CN114794142A - Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero - Google Patents

Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero Download PDF

Info

Publication number
CN114794142A
CN114794142A CN202110082224.1A CN202110082224A CN114794142A CN 114794142 A CN114794142 A CN 114794142A CN 202110082224 A CN202110082224 A CN 202110082224A CN 114794142 A CN114794142 A CN 114794142A
Authority
CN
China
Prior art keywords
disinfectant
hydrogen peroxide
mixed
disinfection
peroxyacetic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110082224.1A
Other languages
Chinese (zh)
Inventor
师强
刘杉林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Bioniclean Biotechnology Co ltd
Original Assignee
Suzhou Bioniclean Biotechnology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Bioniclean Biotechnology Co ltd filed Critical Suzhou Bioniclean Biotechnology Co ltd
Priority to CN202110082224.1A priority Critical patent/CN114794142A/en
Publication of CN114794142A publication Critical patent/CN114794142A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/12Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/16Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof

Abstract

The invention discloses a peroxyacetic acid and hydrogen peroxide composite disinfectant used in an environment with the temperature of above 24 ℃ below zero, which comprises peroxyacetic acid with the disinfection function and the volume percentage of 0.1-1 percent, hydrogen peroxide with the volume percentage of 1-6 percent, propylene glycol with the disinfection and anti-freezing functions and the volume percentage of 20-60 percent, and a solvent; the invention can be used in the environment of more than 24 ℃ below zero, has high-level disinfection and more environmental protection and safety, and simultaneously has long-term effective medium-level disinfection and antibacterial and bacteriostatic effects, because the hydrogen peroxide is added into the mixed disinfectant, the stability of the disinfectant is further improved, and the disinfection capability is further improved on the basis of the disinfection capability of the peracetic acid.

Description

Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero
Technical Field
The invention belongs to the field of disinfection, and particularly relates to a peroxyacetic acid and hydrogen peroxide composite disinfectant suitable for an environment with a temperature of above-24 ℃.
Background
In the outdoor disinfection operation in winter, or in the disinfection operation in a cold storage house or in the disinfection operation in the cold chain transportation link, the common disinfectant can be frozen and cannot be used; or the water is frozen in the spraying process and cannot be used; or ice is formed on the surface of the object, which affects the disinfection effect. With the popularity of frozen foods and the development of cold chain transportation, the low-temperature disinfectant which is high-efficiency and sustainable has wide market demand. The common alcohol disinfectant has better anti-freezing performance, but has lower disinfection capability, and in addition, the alcohol disinfectant has the characteristics of flammability and explosiveness, has special requirements on storage and transportation, and brings inconvenience to use.
The current disinfectants are classified into high-level disinfectants, medium-level disinfectants and low-level disinfectants, wherein the high-level disinfectants can be used for broad-spectrum disinfection, and commonly used disinfectants containing chlorine (such as 84 disinfectant), disinfectants containing bromine, ozone, glutaraldehyde, chlorine dioxide, hydrogen peroxide, peracetic acid, formaldehyde (formalin), and the like; among them, chlorine-containing disinfectants (hypochlorous acid aqueous solutions), chlorine dioxide aqueous solutions, hydrogen peroxide aqueous solutions, peracetic acid aqueous solutions, etc. are used for environmental spraying work. Aqueous solutions of these disinfectants cannot be used below freezing.
For the disinfectant used in winter, in order to lower the freezing temperature, there is generally a method of adding methanol, ethanol or ethylene glycol. For example CN 2019114139173, CN2014107879645, CN 2020111071063. When the antifreezing agent is used, the disinfectant can be kept liquid when being sprayed or sprinkled, but the problem of condensation and precipitation of the water agent can occur along with the volatilization of the alcohol. In addition, the alcohols are dangerous chemicals, and the links of production, transportation, storage and the like all need to meet relevant regulations, and are complex and inconvenient. More importantly, the alcohols are flammable and explosive, are not used properly and have the risk of flash explosion; meanwhile, methanol is a toxic substance, and the use is reduced or avoided; the toxicity of the disinfectant component is also a consideration if it is to be used for the sterilization of food overwrap; there is a need to find a high level disinfectant that not only can be used well in sufficiently low temperature environments, but also is more environmentally safe.
Disclosure of Invention
In view of the above, there is a need to overcome at least one of the above-mentioned deficiencies in the prior art. The invention provides a peroxyacetic acid and hydrogen peroxide composite disinfectant used in an environment with the temperature of more than 24 ℃ below zero, which comprises peroxyacetic acid with the disinfection function and the volume percentage of 0.1-1 percent, hydrogen peroxide with the volume percentage of 1-6 percent, propylene glycol with the disinfection and anti-freezing functions and the volume percentage of 20-60 percent, and a solvent.
The technical scheme provides a high-level disinfectant which can be used for disinfecting in an environment with the temperature of more than 24 ℃ below zero and is more environment-friendly and safer, and meanwhile, the disinfectant has long-term antibacterial and bacteriostatic effects; in the scheme, the mixed liquid of peracetic acid, hydrogen peroxide and propylene glycol is adopted, so that the functions can be realized, wherein the peracetic acid is a high-efficiency disinfectant and is a non-hazardous chemical product, and meanwhile, the peracetic acid is decomposed into acetic acid after entering the environment, so that the environment-friendly and safe green disinfectant is provided; furthermore, compared with ethanol, the propylene glycol has good low-temperature characteristics, also has certain disinfection capacity, has the effect close to that of ethanol, can be used as a food additive, and has better safety; wherein, all disinfectant components are safe in the mixed disinfectant, can be used for the disinfection of food package, because add hydrogen peroxide in the mixed disinfectant, not only further promoted the stability of disinfectant, also further promoted the disinfection ability on the basis of peracetic acid disinfection ability.
In addition, the peroxyacetic acid and hydrogen peroxide composite disinfectant used in the environment above-24 ℃ disclosed by the invention also has the following additional technical characteristics:
further, the peroxyacetic acid is 0.1-1.0% by volume.
Hydrogen peroxide with the concentration of 1-6 percent is a high-efficiency disinfectant and is a non-dangerous chemical; hydrogen peroxide can be decomposed into water and oxygen after entering the environment, and the hydrogen peroxide is a green disinfectant; the mixed disinfectant is added with hydrogen peroxide, so that the stability of the mixed disinfectant is improved, and the storage life is prolonged. Meanwhile, the disinfectant liquid of the unitary peroxyacetic acid (containing hydrogen peroxide) is used, so that the preparation of the disinfectant liquid is convenient.
Further, the propylene glycol accounts for 20-60% by volume.
Furthermore, the mixed disinfectant also comprises NaCl with anti-freezing and ice-melting functions, the solvent is water, and the NaCl can effectively lower the freezing point of water, has an ice-melting effect and enhances the efficacy of the disinfectant.
Furthermore, the weight concentration of the NaCl accounts for 0.5 to 5 percent.
Furthermore, the mixed disinfectant also comprises a mixture of high molecular polymers, wherein the mixture contains 50-2000PPM of double-chain quaternary ammonium salt. The mixture is a high molecular polymer, has good stability, can exist in the environment for a long time, has the effects of killing and inhibiting bacteria and viruses, has the antibacterial effect lasting for more than three months, and can effectively kill escherichia coli and staphylococcus aureus even with the concentration of only 10-50ppm in the melting process of ice on the surface of an object. Therefore, the sterilizing capability can be kept for a long time, and the sterilizing effect of the disinfectant can be enhanced by using the mixture and the alcohol compound. The mixture of high molecular weight polymers herein may also be a high molecular weight polymer or a mixture of a plurality of high molecular weight polymers.
Wherein the double-chain quaternary ammonium salt can be didecyl dimethyl ammonium chloride. Or can be replaced by a high molecular polymer with the same property or a mixture of a plurality of high molecular polymers with the same property, such as other double-chain compound quaternary ammonium salts, biguanide disinfectants and the like.
Further, the solvent is an aqueous solution, preferably, the solvent is water.
The disinfectant with the formula can be used as a high-level disinfectant, is suitable for the environment temperature of more than-24 ℃, can be used for disinfecting the surface of an object, and has a disinfecting effect lasting for more than three months.
The invention also provides a using method of the mixed disinfectant, which comprises the step of attaching the mixed disinfectant to the surface of an article to be disinfected for surface disinfection or soaking the article to be disinfected in the mixed disinfectant solution for disinfection.
Further, the surface disinfection is carried out by spraying or sprinkling or spraying or wiping.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Drawings
Detailed Description
The following examples are illustrative only and are not to be construed as limiting the invention.
The embodiment of the invention comprises 0.1-5% of peracetic acid with a disinfecting function, 1-6% of hydrogen peroxide with a disinfecting and antifreezing function, propylene glycol and a solvent.
In addition, the mixed disinfectant of peracetic acid and hydrogen peroxide disclosed by the invention also has the following additional technical characteristics:
according to an embodiment of the invention, the peroxyacetic acid content is between 0.1% and 1.5% by volume.
According to an embodiment of the invention, the propylene glycol content is between 20% and 60% by volume.
According to the embodiment of the invention, the mixed disinfectant also comprises NaCl with thawing and antifreezing functions, the solvent is water, and the NaCl can effectively lower the freezing point of water, has an ice melting effect and enhances the efficacy of the disinfectant.
Further, the weight concentration of the NaCl accounts for 0.5 to 5 percent.
According to the embodiment of the invention, the mixed disinfectant also comprises a mixture of high molecular polymers, wherein the mixture contains 50-2000PPM of double-chain quaternary ammonium salt. Wherein the double-chain quaternary ammonium salt can be didecyl dimethyl ammonium chloride.
According to an embodiment of the present invention, the solvent is an aqueous solution, preferably the solvent is water.
The invention also provides a using method of the mixed disinfectant, which comprises the step of attaching the mixed disinfectant to the surface of an article to be disinfected for surface disinfection or soaking the article to be disinfected in the mixed disinfectant solution for disinfection.
According to an embodiment of the invention, the surface disinfection is performed by spraying or sprinkling or spraying or wiping.
According to some embodiments of the invention, the data for the low temperature freezing test is as follows, wherein the content of the non-mentioned components is within the disclosed compounding ratio:
Figure 146202DEST_PATH_IMAGE001
cryosterilization test data according to some embodiments of the present invention, as shown in the following table, wherein the non-mentioned component levels are within the disclosed ranges:
Figure 440786DEST_PATH_IMAGE002
in the two tables, the values of hydrogen peroxide are 3%, 3.5%, 4%,4.5%, 5%,5.5%, 6% and other stage values, the propylene glycol is subjected to an incremental numerical test from the base number in the table by using the value of 5%, and a certain mixing ratio test is also performed, so that the effect is expected correspondingly, and only part of data is selected in the table for explanation.
Wherein, the mixture of the high molecular polymers contains double-chain quaternary ammonium salt which can be didecyl dimethyl ammonium chloride, and the high molecular polymers in the two tables can also be replaced by the didecyl dimethyl ammonium chloride or other high molecular polymers with the same performance or the mixture of a plurality of high molecular polymers with the same performance; the Disinfection capacity of the didecyl dimethyl ammonium chloride is shown in the following table:
Figure 773678DEST_PATH_IMAGE003
any reference to "one embodiment," "an embodiment," "example embodiment," etc., means that a particular proportion or feature described in connection with the embodiment is included in at least one embodiment of the present invention. This schematic representation in various places throughout this specification does not necessarily refer to the same embodiment. Further, when a particular arrangement or feature is described in connection with any embodiment, it is claimed that it is within the purview of one skilled in the art to effect such particular arrangement or feature in connection with other ones of the embodiments.
While specific embodiments of the invention have been described in detail with reference to a number of illustrative embodiments thereof, it should be understood that numerous other modifications and embodiments can be devised by those skilled in the art that will fall within the spirit and scope of the principles of this invention. In particular, reasonable variations and modifications in the respective proportions can be made within the scope of the foregoing disclosure and the appended claims without departing from the spirit of the invention.

Claims (11)

1. A peroxyacetic acid and hydrogen peroxide composite disinfectant used in an environment with the temperature of more than 24 ℃ below zero is characterized by comprising 0.1 to 1 volume percent of peroxyacetic acid with a disinfecting function, 1 to 6 volume percent of hydrogen peroxide, 20 to 60 volume percent of propylene glycol with disinfecting and antifreezing functions and a solvent.
2. The hybrid disinfectant according to claim 1, wherein said peroxyacetic acid is present in an amount of 0.1% to 1.0% by volume.
3. A hybrid disinfectant according to claim 1, wherein said hydrogen peroxide is present in an amount of 1-6% by volume.
4. The disinfectant mixture according to claim 1, wherein said propylene glycol is present in an amount of 20-60% by volume.
5. The mixed disinfectant according to claim 1, wherein the mixed disinfectant further comprises NaCl having anti-freeze and de-icing functions, and the solvent comprises water.
6. The mixed disinfectant according to claim 4, wherein the NaCl concentration by weight is 0.5% -5%.
7. The mixed disinfectant as set forth in claim 1, further comprising a mixture of high molecular weight polymers containing 50-2000PPM of a double-stranded quaternary ammonium salt.
8. The hybrid disinfectant as set forth in claim 7, wherein said double-chain quaternary ammonium salt is didodecyldimethylammonium chloride.
9. A hybrid disinfectant according to claim 1, characterised in that said solvent is an aqueous solution.
10. A method of using the mixed disinfectant of claims 1 to 9, wherein the method of using the mixed disinfectant is to sterilize the surface by attaching the mixed disinfectant to the surface of an article to be sterilized or by immersing the article to be sterilized in the mixed disinfectant solution.
11. Use according to claim 10, wherein the surface disinfection is carried out by spraying or sprinkling or spraying or wiping.
CN202110082224.1A 2021-01-21 2021-01-21 Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero Pending CN114794142A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110082224.1A CN114794142A (en) 2021-01-21 2021-01-21 Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110082224.1A CN114794142A (en) 2021-01-21 2021-01-21 Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero

Publications (1)

Publication Number Publication Date
CN114794142A true CN114794142A (en) 2022-07-29

Family

ID=82523822

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110082224.1A Pending CN114794142A (en) 2021-01-21 2021-01-21 Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero

Country Status (1)

Country Link
CN (1) CN114794142A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101507430A (en) * 2009-03-31 2009-08-19 中国检验检疫科学研究院 Freezeproof foam disinfectant and preparation method thereof
CN101828551A (en) * 2010-04-28 2010-09-15 广州康盛生物科技有限公司 Stable peroxyacetic acid disinfectant
CN102037959A (en) * 2010-12-29 2011-05-04 广东环凯微生物科技有限公司 Method for preparing stable peracetic acid disinfectant
CN111406757A (en) * 2020-03-25 2020-07-14 上海柯珑清洁技术有限公司 Low-temperature acidic disinfectant and preparation method and application thereof
WO2020243915A1 (en) * 2019-06-03 2020-12-10 南通思锐生物科技有限公司 Formula and method for immediately and quickly generating peracetic acid disinfectant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101507430A (en) * 2009-03-31 2009-08-19 中国检验检疫科学研究院 Freezeproof foam disinfectant and preparation method thereof
CN101828551A (en) * 2010-04-28 2010-09-15 广州康盛生物科技有限公司 Stable peroxyacetic acid disinfectant
CN102037959A (en) * 2010-12-29 2011-05-04 广东环凯微生物科技有限公司 Method for preparing stable peracetic acid disinfectant
WO2020243915A1 (en) * 2019-06-03 2020-12-10 南通思锐生物科技有限公司 Formula and method for immediately and quickly generating peracetic acid disinfectant
CN111406757A (en) * 2020-03-25 2020-07-14 上海柯珑清洁技术有限公司 Low-temperature acidic disinfectant and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈伟 等: "过氧乙酸与过氧化氢消毒剂及其研究进展", 《中国消毒学杂志》 *

Similar Documents

Publication Publication Date Title
AU2022221481B2 (en) Stable percarboxylic acid compositions and uses thereof
CN101233845A (en) Disinfection antifreeze agent and preparation thereof
CN112586504A (en) Composite low-temperature disinfectant and preparation method thereof
CN108477209B (en) Disinfectant and preparation method thereof
CN114081031A (en) Low-temperature peracetic acid disinfectant
CN113367126A (en) Low-temperature sodium hypochlorite disinfectant and preparation method thereof
CN112956474A (en) Chlorine-containing low-temperature disinfectant and preparation method thereof
CN114794142A (en) Peroxyacetic acid and hydrogen peroxide composite disinfectant used in environment with temperature of above 24 ℃ below zero
KR20180054550A (en) Composition for anti-freezing agent and method for preventing freezing of chlorine compounds using it
CN114794143A (en) Hydrogen peroxide disinfectant suitable for use in low temperature environment above-24 DEG C
CN114794107A (en) Peroxyacetic acid disinfectant suitable for environment above-24 DEG C
CN113261559A (en) Low-temperature quaternary ammonium salt disinfectant and preparation method thereof
CN113229288A (en) Novel low-temperature cold-chain quaternary ammonium salt disinfectant and preparation method thereof
CN108849976A (en) A kind of environment-friendly type Biocidal algae-killing agent
CN112042671A (en) Household rare earth hypochlorous acid sterilizing disinfectant
CN114190371A (en) Ultralow-temperature peroxyacetic acid disinfectant
CN108013072B (en) High-efficiency sterilizing disinfectant and preparation method thereof
KR20150030525A (en) Composition for disinfecting foot-and-mouth disease virus
CN103039514A (en) Preparation method and application of double quaternary phosphonium salt sterilization composition
CN113749093B (en) Low-temperature synergistic compound amine disinfectant and preparation method thereof
CN112244017A (en) Composite quaternary ammonium salt antibacterial spray
CN101590064A (en) Aseptic skin sterilizing agent for external use
CN115067356B (en) Anti-freezing and disinfecting composition and preparation method thereof
CN117546841A (en) Low-temperature disinfectant and preparation method and application thereof
CN113273579A (en) Low-temperature composite disinfectant and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20220729