CN113318011B

CN113318011B - Cleansing water and preparation method thereof

Info

Publication number: CN113318011B
Application number: CN202110810920.XA
Authority: CN
Inventors: 钟学鹏; 蓝林鹏
Original assignee: Shenzhen City Daimei Poetry Cosmetics Co ltd
Current assignee: Shenzhen City Daimei Poetry Cosmetics Co ltd
Priority date: 2021-07-19
Filing date: 2021-07-19
Publication date: 2022-09-06
Anticipated expiration: 2041-07-19
Also published as: CN113318011A

Abstract

The invention discloses a cleansing water and a preparation method thereof, namely an A phase, a B phase, a C phase, a D phase, an E phase and an F phase, and relates to the technical field of cleansing water. According to the makeup remover and the preparation method thereof, various oils and fats are dissolved by PEG-6 caprylic/capric glycerides, PEG-40 hydrogenated castor oil effectively enhances the high-temperature stability of the PEG-6 caprylic/capric glycerides in a formula, effectively prevents the PEG-6 caprylic/capric glycerides from being separated out, enables the product to be more easily cleaned after makeup removal on the face, and xylitol-based glucoside, dehydrated xylitol and xylitol are active ingredients of natural plant sources, can moisturize and reconstruct a skin structural system, promotes the increase of the content of GAGs (hyaluronic acid and chondroitin sulfate), improves the moisture content of epidermis and dermis, promotes the synthesis of ceramide, enhances the barrier action of the skin, improves the skin structure, reduces the moisture loss, and particularly can reduce and reduce the irritation of a surface active agent to the skin.

Description

Cleansing water and preparation method thereof

Technical Field

The invention relates to the technical field of makeup remover, in particular to makeup remover and a preparation method thereof.

Background

Makeup removal is the basis of skin care, and residual makeup is oily dirt which can block pores, prevent cells from breathing smoothly and obstruct normal metabolism of the skin, so that the skin gradually becomes rough, the pores are large, the skin color is yellow, and dark grains and acnes are also bred. The makeup remover on the current market comprises: the makeup remover comprises makeup removing water, makeup removing cream, makeup removing oil and makeup removing cream, wherein the used components of the makeup removing oil and the makeup removing cream are emulsifier and grease which can be fused with makeup removing oil stains on the face, and then the makeup remover can thoroughly dissolve the makeup in a water emulsification mode. The water content of the makeup removing emulsion is more than that of makeup removing oil and makeup removing cream, and the makeup removing emulsion is prepared by dissolving makeup pigments which are difficult to remove by water by adopting grease and then removing the grease by using a washing product. However, makeup remover cream, makeup remover oil or makeup remover cream cannot be used for removing waterproof mascara, and if the makeup remover cream is carelessly put into eyes, the damage to the eyes is great. Moreover, when makeup removing cream, makeup removing oil or makeup removing cream are used too much, skin aging can occur, and in recent years, the makeup removing water is popular among consumers due to the mildness, convenience in use and low price. However, the makeup remover in the prior art cannot solve the problems that wrinkles are easy to appear on eye skin and lip lines of lips are easy to appear on the eye skin. Patent application document CN104288027A provides a cosmetic-cleansing liquid for the lips and a preparation method thereof, which uses plant extract, oil and inorganic salt as main ingredients.

The mild and effective makeup removing micelle water disclosed by the invention with the patent number of CN104000766B only has the makeup removing effect when in use, cannot play a role in maintaining the skin, and cannot play a role in preventing the water loss of the skin when in use.

Disclosure of Invention

Aiming at the defects of the prior art, the invention provides makeup remover and a preparation method thereof, and solves the problems that only the makeup remover can remove makeup when in use, the skin can not be maintained, and the skin can not be prevented from water loss when in use.

In order to achieve the purpose, the invention is realized by the following technical scheme: a cleansing water comprises a phase A, a phase B, a phase C, a phase D, a phase E and a phase F;

the phase A comprises the following components: 4-5% of first nonionic surfactant, 1-2% of second nonionic surfactant, 0.5-1.5% of third nonionic surfactant, 0.1-0.3% of cationic surfactant and the balance of solvent;

the phase B comprises the following components: 6-8% of first humectant and 0.1-0.3% of second humectant;

the phase C comprises the following components: 0.425-0.625% of first skin conditioner, 0.29-0.59% of second skin conditioner and 0.1-0.3% of third skin conditioner;

phase D comprises the following components: 1-3% of an anti-allergic agent, 1-3% of an anti-inflammatory agent and 1-3% of a sedative;

phase E comprises 8-12% fragrance;

the phase F comprises 0.05-0.15% of chelating agent;

the production method of the cleansing water comprises the following steps:

firstly, cleaning relevant tools of a manufacturing kettle, a container and a valve with sterilizing water of more than 80 ℃, then washing with 75% of sterilizing alcohol, and waiting for the alcohol to volatilize after the washing is clean;

step two, in the main kettle, after determining the mass fraction, weighing the phase A component according to the mass percentage: 4-5% of a solvent, 1-2% of a first nonionic surfactant, 0.5-1.5% of a third nonionic surfactant and 0.1-0.3% of a cationic surfactant, and uniformly stirring and mixing;

step three, heating the phase A in the step two to 80-85 ℃, preserving heat, stirring for 30 minutes, and then cooling;

step four, cooling the temperature to 45 ℃, and sequentially adding B, C, D phase components: 6-8% of first humectant, 0.1-0.3% of second humectant, 0.425-0.625% of first skin conditioner, 0.29-0.59% of second skin conditioner, 0.1-0.3% of third skin conditioner, 1-3% of anti-allergy agent, 1-3% of anti-inflammatory agent and 1-3% of sedative, and stirring until the components are completely and uniformly dissolved;

step five, cooling the temperature to 36 ℃, and sequentially adding E, F and phase components; 8 to 12 percent of aromatic and 0.05 to 0.15 percent of chelating agent, stirring for 30 minutes until the mixture is uniform and transparent;

and step six, after testing the pH value, sequentially testing the heat resistance stability and the cold resistance stability, and bottling and packaging after the test is finished.

As a further scheme of the invention: the solvent in the phase A is deionized water, the first nonionic surfactant is PEG-6 caprylic/capric glycerides and water-soluble liquid with surface activity, the surfactant is used as a fat-endowing agent and a solubilizer in a cosmetic and medical formula, the HLB value of the surfactant is 19, the surfactant is used in makeup removing water and can dissolve various oils and fat to enable makeup to fall off easily, the second nonionic surfactant is PEG-40 hydrogenated castor oil and has good solubilization performance, the surfactant is suitable to be used as a solubilizer for essential oil and essence to effectively enhance the makeup removing capability of the formula, the high-temperature stability of the PEG-6 caprylic/capric glycerides in the formula can be effectively enhanced, the precipitation of the PEG-6 caprylic/capric glycerides can be effectively prevented, and the third ionic surfactant is PPG-26-butanol polyether-26, the cationic surfactant is cetrimide, is a very mild surfactant, is a good skin conditioner due to the cationic property, can effectively reduce the irritation of other surfactants, can obviously improve the washing effect of the formula after washing, and enables the product to be more easily washed after makeup removal on the face.

As a further scheme of the invention: the first humectant in phase B is glycerin and the second humectant is ethylhexylglycerin.

As a further scheme of the invention: the first skin conditioning agent in the phase C is xylitol-based glucoside, the second skin conditioning agent is dehydrated xylitol, the third skin conditioning agent is xylitol, the xylitol-based glucoside, the dehydrated xylitol and the xylitol are active ingredients of natural plant sources, and the skin conditioning agent can preserve moisture and rebuild a skin structural system, promote the content increase of GAGs (hyaluronic acid and chondroitin sulfate), improve the moisture content of epidermis and dermis, promote the synthesis of ceramide, strengthen the barrier effect of skin, improve the structure of skin, reduce the moisture loss, and particularly reduce and reduce the irritation of the surface active agent to the skin.

As a further scheme of the invention: the anti-allergy agent in the phase D is mushroom glucan which can obtain remarkable effects of healing wounds, enhancing immunity, proliferating cells and synthesizing collagen protein under the condition that the addition amount of the mushroom glucan is 0.1-10%, and has the effects of resisting aging, preserving moisture, resisting allergy and relieving, the anti-inflammation agent is a purslane extract, the purslane extract can obtain remarkable anti-inflammation, anti-irritation and anti-allergy effects under the condition that the addition amount of the purslane extract is 0.5-5%, the sedative is a cucumber fruit extract, and the cucumber fruit extract can play the effects of diminishing inflammation, calming, soothing and relieving and can relieve irritated skin; can well increase the water content of stratum corneum, has moisture keeping effect, and can be used for preventing and treating dry skin. The cucumber contains rich vitamin E and has the function of resisting aging; the cucumber enzyme has strong biological activity, can effectively promote the metabolism of the organism, and has the effects of moistening the skin and stretching wrinkles.

As a further scheme of the invention: the aromatic in the E phase is essence.

As a further scheme of the invention: the chelating agent in the F phase is disodium EDTA.

As a further scheme of the invention: and the heat resistance stability condition in the sixth step is to keep the temperature at 45 ℃ for 24 hours, and the cold resistance stability condition is to keep the temperature at-10 ℃ for 24 hours.

The invention also discloses a preparation method of the cleansing water, which comprises the following steps:

firstly, cleaning relevant tools such as manufacturing kettles, containers, valves and the like by using sterilized water with the temperature of more than 80 ℃, and then washing by using 75% sterilized alcohol;

step two, in the main kettle, weighing phase A components according to mass percentage: deionized water, a nonionic surfactant and a cationic surfactant are stirred and mixed uniformly;

step three, heating to 80-85 ℃, keeping the temperature and stirring for 30 minutes, and then cooling;

step four, cooling the temperature to 45 ℃, sequentially adding B, C, D phase components, and stirring until the components are completely and uniformly dissolved;

step five, cooling the temperature to 36 ℃, sequentially adding E, F and the phase component, stirring for 30 minutes, and stirring until the mixture is uniform and transparent;

and step six, bottling and packaging after testing.

Compared with the prior art, the invention has the following beneficial effects: the PEG-40 hydrogenated castor oil has good solubilization performance, is suitable to be used as a solubilizer for essential oil and essence, effectively enhances the makeup removing capability of a formula, can effectively enhance the high-temperature stability of the PEG-6 caprylic/capric glyceride in the formula, effectively prevents the precipitation of the PEG-6 caprylic/capric glyceride, cetrimonium bromide and a very mild surfactant, can effectively reduce the irritation of other surfactants due to the cationic property of the surfactant, can obviously improve the flushing and cleaning effects of the formula after washing, enables the product to be more easily cleaned after facial makeup removal, and can be used as active ingredients of natural plant sources such as xylitol-based glucoside, dehydrated xylitol and xylitol, promoting the increase of GAGs (hyaluronic acid and chondroitin sulfate) content, increasing the moisture content of epidermis and dermis, promoting ceramide synthesis, enhancing skin barrier effect, improving skin structure, reducing water loss, and especially reducing and decreasing the irritation of surface active agent to skin.

Detailed Description

To further illustrate the technical means and effects of the present invention adopted to achieve the predetermined objects, the following detailed description of the embodiments, structures, characteristics and effects according to the present invention will be given with reference to the preferred embodiments.

Example one

The cleansing water is prepared by the following method:

firstly, cleaning relevant tools of a manufacturing kettle, a container and a valve by using sterilized water with the temperature of more than 80 ℃, then washing by using 75% sterilized alcohol, and waiting for the alcohol to volatilize after the washing is clean;

step two, in the main kettle, after determining the mass fraction, weighing the phase A component according to the mass percentage: the detergent comprises a solvent, 4% of a first nonionic surfactant, 1% of a second nonionic surfactant, 0.5% of a third nonionic surfactant and 0.1% of a cationic surfactant, wherein the first nonionic surfactant is PEG-6 caprylic/capric glycerides, the second nonionic surfactant is PEG-40 hydrogenated castor oil, the third ionic surfactant is PPG-26-butanol polyether-26, and the cationic surfactant is cetrimide;

step four, cooling the temperature to 45 ℃, and sequentially adding B, C, D phase components: 6 percent of first humectant, 0.1 percent of second humectant, 0.425 percent of first skin conditioner, 0.29 percent of second skin conditioner, 0.1 percent of third skin conditioner, 1 percent of anti-allergy agent, 1 percent of anti-inflammatory agent and 1 percent of sedative, which are stirred to be completely and uniformly dissolved, wherein the first humectant in phase B is glycerol, the second humectant is ethylhexylglycerol, the first skin conditioner in phase C is xylitol-based glucoside, the second skin conditioner is dehydrated xylitol, the third skin conditioner is xylitol, the xylitol-based glucoside, the dehydrated xylitol and the xylitol are active ingredients of natural plant sources, can moisturize and rebuild a skin structure system, promote the increase of the content of GAGs (hyaluronic acid and chondroitin sulfate), improve the moisture content of epidermis and dermis, promote the synthesis of ceramide, strengthen the barrier action of skin, improve the skin structure, reduce the moisture loss, particularly reduce and reduce the irritation of the skin indicating active agents, the anti-allergy agent in the phase D is mushroom glucan which can obtain remarkable effects of healing wounds, enhancing immunity, cell proliferation and synthesizing collagen under the condition that the addition amount of the mushroom glucan is 0.1-10%, and has the effects of resisting aging, preserving moisture, resisting allergy and relieving, the anti-inflammatory agent is a purslane extract, the purslane extract can obtain remarkable anti-inflammatory, anti-irritation and anti-allergy effects under the condition that the addition amount of the purslane extract is 0.5-5%, the sedative is a cucumber fruit extract, and the cucumber fruit extract can play the effects of diminishing inflammation, calming, soothing and relieving, and can relieve irritated skin; can well increase the water content of stratum corneum, has moisture keeping effect, and can be used for preventing and treating dry skin. The cucumber contains rich vitamin E and has the function of resisting aging; the cucumber enzyme has strong biological activity, can effectively promote the metabolism of organisms, and has the effects of moistening skin and stretching wrinkles;

step five, cooling the temperature to 36 ℃, and sequentially adding E, F and phase components; stirring 8 of an aromatic and 0.05% of a chelating agent for 30 minutes until the mixture is uniform and transparent, wherein the aromatic is essence, and the chelating agent is EDTA disodium;

Example two

The cleansing water is prepared by the following method:

step two, in the main kettle, after determining the mass fraction, weighing the phase A component according to the mass percentage: the detergent comprises a solvent, 4.5% of a first nonionic surfactant, 1.5% of a second nonionic surfactant, 1% of a third nonionic surfactant and 0.2% of a cationic surfactant, and is uniformly stirred and mixed, wherein the first nonionic surfactant is PEG-6 caprylic/capric glycerides, the second nonionic surfactant is PEG-40 hydrogenated castor oil, the third ionic surfactant is PPG-26-butanol polyether-26, and the cationic surfactant is cetrimide;

step four, cooling the temperature to 45 ℃, and sequentially adding B, C, D phase components: 7% of a first moisturizing agent, 0.2% of a second moisturizing agent, 0525% of a first skin conditioning agent, 0.39% of a second skin conditioning agent, 0.2% of a third skin conditioning agent, 2% of an anti-allergy agent, 2% of an anti-inflammatory agent and 2% of a sedative agent, wherein the first moisturizing agent in phase B is glycerin, the second moisturizing agent is ethylhexyl glycerin, the first skin conditioning agent in phase C is xylitol-based glucoside, the second skin conditioning agent is dehydrated xylitol, the third skin conditioning agent is xylitol, the xylitol-based glucoside, dehydrated xylitol and xylitol are active ingredients of natural plant sources, can moisturize and rebuild a skin structural system, promote the increase of the content of GAGs (hyaluronic acid and chondroitin sulfate), improve the moisture content of epidermis and dermis, promote the synthesis of ceramide, strengthen the barrier effect of the skin, improve the skin structure, reduce the moisture loss, and particularly reduce and reduce the irritation of the skin indicating active agents, the anti-allergy agent in the phase D is mushroom glucan which can obtain remarkable effects of healing wounds, enhancing immunity, proliferating cells and synthesizing collagen under the condition that the addition amount of the mushroom glucan is 0.1-10%, and the anti-allergy agent has the effects of resisting aging, preserving moisture, resisting allergy and relieving stress, the anti-inflammatory agent is a purslane extract, the purslane extract can obtain remarkable anti-inflammatory, anti-irritation and anti-allergy effects under the condition that the addition amount of the purslane extract is 0.5-5%, the sedative is a cucumber fruit extract, and the cucumber fruit extract can play the effects of diminishing inflammation, calming, soothing and relieving stress and can relieve irritated skins; can well increase the water content of stratum corneum, has moisture keeping effect, and can be used for preventing and treating dry skin. Cucumber contains abundant vitamin E, and has antiaging effect; the cucumber enzyme has strong biological activity, can effectively promote the metabolism of organisms, and has the effects of moistening skin and stretching wrinkles;

step five, cooling the temperature to 36 ℃, and sequentially adding E, F and phase components; stirring 10% of an aromatic and 0.1% of a chelating agent for 30 minutes until the mixture is uniform and transparent, wherein the aromatic is essence, and the chelating agent is EDTA disodium;

EXAMPLE III

The cleansing water is prepared by the following method:

step two, after determining the mass fraction in the main kettle, weighing phase A components according to mass percentage: the detergent comprises a solvent, 5% of a first nonionic surfactant, 2% of a second nonionic surfactant, 1.5% of a third nonionic surfactant and 0.3% of a cationic surfactant, wherein the first nonionic surfactant is PEG-6 caprylic/capric glycerides, the second nonionic surfactant is PEG-40 hydrogenated castor oil, the third ionic surfactant is PPG-26-butanol polyether-26, and the cationic surfactant is cetrimide;

step four, cooling the temperature to 45 ℃, and sequentially adding B, C, D phase components: 8% of a first moisturizing agent, 0.3% of a second moisturizing agent, 0.625% of a first skin conditioning agent, 0.59% of a second skin conditioning agent, 0.3% of a third skin conditioning agent, 3% of an anti-allergic agent, 3% of an anti-inflammatory agent and 3% of a sedative agent, wherein the first moisturizing agent in phase B is glycerol, the second moisturizing agent is ethylhexyl glycerol, the first skin conditioning agent in phase C is xylitol-based glucoside, the second skin conditioning agent is dehydrated xylitol, the third skin conditioning agent is xylitol, the xylitol-based glucoside, dehydrated xylitol and xylitol are active ingredients of natural plant origin, and can moisturize and rebuild a skin structural system, promote the increase of the content of GAGs (hyaluronic acid and chondroitin sulfate), improve the moisture content of epidermis and dermis, promote the synthesis of ceramides, strengthen the skin barrier function, improve the skin structure, reduce the moisture loss, and particularly reduce and reduce the irritation of the skin indicating active agents, the anti-allergy agent in the phase D is mushroom glucan which can obtain remarkable effects of healing wounds, enhancing immunity, cell proliferation and synthesizing collagen under the condition that the addition amount of the mushroom glucan is 0.1-10%, and has the effects of resisting aging, preserving moisture, resisting allergy and relieving, the anti-inflammatory agent is a purslane extract, the purslane extract can obtain remarkable anti-inflammatory, anti-irritation and anti-allergy effects under the condition that the addition amount of the purslane extract is 0.5-5%, the sedative is a cucumber fruit extract, and the cucumber fruit extract can play the effects of diminishing inflammation, calming, soothing and relieving, and can relieve irritated skin; can well increase the water content of stratum corneum, has moisture keeping effect, and can be used for preventing and treating dry skin. Cucumber contains abundant vitamin E, and has antiaging effect; the cucumber enzyme has strong biological activity, can effectively promote the metabolism of organisms, and has the effects of moistening skin and stretching wrinkles;

step five, cooling the temperature to 36 ℃, and sequentially adding E, F and phase components; stirring 12% of an aromatic and 0.15% of a chelating agent for 30 minutes until the mixture is uniform and transparent, wherein the aromatic is essence and the chelating agent is EDTA disodium;

The cleansing water prepared in examples 1 to 3 was used to evaluate 10 female testers who were healthy, and the cleansing effect, the cleansing time, and the comfort after use were evaluated in 10 minutes, and the average was calculated by removing the highest and lowest values, with 10 being the best, 9 being the lowest, and 1 being the worst, and the results shown in the following table:

test meter

	Example 1	Example 2	Example 3
				Makeup removal effect	9.125	9.875	9.25
Time of makeup removal	8.875	9.25	9.375
				Comfort of the wearer	9.125	9.75	8.75

From the test results, the cleansing water prepared in example 2 of the invention has stronger cleansing ability than those prepared in examples 1 and 3, and is more comfortable to use and better in effect.

Although the present invention has been described with reference to the preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the present invention.

Claims

1. The makeup remover is characterized in that: comprises a phase A, a phase B, a phase C, a phase D, a phase E and a phase F;

the phase A comprises the following components: 4-5% of first nonionic surfactant, 1-2% of second nonionic surfactant, 0.5-1.5% of third nonionic surfactant, 0.1-0.3% of cationic surfactant and the balance of solvent; the first nonionic surfactant is PEG-6 caprylic/capric glycerides, the second nonionic surfactant is PEG-40 hydrogenated castor oil, and the third ionic surfactant is PPG-26-butanol polyether-26;

the phase B comprises the following components: the first humectant is 6-8% of glycerol, and the second humectant is 0.1-0.3% of ethylhexyl glycerol;

the phase C comprises the following components: the first skin conditioning agent is xylitol-based glucoside 0.425-0.625%, the second skin conditioning agent is dehydrated xylitol 0.29-0.59%, and the third skin conditioning agent is xylitol 0.1-0.3%;

the phase D comprises the following components: 1-3% of an anti-allergy agent, 1-3% of an anti-inflammation agent, 1-3% of a purslane extract, 1-3% of a sedative agent and 1-3% of a sedative agent, wherein the antiallergic agent is a cucumber fruit extract;

phase E comprises 8-12% fragrance;

the phase F comprises 0.05-0.15% of chelating agent;

the production method of the cleansing water comprises the following steps:

step five, cooling the temperature to 36 ℃, and sequentially adding E, F phase components; 8 to 12 percent of aromatic and 0.05 to 0.15 percent of chelating agent, stirring for 30 minutes until the mixture is uniform and transparent;

2. The cleansing water according to claim 1, wherein: the aromatic in the E phase is essence.

3. The makeup remover according to claim 1, wherein: the chelating agent in the F phase is disodium EDTA.

4. The cleansing water according to claim 1, wherein: and in the sixth step, the heat-resistant stability condition is kept for 24 hours at 45 ℃, and the cold-resistant stability condition is kept for 24 hours at-10 ℃.