CN114181765A - 一种挥发性精密冲压油及其制备方法 - Google Patents

一种挥发性精密冲压油及其制备方法 Download PDF

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CN114181765A
CN114181765A CN202111567128.2A CN202111567128A CN114181765A CN 114181765 A CN114181765 A CN 114181765A CN 202111567128 A CN202111567128 A CN 202111567128A CN 114181765 A CN114181765 A CN 114181765A
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oil
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precision stamping
hydrocarbon solvent
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赵鹏
谢宗生
汪小龙
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Amer Technology Co Ltd
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Abstract

本发明提供一种挥发性精密冲压油及其制备方法,涉及冲压成型工艺的润滑剂技术领域,本发明中,在传统的挥发性精密冲压油的制备基础上,通过表面活性剂,能够在加工形状复杂的零件或塑性变形阻力大的材料时,有效的抑制冲压油与工件之间摩擦产生的热量,提高了冲压油的冷却性能,同时也增加了冲压油的润滑效果,避免热量过高导致工件产生变形,或导致润滑膜破裂,从而造成烧结、拉伤和破裂等故障,同时通过设置复合抗泡剂,相比于传统抗泡剂的使用,提高了其抗泡功能的稳定性,满足油品使用性能的要求,增强了抗泡效果,同时该油品具备良好的挥发性,残留很低,并且具备极佳的极压润滑性。

Description

一种挥发性精密冲压油及其制备方法
技术领域
本发明涉及冲压成型工艺的润滑剂技术领域,尤其涉及一种挥发性精密冲压油及其制备方法。
背景技术
随着工业科技的发展,现代金属加工业对特种加工油的需求将会越来越高,目前许多汽车零部件和五金件加工一般冲压后续为焊接工艺,因为普遍的冲压油粘度都比较大,工件上残留较多,后续焊接时会产生大量油烟,严重影响工人的工作环境,同时产生的油烟对环境也产生污染,如果为了控制油烟,增加清洗工序就严重影响生产效率也会增加生产成本,并且在冲压过程中,模具与材料间的摩擦热及材料塑性变形热都以加工热的形式表现出来,特别是加工形状复杂的零件或塑性变形阻力大的材料时,产生的热量更大,长时间连续进行这种加工时,要是不除去或不抑制这种热量,热量就蓄积到模具上,使模具温度继续上升,最终导致润滑膜破裂,从而造成烧结、拉伤和破裂等故障。
发明内容
本发明的目的是为了解决现有技术中存在的缺点,而提出的一种挥发性精密冲压油及其制备方法。
为了实现上述目的,本发明采用了如下技术方案:一种挥发性精密冲压油,所述的一种挥发性精密冲压油的制备材料是由极压剂、抗磨剂、油性剂、防锈剂、钝化剂、碳氢溶剂油、表面活性剂和复合抗泡剂,且各材料的重量比如下:极压剂0.1~3份、抗磨剂0.1~3份、油性剂0.1~5份、防锈剂0.1~1份、钝化剂0.05~0.5份、碳氢溶剂油余量、表面活性剂0.2~0.5份、复合抗泡剂0.1~0.3份。
为了防止金属材料黏着,本发明改进有,所述极压剂为硫化脂肪酸甲酯、聚乙烯醇、滑石粉、硅酸钠、氟硼酸钠和硬脂酸锌中的其中一种或多种。
为了起到养护工件作用,本发明改进有,所述抗磨剂是由纳米二氧化硅、甲基三氯硅烷、脂肪酸、亚麻油酸和季戊四醇中的一种或多种混合而成。
为了增加润滑效果,本发明改进有,所述油性剂为棕榈酸、油酸、硬脂酸丁酯和酸式磷酸油酰酯中的其中一种或多种。
为了提高金属的防锈能力,本发明改进有,所述防锈剂为氧化石蜡丁酯、三聚磷酸酯和纳米甲基硅盐的混合物、石油稀土磺酸盐、甲基纤维素和羟乙纤维素的混合物中的其中一种或多种。
为了增强防腐能力,本发明改进有,所述钝化剂为噻二唑衍生物、有机膦酸、丙二酸和蓖麻油聚氧乙烯醚中的其中一种或多种。
为了制备冲压油,本发明改进有,所述碳氢溶剂油为D60、D70和D80中的一种或几种。
为了减少冲压油使用时产生的热量,本发明改进有,所述表面活性剂是由自乳化合成酯、聚合脂肪酸和植物油改性润滑剂混合调配而成。
为了提高抗泡性能,本发明改进有,所述复合抗泡剂为环氧乙烷、环氧丙烷的共聚物。
一种挥发性精密冲压油的制备方法,包括以下步骤:
S1:初步混合,将碳氢溶剂油加入反应釜中,接着加入防锈剂和抗磨剂,同时将反应釜预热至180~200℃,此时启动搅拌设备对碳氢溶剂油以及添加剂进行初步混合搅拌,同时将搅拌的转速控制在4500~6500rpm之间,搅拌时长在15~30min之间;
S2:混合添加剂,将油性剂、防锈剂、钝化剂、碳氢溶剂油和表面活性剂依次加入反应釜内,同时将反应釜温度保持在80~90℃,并经过10~20min的搅拌,当搅拌完成后,此时加入复合抗泡剂,继续搅拌3~5min;
S3:超声处理,当搅拌工作完成时,此时将反应釜内原油静置4~8min,接着将原油放置超声波振荡器中震荡60~70min,使得原油分散均匀;
S4:杂质过滤,最终通过滤机对原油中的杂质进行过滤,并完成装桶操作,从而制备成原油。
与现有技术相比,本发明的优点和积极效果在于,
本发明中,在传统的挥发性精密冲压油的制备基础上,通过表面活性剂,能够在加工形状复杂的零件或塑性变形阻力大的材料时,有效的抑制冲压油与工件之间摩擦产生的热量,提高了冲压油的冷却性能,同时也增加了冲压油的润滑效果,避免热量过高导致工件产生变形,或导致润滑膜破裂,从而造成烧结、拉伤和破裂等故障,同时通过设置复合抗泡剂,相比于传统抗泡剂的使用,提高了其抗泡功能的稳定性,满足油品使用性能的要求,增强了抗泡效果,同时该油品具备良好的挥发性,残留很低,并且具备极佳的极压润滑性,使用该油品时,会减少冲压件上的残留,不影响后续焊接,油烟极少,同时具备工序间防锈的功能,对于提高生产效率和保护环境都有很重要的意义。
附图说明
图1为本发明提出一种挥发性精密冲压油及其制备方法的制备流程图。
具体实施方式
为了能够更清楚地理解本发明的上述目的、特征和优点,下面结合附图和实施例对本发明做进一步说明。需要说明的是,在不冲突的情况下,本申请的实施例及实施例中的特征可以相互组合。
在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是,本发明还可以采用不同于在此描述的其他方式来实施,因此,本发明并不限于下面公开说明书的具体实施例的限制。
实施例一,请参阅图1,本发明提供一种技术方案:一种挥发性精密冲压油,所述的一种挥发性精密冲压油的制备材料是由极压剂、抗磨剂、油性剂、防锈剂、钝化剂、碳氢溶剂油、表面活性剂和复合抗泡剂,且各材料的重量比如下:极压剂0.1份、抗磨剂3份、油性剂5份、防锈剂0.1份、钝化剂0.5份、碳氢溶剂油D60 60份,D80余量、表面活性剂0.3份、复合抗泡剂0.25份。
所述极压剂为硫化脂肪酸甲酯、聚乙烯醇、滑石粉、硅酸钠、氟硼酸钠和硬脂酸锌中的其中一种或多种,通过设置极压剂,起到了润滑的作用,防止金属表面擦伤,甚至熔焊。
所述抗磨剂是由纳米二氧化硅、甲基三氯硅烷、脂肪酸、亚麻油酸和季戊四醇中的一种或多种混合而成,通过设置抗磨剂,抗磨剂比普通机油黏附力更强、更耐热、耐腐蚀,可黏附在汽缸内壁形成一层保护膜,增强润滑效果,并修复气缸内壁的划痕、让粗糙的表面光滑,保证发动机正常高速运转,起到养护和修复作用。
所述油性剂为棕榈酸、油酸、硬脂酸丁酯和酸式磷酸油酰酯中的其中一种或多种,油性剂是指在边界润滑中降低摩擦及磨损的能力,同样起到了润滑和养护的作用。
所述防锈剂为氧化石蜡丁酯、三聚磷酸酯和纳米甲基硅盐的混合物、石油稀土磺酸盐、甲基纤维素和羟乙纤维素的混合物中的其中一种或多种,防锈剂有效的防锈取决于对金属表面的保护,从而停止或延迟水分、氧气和其它杂质的入侵。
所述钝化剂为噻二唑衍生物、有机膦酸、丙二酸和蓖麻油聚氧乙烯醚中的其中一种或多种,钝化剂能通过其作用在金属表面形成一层致密氧化膜(钝化膜),以增强金属的防腐能力。
所述碳氢溶剂油为D60、D70和D80中的一种或几种,通过设置碳氢溶剂油,并使其作为基础油,起到了制备冲压油的作用。
所述表面活性剂是由自乳化合成酯、聚合脂肪酸和植物油改性润滑剂混合调配而成,通过设置表面活性剂,有效的抑制冲压油与工件之间摩擦产生的热量,提高了冲压油的冷却性能。
所述复合抗泡剂为环氧乙烷、环氧丙烷的共聚物,通过设置复合抗泡剂,提高了抗泡性能,满足油品使用性能的要求。
一种挥发性精密冲压油的制备方法,包括以下步骤:
S1:初步混合,将碳氢溶剂油加入反应釜中,接着加入防锈剂和抗磨剂,同时将反应釜预热至200℃,此时启动搅拌设备对碳氢溶剂油以及添加剂进行初步混合搅拌,同时将搅拌的转速控制在5500rpm之间,搅拌时长在18min之间;
S2:混合添加剂,将油性剂、防锈剂、钝化剂、碳氢溶剂油和表面活性剂依次加入反应釜内,同时将反应釜温度保持在85℃,并经过20min的搅拌,当搅拌完成后,此时加入复合抗泡剂,继续搅拌4min;
S3:超声处理,当搅拌工作完成时,此时将反应釜内原油静置8min,接着将原油放置超声波振荡器中震荡65min,使得原油分散均匀;
S4:杂质过滤,最终通过滤机对原油中的杂质进行过滤,并完成装桶操作,从而制备成原油。
实施例二,请参阅图1,本发明提供一种技术方案:一种挥发性精密冲压油,所述的一种挥发性精密冲压油的制备材料是由极压剂、抗磨剂、油性剂、防锈剂、钝化剂、碳氢溶剂油、表面活性剂和复合抗泡剂,且各材料的重量比如下:极压剂3份、抗磨剂0.1份、油性剂0.1份、防锈剂1份、钝化剂0.05份、碳氢溶剂油D70余量、表面活性剂0.5份、复合抗泡剂0.1份。
所述极压剂为硫化脂肪酸甲酯、聚乙烯醇、滑石粉、硅酸钠、氟硼酸钠和硬脂酸锌中的其中一种或多种,通过设置极压剂,起到了润滑的作用,防止金属表面擦伤,甚至熔焊。
所述抗磨剂是由纳米二氧化硅、甲基三氯硅烷、脂肪酸、亚麻油酸和季戊四醇中的一种或多种混合而成,通过设置抗磨剂,抗磨剂比普通机油黏附力更强、更耐热、耐腐蚀,可黏附在汽缸内壁形成一层保护膜,增强润滑效果,并修复气缸内壁的划痕、让粗糙的表面光滑,保证发动机正常高速运转,起到养护和修复作用。
所述油性剂为棕榈酸、油酸、硬脂酸丁酯和酸式磷酸油酰酯中的其中一种或多种,油性剂是指在边界润滑中降低摩擦及磨损的能力,同样起到了润滑和养护的作用。
所述防锈剂为氧化石蜡丁酯、三聚磷酸酯和纳米甲基硅盐的混合物、石油稀土磺酸盐、甲基纤维素和羟乙纤维素的混合物中的其中一种或多种,防锈剂有效的防锈取决于对金属表面的保护,从而停止或延迟水分、氧气和其它杂质的入侵。
所述钝化剂为噻二唑衍生物、有机膦酸、丙二酸和蓖麻油聚氧乙烯醚中的其中一种或多种,钝化剂能通过其作用在金属表面形成一层致密氧化膜(钝化膜),以增强金属的防腐能力。
所述碳氢溶剂油为D60、D70和D80中的一种或几种,通过设置碳氢溶剂油,并使其作为基础油,起到了制备冲压油的作用。
所述表面活性剂是由自乳化合成酯、聚合脂肪酸和植物油改性润滑剂混合调配而成,通过设置表面活性剂,有效的抑制冲压油与工件之间摩擦产生的热量,提高了冲压油的冷却性能。
所述复合抗泡剂为环氧乙烷、环氧丙烷的共聚物,通过设置复合抗泡剂,提高了抗泡性能,满足油品使用性能的要求。
一种挥发性精密冲压油的制备方法,包括以下步骤:
S1:初步混合,将碳氢溶剂油加入反应釜中,接着加入防锈剂和抗磨剂,同时将反应釜预热至185℃,此时启动搅拌设备对碳氢溶剂油以及添加剂进行初步混合搅拌,同时将搅拌的转速控制在6500rpm之间,搅拌时长在15min之间;
S2:混合添加剂,将油性剂、防锈剂、钝化剂、碳氢溶剂油和表面活性剂依次加入反应釜内,同时将反应釜温度保持在90℃,并经过18min的搅拌,当搅拌完成后,此时加入复合抗泡剂,继续搅拌4min;
S3:超声处理,当搅拌工作完成时,此时将反应釜内原油静置5min,接着将原油放置超声波振荡器中震荡60min,使得原油分散均匀;
S4:杂质过滤,最终通过滤机对原油中的杂质进行过滤,并完成装桶操作,从而制备成原油。
实施例三,请参阅图1,本发明提供一种技术方案:一种挥发性精密冲压油,所述的一种挥发性精密冲压油的制备材料是由极压剂、抗磨剂、油性剂、防锈剂、钝化剂、碳氢溶剂油、表面活性剂和复合抗泡剂,且各材料的重量比如下:极压剂1.5份、抗磨剂0.6份、油性剂3份、防锈剂0.5份、钝化剂0.2份、碳氢溶剂油D60 20份D70 60份D80余量、表面活性剂0.25份、复合抗泡剂0.3份。
所述极压剂为硫化脂肪酸甲酯、聚乙烯醇、滑石粉、硅酸钠、氟硼酸钠和硬脂酸锌中的其中一种或多种,通过设置极压剂,起到了润滑的作用,防止金属表面擦伤,甚至熔焊。
所述抗磨剂是由纳米二氧化硅、甲基三氯硅烷、脂肪酸、亚麻油酸和季戊四醇中的一种或多种混合而成,通过设置抗磨剂,抗磨剂比普通机油黏附力更强、更耐热、耐腐蚀,可黏附在汽缸内壁形成一层保护膜,增强润滑效果,并修复气缸内壁的划痕、让粗糙的表面光滑,保证发动机正常高速运转,起到养护和修复作用。
所述油性剂为棕榈酸、油酸、硬脂酸丁酯和酸式磷酸油酰酯中的其中一种或多种,油性剂是指在边界润滑中降低摩擦及磨损的能力,同样起到了润滑和养护的作用。
所述防锈剂为氧化石蜡丁酯、三聚磷酸酯和纳米甲基硅盐的混合物、石油稀土磺酸盐、甲基纤维素和羟乙纤维素的混合物中的其中一种或多种,防锈剂有效的防锈取决于对金属表面的保护,从而停止或延迟水分、氧气和其它杂质的入侵。
所述钝化剂为噻二唑衍生物、有机膦酸、丙二酸和蓖麻油聚氧乙烯醚中的其中一种或多种,钝化剂能通过其作用在金属表面形成一层致密氧化膜(钝化膜),以增强金属的防腐能力。
所述碳氢溶剂油为D60、D70和D80中的一种或几种,通过设置碳氢溶剂油,并使其作为基础油,起到了制备冲压油的作用。
所述表面活性剂是由自乳化合成酯、聚合脂肪酸和植物油改性润滑剂混合调配而成,通过设置表面活性剂,有效的抑制冲压油与工件之间摩擦产生的热量,提高了冲压油的冷却性能。
所述复合抗泡剂为环氧乙烷、环氧丙烷的共聚物,通过设置复合抗泡剂,提高了抗泡性能,满足油品使用性能的要求。
一种挥发性精密冲压油的制备方法,包括以下步骤:
S1:初步混合,将碳氢溶剂油加入反应釜中,接着加入防锈剂和抗磨剂,同时将反应釜预热至185℃,此时启动搅拌设备对碳氢溶剂油以及添加剂进行初步混合搅拌,同时将搅拌的转速控制在5200rpm之间,搅拌时长在18min之间;
S2:混合添加剂,将油性剂、防锈剂、钝化剂、碳氢溶剂油和表面活性剂依次加入反应釜内,同时将反应釜温度保持在85℃,并经过14min的搅拌,当搅拌完成后,此时加入复合抗泡剂,继续搅拌4min;
S3:超声处理,当搅拌工作完成时,此时将反应釜内原油静置4min,接着将原油放置超声波振荡器中震荡70min,使得原油分散均匀;
S4:杂质过滤,最终通过滤机对原油中的杂质进行过滤,并完成装桶操作,从而制备成原油。
以上所述,仅是本发明的较佳实施例而已,并非是对本发明作其它形式的限制,任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为等同变化的等效实施例应用于其它领域,但是凡是未脱离本发明技术方案内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与改型,仍属于本发明技术方案的保护范围。

Claims (10)

1.一种挥发性精密冲压油,其特征在于:所述的一种挥发性精密冲压油的制备材料是由极压剂、抗磨剂、油性剂、防锈剂、钝化剂、碳氢溶剂油、表面活性剂和复合抗泡剂,且各材料的重量比如下:极压剂0.1~3份、抗磨剂0.1~3份、油性剂0.1~5份、防锈剂0.1~1份、钝化剂0.05~0.5份、碳氢溶剂油余量、表面活性剂0.2~0.5份、复合抗泡剂0.1~0.3份。
2.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述极压剂为硫化脂肪酸甲酯、聚乙烯醇、滑石粉、硅酸钠、氟硼酸钠和硬脂酸锌中的其中一种或多种。
3.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述抗磨剂是由纳米二氧化硅、甲基三氯硅烷、脂肪酸、亚麻油酸和季戊四醇中的一种或多种混合而成。
4.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述油性剂为棕榈酸、油酸、硬脂酸丁酯和酸式磷酸油酰酯中的其中一种或多种。
5.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述防锈剂为氧化石蜡丁酯、三聚磷酸酯和纳米甲基硅盐的混合物、石油稀土磺酸盐、甲基纤维素和羟乙纤维素的混合物中的其中一种或多种。
6.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述钝化剂为噻二唑衍生物、有机膦酸、丙二酸和蓖麻油聚氧乙烯醚中的其中一种或多种。
7.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述碳氢溶剂油为D60、D70和D80中的一种或几种。
8.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述表面活性剂是由自乳化合成酯、聚合脂肪酸和植物油改性润滑剂混合调配而成。
9.根据权利要求1所述的一种挥发性精密冲压油,其特征在于:所述复合抗泡剂为环氧乙烷、环氧丙烷的共聚物。
10.一种挥发性精密冲压油的制备方法,其特征在于,包括以下步骤:
S1:初步混合,将碳氢溶剂油加入反应釜中,接着加入防锈剂和抗磨剂,同时将反应釜预热至180~200℃,此时启动搅拌设备对碳氢溶剂油以及添加剂进行初步混合搅拌,同时将搅拌的转速控制在4500~6500rpm之间,搅拌时长在15~30min之间;
S2:混合添加剂,将油性剂、防锈剂、钝化剂、碳氢溶剂油和表面活性剂依次加入反应釜内,同时将反应釜温度保持在80~90℃,并经过10~20min的搅拌,当搅拌完成后,此时加入复合抗泡剂,继续搅拌3~5min;
S3:超声处理,当搅拌工作完成时,此时将反应釜内原油静置4~8min,接着将原油放置超声波振荡器中震荡60~70min,使得原油分散均匀;
S4:杂质过滤,最终通过滤机对原油中的杂质进行过滤,并完成装桶操作,从而制备成原油。
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