CN114748368A - Lip product with cream texture and preparation method thereof - Google Patents

Abstract

The present invention provides a lip product with a frosty texture. Compared with the prior art, the second polydimethylsiloxane crosslinked polymer which is a spherical and flaky silicon elastomer is selectively compounded and added, wherein the spherical silicon elastomer can enable the material body to have high consistency and good pushing coating performance, and the flaky silicon elastomer have synergistic effect, so that the spreadability of the material body is increased, the material body is uniformly distributed on the lip, and the uniformity of feeding is ensured; secondly, mango seed fat is added into the formula, is solid at normal temperature, has low volatility, is rich in unsaturated fatty acid, can be well compatible with lips, is tightly attached to skin, forms an oil film on the lips, and can improve the degree of fitness of a material body on the lips while ensuring the moistening degree of a product; meanwhile, the silicone elastomer also contains vegetable oil and fat, so that the silicone elastomer and the silicone elastomer can be better compatible, and the material body can be tightly attached to the lip.

Description

Lip product with cream texture and preparation method thereof

Technical Field

The invention belongs to the technical field of makeup products, and particularly relates to a lip product with a frost-like texture and a preparation method thereof.

Background

Lip products can be classified into different categories, such as lipstick, lip gloss, etc., depending on their texture, formulation, etc. The lipstick has higher requirements on a formula system and a process, is difficult to control stability while giving consideration to use feeling and cosmetic effect, and is easy to cause phenomena of sweating, frosting and the like after being placed for a long time or changing temperature, so that the user experience feeling is reduced, and even the whole cosmetic effect of the product is influenced.

With the development of the cosmetic industry, the liquid lip glaze is more popular with consumers due to the reasons of convenient use, various textures, natural make-up effect and the like, and the common lip glaze with velvet matte texture generally achieves the soft-focus effect by adding a silicon elastomer with a solvent being nonvolatile silicone oil (the Chinese patent with the publication number of CN 112120968A). The high-brightness non-stick lip glaze mostly combines different film forming agents to achieve the color fixing effect while using high-brightness grease (Chinese patent with publication number CN 110302094A).

Although the quantity of the liquid lip glaze on the market is large, the dosage form, the formula composition and the like of the liquid lip glaze are similar, the innovation is lacked, and lip products with brand new texture are urgently needed to be developed in order to meet the requirements of consumers on novel and special products.

Disclosure of Invention

In view of the above, the technical problem to be solved by the present invention is to provide a lip product with cream texture and a preparation method thereof, wherein the lip product has no fluidity, is spread in layers and is easy to apply, and the upper lip is light, thin and not thick and has good color spreading.

The present invention provides a lip product having a creamy texture comprising:

the first polydimethylsiloxane crosslinked polymer is a crosslinked polymer of shea butter, octyl polymethylsiloxane and polydimethylsiloxane;

the second polydimethylsiloxane crosslinked polymer is a crosslinked polymer of polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer and polydimethylsiloxane.

Preferably, the polyglycerol ester emollient is selected from the group consisting of polyglycerol-2 triisostearate and polyglycerol-2 diisostearate; the mass ratio of the polyglycerol-2 triisostearate to the polyglycerol-2 diisostearate is (1-5): (0.5 to 4).

Preferably, the wax is selected from behenyl trisaccharide;

the adsorbent is selected from silica dimethyl silylate.

Preferably, the emulsifier is selected from cetyl PEG/PPG-10/1 dimethicone and sorbitan isostearate; the mass ratio of cetyl PEG/PPG-10/1 polydimethylsiloxane to sorbitan isostearate is (1-4): (0.5 to 4).

Preferably, the thickener is selected from VP/eicosene copolymer with triacontyl PVP; the mass ratio of the VP/eicosene copolymer to the triacontyl PVP is (1-5): (0.5 to 4).

Preferably, the humectant is selected from the group consisting of di-diglycerol polyacyladipate and 1, 3-butylene glycol; the mass ratio of the di-diglycerol polyacyladipate to the 1, 3-butanediol is (1-5): (0.5-5).

Preferably, the first polydimethylsiloxane-based cross-linked polymer is prepared according to the following method:

s1) mixing vinyl silicone oil and hydrogen-containing silicone oil, and carrying out emulsion polymerization reaction to obtain a solid elastomer;

s2) mixing and stirring the solid elastomer, the shea butter and the octyl polymethylsiloxane to obtain a first polydimethylsiloxane crosslinked polymer;

the second polydimethylsiloxane-based cross-linked polymer was prepared according to the following method:

A1) mixing vinyl silicone oil, hydrogen-containing silicone oil and water, and carrying out emulsion polymerization reaction to obtain a solid elastomer;

A2) and mixing the solid elastomer with polydimethylsiloxane to obtain a second polydimethylsiloxane crosslinked polymer.

Preferably, the mass ratio of the solid elastomer, the shea butter and the octyl methicone in S2) is (26-38): (32-38): (30-36).

Preferably, the mass ratio of the solid elastomer to the polydimethylsiloxane in A2) is (16-35): (70-80).

The invention also provides a preparation method of the lip product with the cream texture, which comprises the following steps:

uniformly stirring polydimethylsiloxane, polyglycerol ester emollient, diisostearyl malate and wax to obtain a first mixed phase;

adding the first polydimethylsiloxane crosslinked polymer, the second polydimethylsiloxane crosslinked polymer and the mango seed fat into the phase A, heating, stirring and mixing to obtain a second mixed phase;

adding a colorant into the second mixed phase, stirring and grinding to obtain a third mixed phase;

adding emulsifier, thickener, humectant and adsorbent into the third mixed phase, and mixing to obtain lip product with cream texture.

The present invention provides a lip product with a frosty texture comprising: 3-20 parts by weight of polydimethylsiloxane; 0.2 to 2 parts by weight of a first polydimethylsiloxane-based crosslinked polymer; 40-65 parts by weight of a second polydimethylsiloxane-based cross-linked polymer; 1.5-9 parts of polyglycerol ester emollient; 1-4 parts by weight of diisostearyl malate; 2-6 parts of wax; 0.5-4 parts of mango seed grease; 1.5-8 parts by weight of an emulsifier; 1.5-9 parts of a thickening agent; 1.5-10 parts by weight of a humectant; 0.01-1.5 parts by weight of an adsorbent; 0.01 to 4 parts by weight of a colorant; the first polydimethylsiloxane crosslinked polymer is a crosslinked polymer of shea butter, octyl polymethylsiloxane and polydimethylsiloxane; the second polydimethylsiloxane crosslinked polymer is a crosslinked polymer of polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer and polydimethylsiloxane. Compared with the prior art, the second polydimethylsiloxane crosslinked polymer which is a spherical and flaky silicon elastomer is selectively compounded and added, wherein the spherical silicon elastomer can enable the material body to have high consistency and good pushing coating performance, and the flaky silicon elastomer have synergistic effect, so that the spreadability of the material body is increased, the material body is uniformly distributed on the lip, and the uniformity of feeding is ensured; secondly, mango seed fat is added into the formula, is solid at normal temperature, has low volatility, is rich in unsaturated fatty acid, can be well compatible with lips, is tightly attached to skin, forms an oil film on the lips, and can improve the degree of fitness of a material body on the lips while ensuring the moistening degree of a product; meanwhile, the silicone elastomer also contains vegetable oil and fat, so that the silicone elastomer and the silicone elastomer can be better compatible, and a body can be tightly attached to the lip.

Drawings

FIG. 1 is a schematic view of a process for preparing a first polydimethylsiloxane-based crosslinked polymer according to the present invention;

FIG. 2 is a schematic view of a process for preparing a second polydimethylsiloxane-based crosslinked polymer according to the present invention.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The present invention provides a lip product with a frosty texture comprising:

the first polydimethylsiloxane crosslinked polymer is a crosslinked polymer of shea butter, octyl polymethylsiloxane and polydimethylsiloxane;

the second polydimethylsiloxane crosslinked polymer is a crosslinked polymer of polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer and polydimethylsiloxane.

The lip product provided by the invention has the texture like cream, has no fluidity, is easy to apply after being spread in a layered manner, and has light, thin and thick upper lip and good color spreading degree.

The lip product with the cream texture provided by the invention takes the organic silicon substance as the film forming substance.

Wherein, the content of the polydimethylsiloxane is preferably 5 to 20 parts by weight, more preferably 10 to 20 parts by weight, still more preferably 15 to 20 parts by weight, and most preferably 17 to 18 parts by weight.

The first polydimethylsiloxane crosslinked polymer is a crosslinked polymer of shea butter, octyl polymethylsiloxane and polydimethylsiloxane; the content of the first polydimethylsiloxane-based cross-linked polymer in the lip product provided by the invention is preferably 0.2-1.5 parts by weight, more preferably 0.5-1 part by weight, and still more preferably 0.5 part by weight; the mass ratio of the shea butter, the octyl polymethylsiloxane and the polydimethylsiloxane is preferably (26-38): (32-38): (30-36).

In the present invention, the first polydimethylsiloxane-based cross-linked polymer is preferably prepared according to the following method: s1) mixing vinyl silicone oil and hydrogen-containing silicone oil, and carrying out emulsion polymerization reaction to obtain a solid elastomer; s2) mixing and stirring the solid elastomer, the shea butter and the octyl polymethylsiloxane to obtain a first polydimethylsiloxane crosslinked polymer; wherein, the vinyl silicone oil and the hydrogen-containing silicone oil are subjected to emulsion polymerization reaction preferably in the presence of a catalyst; the catalyst is preferably chloroplatinic acid; the temperature of the emulsion polymerization reaction is preferably 70-90 ℃, and more preferably 80 ℃; generating solid elastomer through emulsion polymerization; the generated solid elastomer is preferably rolled by a three-roller machine and then mixed with the shea butter and the octyl polymethylsiloxane for stirring; the roller spacing of the three-roller machine is preferably 1-3 mu m, and more preferably 2 mu m; the rolling frequency is preferably 2-4 times, and more preferably 3 times; the mass ratio of the solid elastomer, the shea butter and the octyl polymethylsiloxane is preferably (26-38): (32-38): (30-36); the mixing and stirring are preferably carried out in a planetary stirring pot; the shea butter and octyl polymethylsiloxane are preferably slowly added into the solid elastomer, more preferably within 20-40 min, and further preferably within 30 min; the mixing and stirring time is preferably 20-40 min, and more preferably 30 min; mixing and stirring, and preferably performing pressure filtration to obtain a first polydimethylsiloxane crosslinked polymer; referring to fig. 1, fig. 1 is a schematic view of a preparation process of a first polydimethylsiloxane-based cross-linked polymer provided by the present invention.

The second polydimethylsiloxane crosslinked polymer is a crosslinked polymer of polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer and polydimethylsiloxane; the mass ratio of the polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer to the polydimethylsiloxane is preferably (16-35): (70-80); the mass ratio of the polydimethylsiloxane cross-linked polymer to the vinyl polydimethylsiloxane cross-linked polymer in the polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer is preferably (1-10): (15-25); the content of the second polydimethylsiloxane crosslinked polymer in the lip product provided by the invention is preferably 45-65 parts by weight, and more preferably 47-63 parts by weight; in the examples provided herein, the content of the second dimethicone-based cross polymer in the lip product is specifically 56.1 parts by weight, 47 parts by weight, or 63 parts by weight.

The second polydimethylsiloxane-based cross-linked polymer is preferably prepared according to the following method: A1) mixing vinyl silicone oil, hydrogen-containing silicone oil and water, and carrying out emulsion polymerization reaction to obtain a solid elastomer; A2) mixing the solid elastomer with polydimethylsiloxane to obtain a second polydimethylsiloxane-type cross-linked polymer; the emulsion polymerization is preferably carried out in the presence of a catalyst; the catalyst is preferably chloroplatinic acid; the temperature of the emulsion polymerization reaction is preferably 70-90 ℃, and more preferably 80 ℃; generating solid elastomer through emulsion polymerization; the generated solid elastomer is preferably rolled by a three-roller machine and then mixed with the shea butter and the octyl polymethylsiloxane for stirring; the roller spacing of the three-roller machine is preferably 1-3 mu m, and more preferably 2 mu m; the rolling frequency is preferably 2-4 times, and more preferably 3 times; the mass ratio of the solid elastomer to the polydimethylsiloxane is preferably (16-35): (70-80); the mixing and stirring are preferably carried out in a planetary stirring pot; the polydimethylsiloxane is preferably slowly added into the solid elastomer, more preferably within 20-40 min, and further preferably within 30 min; the mixing and stirring time is preferably 20-40 min, and more preferably 30 min; mixing and stirring, and preferably performing pressure filtration to obtain a second polydimethylsiloxane crosslinked polymer; referring to fig. 2, fig. 2 is a schematic view of a preparation process of a second polydimethylsiloxane-based crosslinked polymer provided by the present invention.

The lip product provided by the invention is added with the polyglycerol ester emollient; the preferred polyglyceryl ester emollients are polyglyceryl-2 triisostearate and polyglyceryl-2 diisostearate; the mass ratio of the polyglycerol-2 triisostearate to the polyglycerol-2 diisostearate is preferably (1-5): (0.5-4), more preferably (1-4): (0.5-3), preferably (2-3): (1-2), most preferably 2: 1; the content of the polyglycerol ester emollient in the lip product provided by the invention is preferably 1.5-9 parts by weight, more preferably 1.5-7 parts by weight, still more preferably 3-5 parts by weight, and most preferably 3 parts by weight.

The lip product provided by the invention is added with diisostearyl malate as a skin conditioner; the content of diisostearyl malate in the lip product is preferably 2 to 4 parts by weight, more preferably 2.5 to 3.5 parts by weight, and still more preferably 3 parts by weight.

In the present invention, the wax is preferably behenyl trisilicate; the content of the wax is preferably 3 to 5 parts by weight, and more preferably 4 parts by weight.

Because the content of the silicon elastomer is high, the phenomenon of drying is easily caused after the grease is volatilized, so that the invention adds mango seed grease into a lip product in order to ensure the moistening degree of the product and simultaneously improve the degree of conformity of a material body on the lip; the mango seed grease is solid at normal temperature, has low volatility, is rich in unsaturated fatty acid, can be well compatible with lips, is tightly attached to skin and forms a layer of oil film on the lips, and meanwhile, because the silicone elastomer also contains vegetable oil, the mango seed grease and the silicone elastomer can be well compatible, so that a material body is tightly attached to the lips; the content of mango seed fat in the lip product provided by the invention is preferably 1-4 parts by weight, and more preferably 2-3 parts by weight.

In the present invention, the emulsifier is preferably cetyl PEG/PPG-10/1 dimethicone with sorbitan isostearate; the mass ratio of the cetyl PEG/PPG-10/1 polydimethylsiloxane to the sorbitan isostearate is preferably (1-4): (0.5-4), more preferably (1-4): (1-4), and more preferably (1-3): (1-3); the content of the emulsifier in the lip product provided by the invention is preferably 2-7 parts by weight, more preferably 3-6 parts by weight, and still more preferably 4-5 parts by weight.

In the present invention, the thickener is preferably a VP/eicosene copolymer with triacontyl PVP; the mass ratio of the VP/eicosene copolymer to the triacontyl PVP is preferably (1-5): (0.5-4), more preferably (2-4): (1-3), more preferably (2-3): (1-2), most preferably 2: 1; in the lip product provided by the invention, the content of the thickening agent is preferably 2-8 parts by weight, more preferably 2-6 parts by weight, still more preferably 3-5 parts by weight, and most preferably 3-4 parts by weight.

In the present invention, the humectant is preferably a mixture of di-diglycerol polyacyladipate and 1, 3-butylene glycol; the mass ratio of the bis-diglycerol polyacyladipate to 1, 3-butanediol is preferably (1-5): (0.5-5), more preferably (2-5): (1-4), and more preferably (3-4): (2-3), most preferably 3: 2; in the lip product provided by the invention, the content of the humectant is preferably 3-8 parts by weight, more preferably 4-6 parts by weight, and still more preferably 5 parts by weight.

The lip product provided by the invention preferably takes silica dimethyl silylate as an adsorbent; the content of the dimethylsilylated silica is preferably 0.03 to 1.2 parts by weight, more preferably 0.03 to 1 part by weight, still more preferably 0.05 to 0.08 parts by weight, and most preferably 0.06 parts by weight.

The content of the colorant in the lip product provided by the invention is preferably 0.05-3 parts by weight, more preferably 0.5-2 parts by weight, still more preferably 1-2 parts by weight, and most preferably 1.42 parts by weight.

According to the invention, the second polydimethylsiloxane cross-linked polymer which is a spherical and flaky silicon elastomer is selectively compounded and added, wherein the spherical silicon elastomer can enable the material body to have good push coating property while having higher consistency, and the flaky silicon elastomer and the spherical silicon elastomer have synergistic effect, so that the spreadability of the material body is increased, the material body is uniformly distributed on the lip, and the uniformity of feeding is ensured; secondly, mango seed fat is added into the formula, is solid at normal temperature, has low volatility, is rich in unsaturated fatty acid, can have good compatibility with lips, is tightly attached to skin and forms a layer of oil film on the lips, and can improve the degree of conformity of a material body on the lips while ensuring the moistening degree of a product; meanwhile, the silicone elastomer also contains vegetable oil and fat, so that the silicone elastomer and the silicone elastomer can be better compatible, and the material body can be tightly attached to the lip.

The invention also provides a preparation method of the lip product with the cream texture, which comprises the following steps: uniformly stirring polydimethylsiloxane, polyglycerol ester emollient, diisostearyl malate and wax to obtain a first mixed phase; adding the first polydimethylsiloxane crosslinked polymer, the second polydimethylsiloxane crosslinked polymer and the mango seed fat into the phase A, heating, stirring and mixing to obtain a second mixed phase; adding a colorant into the second mixed phase, stirring and grinding to obtain a third mixed phase; adding emulsifier, thickener, humectant and adsorbent into the third mixed phase, and mixing to obtain lip product with cream texture.

In the present invention, the sources of all raw materials are not particularly limited, and they may be commercially available.

The polydimethylsiloxane, the polyglycerol ester emollient, the diisostearyl malate and the wax are uniformly stirred to obtain a first mixed phase.

Adding the first polydimethylsiloxane crosslinked polymer, the second polydimethylsiloxane crosslinked polymer and the mango seed fat into the phase A, heating, stirring and mixing to obtain a second mixed phase; the temperature of the heating and stirring is preferably 70 ℃ to 90 ℃, and more preferably 80 ℃.

And adding the colorant into the second mixed phase, stirring and grinding to obtain a third mixed phase.

Adding the emulsifier, the thickener, the humectant and the adsorbent into the third mixed phase for mixing; after mixing uniformly, preferably heating and preserving heat for canning to obtain a lip product with cream texture; the temperature of the heating and heat preservation is preferably 70-75 ℃.

To further illustrate the present invention, a lip product having a cream texture and a method for preparing the same, which is provided by the present invention, will be described in detail with reference to the following examples.

The reagents used in the following examples are all commercially available.

Examples 1 to 3 and comparative examples 1 to 3

1.1 weighing the oil and the wax according to the types and the contents in the table 1, and stirring the oil and the wax according to the selected weight parts until the oil and the wax are uniformly mixed to obtain a first mixed phase.

1.2 weighing the components of the phase B according to parts by weight, adding the components into the first mixed phase, heating to 80 ℃, and stirring to uniformly mix to obtain a second mixed phase.

1.3 weighing the components of the phase C in parts by weight, adding the components into the second mixed phase, uniformly stirring, and grinding for three times by using a three-roll grinder to obtain a third mixed phase.

And 1.4, weighing the components of the phase D according to parts by weight, adding the components into a third mixed phase, uniformly stirring, heating and preserving heat at 70-75 ℃, and filling to obtain the finished lip product with cream texture.

TABLE 1 lip product Components and amounts

Elastomer mixing ratios in table 1: an elastomer A: sheet-shaped: spherical shape 1: 5; an elastomer B: sheet-shaped: spherical shape is 3: 3; an elastomer C: sheet-shaped: spherical shape is 5: 1.

lip products obtained in examples 3 to 6 and comparative examples 1 to 3 were tested according to the following test methods:

60 women with the average age of 25 +/-10 years are selected and randomly divided into 6 groups, 10 persons in each group are respectively smeared with the same amount of the samples of the embodiment of the invention and the samples of the comparative example, and the testers evaluate, test and compare the samples according to the smearing process and the smeared effect.

The test scoring criteria were as follows:

smearing feeling: 1 minute: a difference; and 2, dividing: poor; and 3, dividing: generally; and 4, dividing: better is the result; and 5, dividing: the method is good.

Color uniformity: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

The texture liking degree is as follows: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better is the result; and 5, dividing: good results are obtained.

Color rendering: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

Moistening degree: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

Non-stickiness: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

Persistence degree: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

The cosmetic effect preference degree is as follows: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.

The testers score according to the scoring standards, and finally, all scores are counted to calculate the average value, and the specific scoring result is shown in table 2.

Table 2 lip product test scoring results

Dimension of test	Example 3	Example 4	Example 5	Example 6	Comparative example 1	Comparative example 2	Comparative example 3
								Feeling of smearing	3.57	3.23	3.89	3.52	3.61	3.33	3.18
Color uniformity	3.67	3.72	3.17	3.49	3.72	3.29	3.22
								Preference of texture	3.43	3.36	3.15	3.45	3.38	3.02	3.25
Color rendering	3.71	3.86	3.24	3.66	3.89	3.81	3.85
								Moistening degree	3.33	3.29	3.68	3.37	3.18	3.22	3.37
Degree of non-stickiness	3.79	3.76	3.85	3.75	3.75	3.64	3.71
								Degree of persistence	3.43	3.58	3.12	3.32	3.24	3.37	3.51
Cosmetic effect preference	3.43	3.22	3.29	3.40	3.31	3.15	3.09

Claims (10)

1. A lip product of frosty texture comprising:

the first polydimethylsiloxane crosslinked polymer is a crosslinked polymer of shea butter, octyl polymethylsiloxane and polydimethylsiloxane;

the second polydimethylsiloxane crosslinked polymer is a crosslinked polymer of polydimethylsiloxane/vinyl polydimethylsiloxane crosslinked polymer and polydimethylsiloxane.

2. A lip product according to claim 1, wherein said polyglycerol based emollient is selected from the group consisting of polyglycerol-2 triisostearate and polyglycerol-2 diisostearate; the mass ratio of the polyglycerol-2 triisostearate to the polyglycerol-2 diisostearate is (1-5): (0.5-4).

3. A lip product according to claim 1, wherein said wax is selected from behenyl trisilicate;

the adsorbent is selected from silica dimethyl silylate.

4. A lip product according to claim 1, wherein said emulsifier is selected from cetyl PEG/PPG-10/1 dimethicone and sorbitan isostearate; the mass ratio of cetyl PEG/PPG-10/1 polydimethylsiloxane to sorbitan isostearate is (1-4): (0.5 to 4).

5. A lip product according to claim 1, wherein the thickener is selected from VP/eicosene copolymer with triacontyl PVP; the mass ratio of the VP/eicosene copolymer to the triacontyl PVP is (1-5): (0.5 to 4).

6. A lip product according to claim 1, wherein the humectant is selected from the group consisting of di-diglycerol polyacyladipate and 1, 3-butanediol; the mass ratio of the di-diglycerol polyacyladipate to the 1, 3-butanediol is (1-5): (0.5-5).

7. A lip product according to claim 1, wherein said first polydimethylsiloxane-type cross-polymer is prepared according to the following method:

s1) mixing vinyl silicone oil and hydrogen-containing silicone oil, and carrying out emulsion polymerization reaction to obtain a solid elastomer;

s2) mixing and stirring the solid elastomer, the shea butter and the octyl methicone to obtain a first polydimethylsiloxane cross-linked polymer;

the second polydimethylsiloxane-based cross-linked polymer was prepared according to the following method:

A1) mixing vinyl silicone oil, hydrogen-containing silicone oil and water, and carrying out emulsion polymerization reaction to obtain a solid elastomer;

A2) and mixing the solid elastomer with polydimethylsiloxane to obtain a second polydimethylsiloxane crosslinked polymer.

8. The lip product according to claim 7, wherein the mass ratio of the solid elastomer, the shea butter and the octyl methicone in S2) is (26-38): (32-38): (30-36).

9. A lip product according to claim 7, wherein the mass ratio of solid elastomer to polydimethylsiloxane in A2) is (16-35): (70-80).

10. A method of making a lip product of frosty texture as in claim 1, comprising:

uniformly stirring polydimethylsiloxane, polyglycerol ester emollient, diisostearyl malate and wax to obtain a first mixed phase;

adding the first polydimethylsiloxane crosslinked polymer, the second polydimethylsiloxane crosslinked polymer and the mango seed fat into the phase A, heating, stirring and mixing to obtain a second mixed phase;

adding a colorant into the second mixed phase, stirring and grinding to obtain a third mixed phase;

adding emulsifier, thickener, humectant and adsorbent into the third mixed phase, and mixing to obtain lip product with cream texture.

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