CN114808434B - 高耐静水压持久抗菌面料的制备方法 - Google Patents

高耐静水压持久抗菌面料的制备方法 Download PDF

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CN114808434B
CN114808434B CN202210286010.0A CN202210286010A CN114808434B CN 114808434 B CN114808434 B CN 114808434B CN 202210286010 A CN202210286010 A CN 202210286010A CN 114808434 B CN114808434 B CN 114808434B
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hydrostatic pressure
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CN114808434A (zh
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齐元章
国靖
许秋生
李庆印
丁继惠
仲伟浩
王桂艳
谢汝义
刘桂杰
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Lufeng Weaving and Dyeing Co Ltd
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Abstract

本发明涉及一种高耐静水压持久抗菌面料的制备方法，属于纺织印染技术领域。本发明所述的高耐静水压持久抗菌面料的制备方法，面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；面料采用新疆长绒棉纤维与汉麻纤维为原料的混纺纱织造；所述混纺纱选用普梳环锭纺纱线。本发明设计科学合理，工艺流程简短，制得的面料耐可静水压500mm H2O以上，具有优异的持久抗菌、防水、高耐静水压功能。

Description

高耐静水压持久抗菌面料的制备方法
技术领域
本发明涉及一种高耐静水压持久抗菌面料的制备方法，属于纺织印染技术领域。
背景技术
汉麻具有广谱抗菌效果，并有极佳的吸湿透气性能，将汉麻用于厨师服、餐厅服务员围裙、护士罩衣等劳保面料可有效改善从业人员的工作条件，大部分此类劳保用品都具有防水甚至耐高静水压的功能。但麻类面料的防水加工难度大，麻结、织疵多使得耐静水压性能也较差。
目前主流解决高耐静水压的方案是在面料里面覆膜，但是此工艺加工流程长，透气性差，完全损失了汉麻透气性的优势。
专利CN201910667102.1中公开了一种抗菌复合面料，其通过在面料层表面设置抗菌TPU膜层来实现防水功能，面料层和抗菌TPU膜层之间设置有胶黏层，胶黏层包括1-10wt％的阻燃型环氧树脂和90-99wt％的热熔胶，制得的复合面料具有防水性能，但是其使用的粘合剂安全性低、透气性差。
在纺织印染领域经常用到的设备为空气洗设备，而空气洗设备配有料槽、轧车、烘房，可以对面料进行轧料处理，但目前空气洗设备主要是进行轧水或面料直接进入烘房，即现有技术中并未对该设备进行充分利用。
专利CN202110153710.8中公开了一种亚麻弹力面料的制备方法，其用空气洗设备进行超柔软整理，超柔软车速为40-60m/min，风量为50-60％，并未使用任何助剂，其目的单纯的是为改善手感。
发明内容
本发明的目的在于提供一种高耐静水压持久抗菌面料的制备方法，其设计科学合理，工艺流程简短，制得的面料耐可静水压500mm H2O以上，具有优异的持久抗菌、防水、高耐静水压功能。
本发明所述的高耐静水压持久抗菌面料的制备方法，包括以下步骤：
面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；
面料采用新疆长绒棉纤维与汉麻纤维为原料的混纺纱织造；
所述混纺纱选用普梳环锭纺纱线。
优选的，新疆长绒棉纤维的用量为55％-70％，汉麻纤维的用量为30％-45％。
为了实现最佳抗净水压效果，需要调整面料的最佳密度与组织。优选的，面料成品规格：C/L30*C/L30*145*85*55/56，组织：1/1。
优选的，冷轧堆工序中，堆置时间18-26h，堆置温度30-36℃，车速40-50m/min，冷堆液组成为：烧碱30-35g/L，双氧水3-5g/L，螯合剂3-4g/L，精炼剂4-5g/L，渗透剂3-5g/L，余量为水。
其中，渗透剂、螯合剂、精炼剂可以选择市售任意产品。
进一步优选的，螯合剂选择鲁瑞精细化工有限公司的SQ-A；渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择鲁瑞精细化工有限公司的SA-U。
优选的，煮漂工序中，工作液组成为：双氧水12-15g/L，烧碱2-3g/L，渗透剂3-5g/L，精炼剂3-4g/L，稳定剂4-5g/L，余量为水；经过蒸箱的时间为20-25分钟，车速40-45m/min。其中，渗透剂、精炼剂、稳定剂可以选择市售任意产品。
进一步优选的，渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择科莱恩化工有限公司的Hostapal*UH；稳定剂选择鲁瑞精细化工有限公司的HP-S。
优选的，染色工序中：
轧干工序，染料使用高日晒还原染料，轧干车速30-40m/min；
固色工序中，车速40--50m/min，蒸箱温度99±2℃，溢流水3000-3600L/H，水洗槽温度95±2℃，元明粉：120-150g/L，纯碱：10-20g/L，防染盐：1-3g/L。
优选的，空气洗工序中：温度110-120℃，上风量80％，下风量45％，排风量：70％，烘房处理时间25-30min，工作液使用C6三防整理剂与抗菌助剂，工作液组成为：疏水剂120-180g/L，交联促进剂40-60g/L，抗菌剂：30-60g/L，余量为水。
所述疏水剂为氟碳化合物共聚物，进一步优选的，疏水剂为青岛欧诺思化工有限公司AM-5602；所述交联促进剂为封端聚氨酯，进一步优选的，交联促进剂为青岛欧诺思化工有限公司NN-1；所述抗菌剂为银离子无机盐、氢氧化铵以及乙醇的混合物，进一步优选的，抗菌剂为陶氏化学(中国)投资有限公司的930-flex。
优选的，焙烘工序中，烘房温度为165-175℃，焙烘时间为3-4min。
本发明通过使用棉麻混纺纱线，改善麻类面料手感，提高布面均匀程度；并研发空气洗技术，提升面料的毛羽效果，填充纱线间空隙、弥补织疵；在空气洗设备中将三防助剂、抗菌助剂有机结合，最终实现短流程的高耐静水压持久抗菌面料制备方法，并实现持久抗菌、防水等多种功能的整合，可用于包括厨师服、餐厅服务员围裙、护士罩衣等在内的劳保面料以及装饰用途。
与现有技术相比，本发明具有以下有益效果：
(1)本发明所述的面料使用普梳环锭纺纱线，提高了面料纱线间的填充程度，面料成本低；
(2)本发明所述的面料汉麻纤维的用量为30％-45％，纱线材料上具有广谱抗菌效果，再叠加银离子抗菌技术，能够实现持久抗菌；
(3)本发明通过优选组织规格，C/L30*C/L30*145*85*55/56，组织：1/1，结合三防整理可实现最佳耐静水压效果，耐静水压可达500mm H2O以上；
(4)本发明通过空气洗技术，改善面料手感，并填充纱线间的孔隙以及纱疵造成的空洞；
(5)本发明在空气洗中将抗菌助剂与三防助剂一浴，防水(AATCC 22)洗前100分15次洗后90分；50次水洗后抗菌效果仍能达到金黄色葡萄球均抑制率99％，大肠杆菌抑制率99％。
具体实施方式
下面结合实施例对本发明作进一步的说明，但其并不限制本发明的实施。
所用原料如无特别说明，均为市售常规产品。
实施例1
一种高耐静水压持久抗菌面料，面料成品规格：C/L30*C/L30*145*85*55/56，组织：1/1，采用新疆长绒棉纤维与汉麻纤维为原料的混纺纱织造，新疆长绒棉纤维与汉麻的混纺比例为65％：35％；所述混纺纱选用普梳环锭纺纱线。
面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；具体步骤如下：
(1)冷堆：堆置时间18h，堆置温度30℃，车速40m/min，冷堆液组成为：烧碱30g/L，双氧水3g/L，螯合剂3g/L，精炼剂4g/L，渗透剂3g/L，余量为水。
螯合剂选择鲁瑞精细化工有限公司的SQ-A；渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择鲁瑞精细化工有限公司的SA-U。
(2)煮漂：工作液组成为：双氧水12g/L，烧碱2g/L，渗透剂3g/L，精炼剂3g/L，稳定剂4g/L，余量为水；经过蒸箱的时间为20分钟，车速40m/min。
渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择科莱恩化工有限公司的Hostapal*UH；稳定剂选择鲁瑞精细化工有限公司的HP-S。
(3)染色：轧干工序，染料使用高日晒还原染料，轧干车速30m/min，固色工序中，车速40m/min，蒸箱温度99±2℃，溢流水3000L/H，水洗槽温度95±2℃，元明粉：120g/L，纯碱：10g/L，防染盐：1g/L
高日晒染料为Huntsman生产的BCL-BR。
(4)空气洗：温度110℃，上风量80％，下风量45％，排风量：70％，烘房处理时间30min，工作液组成为：疏水剂180g/L，交联促进剂60g/L，抗菌剂：60g/L，余量为水。
疏水剂选择青岛欧诺思化工有限公司的AM-5602；交联促进剂选择青岛欧诺思化工有限公司的NN-1；抗菌剂选择陶氏化学(中国)投资有限公司的930-flex。
(5)焙烘：温度175℃，焙烘时间3min。
实施例2
面料成品规格：：C/30*C/L30*145*85*55/56，组织：1/1，新疆长绒棉纤维与汉麻的混纺比例为65％：35％；所述混纺纱选用普梳环锭纺纱线。
面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；具体步骤如下：
(1)冷堆：堆置时间26h，堆置温度36℃，车速50m/min，冷堆液组成为：烧碱35g/L，双氧水5g/L，螯合剂4g/L，精炼剂5g/L，渗透剂5g/L，余量为水。
螯合剂选择鲁瑞精细化工有限公司的SQ-A；渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择鲁瑞精细化工有限公司的SA-U。
(2)煮漂：工作液组成为：双氧水15g/L，烧碱3g/L，渗透剂5g/L，精炼剂4g/L，稳定剂5g/L，余量为水；经过蒸箱的时间为25分钟，车速45m/min。
渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择科莱恩化工有限公司的Hostapal*UH；稳定剂选择鲁瑞精细化工有限公司的HP-S。
(3)染色：轧干工序，染料使用高日晒还原染料，轧干车速40m/min，固色工序中，车速50m/min，蒸箱温度99±2℃，溢流水3600L/H，水洗槽温度95±2℃，元明粉：150g/L，纯碱：20g/L，防染盐：3g/L。
高日晒染料为Huntsman生产的BCL-BR。
(4)空气洗：温度120℃，上风量80％，下风量45％，排风量：70％，烘房处理时间25-min，工作液组成为：疏水剂120g/L，交联促进剂40g/L，抗菌剂：30g/L，余量为水。
疏水剂选择青岛欧诺思化工有限公司的AM-5602；交联促进剂选择青岛欧诺思化工有限公司的NN-1；抗菌剂选择陶氏化学(中国)投资有限公司的930-flex。
(5)焙烘：温度165℃，焙烘时间4min。
实施例3
一种高耐静水压持久抗菌面料，面料成品规格：C/L30*C/L30*145*85*55/56，组织：1/1，采用新疆长绒棉纤维与汉麻纤维为原料的混纺纱织造，新疆长绒棉纤维与汉麻的混纺比例为65％：35％；所述混纺纱选用普梳环锭纺纱线。
面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；具体步骤如下：
(1)冷堆：堆置时间24h，堆置温度34℃，车速45m/min，冷堆液组成为：烧碱32g/L，双氧水4g/L，螯合剂3g/L，精炼剂4g/L，渗透剂3g/L，余量为水。
螯合剂选择鲁瑞精细化工有限公司的SQ-A；渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择鲁瑞精细化工有限公司的SA-U。
(2)煮漂：工作液组成为：双氧水14g/L，烧碱3g/L，渗透剂4g/L，精炼剂3g/L，稳定剂4g/L，余量为水；经过蒸箱的时间为22分钟，车速42m/min。
渗透剂选择鲁瑞精细化工有限公司的WA-M；精炼剂选择科莱恩化工有限公司的Hostapal*UH；稳定剂选择鲁瑞精细化工有限公司的HP-S。
(3)染色：轧干工序，染料使用高日晒还原染料，轧干车速30m/min，固色工序中，车速35m/min，蒸箱温度99±2℃，溢流水3000L/H，水洗槽温度95±2℃，元明粉：120g/L，纯碱：10g/L，防染盐：1g/L
高日晒染料为Huntsman生产的BCL-BR。
(4)空气洗：温度115℃，上风量80％，下风量45％，排风量：70％，烘房处理时间28min，工作液组成为：疏水剂150g/L，交联促进剂45g/L，抗菌剂：50g/L，余量为水。
疏水剂选择青岛欧诺思化工有限公司的AM-5602；交联促进剂选择青岛欧诺思化工有限公司的NN-1；抗菌剂选择陶氏化学(中国)投资有限公司的930-flex。
(5)焙烘：温度170℃，焙烘时间3.5min。
对比例1
本对比例制备的面料，与实施例1的面料同材质、同纺纱方式，面料成品规格：C/30*C/L30*140*75*55/56，组织：1/1，新疆长绒棉纤维与汉麻的混纺比例为65％：35％；所述混纺纱选用普梳环锭纺纱线。
面料整理工艺流程与实施例1完全相同。
对比例2
本对比例制备的面料，与实施例1的面料同克重、同纺纱方式，面料成品规格CVC30*CVC 30*145*85*55/56，组织：1/1，涤纶短纤维与新疆长绒棉纤维的混纺比例为35％：65％；
面料整理工艺流程与实施例1完全相同。
对比例3
本对比例制备的面料，与实施例1的面料同克重、同材质，面料成品规格、组织、纱线完全相同。
面料整理工艺流程与实施例1基本相同，不同点仅在于：
空气洗工序中，三防整理剂使用碳氢化合物类无氟防水剂(此防水剂为青岛欧诺斯化工SA-9)，SA-9：150g/L。
对比例4
本对比例制备的面料，与实施例1的面料同克重、同材质，面料成品规格、组织、纱线完全相同。
面料整理工艺流程与实施例1基本相同，不同点仅在于：
将空气洗工序替换为拉幅三防，工艺为：工作液组成为：疏水剂120g/L，交联促进剂40g/L，抗菌剂：30g/L，余量为水；烘干温度120℃，车速30m/min。
将实施例1-2和对比例1-4的布面料进行性能测试，测试结果如表1所示。
表1性能测试结果

Claims (2)

1.一种高耐静水压持久抗菌面料的制备方法，其特征在于：面料整理工艺流程为：冷堆→煮漂→染色→空气洗→焙烘；
面料采用新疆长绒棉纤维与汉麻纤维为原料的混纺纱织造；
所述混纺纱选用普梳环锭纺纱线；
新疆长绒棉纤维的用量为55%-70%，汉麻纤维的用量为30%-45%；
面料成品规格：C/L30* C/L30*145*85*55/56，组织：1/1；
空气洗工序中，工作液使用C6三防整理剂与抗菌助剂，进烘房在110-120℃温度下拍打25-30min；
工作液组成为：疏水剂AM-5602 120-180g/L，交联促进剂NN-1 40-60g/L，抗菌剂930-flex：30-60g/L，余量为水。
2.根据权利要求1所述的高耐静水压持久抗菌面料的制备方法，其特征在于：焙烘工序中，烘房温度为165-175℃，焙烘时间为3-4min。
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