CN114099382A - Soap-based facial cleanser and preparation method thereof - Google Patents
Soap-based facial cleanser and preparation method thereof Download PDFInfo
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- CN114099382A CN114099382A CN202111385160.9A CN202111385160A CN114099382A CN 114099382 A CN114099382 A CN 114099382A CN 202111385160 A CN202111385160 A CN 202111385160A CN 114099382 A CN114099382 A CN 114099382A
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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Abstract
The invention discloses soap-based facial cleanser and a preparation method thereof, and belongs to the technical field of daily chemicals. The soap-based facial cleanser provided by the invention comprises the following components in parts by weight: 26-33 parts of fatty acid, 4-7 parts of neutralizing agent, 25-40 parts of humectant, 0.8-2.8 parts of emulsifier, 2-6 parts of auxiliary surfactant, 1.8-3.6 parts of suspension stabilizer, 0.5-2.5 parts of pearling agent, 0.3-0.5 part of grinding agent, 0.9-1 part of adsorbent and 0.75 part of skin conditioner. According to the invention, the high and low temperature stability of the product is increased by adjusting the addition amounts of the grinding agent and the adsorbent, so that the facial cleanser can tolerate the high temperature of 50 ℃ for 3 months, and the facial cleanser has rich and fine foam, is mild and efficient to clean, and is fresh and not tight after washing.
Description
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to soap-based facial cleanser and a preparation method thereof.
Background
At present, facial cleaning products in the market are full of precious minerals, and can be roughly divided into three types according to the types of main cleaning components of the product formula: the soap base cleansing cream is characterized by rich and fine foam, cleanness, thoroughness, easy washing, fresh and cool skin after washing and the like, and is popular with Asian consumers.
The soap base facial cleanser is milky or pasty in appearance, and the pasty soap base facial cleanser is the mainstream in the market. Conventionally, soap-based facial cleanser has poor high-temperature stability, and frequently has the problems of penetration and delamination at high temperature, hardening at recovery room temperature and the like.
The stability problem of soap-based facial cleanser influences the quality and normal sale of products, limits the application development of industrialization and needs to be solved urgently.
Disclosure of Invention
The invention aims to provide soap-based facial cleanser and a preparation method thereof, and the soap-based facial cleanser has excellent high and low temperature stability, rich and fine foam, mild and efficient cleaning and refreshing and is not tight after washing.
In order to achieve the purpose, the invention adopts the following technical scheme:
a soap-based facial cleanser mainly comprises water and the following components in parts by weight: 26-33 parts of fatty acid, 4-7 parts of neutralizing agent, 25-40 parts of humectant, 0.8-2.8 parts of emulsifier, 2-6 parts of auxiliary surfactant, 1.8-3.6 parts of suspension stabilizer, 0.5-2.5 parts of pearling agent, 0.3-0.5 part of grinding agent, 0.9-1 part of adsorbent and 0.75 part of skin conditioner.
Further, the soap-based facial cleanser mainly comprises water and the following components in parts by weight: 29.5 parts of fatty acid, 5.5 parts of neutralizer, 32.5 parts of humectant, 1.8 parts of emulsifier, 4 parts of auxiliary surfactant, 2.7 parts of suspension stabilizer, 1.5 parts of pearling agent, 0.5 part of grinding agent, 1 part of adsorbent and 0.75 part of skin conditioner.
Further, the fatty acid is composed of 2-10% by weight of lauric acid, 44-60% by weight of myristic acid, 22-42% by weight of palmitic acid and 8-18% by weight of stearic acid.
Further, the neutralizing agent is potassium hydroxide.
Further, the humectant is glycerol and polyethylene glycol-32.
Further, the emulsifier is one or more of PEG-100 glyceryl stearate, glyceryl stearate and polyglycerol-10 myristate.
Further, the auxiliary surfactant is one or two of sodium cocoyl methyl taurate and cocamidopropyl betaine.
Further, the suspension stabilizer is an acrylic acid (ester) copolymer.
Further, the pearling agent is ethylene glycol distearate.
Further, the grinding agent and the adsorbent are walnut shell powder and silica respectively.
Further comprises a skin conditioner, wherein the skin conditioner comprises dipotassium glycyrrhizinate, lemon bahao leaf extract, salvia miltiorrhiza root extract, clove bud extract, scutellaria baicalensis root extract, angelica sinensis root extract, liquorice root extract and centella asiatica extract.
The preparation method of the soap base facial cleanser comprises the following steps:
s1 adding fatty acid, emulsifier, pearlescing agent and adsorbent into an oil phase pot, heating to 80-90 deg.C, stirring and dispersing until completely dissolved, adding into an emulsifying pot, starting vacuum, and stirring;
s2 adding water, neutralizer and humectant into water phase pot, heating to 70-90 deg.C, stirring, and dispersing until completely dissolved;
s3, keeping a proper vacuum, adding the dissolved water phase and the suspension stabilizer into an emulsifying pot, stirring and homogenizing until the materials are uniform;
s4 breaking vacuum, keeping the temperature at 80-90 deg.C, stirring, and saponifying for 20-40 min;
s5, adding the auxiliary surfactant into the emulsifying pot, opening a cooling system, and cooling to 50-62 ℃ while stirring;
s6 adding the grinding agent, skin conditioner, essence and antiseptic into emulsifying pot, stirring at 50-62 deg.C for 5-15 min;
s7, lowering the stirring speed, opening a cooling system, cooling to 42-50 ℃ while stirring, and then keeping the temperature and stirring for 15-35 min;
s8, opening a cooling system, cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
Further, the stirring speed in the steps S1, S2, S4, S5 and S6 is 30-50 r/min. The stirring speed in the steps S7 and S8 is 20-40 r/min. The step S3 is performed at a homogenization rate of 500-1500 r/min.
According to the soap-based cleansing milk provided by the invention, the fatty acid consists of lauric acid, myristic acid, palmitic acid and stearic acid, the four fatty acids are suitably matched as main cleansing components, and cocoamidopropyl betaine and cocoyl methyl sodium taurate are used as auxiliary cleansing components, so that rich and fine foam and good cleansing and decontamination capabilities are realized;
according to the soap base cleansing milk provided by the invention, the moisturizing agents are glycerin and polyethylene glycol-32, so that the moisturizing effect is good, the skin is kept moist, and the dry and unsmooth feeling brought by the soap base is relieved.
The soap-based facial cleanser provided by the invention comprehensively realizes mild and non-irritant washing, clean and thorough cleaning of facial dirt and redundant grease, and fresh and non-tight skin after washing.
According to the soap-based facial cleanser provided by the invention, the grinding agent is walnut shell powder and natural frosted particle walnut shell powder, so that old skin cutin is mildly removed, and the facial skin is tender and smooth.
According to the soap-based cleansing milk provided by the invention, the adsorbent is silica, so that sebum dirt on facial skin can be removed and accumulation of the sebum dirt can be reduced through effective adsorption.
The soap-based cleansing milk provided by the invention comprises dipotassium glycyrrhizinate, lemon bahao leaf extract, salvia miltiorrhiza root extract, clove bud extract, scutellaria baicalensis root extract, angelica sinensis root extract, liquorice root extract and centella asiatica extract. Dipotassium glycyrrhizinate can alleviate external irritation and prevent skin injury. The composite components of the lemon bahao leaf extract, the salvia miltiorrhiza root extract, the clove bud extract, the scutellaria root extract, the angelica root extract, the liquorice root extract and the centella extract can shrink pores, improve oil secretion and achieve a certain oil control effect.
The soap-based facial cleanser provided by the invention has the advantages that the suspension stabilizer is the acrylic acid (ester) copolymer, the addition amount is proper, the prepared facial cleanser is moderate in paste consistency, good in stability, easy to coat and use and good in foaming performance.
Compared with the prior art, the soap-based facial cleanser provided by the invention has the following beneficial effects:
(1) according to the soap-based facial cleanser provided by the invention, the stability of the formula is obviously improved by properly matching the four fatty acids of lauric acid, myristic acid, palmitic acid and stearic acid, and the problems that most of commercially available soap-based facial cleansers are obviously hardened and thickened when the temperature and the circulation conditions are recovered to the room temperature and are softened when the commercially available soap-based facial cleanser is placed at a low temperature are solved.
(2) The soap-based facial cleanser provided by the invention has the advantages that the acrylic acid (ester) copolymer is properly added, the formula stability is improved, and the problem of high-temperature layering is solved.
(3) According to the soap-based facial cleanser provided by the invention, through proper matching of four fatty acids of lauric acid, myristic acid, palmitic acid and stearic acid and the auxiliary addition of cocoamidopropyl betaine and sodium methyl cocoyl taurate, the irritation of the formula is reduced to the minimum, and mild and effective cleaning is realized. The proper addition of the glycerol and the polyethylene glycol-32 can comfortably infiltrate the skin and effectively relieve the dry and tight feeling after washing.
(4) According to the soap-based facial cleanser provided by the invention, the dipotassium glycyrrhizinate is added into the skin conditioner, so that external stimulation is relieved, and skin injury is prevented. The composite components of the lemon bahao leaf extract, the salvia miltiorrhiza root extract, the clove bud extract, the scutellaria root extract, the angelica root extract, the liquorice root extract and the centella extract are added to shrink pores, improve oil secretion and achieve the effect of controlling oil.
Drawings
FIG. 1 shows the results of the self-evaluation feedback of skin condition at 2h, 4h and 6h after the application of the samples.
Detailed Description
In order to make the present invention more comprehensible, the technical solutions of the present invention are further described below with reference to specific embodiments, but the present invention is not limited thereto.
The raw materials adopted in the invention are all commercially available cosmetic raw material products.
EXAMPLE 1 soap-based facial cleanser
The soap base facial cleanser mainly comprises water and the following components in parts by weight: 26 parts of fatty acid, 4 parts of neutralizer, 25 parts of humectant, 0.8 part of emulsifier, 2 parts of auxiliary surfactant, 1.8 parts of suspension stabilizer, 0.5 part of pearling agent, 0.3 part of grinding agent, 0.9 part of adsorbent and 0.75 part of skin conditioner.
The fatty acid consists of 5% by weight of lauric acid, 52% by weight of myristic acid, 32% by weight of palmitic acid and 11% by weight of stearic acid, the grinding agent is walnut shell powder, and the adsorbent is silica.
The preparation method of the soap base facial cleanser comprises the following steps:
s1 adding fatty acid, emulsifier, pearlescing agent and adsorbent into an oil phase pot, heating to 80-90 deg.C, stirring and dispersing until completely dissolved, adding into an emulsifying pot, starting vacuum, and stirring;
s2 adding water, neutralizer and humectant into water phase pot, heating to 70-90 deg.C, stirring, and dispersing until completely dissolved;
s3, keeping a proper vacuum, adding the dissolved water phase and the suspension stabilizer into an emulsifying pot, stirring and homogenizing until the materials are uniform;
s4 breaking vacuum, keeping the temperature at 80-90 deg.C, stirring, and saponifying for 20-40 min;
s5, adding the auxiliary surfactant into the emulsifying pot, opening a cooling system, and cooling to 50-62 ℃ while stirring;
s6 adding the grinding agent, skin conditioner, essence and antiseptic into emulsifying pot, stirring at 50-62 deg.C for 5-15 min;
s7, lowering the stirring speed, opening a cooling system, cooling to 42-50 ℃ while stirring, and then keeping the temperature and stirring for 15-35 min;
s8, opening a cooling system, cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
Further, the stirring rate in the steps S1, S2, S4, S5, S6 is 30 r/min. The stirring rate in steps S7 and S8 was 20 r/min. Step S3 homogenization rate is 1000 r/min.
Example 2 soap-based facial cleanser
The soap base facial cleanser mainly comprises water and the following components in parts by weight: 29.5 parts of fatty acid, 5.5 parts of neutralizer, 32.5 parts of humectant, 1.8 parts of emulsifier, 4 parts of auxiliary surfactant, 2.7 parts of suspension stabilizer, 1.5 parts of pearling agent, 0.5 part of grinding agent, 1 part of adsorbent and 0.75 part of skin conditioner.
The fatty acid consists of 5% by weight of lauric acid, 52% by weight of myristic acid, 32% by weight of palmitic acid and 11% by weight of stearic acid, the grinding agent is walnut shell powder, and the adsorbent is silica.
The preparation method of the soap base facial cleanser comprises the following steps:
s1 adding fatty acid, emulsifier, pearlescing agent and adsorbent into an oil phase pot, heating to 80-90 deg.C, stirring and dispersing until completely dissolved, adding into an emulsifying pot, starting vacuum, and stirring;
s2 adding water, neutralizer and humectant into water phase pot, heating to 70-90 deg.C, stirring, and dispersing until completely dissolved;
s3, keeping a proper vacuum, adding the dissolved water phase and the suspension stabilizer into an emulsifying pot, stirring and homogenizing until the materials are uniform;
s4 breaking vacuum, keeping the temperature at 80-90 deg.C, stirring, and saponifying for 20-40 min;
s5, adding the auxiliary surfactant into the emulsifying pot, opening a cooling system, and cooling to 50-62 ℃ while stirring;
s6 adding the grinding agent, skin conditioner, essence and antiseptic into emulsifying pot, stirring at 50-62 deg.C for 5-15 min;
s7, lowering the stirring speed, opening a cooling system, cooling to 42-50 ℃ while stirring, and then keeping the temperature and stirring for 15-35 min;
s8, opening a cooling system, cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
Further, the stirring rate in the steps S1, S2, S4, S5, S6 is 40 r/min. The stirring rate in steps S7 and S8 was 30 r/min. Step S3 homogenization rate is 1000 r/min.
EXAMPLE 3 soap-based facial cleanser
The soap base facial cleanser mainly comprises water and the following components in parts by weight: 33 parts of fatty acid, 7 parts of a neutralizer, 40 parts of a humectant, 2.8 parts of an emulsifier, 6 parts of an auxiliary surfactant, 3.6 parts of a suspension stabilizer, 2.5 parts of a pearling agent, 0.5 part of a grinding agent, 1 part of an adsorbent and 0.75 part of a skin conditioner.
The fatty acid consists of 5% by weight of lauric acid, 52% by weight of myristic acid, 32% by weight of palmitic acid and 11% by weight of stearic acid, the grinding agent is walnut shell powder, and the adsorbent is silica.
The preparation method of the soap base facial cleanser comprises the following steps:
s1 adding fatty acid, emulsifier, pearlescing agent and adsorbent into an oil phase pot, heating to 80-90 deg.C, stirring and dispersing until completely dissolved, adding into an emulsifying pot, starting vacuum, and stirring;
s2 adding water, neutralizer and humectant into water phase pot, heating to 70-90 deg.C, stirring, and dispersing until completely dissolved;
s3, keeping a proper vacuum, adding the dissolved water phase and the suspension stabilizer into an emulsifying pot, stirring and homogenizing until the materials are uniform;
s4 breaking vacuum, keeping the temperature at 80-90 deg.C, stirring, and saponifying for 20-40 min;
s5, adding the auxiliary surfactant into the emulsifying pot, opening a cooling system, and cooling to 50-62 ℃ while stirring;
s6 adding the grinding agent, skin conditioner, essence and antiseptic into emulsifying pot, stirring at 50-62 deg.C for 5-15 min;
s7, lowering the stirring speed, opening a cooling system, cooling to 42-50 ℃ while stirring, and then keeping the temperature and stirring for 15-35 min;
s8, opening a cooling system, cooling to 35-42 ℃ while stirring, and stopping cooling to form a smooth and uniform material body.
Further, the stirring rate in the steps S1, S2, S4, S5, S6 is 50 r/min. The stirring rate in steps S7 and S8 was 40 r/min. Step S3 the homogenization rate is 1500 r/min.
Comparative example 1
The difference from example 1 is that the grinding agent is changed from 0.5% to 0%.
Comparative example 2
The difference from example 1 is that the adsorbent was changed from 1% to 0%.
Comparative example 3
The difference from example 1 is that the adsorbent 1% becomes 0.5%.
Comparative example 4
The difference from example 2 is that the adsorbent 1% becomes 0.5%.
Comparative example 5
The difference from example 2 is that the suspension stabilizer is reduced from 2.7 parts to 1 part.
Comparative example 6
The difference from example 2 is that the suspension stabilizer is increased from 2.7 parts to 4.5 parts.
Test example I, stability test
The stability test method comprises the following steps: taking about 30g of the facial cleanser samples obtained in the examples 1-3 and the comparative examples 1-6 in a 50ml transparent inspection bottle, placing the bottle in an oven at 50 +/-1 ℃ and an oven at 45 +/-1 ℃ for 3 months, and observing the appearance of the samples after the samples are restored to room temperature so as to detect the heat resistance of the samples; placing in a high-low temperature alternating test chamber at (48 +/-1 ℃) to (-15 +/-1 ℃) for 1 month, and observing the appearance of the sample after the sample is restored to the room temperature so as to detect the cold-heat exchange resistance of the sample; placing in an oven at-10 +/-1 ℃ for 3 months, and observing the appearance of the sample after the temperature is restored to room temperature so as to detect the cold resistance of the sample.
And (3) test results: the results are shown in Table 1
Table 1 soap-based facial cleanser stability test results
As can be seen from the above table, examples 1-3 are all normal in heat resistance, cold and hot alternation, and cold resistance, and all have better stability. The problems of softening caused by cold resistance of comparative examples 1 and 2 and hardening caused by different degrees by heat resistance and cold and heat alternation investigation of comparative examples 3 and 4 show that the type and proportion collocation of fatty acid influence the stability of soap base facial cleanser, the formula stability is obviously improved by adding and adjusting the addition amount of grinding agent and adsorbent, and the problems of obvious hardening and thickening caused by the fact that most of commercially available soap base facial cleanser products are recovered to room temperature under high temperature and circulation conditions and are recovered to the room temperature after being placed at low temperature are avoided. Comparative example 5 shows the layering problem in cold and hot alternation, while comparative example 6 shows that the normal heat resistance, cold and hot alternation and cold resistance are examined, but the operation is difficult during saponification and paste forming stirring due to overlarge consistency, the obtained sample is difficult to coat and use, and the addition of the acrylic acid (ester) copolymer influences the stability of the soap-based facial cleanser, and the formula stability is improved on the premise of not influencing the use feeling by proper addition of the acrylic acid (ester) copolymer, so that the high-temperature layering problem is solved.
Test example two, safety test
The safety evaluation method comprises the following steps: multiple (acute) skin irritation tests.
And (3) test results: the results are shown in Table 2
TABLE 2 soap-based facial cleanser safety test results
As can be seen from the table above, the formula of the facial cleanser in the examples 1 to 3 is high in safety, and through proper matching of four fatty acids, namely lauric acid, myristic acid, palmitic acid and stearic acid and the addition of cocamidopropyl betaine and sodium methyl cocoyl taurate, the irritation of the formula is minimized, and mild and effective cleaning is realized.
Test example three, evaluation of efficacy
The efficacy evaluation method comprises the following steps: 31 Chinese healthy male subjects in the age range of 18-45 years were screened. The subjects were asked to investigate the feeling of use and the skin condition of the samples before using the sample of example 2, immediately after using the sample (immediately after using), 2h (2h) after using the sample, 4h (4h) after using the sample, and 6h (6h) after using the sample.
And (3) test results: the results are shown in Table 3 and FIG. 1
TABLE 3 immediate skin status feedback results after subjects use the samples
As can be seen from the above table, the subjects have high satisfaction degree on each index of the sample in the example 2, which shows that the sample in the example 2 has rich foam and can be well cleaned, and the skin can be well cleaned, the skin feel is fresh and clean without greasy, and the facial skin feels not dry and tight after the skin cleaning agent is used. As can be seen from the above figure, the subjects feel that the facial skin is not greasy after 2h, 4h and 6h of using the sample of example 2, which shows that the face-cleaning oil-controlling effect of example 2 is very good.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can make appropriate modifications or improvements within the technical scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (8)
1. A soap base facial cleanser is characterized in that: the paint comprises the following components in parts by weight: 26-33 parts of fatty acid, 4-7 parts of neutralizing agent, 25-40 parts of humectant, 0.8-2.8 parts of emulsifier, 2-6 parts of auxiliary surfactant, 1.8-3.6 parts of suspension stabilizer, 0.5-2.5 parts of pearling agent, 0.3-0.5 part of grinding agent, 0.9-1 part of adsorbent and 0.75 part of skin conditioner.
2. The soap-based facial cleanser of claim 1, wherein: the paint comprises the following components in parts by weight: 29.5 parts of fatty acid, 5.5 parts of neutralizer, 32.5 parts of humectant, 1.8 parts of emulsifier, 4 parts of auxiliary surfactant, 2.7 parts of suspension stabilizer, 1.5 parts of pearling agent, 0.5 part of grinding agent, 1 part of adsorbent and 0.75 part of skin conditioner.
3. The soap-based facial cleanser of claim 1 or 2, wherein: the fatty acid is lauric acid, myristic acid, palmitic acid and stearic acid, and is calculated according to the mass percentage: 2-10% of lauric acid, 44-60% of myristic acid, 22-42% of palmitic acid and 8-18% of stearic acid, wherein the sum of the four components is 100%.
4. The soap-based facial cleanser of claim 1 or 2, wherein: the neutralizer is potassium hydroxide; the humectant is glycerol and polyethylene glycol-32; the emulsifier is at least one of PEG-100 glyceryl stearate, glyceryl stearate and polyglycerol-10 myristate; the auxiliary surfactant is at least one of sodium cocoyl methyl taurate and cocamidopropyl betaine; the suspension stabilizer is acrylate copolymer; the pearling agent is ethylene glycol distearate.
5. The soap-based facial cleanser of claim 1 or 2, wherein: the grinding agent is walnut shell powder; the adsorbent is silica.
6. The soap-based facial cleanser of claim 1 or 2, wherein: the skin conditioner comprises dipotassium glycyrrhizinate, lemon bahao leaf extract, salvia miltiorrhiza root extract, clove bud extract, scutellaria baicalensis root extract, angelica root extract, liquorice root extract and centella asiatica extract.
7. A process for preparing the soap-based facial cleanser of any one of claims 1 to 6, wherein: the method comprises the following steps:
s1 adding fatty acid, emulsifier, pearlescing agent and adsorbent into an oil phase pot, heating to 80-90 deg.C, stirring, adding into an emulsifying pot, vacuumizing, and stirring;
s2 adding water, neutralizer and humectant into a water phase pot, heating to 70-90 deg.C, and stirring;
s3, maintaining proper vacuum, adding the S2 water-phase material and the suspension stabilizer into an emulsifying pot, and homogenizing;
s4 breaking vacuum, keeping the temperature at 80-90 deg.C, stirring, and saponifying for 20-40 min;
s5, adding the auxiliary surfactant into an emulsifying pot, and cooling to 50-62 ℃ while stirring;
s6 adding the grinding agent, skin conditioner, essence and antiseptic into the emulsifying pot, stirring at 50-62 deg.C for 5-15 min;
s7, cooling to 42-50 ℃ while stirring, preserving heat and stirring for 15-35 min;
s8, cooling to 35-42 ℃ while stirring to obtain the soap-based facial cleanser.
8. The method of claim 7, wherein: the stirring speed in the steps S1, S2, S4, S5 and S6 is 30-50 r/min; the stirring speed in the steps S7 and S8 is 20-40 r/min; the homogenization rate in step S3 is 500-1500 r/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115813788A (en) * | 2022-12-26 | 2023-03-21 | 福建片仔癀化妆品有限公司 | Mild self-corrosion-resistant and foam-dense cleansing bubble liquid and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107157799A (en) * | 2017-05-18 | 2017-09-15 | 上海伊匠生物科技有限公司 | A kind of soap base mildy wash |
| CN108836884A (en) * | 2018-09-26 | 2018-11-20 | 湖南御家化妆品制造有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN109628242A (en) * | 2018-12-26 | 2019-04-16 | 广州蜜妆生物科技有限公司 | A kind of mildly stable Soap-base facial cleanser and preparation method thereof |
| CN111840099A (en) * | 2020-07-28 | 2020-10-30 | 广州蜜妆生物科技有限公司 | Facial cleanser with soap base compounded with amino acid surfactant |
| KR20210032799A (en) * | 2019-09-17 | 2021-03-25 | (주)아모레퍼시픽 | Cosmetic composition and detergent using the same |
| CN112957302A (en) * | 2021-02-08 | 2021-06-15 | 福建片仔癀化妆品有限公司 | Amino acid facial cleanser and preparation method thereof |
-
2021
- 2021-11-22 CN CN202111385160.9A patent/CN114099382B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107157799A (en) * | 2017-05-18 | 2017-09-15 | 上海伊匠生物科技有限公司 | A kind of soap base mildy wash |
| CN108836884A (en) * | 2018-09-26 | 2018-11-20 | 湖南御家化妆品制造有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN109628242A (en) * | 2018-12-26 | 2019-04-16 | 广州蜜妆生物科技有限公司 | A kind of mildly stable Soap-base facial cleanser and preparation method thereof |
| KR20210032799A (en) * | 2019-09-17 | 2021-03-25 | (주)아모레퍼시픽 | Cosmetic composition and detergent using the same |
| CN111840099A (en) * | 2020-07-28 | 2020-10-30 | 广州蜜妆生物科技有限公司 | Facial cleanser with soap base compounded with amino acid surfactant |
| CN112957302A (en) * | 2021-02-08 | 2021-06-15 | 福建片仔癀化妆品有限公司 | Amino acid facial cleanser and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 福建片仔癀化妆品有限公司: "片仔癀牌男士净爽控油洗面奶", Retrieved from the Internet <URL:https://hzpba.nmpa.gov.cn/gccx/chakan.html?prodId=1052275016659369984&gb=G> * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115813788A (en) * | 2022-12-26 | 2023-03-21 | 福建片仔癀化妆品有限公司 | Mild self-corrosion-resistant and foam-dense cleansing bubble liquid and preparation method thereof |
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