TWI740887B - Lip cosmetic composition - Google Patents

Lip cosmetic composition Download PDF

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TWI740887B
TWI740887B TW106102844A TW106102844A TWI740887B TW I740887 B TWI740887 B TW I740887B TW 106102844 A TW106102844 A TW 106102844A TW 106102844 A TW106102844 A TW 106102844A TW I740887 B TWI740887 B TW I740887B
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cosmetic composition
lip cosmetic
weight
lip
powder
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TW106102844A
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TW201728321A (en
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黃貞善
沈珉敬
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南韓商愛茉莉太平洋股份有限公司
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips

Abstract

A lip cosmetic composition of high coloration is provided. More specifically, provided is a lip cosmetic composition that replaces a powder that causes a feeling of dryness with a best combined use of silicone and a slurry compound. This lip cosmetic composition not only has good coloration and is long-wearing but also has soft ductility and causes no feeling of dryness.

Description

唇用化妝品組成物Lip cosmetic composition

本發明是有關於一種無卡色現象及乾燥感的高顯色的唇用化妝品組成物。 The present invention relates to a lip cosmetic composition with high color rendering without color blocking phenomenon and dry feeling.

口紅通常為油性劑型,包括蠟、油、色素及粉末。上述蠟保持口紅的外形,油賦予奢華的使用感與光澤感,色素作為顏料及/或染料而呈現色感,粉末用於提高展延性、附著性及持久性,同時用於實現啞光質感。 Lipsticks are usually oily formulations, including waxes, oils, pigments and powders. The wax maintains the shape of the lipstick, the oil gives a luxurious feeling of use and gloss, the pigment acts as a pigment and/or dye to give a sense of color, and the powder is used to improve the ductility, adhesion and durability, and at the same time to achieve a matte texture.

跟隨時代變化,化妝的流行趨勢亦發生變化,至90年代為止主要使用呈現啞光及不透明妝感的口紅,但進入至2000年後,強調唇彩或唇蜜等的透明感與潤澤感。上述唇彩或唇蜜具有使用感輕薄的優點,但具有顏色的持久力與密接力較弱而容易脫妝的問題。 With the changes of the times, the fashion trend of makeup has also changed. Until the 1990s, lipsticks with matte and opaque makeup were mainly used, but after 2000, the transparency and moisturizing feeling of lip gloss or lip gloss were emphasized. The above-mentioned lip gloss or lip gloss has the advantage of being light and thin in use, but has the problem that the color lasting power and adhesion are weak and it is easy to take off the makeup.

最近,除以蠟製備的口紅以外,流行唇蠟筆、唇馬克筆、唇釉、唇脂、唇彩油、唇筆等各種形態的口紅,以及具有鮮明的色彩感的高顯色的口紅倍受青睞。 Recently, in addition to lipsticks made with wax, various forms of lipsticks such as lip crayons, lip markers, lip glazes, lip glosses, lip gloss oils, and lip pencils are popular, as well as lipsticks with bright colors and high color rendering. .

高顯色口紅是指色彩密接至唇部而長時間保持的口 紅,具有鮮明的色彩感。上述密接性及持久性與構成口紅的組成中的粉末有關。 High color rendering lipstick refers to the mouth that adheres to the lips and maintains it for a long time. Red, with a vivid sense of color. The aforementioned adhesion and durability are related to the powder in the composition of the lipstick.

如上所述,粉末與口紅的展延性、即易於塗抹的程度有關,通常若球狀粉末較多,則口紅具有柔和的展延性。並且,粉末的含量越高,則口紅易於黏附至唇部的附著性越高。 As described above, the powder is related to the extensibility of the lipstick, that is, the degree of ease of application. Generally, if there are more spherical powders, the lipstick has soft extensibility. Also, the higher the powder content, the higher the adhesion of the lipstick to the lips.

高顯色口紅藉由使用10重量%以上的過量的粉末而實現高顯色的色彩呈現力與顏色持久力,具有乾燥且無光澤的啞光感,且具有柔軟的妝感。然而,高顯色口紅無油分,故而產生如下問題:展延性較為乾澀,顏色塗抹不均勻,隨著時間經過誘發乾燥感與角質而使唇部乾裂、乾燥,因顏色浮起或卡色現象而使角質或皺紋凸顯。 High color rendering lipsticks use more than 10% by weight of excessive powder to achieve high color rendering and color durability. It has a dry and matte matte feel and has a soft makeup feel. However, the high color rendering lipstick has no oil content, so it has the following problems: the stretchability is relatively dry, the color is unevenly applied, and the dryness and keratin are induced over time, causing the lips to dry and dry, and the color floats or jams. Makes cuticles or wrinkles stand out.

因此,為了克服乾燥感,提出添加保濕劑或油等組成的方法。 Therefore, in order to overcome the dry feeling, a method of adding a composition such as a moisturizer or oil has been proposed.

於韓國公開專利第2001-0110563號中,提出一種含有全氟乙基烷基聚二甲基矽氧烷、烷基聚二甲基矽氧烷、植物性多醣類及板狀粉末以防止唇部乾燥、賦予潤澤與光澤的唇用化妝品組成物。 In Korean Published Patent No. 2001-0110563, a perfluoroethyl alkyl polydimethylsiloxane, alkyl polydimethylsiloxane, vegetable polysaccharides and plate-like powder are proposed to prevent lips. A lip cosmetic composition that dries, moisturizes and gives gloss.

並且,於韓國公開專利第2003-003042號中,揭示一種口紅組成物,其為包括膨潤土或鋰皂石2重量%至10重量%、乙醇0.5重量%至5重量%及剩餘量的揮發性油的凝膠基質而具有持久性(long-wearing),並且可減少唇部的乾燥現象。 In addition, in Korean Patent Publication No. 2003-003042, a lipstick composition is disclosed, which is composed of bentonite or laponite 2% to 10% by weight, ethanol 0.5% to 5% by weight, and the remaining amount of volatile oil The gel matrix is long-wearing and can reduce the dryness of the lips.

藉由此種嘗試,得到如下結果:雖於某種程度上克服了 唇部的乾燥感,但高顯色口紅所要求的高顯色、均勻的色彩呈現力、持久力及密接性等效果反而下降。因此,難以實現具有高顯色特性且無乾燥感的高顯色口紅。 Through this attempt, the following results have been obtained: Although to some extent it has overcome Lips feel dry, but the effects of high color rendering, uniform color rendering, endurance and adhesion required by high color rendering lipsticks are reduced. Therefore, it is difficult to realize a high-color-rendering lipstick with high color-rendering properties and no dryness.

[先前技術文獻] [Prior Technical Literature]

韓國公開專利第2001-0110563號,唇用化妝品組成物 Korean Published Patent No. 2001-0110563, lip cosmetic composition

韓國公開專利第2003-003042號,持久性口紅組成物 Korean Published Patent No. 2003-003042, Persistent Lipstick Composition

因此,本發明者等人以可同時滿足高顯色與乾燥感的相反屬性的方式選擇特定組成,並按照固定含量比調配上述特定組成,藉此製備可同時確保上述效果的唇用化妝品組成物。 Therefore, the inventors of the present invention select a specific composition in a manner that can simultaneously satisfy the opposite attributes of high color rendering and dryness, and formulate the specific composition according to a fixed content ratio, thereby preparing a lip cosmetic composition that can simultaneously ensure the above effects .

因此,本發明的目的在於提供一種唇用化妝品組成物,其具有高顯色且均勻的色彩呈現力、持久力與柔和的使用感,同時隨著時間經過,唇部亦無乾燥感或卡色現象。 Therefore, the object of the present invention is to provide a lip cosmetic composition, which has high color rendering and uniform color rendering power, lasting power and soft use feeling, and at the same time, there is no dry feeling or color jam on the lips as time passes. Phenomenon.

為了達成上述目的,本發明提供一種唇用化妝品組成物,其中包括蠟、油、色素及粉末,上述組成物包括矽膠與漿料化合物。 In order to achieve the above-mentioned object, the present invention provides a lip cosmetic composition, which includes wax, oil, pigment and powder, and the composition includes a silicone gel and a slurry compound.

較佳為,上述唇用化妝品組成物以1:4至4:1的重量比包括上述矽膠與漿料化合物。 Preferably, the above-mentioned lip cosmetic composition includes the above-mentioned silicone gel and the slurry compound in a weight ratio of 1:4 to 4:1.

此時,上述矽膠包括選自由聚二甲基矽氧烷/乙烯基聚二 甲基矽氧烷交聯聚合物、丙烯酸酯/丙烯酸硬脂酯/聚二甲基矽氧烷/甲基丙烯酸酯共聚物及其組合所構成的族群中的一種。 At this time, the above-mentioned silicone rubber includes selected from polydimethylsiloxane/vinyl poly One of the group consisting of methylsiloxane cross-linked polymer, acrylate/stearyl acrylate/polydimethylsiloxane/methacrylate copolymer and combinations thereof.

並且,上述漿料化合物包括選自由氫化蓖麻油異硬脂酸酯、雙-二甘油多脂醯基己二酸酯-2、氫化聚苯乙烯、乙烯/丙烯/苯乙烯共聚物、丁烯/乙烯/苯乙烯共聚物、油酸/亞油酸/亞麻酸聚甘油酯、石蠟油、礦物油、辛酸/癸酸三甘油酯、氫化苯乙烯/異戊二烯共聚物、雙-羥基月桂基聚二甲基矽氧烷/異佛爾酮二異氰酸酯(Isphoronethe Diisocyanate,IPDI)共聚物、植物固醇/異硬脂醇/鯨蠟醇/硬脂醇/山崳醇二聚亞油酸酯及其組合所構成的族群中的一種。 And, the above-mentioned slurry compound includes selected from hydrogenated castor oil isostearate, bis-diglycerol polyglyceryl adipate-2, hydrogenated polystyrene, ethylene/propylene/styrene copolymer, butene/ Ethylene/styrene copolymer, oleic acid/linoleic acid/linolenic acid polyglyceride, paraffin oil, mineral oil, caprylic acid/capric triglyceride, hydrogenated styrene/isoprene copolymer, bis-hydroxylauryl Polydimethylsiloxane/isophorone diisocyanate (Isphoronethe Diisocyanate, IPDI) copolymer, plant sterol/isostearyl alcohol/cetyl alcohol/stearyl alcohol/behenyl dimer linoleate and One of the ethnic groups formed by its combination.

特別是,於整體組成物中,使用3重量%以下的粉末。 In particular, in the overall composition, 3% by weight or less of powder is used.

本發明的唇用化妝品組成物具有如下優點:高顯色的顏色均勻地呈現至整體唇部,因優異的密接性而長時間保持色彩呈現力。 The lip cosmetic composition of the present invention has the following advantages: a high color rendering color is uniformly presented to the entire lip, and the color rendering power is maintained for a long time due to excellent adhesion.

特別是,上述組成物的保濕力優異,從而可於源頭上改善先前高顯色的唇用化妝品組成物隨著時間經過產生的乾燥感、角質、浮起現象及卡色現象等,以始終表現出滋潤感妝容。 In particular, the above-mentioned composition has excellent moisturizing power, so that it can improve the dryness, cutin, floating phenomenon, jamming phenomenon, etc. of the previous high color lip cosmetic composition over time at the source, so as to always express Gives a moisturizing look.

圖1是表示於本發明的(a)實施例1、(b)比較例1、(c) 比較例2、(d)比較例3及(e)比較例4中製備的口紅的展延性的照片。 Figure 1 shows (a) Example 1, (b) Comparative Example 1, (c) of the present invention Photographs of the spreadability of the lipsticks prepared in Comparative Example 2, (d) Comparative Example 3, and (e) Comparative Example 4.

於唇用化妝品組成物中,為了獲得高顯色、均勻的色彩呈現力及持久性等優點而添加的粉末具有如下等缺點:降低展延性;於塗佈至唇部後,發生化妝品組成物凝結至唇部皺紋的卡色;誘發乾燥感及角質。高顯色的啞光口紅同時表現出上述兩種優缺點。然而,於本發明中提出一種唇用化妝品組成物,可按照原樣表現出高顯色、均勻的色彩呈現力及持久性的優點,提高展延性,於塗佈至唇部後不發生卡色及乾燥感相關的缺點。 In the lip cosmetic composition, the powder added in order to obtain the advantages of high color rendering, uniform color rendering and durability, etc. has the following disadvantages: reduced elongation; after being applied to the lips, the cosmetic composition coagulates Card color to lip wrinkles; induce dryness and keratin. A matte lipstick with high color rendering shows both advantages and disadvantages. However, in the present invention, a lip cosmetic composition is proposed, which can exhibit the advantages of high color rendering, uniform color rendering power and durability as it is, improve extensibility, and prevent color jams after being applied to the lips. Disadvantages related to dryness.

具體而言,本發明的唇用化妝品組成物添加藉由以最佳的組合使用矽膠與漿料化合物而具有黏著力的凝膠劑型,以代替減少引起以上所提及的問題的粉末的含量,從而即便減少粉末的含量,亦可實現高顯色且均勻的色彩呈現力,改善先前因粉末引起的卡色現象、唇部乾燥感、角質及展延性下降等問題。 Specifically, the lip cosmetic composition of the present invention adds a gel formulation that has adhesive force by using silicone gel and a slurry compound in an optimal combination, instead of reducing the content of powder that causes the above-mentioned problems. Therefore, even if the content of powder is reduced, high color rendering and uniform color rendering can be achieved, and the problems of color blocking, dry lips, reduced keratin and ductility caused by powder can be improved.

矽膠對唇用化妝品組成物賦予柔滑感,柔和地填平唇紋而實現豐滿的妝容。並且,發揮如下作用:形成柔軟的薄膜而有效地固定色素(即,顏料)及粉末,於塗抹至唇部後,提高密接力及持久力。 Silicone imparts a smoothness to the lip cosmetic composition, softly fills out lip wrinkles and achieves a plump look. In addition, it plays the role of forming a soft film to effectively fix the pigment (i.e., pigment) and powder, and improving adhesion and endurance after being applied to the lips.

漿料化合物是為了保濕及展延性而使用,其為如下物質:於固體狀態下表現出各向異性晶質排列,於特定溫度下發生 固體及液體的性狀可逆性變化。此種物質的熔點低至10℃至40℃,因此於常溫下亦以柔和的漿料狀存在,從而即便時間經過,亦不會經時間變化而保持柔和的使用感。 The slurry compound is used for moisture retention and ductility. It is a substance that exhibits an anisotropic crystalline arrangement in a solid state and occurs at a specific temperature. Reversible changes in the properties of solids and liquids. The melting point of this substance is as low as 10°C to 40°C, so it exists as a soft paste at room temperature, so that even if time passes, it will not change over time and maintain a soft feeling of use.

若混合上述矽膠與漿料化合物,則獲得具有黏著力的凝膠劑型的組成,上述凝膠劑型的組成與其他組成(例如蠟、油、色素等)混合而製備成唇用化妝品組成物。具有黏著力的上述凝膠形態的組成因對唇部具有較高的密接力而持久性提高,因色素均勻分散而可於整體上實現均勻的色彩呈現,表現出柔和的展延性。特別是,當唇部因產生角質或唇部皺紋等而存在凹凸時,具有黏著力的上述凝膠劑型填平上述凹凸而呈現色彩,因此變得可於唇部整體上實現柔滑的妝容。 When the above-mentioned silicone gel and the slurry compound are mixed, a composition of a gel formulation having adhesive force is obtained. The composition of the above-mentioned gel formulation is mixed with other components (for example, wax, oil, pigment, etc.) to prepare a lip cosmetic composition. The composition of the above-mentioned gel form with adhesive force improves durability due to its high adhesion to the lips, and achieves uniform color presentation on the whole due to the uniform dispersion of pigments, and exhibits soft extensibility. In particular, when there are irregularities on the lips due to keratin, lip wrinkles, etc., the adhesive gel formulation fills in the irregularities and presents colors, so that a smooth makeup can be achieved on the entire lips.

較佳為,具有黏著力的上述凝膠劑型以1:4至4:1的重量比、較佳為1.2:1至3:1的重量比、最佳為1.5:1的重量比混合矽膠與漿料化合物而使用。於上述矽膠的含量過多的情形時,化妝品組成物於塗佈至唇部後卡入至唇紋的卡色現象或凝結現象得到改善,但密接力下降而產生難以持久地呈現色彩的問題。並且,於過多地使用上述漿料化合物的情形時,保濕特性變良好而實現滋潤感且不產生角質,但色彩脫落凝結而變得難以於唇部整體實現均勻的色彩呈現力,因此較佳為於上述範圍內適當地混合而使用。 Preferably, the above-mentioned gel formulation with adhesive force is mixed with silicone rubber in a weight ratio of 1:4 to 4:1, preferably 1.2:1 to 3:1, and most preferably 1.5:1. Slurry compound is used. In the case where the content of the silicone gel is too high, the color blocking phenomenon or the coagulation phenomenon of the cosmetic composition jamming into the lip lines after being applied to the lips is improved, but the adhesion strength is reduced, which causes the problem that it is difficult to display the color for a long time. In addition, when the above-mentioned slurry compound is used excessively, the moisturizing properties become good and the moisturizing feeling is achieved without the generation of keratin, but the color peels off and condenses and it becomes difficult to achieve uniform color rendering on the entire lip, so it is preferably It is mixed and used suitably within the above-mentioned range.

並且,為了進一步提高本發明所欲獲得的效果,調節上述矽膠與漿料化合物的調配比,同時於整體組成物中控制各組成 的含量。 In addition, in order to further improve the desired effect of the present invention, the mixing ratio of the above-mentioned silicone rubber and the slurry compound is adjusted, and at the same time, each composition is controlled in the overall composition. Content.

較佳為,於唇用化妝品組成物100重量%中,使用10重量%至50重量%、較佳為20重量%至40重量%的上述矽膠。若上述矽膠的含量小於上述範圍,則存在乾澀的展延性,產生化妝品組成物凝結至唇部角質或唇部皺紋等現象而於整體上均勻的色彩呈現力變得不足的問題,與此相反,若超過上述範圍,則具有密接力及持久性下降的問題,因此於上述範圍內適當地使用。 Preferably, in 100% by weight of the lip cosmetic composition, 10% by weight to 50% by weight, preferably 20% by weight to 40% by weight of the aforementioned silicone gel is used. If the content of the above silicone gel is less than the above range, there will be dry stretchability, causing the cosmetic composition to condense to the lip keratin or lip wrinkles, and the overall uniform color rendering power becomes insufficient. On the contrary, If it exceeds the above range, there is a problem of decreased adhesion and durability, so it is appropriately used within the above range.

並且,於唇用化妝品組成物100重量%中,使用5重量%至40重量%、較佳為10重量%至30重量%的上述漿料化合物。若上述漿料化合物的含量小於上述範圍,則具有皮膚展延性變差或乾燥感增加的問題,與此相反,若超過上述範圍,則具有色彩脫落凝結而變得不足以於整個唇部實現均勻且柔滑的色彩呈現力的問題,因此於上述範圍內適當地使用。 In addition, in 100% by weight of the lip cosmetic composition, 5% to 40% by weight, preferably 10% to 30% by weight of the above-mentioned slurry compound is used. If the content of the above-mentioned slurry compound is less than the above-mentioned range, the skin stretchability will be deteriorated or the dryness will be increased. On the contrary, if it exceeds the above-mentioned range, the color will fall off and condense and become insufficient to achieve uniformity over the entire lip. And because of the problem of smooth color rendering, use it appropriately within the above range.

此時,於本發明中,使用的矽膠與漿料化合物的種類並無特別限定,只要為於化妝品原料領域內通常使用者,則可為任一種。 At this time, in the present invention, the types of silicone and slurry compounds used are not particularly limited, and any of them may be used as long as they are common users in the field of cosmetic raw materials.

作為代表性的上述矽膠,可為選自由聚二甲基矽氧烷/乙烯基聚二甲基矽氧烷交聯聚合物、丙烯酸酯/丙烯酸硬脂酯/聚二甲基矽氧烷/甲基丙烯酸酯共聚物及其組合所構成的族群中的一種。 As a representative of the above-mentioned silicone rubber, it can be selected from polydimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer, acrylate/stearyl acrylate/polydimethylsiloxane/methicone Acrylate copolymer and its combination constitute one of the groups.

並且,上述漿料化合物可為松脂類漿料,較佳為可為氫化蓖麻油異硬脂酸酯、雙-二甘油多脂醯基己二酸酯-2、氫化聚苯 乙烯、乙烯/丙烯/苯乙烯共聚物、丁烯/乙烯/苯乙烯共聚物、油酸/亞油酸/亞麻酸聚甘油酯、石蠟油、礦物油、辛酸/癸酸三甘油酯、氫化苯乙烯/異戊二烯共聚物、雙-羥基月桂基聚二甲基矽氧烷/IPDI共聚物、植物固醇/異硬脂醇/鯨蠟醇/硬脂醇/山崳醇二聚亞油酸酯及其組合所構成的族群中的一種,較佳為使用雙-二甘油多脂醯基己二酸酯-2及油酸/亞油酸/亞麻酸聚甘油酯。 In addition, the above-mentioned slurry compound may be a rosin-based slurry, preferably hydrogenated castor oil isostearate, bis-diglyceride fatty acid adipate-2, hydrogenated polystyrene Ethylene, ethylene/propylene/styrene copolymer, butene/ethylene/styrene copolymer, oleic acid/linoleic acid/linolenic acid polyglyceride, paraffin oil, mineral oil, caprylic/capric triglyceride, hydrogenated benzene Ethylene/isoprene copolymer, bis-hydroxylauryl polydimethylsiloxane/IPDI copolymer, plant sterol/isostearyl alcohol/cetyl alcohol/stearyl alcohol/behenyl alcohol dimer linoleum As one of the group consisting of acid esters and combinations thereof, it is preferable to use bis-diglycerol polyadipate-2 and oleic acid/linoleic acid/linolenic acid polyglyceride.

如上所述的矽膠與漿料化合物的調配比得到調節的唇用化妝品組成物可製備成各種劑型,具有柔和的展延性,於乾燥的唇部、特別是產生角質的部分亦可實現鮮明的顯色,且亦可填平唇紋而實現既柔滑亦豐滿的妝感。 The lip cosmetic composition whose blending ratio of silicone gel and slurry compound is adjusted as described above can be prepared into various formulations, has soft stretchability, and can also achieve a clear appearance on dry lips, especially the parts that produce keratin. It can also fill in lip wrinkles and achieve a smooth and plump makeup.

特別是,與先前使用10重量%以上的粉末含量的唇用化妝品組成物相比,本發明的唇用化妝品組成物即便使用3重量%以下的粉末,亦可實現高顯色的色彩呈現,且密接力及持久性優異。而且,不產生於為了實現啞光質感而使用高含量的粉末時產生的唇部乾燥感與角質、浮起現象及卡色現象,從而可始終呈現潤澤感妝容。 In particular, compared with the previous lip cosmetic composition using a powder content of 10% by weight or more, the lip cosmetic composition of the present invention can achieve high color rendering even if it uses a powder of 3% by weight or less, and Excellent adhesion and durability. In addition, it does not produce dry lips, cuticles, floating phenomenon, and color blocking that occur when high content of powder is used to achieve a matte texture, so that it can always present a moisturizing makeup look.

作為可使用的粉末,於本發明中並無特別限定,只要為於本技術領域內公知的材質,則可為任一種。 The usable powder is not particularly limited in the present invention, and it may be any material as long as it is a material known in the technical field.

作為代表性的上述粉末組成,可使用白雲母、合成雲母、絹雲母、二氧化鈦、二氧化鈦被覆雲母、氧化鋁、氧化鐵黃、氧化鐵黑、碳黑、硫酸鋇、氧化矽及沸石等無機粉末;以及尼龍、聚甲基丙烯酸甲酯(PMMA)、聚苯乙烯、聚乙烯及纖維素等有機 粉末;其等可分別使用或混合使用。 As a representative powder composition, inorganic powders such as muscovite, synthetic mica, sericite, titanium dioxide, titanium dioxide-coated mica, aluminum oxide, iron oxide yellow, iron oxide black, carbon black, barium sulfate, silicon oxide, and zeolite can be used; And nylon, polymethyl methacrylate (PMMA), polystyrene, polyethylene and cellulose and other organic Powder; these can be used separately or mixed.

此時,上述粉末可為球形、板形狀或針形狀,較佳為使用1μm至100μm的球形粒子。較佳為,於本發明的實施例中,作為粉末而混合使用球形的氧化鋁與尼龍。 At this time, the above-mentioned powder may be spherical, plate-shaped, or needle-shaped, and it is preferable to use spherical particles of 1 μm to 100 μm. Preferably, in the embodiment of the present invention, spherical alumina and nylon are mixed and used as the powder.

此時,於整體唇用化妝品組成物中,使用3重量%以下的上述粉末,較佳為於0.5重量%至3重量%的範圍內使用上述粉末。若上述粉末的含量小於上述範圍,則製品的顯色力、持久性及密接力不足,與此相反,若超過上述範圍,則誘發乾燥感與角質,故而於上述範圍內適當地使用。 At this time, in the overall lip cosmetic composition, 3% by weight or less of the above-mentioned powder is used, preferably in the range of 0.5% by weight to 3% by weight. If the content of the powder is less than the above range, the color rendering power, durability, and adhesion of the product will be insufficient. On the contrary, if it exceeds the above range, dryness and keratin will be induced, so use within the above range as appropriate.

本發明的唇用化妝品組成物可連同上述組成一併使用於通常的唇用化妝品組成物中使用的蠟、油、色素及其他添加劑等。 The lip cosmetic composition of the present invention can be used together with the above-mentioned composition in waxes, oils, pigments, and other additives used in ordinary lip cosmetic compositions.

使用於本發明的蠟可列舉通常使用於唇用化妝品的烴類蠟、植物性蠟及矽酮蠟等所有蠟。具體而言,較佳為固相(solid phase)蠟,可列舉微晶蠟、地蠟、蜂蠟、小燭樹蠟、礦蠟、巴西棕櫚蠟、米糠蠟、石蠟、褐煤蠟、木蠟、可可脂等、及以聚乙烯蠟為代表的合成蠟等,但並不僅僅限定於此。於本發明的較佳的實施例中,混合聚乙烯蠟與地蠟而使用。 The waxes used in the present invention include all waxes such as hydrocarbon waxes, vegetable waxes, and silicone waxes that are generally used in lip cosmetics. Specifically, solid phase wax is preferred, and examples include microcrystalline wax, ozokerite wax, beeswax, candelilla wax, mineral wax, carnauba wax, rice bran wax, paraffin wax, montan wax, wood wax, and cocoa wax. Grease, etc., and synthetic wax represented by polyethylene wax, etc. are not limited to these. In a preferred embodiment of the present invention, polyethylene wax and ozokerite wax are mixed for use.

此種蠟發揮對製品賦予使用感,保濕及保持固定的硬度的作用。於整體唇用化妝品組成物100重量%中,蠟的含量較佳為3重量%至30重量%的範圍。於上述蠟的含量小於上述範圍的情形時,難以保持固定的硬度,與此相反,於超過上述範圍的情形時, 會導致最終唇用化妝品組成物的使用感較為乾澀、展延性下降或表面不柔滑。 This wax plays the role of imparting a feeling of use to the product, moisturizing and maintaining a fixed hardness. In 100% by weight of the overall lip cosmetic composition, the content of wax is preferably in the range of 3% by weight to 30% by weight. When the content of the above wax is less than the above range, it is difficult to maintain a fixed hardness. On the contrary, when the content exceeds the above range, it is difficult to maintain a fixed hardness. It will result in a dry feeling in use of the final lip cosmetic composition, a decrease in extensibility, or a non-smooth surface.

使用於本發明的油可列舉通常使用於唇用化妝品的酯類油、烴類油、天然油及其混合物。具體而言,可使用如液態石蠟的礦物性油;角鯊烯及氫化角鯊烯等動物性油;棕櫚油、鱷梨油、荷荷芭油、芝麻油、橄欖油及蓖麻油等植物性油;肉豆蔻酸丁酯、肉豆蔻酸異丙酯、肉豆蔻酸鯨蠟酯、棕櫚酸異丙酯、硬脂酸丁酯、聚丁烯、聚異丁烯、氫化聚異丁烯、各種多元醇、2-乙基己酸三甘油酯、三酸甘油酯類油、乳酸肉豆蔻酯、辛基十二烷醇、碳酸二辛酯及蘋果酸二異硬脂酯等合成油;但並不僅僅限定於此。於本發明的較佳的實施例中,混合蘋果酸二異硬脂酯與碳酸二辛酯而使用。 The oil used in the present invention includes ester oils, hydrocarbon oils, natural oils, and mixtures thereof that are generally used in lip cosmetics. Specifically, mineral oils such as liquid paraffin; animal oils such as squalene and hydrogenated squalene; vegetable oils such as palm oil, avocado oil, jojoba oil, sesame oil, olive oil, and castor oil can be used ; Butyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, butyl stearate, polybutene, polyisobutene, hydrogenated polyisobutene, various polyols, 2- Synthetic oils such as ethyl hexanoic acid triglyceride, triglyceride oil, myristyl lactate, octyldodecanol, dioctyl carbonate, and diisostearyl malate; but not limited to these . In a preferred embodiment of the present invention, diisostearyl malate and dioctyl carbonate are mixed for use.

此種油是為了對製品賦予使用感及保濕感,實現與其他組成的均勻混合而使用,較佳為於整體唇用化妝品組成物100重量%中為40重量%至80重量%的範圍。若上述油的含量小於上述範圍,則無法確保如上所述的效果,與此相反,於超過上述範圍的情形時,難以劑型化,因此於上述範圍內適當地使用。 Such oil is used to impart a feeling of use and moisturizing to the product, and to achieve uniform mixing with other compositions, and is preferably in the range of 40% to 80% by weight in 100% by weight of the overall lip cosmetic composition. If the content of the oil is less than the above range, the above-mentioned effect cannot be ensured. On the contrary, when it exceeds the above range, it is difficult to form a dosage form, so it is appropriately used within the above range.

本發明中使用的色素可為通常使用於唇用化妝品的染料或顏料。具體而言,作為上述顏料,可使用黃色203號、黃色4號、黃色5號、黃色201號、黃色204號、紅色103號、紅色201號、紅色202號、紅色218號、紅色220號、紅色223號、紅色226號、紅色227號、藍色1號、藍色2號等鋇薄片或鋁薄片的有 機顏料及珍珠顏料等,但並不僅僅限定於此。 The pigment used in the present invention may be a dye or pigment generally used in lip cosmetics. Specifically, as the above-mentioned pigments, Yellow No. 203, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 204, Red No. 103, Red No. 201, Red No. 202, Red No. 218, Red No. 220, Red No. 223, Red No. 226, Red No. 227, Blue No. 1, Blue No. 2 and other barium flakes or aluminum flakes have Organic pigments and pearl pigments, but not limited to this.

此種色素用以使製品顯色,於整體唇用化妝品組成物100重量%中,使用1重量%至20重量%。若上述色素的含量小於上述範圍,則難以實現所期望的色彩呈現,於超過上述範圍的情形時,其他組成的含量相對減少而難以確保製品的物性及本發明所欲獲得的效果,因此於上述範圍內適當地使用。 This kind of pigment is used to develop the color of the product, and is used in 100% by weight of the overall lip cosmetic composition, using 1% to 20% by weight. If the content of the above-mentioned pigment is less than the above-mentioned range, it is difficult to achieve the desired color presentation. When the content exceeds the above-mentioned range, the content of other components is relatively reduced, and it is difficult to ensure the physical properties of the product and the effects desired by the present invention. Use appropriately within the range.

作為其他添加劑,可為黃乳油、營養劑、保濕劑、保存劑、防腐劑、紫外線吸收劑、香料、揮發性溶解劑、抗氧化劑等。作為一例,黃乳油可為牛油樹油、巴西木乳油、可可脂、橄欖脂或巴巴樹油等各種黃乳油類。並且,作為保濕劑,可為丁二醇、丙二醇、二丙二醇、戊二醇等多元醇。於本發明中,上述其他添加劑的含量並無特別限定,可由在本技術領域內具有常識者適當地調節而使用。 As other additives, yellow cream, nutrients, moisturizers, preservatives, preservatives, ultraviolet absorbers, fragrances, volatile solvents, antioxidants, etc. can be used. As an example, the yellow butter may be various yellow butters such as shea butter, brazilian butter, cocoa butter, olive butter, or barba butter. In addition, as the humectant, polyhydric alcohols such as butanediol, propylene glycol, dipropylene glycol, and pentanediol may be used. In the present invention, the content of the above-mentioned other additives is not particularly limited, and can be appropriately adjusted and used by a person having common sense in the technical field.

本發明中提出的唇用化妝品組成物的製備並無特別限定,使用於本技術領域內公知的方法。 The preparation of the lip cosmetic composition proposed in the present invention is not particularly limited, and is used in a method known in the art.

作為一例,經由如下步驟製備:將矽膠及漿料化合物放入至混合機或攪拌機,以固定溫度進行加熱,之後進行攪拌而製備具有黏著力的凝膠劑型,向上述凝膠劑型添加蠟及油。向此處添加粉末、顏料、香料及其他添加劑而均勻地混合,之後於冷卻所獲得的混合物後,進行消泡而填充至容器。 As an example, it is prepared by the following steps: put the silicone gel and the slurry compound into a mixer or a mixer, heat it at a fixed temperature, and then stir to prepare a gel dosage form with adhesive force, and add wax and oil to the gel dosage form . Powders, pigments, fragrances, and other additives are added here and mixed uniformly, and then after cooling the obtained mixture, defoaming is performed and the container is filled.

此時,作為混合機或攪拌機的例,可列舉亨舍爾混合機、萬能混合機、均質機、濕式萬能混合機或捏合機等,但並不 僅僅限定於此。 In this case, as examples of mixers or mixers, Henschel mixers, universal mixers, homogenizers, wet universal mixers or kneaders can be cited, but they are not Only limited to this.

並且,上述加熱是於60℃至95℃的溫度下執行,以便可充分地混合各組成,此時根據混合機的尺寸及組成的含量而適當地調節攪拌。 In addition, the above-mentioned heating is performed at a temperature of 60°C to 95°C so that each composition can be sufficiently mixed. At this time, the stirring is appropriately adjusted according to the size of the mixer and the content of the composition.

另一方面,本發明的唇用化妝品組成物的劑型並無特別限定,包括可使用於唇部的所有形態的劑型,例如可劑型化成唇蜜、口紅、唇彩、唇膏或唇線筆等形態,較佳為可為口紅。 On the other hand, the dosage form of the lip cosmetic composition of the present invention is not particularly limited, and includes all forms that can be used for lips, such as lip gloss, lipstick, lip gloss, lipstick, or lip liner. Preferably, it can be a lipstick.

以下,藉由本發明的實施例,更詳細地對本發明的唇用化妝品組成物的製備方法進行說明。當然,本發明並不侷限於這些實施例。 Hereinafter, the preparation method of the lip cosmetic composition of the present invention will be described in more detail based on the examples of the present invention. Of course, the present invention is not limited to these embodiments.

<實施例1至實施例5、及比較例1至比較例4>唇用化妝品組成物的製備<Example 1 to Example 5, and Comparative Example 1 to Comparative Example 4> Preparation of lip cosmetic composition

稱取下述表1的原料而以85℃進行加熱溶解,之後利用均質機進行攪拌而製備混合物。於對所獲得的混合物進行脫氣後,以-20℃進行冷卻而製備口紅劑型的唇用化妝品組成物。 The raw materials of the following Table 1 were weighed, heated and dissolved at 85°C, and then stirred with a homogenizer to prepare a mixture. After deaerating the obtained mixture, it was cooled at -20°C to prepare a lipstick-type lip cosmetic composition.

Figure 106102844-A0305-02-0013-1
Figure 106102844-A0305-02-0013-1
Figure 106102844-A0305-02-0014-2
Figure 106102844-A0305-02-0014-2

<試驗例1>展延性評估<Test Example 1> Evaluation of ductility

為了確認於上述實施例1及比較例1至比較例4中所製備的口紅的卡色現象,以相同的力道於人造皮革上往復塗佈2次,將上述人造皮革的照片示於圖1。 In order to confirm the color blocking phenomenon of the lipsticks prepared in the above-mentioned Example 1 and Comparative Examples 1 to 4, the artificial leather was reciprocated twice with the same force. The photograph of the artificial leather is shown in FIG. 1.

參照圖1,確認到於根據本發明而同時包括矽膠與漿料化合物的實施例1的口紅的情形時,均勻地塗佈至人造皮革,從而可知無卡色而均勻地呈現色彩。具體而言,可知於實施例1的口紅的情形時,具有黏著力的凝膠劑型可一面填平凹凸,一面浸潤(即,滲透)而實現色彩呈現力,而並非為先前因粉末產生的顏色覆蓋至唇部上(即,浮起)的狀態。 Referring to FIG. 1, it was confirmed that in the case of the lipstick of Example 1 that includes both silicone gel and a slurry compound according to the present invention, it was uniformly applied to artificial leather, so that it can be seen that there is no jam and the color is uniform. Specifically, it can be seen that in the case of the lipstick of Example 1, the gel formulation with adhesive force can fill up the unevenness on one side, and infiltrate (i.e., penetrate) on the other side to achieve color rendering, instead of the previous color produced by powder The state of covering (i.e., floating) on the lips.

與此相比,於比較例1至比較例4的口紅的情形時,產生空隙而色彩不均勻地分佈,即便以相同的含量使用相同的色素,顯色力及色彩呈現力亦產生差異。 In contrast, in the case of the lipsticks of Comparative Examples 1 to 4, voids are generated and the colors are unevenly distributed. Even if the same pigment is used in the same content, the color rendering power and color rendering power are different.

<試驗例2>官能評估<Test Example 2> Sensory Evaluation

對在上述實施例及比較例中所製備的唇用化妝品組成物的展延性、色彩呈現力、顯色力、顏色持久力、乾燥感等進行評估。 The extensibility, color rendering power, color rendering power, color staying power, dryness, etc. of the lip cosmetic composition prepared in the above-mentioned Examples and Comparative Examples were evaluated.

評估對象為24歲至35歲的未婚及已婚女性,由10名化妝經驗最少2年以上、一週最少持續使用唇部製品5次以上的女性專業官能檢查員按照各項目以5分標準(1分:非常差,3分:普通,5分:非常優異)進行比較評估。此時,於所有數值均為3分以上的情形時可製品化,將其結果示於下述表2。 The subjects of the assessment are unmarried and married women aged 24 to 35. Ten female professional inspectors with at least 2 years of makeup experience and at least continuous use of lip products for at least 5 times a week will be assigned 5 points according to each item (1 Points: very poor, 3 points: normal, 5 points: very good) for comparative evaluation. At this time, when all the numerical values are 3 points or more, it can be manufactured, and the results are shown in Table 2 below.

Figure 106102844-A0305-02-0015-3
Figure 106102844-A0305-02-0015-3

根據上述表2可知,於本發明的實施例1的口紅的情形時,顏色持久性與顯色力優異,並且使用感亦更良好。特別是,於6小時後亦無乾燥感,且幾乎不產生卡色現象,從而可知既滋潤、均勻,亦具有柔和的展延性。 According to Table 2 above, it can be seen that in the case of the lipstick of Example 1 of the present invention, the color durability and color rendering power are excellent, and the feeling of use is also better. In particular, there is no dry feeling after 6 hours, and there is almost no seizing phenomenon, so it can be seen that it is not only moisturized, uniform, but also has soft stretchability.

具體而言,比較例1的口紅為使用與實施例1相同的含量的粉末,不使用矽膠與漿料化合物的情形,產生嚴重的卡色現 象,表現出顯色力及顏色持久力非常差的結果。 Specifically, the lipstick of Comparative Example 1 used powder with the same content as that of Example 1, and did not use silicone and slurry compounds, resulting in serious jamming. As a result, the color rendering power and color staying power are very poor.

比較例2僅使用矽膠,雖於某種程度上提高顯色力、持久力、展延性等,但如圖1所示,表現出不足以於整體上實現均勻的色彩呈現力的結果。 Comparative Example 2 only uses silicone, and although it improves color rendering power, endurance, and ductility to some extent, as shown in Fig. 1, the result is insufficient to achieve uniform color rendering power as a whole.

比較例3的口紅為僅使用漿料化合物的情形,確認到於某種程度上提高保濕力而於6小時後無乾燥感,但產生卡色現象而顯色力較低。 The lipstick of Comparative Example 3 was a case where only the slurry compound was used, and it was confirmed that the moisturizing power was improved to some extent and there was no dry feeling after 6 hours, but the color jam phenomenon occurred and the color development power was low.

並且,比較例4的口紅為無矽膠及漿料化合物而如先前技術般使用10重量%以上的粉末者,於6小時後產生嚴重的乾燥感,於卡色現象、持久力、展延性等整體評估中表現出非常低的數值。 In addition, the lipstick of Comparative Example 4 is free of silicone and paste compounds and uses more than 10% by weight of powder as in the prior art. After 6 hours, a serious dry feeling is generated, which is in the overall color blocking phenomenon, staying power, and ductility. The evaluation showed very low values.

根據此種結果,可知本發明的唇用化妝品組成物即便減少粉末的含量,亦可藉由使用矽膠與漿料化合物而實現高顯色的色彩呈現力,同時可改善乾燥感。 Based on these results, it can be seen that the lip cosmetic composition of the present invention can achieve high color rendering power by using silicone and slurry compounds even if the powder content is reduced, and at the same time can improve the dryness.

Claims (4)

一種唇用化妝品組成物,其中包括蠟、油、色素及粉末,所述唇用化妝品組成物更包括矽膠及漿料化合物,其中所述粉末包括氧化鋁及尼龍,其中所述矽膠包括選自由聚二甲基矽氧烷/乙烯基聚二甲基矽氧烷交聯聚合物、丙烯酸酯/丙烯酸硬脂酯/聚二甲基矽氧烷/甲基丙烯酸酯共聚物及其組合所構成的族群中的一種,其中所述漿料化合物包括選自由雙-二甘油多脂醯基己二酸酯-2、油酸/亞油酸/亞麻酸聚甘油酯及其組合所構成的族群中的一種,其中於所述唇用化妝品組成物100重量%中,包括0.5重量%至3重量%的所述粉末,其中以1:4至4:1的重量比包括所述矽膠與所述漿料化合物。 A lip cosmetic composition, which includes wax, oil, pigment and powder. The lip cosmetic composition further includes silicone and a slurry compound. The powder includes alumina and nylon. The silicone includes Dimethylsiloxane/vinyl polydimethylsiloxane cross-linked polymer, acrylate/stearyl acrylate/polydimethylsiloxane/methacrylate copolymer and their combinations constitute a group One of, wherein the slurry compound comprises one selected from the group consisting of bis-diglyceride polylipid adipate-2, oleic acid/linoleic acid/linolenic acid polyglycerol ester and combinations thereof , Wherein in 100% by weight of the lip cosmetic composition, 0.5% to 3% by weight of the powder is included, wherein the silicone gel and the slurry compound are included in a weight ratio of 1:4 to 4:1 . 如申請專利範圍第1項所述的唇用化妝品組成物,其中以1.2:1至3:1的重量比包括所述矽膠與所述漿料化合物。 The lip cosmetic composition described in item 1 of the scope of patent application, wherein the silicone gel and the slurry compound are included in a weight ratio of 1.2:1 to 3:1. 如申請專利範圍第1項所述的唇用化妝品組成物,其中於所述唇用化妝品組成物100重量%中,包括10重量%至50重量%的所述矽膠。 The lip cosmetic composition according to the first item of the scope of patent application, wherein in 100% by weight of the lip cosmetic composition, 10% to 50% by weight of the silicone gel is included. 如申請專利範圍第1項所述的唇用化妝品組成物,其中於所述唇用化妝品組成物100重量%中,包括5重量%至40重量%的所述漿料化合物。 The lip cosmetic composition according to the first item of the scope of patent application, wherein in 100% by weight of the lip cosmetic composition, 5 to 40% by weight of the slurry compound is included.
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