CN114341211A - 阻燃抗菌剂及其制备方法和应用及阻燃抗菌热塑性树脂组合物 - Google Patents

阻燃抗菌剂及其制备方法和应用及阻燃抗菌热塑性树脂组合物 Download PDF

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CN114341211A
CN114341211A CN202080062030.9A CN202080062030A CN114341211A CN 114341211 A CN114341211 A CN 114341211A CN 202080062030 A CN202080062030 A CN 202080062030A CN 114341211 A CN114341211 A CN 114341211A
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guanidine
flame
weight
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retardant
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CN114341211B (zh
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王宇韬
初立秋
李�杰
张师军
高达利
尹华
郭鹏
邵静波
李长金
胡晨曦
白弈青
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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Abstract

一种阻燃抗菌剂及其制备方法和应用及阻燃抗菌热塑性树脂组合物。所述阻燃抗菌剂为表面接枝有胍盐的聚合物微球，其中所述聚合物微球包含由衍生自马来酸酐的结构单元A、衍生自单体M的结构单元B和衍生自交联剂的结构单元C构成的交联结构，所述单体M选自C4‑C9脂族烯烃及其混合物；并且所述胍盐包含至少一种具有阻燃性的胍盐。本发明的阻燃抗菌剂兼具良好的抗菌和阻燃效果，是有效的单组分多功能化助剂，具有很好的阻燃和抗菌效率，同时分散性好、流动性好、吸潮性低。包含所述阻燃抗菌剂的阻燃抗菌热塑性树脂组合物也同时具有良好的阻燃和抗菌性能，并且综合性能优良。

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PCT国内申请，说明书已公开。

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  1. PCT国内申请，权利要求书已公开。
CN202080062030.9A 2019-10-30 2020-10-29 阻燃抗菌剂及其制备方法和应用及阻燃抗菌热塑性树脂组合物 Active CN114341211B (zh)

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CN201911042238.XA CN112745456B (zh) 2019-10-30 2019-10-30 一种阻燃抗菌剂及其制法和应用及阻燃抗菌热塑性树脂组合物
CN201911042238X 2019-10-30
PCT/CN2020/124805 WO2021083272A1 (zh) 2019-10-30 2020-10-29 阻燃抗菌剂及其制备方法和应用及阻燃抗菌热塑性树脂组合物

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115536956A (zh) * 2022-12-01 2022-12-30 江苏绿安擎峰新材料有限公司 一种无卤阻燃聚苯乙烯树脂和制备方法
CN116003664A (zh) * 2022-12-09 2023-04-25 北京化工大学 非交联的氯乙烯系树脂粒子及其制备方法
CN116496617A (zh) * 2023-04-26 2023-07-28 江苏金发科技新材料有限公司 抗菌尼龙组合物及其制备方法与应用

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112745456B (zh) * 2019-10-30 2022-07-12 中国石油化工股份有限公司 一种阻燃抗菌剂及其制法和应用及阻燃抗菌热塑性树脂组合物
CN114230906B (zh) * 2021-11-30 2023-05-09 天津金发新材料有限公司 一种低烟密度阻燃聚丙烯复合材料及其制备方法和应用
CN114134592A (zh) * 2021-12-17 2022-03-04 石狮市益明染织有限公司 一种耐阻燃的涤纶丝及其制备方法
CN115286732B (zh) * 2022-08-12 2023-12-22 江西熠亮光电新材料有限公司 一种抗菌阻燃亚克力材料的制备方法
CN115449158B (zh) * 2022-10-17 2023-08-11 广东登峰电线电缆有限公司 一种耐热性的无卤低烟阻燃耐火电缆
CN115785573B (zh) * 2022-12-02 2024-05-17 福建奥翔体育塑胶科技股份有限公司 一种持久抗菌型epdm颗粒及其制备方法
CN116102674A (zh) * 2022-12-09 2023-05-12 北京化工大学 基于非交联的抗菌性聚合物的抗菌性添加剂和其制造方法，氯乙烯系树脂组合物和成形品
CN116102673A (zh) * 2022-12-09 2023-05-12 北京化工大学 基于交联抗菌性聚合物颗粒的抗菌性添加剂和其制造方法，氯乙烯系树脂组合物和成形品
CN115975097A (zh) * 2022-12-09 2023-04-18 北京化工大学 交联的氯乙烯系树脂粒子及其制备方法
CN116814025B (zh) * 2023-08-05 2024-05-28 杭州鑫璐实业有限公司 一种改性复合聚氯乙烯塑料粒子及其生产工艺
CN117487304B (zh) * 2023-12-29 2024-03-26 河北盛泉新材料有限公司 一种基于胍盐聚合物的抗菌母粒及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101628952A (zh) * 2009-08-20 2010-01-20 合肥工业大学 胍类高分子型抗菌剂的制备方法
CN101724284A (zh) * 2008-10-31 2010-06-09 中国石油化工股份有限公司 一种抗菌热塑性塑料组合物及其制备方法
CN109705270A (zh) * 2017-10-25 2019-05-03 中国石油化工股份有限公司 含聚对苯二甲酸乙二醇酯的组合物和制备共混塑料的方法
CN111944233A (zh) * 2019-05-17 2020-11-17 中国石油化工股份有限公司 一种抗菌热塑性树脂组合物及其制备方法和应用
CN111944155A (zh) * 2019-05-17 2020-11-17 中国石油化工股份有限公司 一种胍盐抗菌微球及其制备方法和应用
CN112745456A (zh) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 一种阻燃抗菌剂及其制法和应用及阻燃抗菌热塑性树脂组合物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1733827A4 (en) * 2004-02-26 2008-03-26 Nagoya Oilchemical FLAME-RESILIENT POROUS SURFACE PATTERNS, PARTS THEREFROM AND FLAME-RESISTANT SOUND ABSORPTION VEHICLES FOR MOTOR VEHICLES
TWI585141B (zh) * 2012-03-14 2017-06-01 瑞來斯實業公司 具有自癒性質的熱可逆聚丁二烯橡膠混合物
CN103554595B (zh) * 2013-10-23 2016-01-13 上海富元塑胶科技有限公司 无卤阻燃剂、无卤阻燃聚烯烃组合物及其应用
CN103937003B (zh) * 2014-05-05 2016-09-14 上海富元塑胶科技有限公司 多功能化乙烯基聚合物的制备方法及其应用
CN105754278B (zh) * 2016-03-09 2018-06-26 惠州市环美盛新材料有限公司 一种纳米无机抗菌塑料母粒及其制备方法
EP3464444B1 (en) * 2016-05-25 2024-05-01 Corning Optical Communications LLC Flame retardant additive for a low smoke, zero halogen compound
CN106149091A (zh) * 2016-06-30 2016-11-23 旷达纤维科技有限公司 一种高阻燃抗菌有色环保涤纶纤维的制备方法
CN107879874B (zh) * 2016-09-30 2020-10-23 中国石油化工股份有限公司 一种混合碳四生产正丁烷的方法和装置
CN106800652B (zh) * 2017-01-26 2019-08-06 上海富元塑胶科技有限公司 胍类齐聚物及其制备方法与键合于通用聚合物分子链上的应用
CN106835328B (zh) * 2017-02-26 2019-03-05 浙江峰赫纺织有限公司 一种阻燃抗菌纤维原丝的制备方法
CN107151430B (zh) * 2017-05-26 2019-06-28 吴新贤 一种用于3d打印的阻燃抗菌pla生物降解复合材料
CN109705540B (zh) * 2017-10-25 2021-05-11 中国石油化工股份有限公司 含聚对苯二甲酸乙二醇酯的组合物和制备共混塑料的方法
CN107936233A (zh) * 2017-12-05 2018-04-20 江苏裕兴薄膜科技股份有限公司 一种阻燃型pet/纳米碳微球复合材料及其制备方法
CN109096601A (zh) * 2018-07-03 2018-12-28 广东康百文创科技有限公司 一种耐酸阻燃抗菌聚丙烯片材的制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101724284A (zh) * 2008-10-31 2010-06-09 中国石油化工股份有限公司 一种抗菌热塑性塑料组合物及其制备方法
CN101628952A (zh) * 2009-08-20 2010-01-20 合肥工业大学 胍类高分子型抗菌剂的制备方法
CN109705270A (zh) * 2017-10-25 2019-05-03 中国石油化工股份有限公司 含聚对苯二甲酸乙二醇酯的组合物和制备共混塑料的方法
CN111944233A (zh) * 2019-05-17 2020-11-17 中国石油化工股份有限公司 一种抗菌热塑性树脂组合物及其制备方法和应用
CN111944155A (zh) * 2019-05-17 2020-11-17 中国石油化工股份有限公司 一种胍盐抗菌微球及其制备方法和应用
CN112745456A (zh) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 一种阻燃抗菌剂及其制法和应用及阻燃抗菌热塑性树脂组合物

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115536956A (zh) * 2022-12-01 2022-12-30 江苏绿安擎峰新材料有限公司 一种无卤阻燃聚苯乙烯树脂和制备方法
CN115536956B (zh) * 2022-12-01 2023-03-03 江苏绿安擎峰新材料有限公司 一种无卤阻燃聚苯乙烯树脂和制备方法
CN116003664A (zh) * 2022-12-09 2023-04-25 北京化工大学 非交联的氯乙烯系树脂粒子及其制备方法
CN116496617A (zh) * 2023-04-26 2023-07-28 江苏金发科技新材料有限公司 抗菌尼龙组合物及其制备方法与应用
CN116496617B (zh) * 2023-04-26 2024-03-26 江苏金发科技新材料有限公司 抗菌尼龙组合物及其制备方法与应用

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