.
Table 2 is the automobile-used formula composition except formaldehyde solid pharmaceutical preparation of embodiment 4 ~ 6:
Table 2
The three kinds of different model vehicles of certain brand just to have dispatched from the factory are chosen, detection formaldehyde content of the car is respectively 0.18mg/m3、0.15mg/
m3、0.20mg/m3;1 ~ 6 solid pharmaceutical preparation of embodiment is placed in car simultaneously, per content of formaldehyde measurement is carried out after a period of time, as a result
Such as table 3 ~ 5:
Table 3
Table 4
Table 5
According to shown in table 3 ~ 5,1 ~ 6 product of embodiment can make formaldehyde content of the car be down to 0.10mg/m after acting on 48h3With
Under, content of formaldehyde gradually reduces after monitoring 20 days, and formaldehyde can be effectively removed by illustrating products obtained therefrom of the present invention and effect can be up to 20
It.
Product of the present invention has excellent removal effect of formaldehyde, and smell is fresh and clean and has bacteriostasis efficacy, and product opens wide
It prevents that effectiveness can be continued 20 days, it is easy to use.Product is more environmentally-friendly in use, healthy, safe, meets consumer couple
Green, pure and fresh, the natural requirement of in-vehicle air.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention
The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method
In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Claims (9)
1. a kind of automobile-used except formaldehyde solid pharmaceutical preparation, which is characterized in that in parts by weight, including following components:
0.5 ~ 5 part of gel powder, 0.1 ~ 1.5 part of gel auxiliary agent, 2 ~ 15 parts of solubilizer, 1 ~ 5 part of carboxymethyl chitosan, cinnamic acid diethyl
0.2 ~ 1 part of acetal, 2 ~ 4 parts of glutamic acid, 0.2 ~ 0.5 part of laruyl alcohol, 0.1 ~ 0.3 part of graphene oxide solution, natural essential oil 0.1 ~
0.5 part, 0.1 ~ 0.5 part of sterilization antiseptic, 0.05 ~ 0.1 part of other auxiliary agents, 40 ~ 60 parts of deionized water.
2. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that in parts by weight, packet
Include following components:
0.6 ~ 3 part of gel powder, 0.3 ~ 1.0 part of gel auxiliary agent, 2 ~ 8 parts of solubilizer, 1 ~ 5 part of carboxymethyl chitosan, cinnamic acid diethyl
0.5 ~ 1 part of acetal, 2 ~ 4 parts of glutamic acid, 0.2 ~ 0.3 part of laruyl alcohol, 0.1 ~ 0.3 part of graphene oxide solution, natural essential oil 0.1 ~
0.5 part, 0.2 ~ 0.4 part of sterilization antiseptic, 0.05 ~ 0.1 part of other auxiliary agents, 40 ~ 60 parts of deionized water.
3. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the gel powder is OK a karaoke club
Glue, gellan gum, agar any or two or more mixture.
4. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the gel auxiliary agent is lactic acid
Any or two or more mixture of calcium, sodium citrate.
5. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the solubilizer is tween-
80, rilanit special any one or two or more mixtures.
6. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the sterilization antiseptic is benzene
The mixture of one or more of sodium formate, methylisothiazolinone.
7. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the solid pharmaceutical preparation is by following
Processing step is prepared: (1) first gel powder in 90 ~ 95 DEG C hot water is stirred well to clear solution, gel auxiliary agent is added,
Stirring sufficiently, is then cooled to 60 ~ 65 DEG C, insulated and stirred obtains liquid a;(2) natural essential oil, solubilizer are mixed equal
It is even, obtain liquid b;(3) carboxymethyl chitosan, cinnamaldehyde diethylacetal, paddy will be added after graphene oxide solution ultrasonic disperse
Propylhomoserin, laruyl alcohol, are uniformly mixed, and obtain liquid c;(4) it is then added to after liquid b, c being mixed evenly in liquid a
It is mixed, sterilization antiseptic, other auxiliary agents is then added, stirs evenly, the filling finished product of filtering and discharging.
8. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that other auxiliary agents are that light is steady
Determine agent, antioxidant, pigment etc..
9. one kind according to claim 1 is automobile-used to remove formaldehyde solid pharmaceutical preparation, which is characterized in that the solid pharmaceutical preparation also adds
There is 1 ~ 5 part of polyethylene glycol.
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CN201910115566.1A CN109675429A (en) | 2019-02-15 | 2019-02-15 | It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation |
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CN201910115566.1A CN109675429A (en) | 2019-02-15 | 2019-02-15 | It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110252115A (en) * | 2019-06-20 | 2019-09-20 | 深圳市中拓智森环保科技有限公司 | Multifunctional air cleaning agent |
CN110935298A (en) * | 2019-10-31 | 2020-03-31 | 常晓军 | Formaldehyde removal freshener and preparation method thereof |
CN111701439A (en) * | 2020-07-06 | 2020-09-25 | 上海弘知生物科技有限公司 | Formaldehyde-removing color-changing gel with visual perception and preparation method thereof |
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CN105749479A (en) * | 2016-03-02 | 2016-07-13 | 许五妮 | Formaldehyde removing preparation used in new houses |
CN107185020A (en) * | 2017-04-06 | 2017-09-22 | 肖志远 | The solid freshener of air in purifying vehicle |
CN108753470A (en) * | 2018-06-01 | 2018-11-06 | 郴州博太超细石墨股份有限公司 | A kind of clothing is with removing formaldehyde agent |
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US4443354A (en) * | 1982-03-26 | 1984-04-17 | Minnesota Minning And Manufacturing Company | Sorbent material for reducing formaldehyde emission |
CN103690981A (en) * | 2013-11-13 | 2014-04-02 | 东莞市日友汽车用品有限公司 | Powerful purification paste and preparation method thereof |
CN104274848A (en) * | 2014-05-25 | 2015-01-14 | 许春晖 | Air freshener with aldehyde removing effect |
CN104027829A (en) * | 2014-06-09 | 2014-09-10 | 广州立白企业集团有限公司 | Solid freshener containing lemon tea tree essential oil component and preparation method of solid freshener |
CN105749479A (en) * | 2016-03-02 | 2016-07-13 | 许五妮 | Formaldehyde removing preparation used in new houses |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110252115A (en) * | 2019-06-20 | 2019-09-20 | 深圳市中拓智森环保科技有限公司 | Multifunctional air cleaning agent |
CN110935298A (en) * | 2019-10-31 | 2020-03-31 | 常晓军 | Formaldehyde removal freshener and preparation method thereof |
CN111701439A (en) * | 2020-07-06 | 2020-09-25 | 上海弘知生物科技有限公司 | Formaldehyde-removing color-changing gel with visual perception and preparation method thereof |
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