CN112042671A - Household rare earth hypochlorous acid sterilizing disinfectant - Google Patents

Household rare earth hypochlorous acid sterilizing disinfectant Download PDF

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Publication number
CN112042671A
CN112042671A CN202010791958.2A CN202010791958A CN112042671A CN 112042671 A CN112042671 A CN 112042671A CN 202010791958 A CN202010791958 A CN 202010791958A CN 112042671 A CN112042671 A CN 112042671A
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CN
China
Prior art keywords
rare earth
hypochlorous acid
disinfectant
household
acid
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Pending
Application number
CN202010791958.2A
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Chinese (zh)
Inventor
王保行
王智远
王智宏
刘婕
周玮康
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Henan Kezhihong Environmental Protection Technology Co ltd
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Henan Kezhihong Environmental Protection Technology Co ltd
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Priority to CN202010791958.2A priority Critical patent/CN112042671A/en
Publication of CN112042671A publication Critical patent/CN112042671A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

Abstract

The invention belongs to the field of disinfection materials, and particularly relates to a household rare earth hypochlorous acid sterilizing disinfectant. The sterilizing disinfectant comprises the following raw materials in percentage by mass: 0.8-1% of rare earth, 1-2% of chlorine dioxide, 0.1-0.2% of citric acid, 0.1-0.2% of malic acid and 96.8-98% of water. The rare earth is added into the hypochlorous acid disinfectant, so that the hypochlorous acid disinfectant has the functions of bacteriostasis, sterilization and disinfection, promoting more effective sterilization and disinfection of the hypochlorous acid, inhibiting volatilization of the hypochlorous acid, and ensuring stable performance and long validity period. The rare earth hypochlorous acid water disinfection spray has quick effect, and can kill viruses and pathogenic bacteria within 1 minute; the function is strong, and the sterilization rate is as high as more than 95%; the stability is good, the disinfectant performance is stable, and the validity period can reach 12 months.

Description

Household rare earth hypochlorous acid sterilizing disinfectant
Technical Field
The invention belongs to the field of disinfection materials, and particularly relates to a household rare earth hypochlorous acid sterilizing disinfectant.
Background
The existing sterilization and disinfection methods include electronic equipment disinfection and disinfectant disinfection. The electronic equipment disinfection method is to directly adopt electronic sterilization equipment to generate ozone for disinfection, the efficiency is high, but the cost is high, the involved maintenance and repair needs to spend a lot of money and time, and the improper use can trigger danger. Therefore, at present, disinfectant disinfection methods are still selected in most occasions with less economic budget, but the existing disinfectants generally have the problems of low sterilization efficiency, slow response, poor stability, easy failure and the like.
In order to prevent and resist the invasion of harmful germs, keep the cleanness and sanitation of household articles and individuals and prevent the occurrence of avian influenza infectious diseases. There is a need for an efficient, safe, non-irritating, odor-free disinfecting article for destroying bacteria and viruses in a transmission medium and preventing the spread of bacteria and viruses, cross-contamination.
Disclosure of Invention
In order to overcome the defects of slow effect and easy failure of the disinfectant in the prior art, the invention provides the convenient, safe and efficient household rare earth hypochlorous acid disinfectant.
In order to achieve the purpose, the invention adopts the following technical scheme:
a household rare earth hypochlorous acid sterilizing disinfectant comprises the following raw materials: rare earth, chlorine dioxide, citric acid, malic acid and water.
Further, the sterilizing disinfectant consists of the following raw materials in percentage by mass: 0.8-1% of rare earth, 1-2% of chlorine dioxide, 0.1-0.2% of citric acid, 0.1-0.2% of malic acid and 96.8-98% of water.
Further, the sterilizing disinfectant consists of the following raw materials in percentage by mass: 0.9% of rare earth, 1.5% of chlorine dioxide, 0.1% of citric acid, 0.2% of malic acid and 97.3% of water.
Further, the rare earth is agricultural rare earth nitrate.
Furthermore, the granularity of the agricultural nitric acid rare earth is 100-180 meshes.
Further, the water is deionized water.
Compared with the prior art, the invention has the following beneficial effects:
the rare earth is added into the hypochlorous acid disinfectant, so that the hypochlorous acid disinfectant has the functions of bacteriostasis, sterilization and disinfection, promoting more effective sterilization and disinfection of the hypochlorous acid and inhibiting volatilization of the hypochlorous acid, and the disinfectant has stable performance and long validity period; the citric acid and the malic acid are added, so that the sterilizing function of the bactericide is enhanced, the odor of the hypochlorous acid in the bactericide is neutralized, and the effect of removing peculiar smell is achieved. The invention adopts rare earth and hypochlorous acid with lower proportion, has low concentration, contains more than 95 percent of water, does not hurt skin, can be used for killing personal and household articles, but has the advantage of quick effect, and kills virus and pathogenic bacteria within 1 minute; the function is strong, and the sterilization rate is as high as more than 95%; the stability is good, the disinfectant performance is stable, and the validity period can reach 12 months.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
A household rare earth hypochlorous acid sterilizing disinfectant comprises the following raw materials in percentage by mass: 0.9 percent of agricultural nitric acid rare earth, 1.5 percent of chlorine dioxide, 0.1 percent of citric acid, 0.2 percent of malic acid and 97.3 percent of water.
The preparation method comprises the following steps: firstly, the deionized water is averagely divided into two parts, one part is used for dissolving the agricultural rare earth nitrate, the other part is added with the chlorine dioxide, the two parts are respectively mixed evenly and then are combined, and finally, the citric acid and the malic acid are added, stirred and sealed.
Example 2
A household rare earth hypochlorous acid sterilizing disinfectant comprises the following raw materials in percentage by mass: 1% of agricultural nitric acid rare earth, 1.5% of chlorine dioxide, 0.1% of citric acid, 0.2% of malic acid and 97.2% of water.
The preparation method is the same as example 1.
Example 3
A household rare earth hypochlorous acid sterilizing disinfectant comprises the following raw materials in percentage by mass: 0.8% of agricultural nitric acid rare earth, 2% of chlorine dioxide, 0.2% of citric acid, 0.1% of malic acid and 96.9% of water.
The preparation method is the same as example 1.
Example 4
A household rare earth hypochlorous acid sterilizing disinfectant comprises the following raw materials in percentage by mass: 0.8% of agricultural nitric acid rare earth, 1% of chlorine dioxide, 0.2% of citric acid, 0.1% of malic acid and 97.9% of water.
The preparation method is the same as example 1.
Example 5
The bactericidal disinfectant prepared in the examples 1 to 3 was subjected to sterilization test: the plates containing the bacteria (staphylococcus aureus, escherichia coli and candida albicans) are soaked in the disinfectant for 1 minute, the number of the bacteria before and after soaking is counted, wherein the disinfectant is a product prepared and hermetically stored for 1 day, 1 month, 3 months and 12 months respectively, and the sterilization rate in 1 minute is shown in table 1.
TABLE 1 Sterilization Rate Performance test parameters of examples 1 to 3
Figure BDA0002624116440000021
Figure BDA0002624116440000031
As can be seen from Table 1, the sterilizing rate of the sterilizing agent prepared on the same day is 95% or more, and the sterilizing agent of the sterilizing agent after 12 months of storage is 88% or more, thus demonstrating that the present invention has excellent stability and can be stored for a long period of time.
It should be understood that the detailed description and specific examples, while indicating embodiments of the invention, are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.

Claims (6)

1. A household rare earth hypochlorous acid sterilizing disinfectant is characterized by comprising the following raw materials: rare earth, chlorine dioxide, citric acid, malic acid and water.
2. The household rare earth hypochlorous acid sterilizing disinfectant as claimed in claim 1, wherein the sterilizing disinfectant is composed of the following raw materials by mass percent: 0.8-1% of rare earth, 1-2% of chlorine dioxide, 0.1-0.2% of citric acid, 0.1-0.2% of malic acid and 96.8-98% of water.
3. The household rare earth hypochlorous acid sterilizing disinfectant as claimed in claim 2, wherein the sterilizing disinfectant is prepared from the following raw materials in percentage by mass: 0.9% of rare earth, 1.5% of chlorine dioxide, 0.1% of citric acid, 0.2% of malic acid and 97.3% of water.
4. The household rare earth hypochlorous acid sterilizing disinfectant as claimed in any one of claims 1 to 3, wherein the rare earth is agricultural rare earth nitrate.
5. The household rare earth hypochlorous acid sterilizing disinfectant as claimed in claim 4, wherein the granularity of the agricultural rare earth nitrate is 100-180 meshes.
6. The household rare earth hypochlorous acid sterilizing and disinfecting agent as claimed in any one of claims 1 to 3, wherein the water is deionized water.
CN202010791958.2A 2020-08-08 2020-08-08 Household rare earth hypochlorous acid sterilizing disinfectant Pending CN112042671A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010791958.2A CN112042671A (en) 2020-08-08 2020-08-08 Household rare earth hypochlorous acid sterilizing disinfectant

Applications Claiming Priority (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112889838A (en) * 2021-01-30 2021-06-04 哈尔滨工业大学 Rare earth/ClO2Composite material and preparation method thereof
CN115005207A (en) * 2022-06-30 2022-09-06 内蒙古稀宝方元医疗科技有限责任公司 Rare earth hypochlorous acid disinfectant and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1295795A (en) * 2000-10-31 2001-05-23 济南化肥厂有限责任公司 Agricultural disinfectant
CN1315135A (en) * 2000-03-30 2001-10-03 李天雷 ClO2 disinfectant and its preparing process and application
CN101380031A (en) * 2006-12-08 2009-03-11 吴予奇 Chlorine dioxide sterilization foreign taste removing liquor
CN107802645A (en) * 2017-12-11 2018-03-16 武汉左点科技有限公司 Rare earth element spray

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315135A (en) * 2000-03-30 2001-10-03 李天雷 ClO2 disinfectant and its preparing process and application
CN1295795A (en) * 2000-10-31 2001-05-23 济南化肥厂有限责任公司 Agricultural disinfectant
CN101380031A (en) * 2006-12-08 2009-03-11 吴予奇 Chlorine dioxide sterilization foreign taste removing liquor
CN107802645A (en) * 2017-12-11 2018-03-16 武汉左点科技有限公司 Rare earth element spray

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
HINENOYA, A ET AL.: "Chlorine Dioxide is a Better Disinfectant than Sodium Hypochlorite against Multi-Drug Resistant Staphylococcus aureus, Pseudomonas aeruginosa, and Acinetobacter baumannii", 《JAPANESE JOURNAL OF INFECTIOUS DISEASES》 *
杨昌 主编: "《身边的化学》", 30 June 2017, 广东高等教育出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112889838A (en) * 2021-01-30 2021-06-04 哈尔滨工业大学 Rare earth/ClO2Composite material and preparation method thereof
CN115005207A (en) * 2022-06-30 2022-09-06 内蒙古稀宝方元医疗科技有限责任公司 Rare earth hypochlorous acid disinfectant and preparation process thereof

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Application publication date: 20201208

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