CN108836884A - A kind of Soap-base facial cleanser and preparation method thereof - Google Patents
A kind of Soap-base facial cleanser and preparation method thereof Download PDFInfo
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Abstract
The present invention relates to cleaning class cosmetic technical field, in particular to a kind of Soap-base facial cleansers and preparation method thereof.The raw material of the Soap-base facial cleanser includes:Glycerol, arginine glycerol, 1,3 butylene glycol, EDETATE SODIUM, potassium hydroxide, myristic acid, stearic acid, lauric acid, stearine, emulsifier, alkyl glycosides, sodium methyl cocoyl taurate, hydrolecithin, ceramide, dipotassium glycyrrhizinate, opopanax alcohol and water.Product of the present invention passes through the high pH for reducing Soap-base facial cleanser, to lower the tight, dry of sample, irritation.The process for producing and filling process for improving soap base mildy wash simultaneously make the more environmentally friendly energy conservation of its process, and it is easier to be easy to operate, and product lotion uniformity, performance is stablized, to reduce consumer's complaint.
Description
Technical field
The present invention relates to cleaning class cosmetic technical field, in particular to a kind of Soap-base facial cleansers and preparation method thereof.
Background technique
Face cleaning class product belong to cleaning class cosmetics, for cleaning, nutrition, protect human body skin of face.In cleaning class
In the product of cosmetics, it is exactly face cleaning product that sales volume is maximum at present.Since face cleaning class product washes one's face makeup removing with fabulous
Clean skin health-care efficacy has the advantages that use perfumed soap clean skin incomparable, therefore likes the favor of consumer deeply and like.Soap base face cleaning
Cream is a big branch in face cleaning product.
In general, face cleaning class product is by oil phase thing, aqueous-phase material, surfactant, the nutritional agents of part free state etc.
The lotion or creamy product that ingredient is constituted.The main component of face cleaning class product is oily phase raw material, emulsifier, surfactant, guarantor
Humectant, nutritional agents, Purified Water and essence etc..It is molten by the oil on oil phase thing dissolution face when washing one's face according to the similar principle that mixes
Property rouge dirt;By water-soluble sweat stain dirt on its aqueous-phase material dissolution face.In addition, part free state surface in face cleaning class product
Activating agent has the five big effects such as wetting, dispersion, foaming, decontamination, emulsification, is the chief active object of face cleaning.During washing one's face,
Collaboration oil phase thing and aqueous-phase material remove dirt, greasepaint, cosmetics, cosmetics vestiges etc. jointly.If being aided with during washing one's face
Soft massage, enables percutaneous absorption nutrition and curative effect ingredient, the effect of clean skin nutrition and health care is with regard to more preferable.
The production method of muciform facial cleanser is identical as sweet class cosmetics or milk, relatively simple.Amino acid paste
The production preparation of mildy wash and soap base mildy wash and filling process are complex.Paste face cleaning product in the market presses formula composition
Two major classes can be divided by dividing, and one kind is amino acid surfactant mildy wash, and primary surfactant used in this kind of product is amino
Acids surfactant, such as cocounut oil acyl glycine potassium, sodium lauroyl sarcosine, sodium cocoyl glycinate, lauroyl aspartic acid
Sodium etc..The product lotion of this kind of formula is soft, is easy to be rubbed open and rinse, irritation is small.But in production preparation and pouring process
The middle disposable knot cream molding of needs, if making cream using homogeneous after stirring again due to filling difficult or other reasons after knot cream discharging
Body structure is destroyed, then finally obtained product lotion can viscosity is relatively low, appearance it is coarse it is uneven, there are particles when using
Sense.
Another kind of is soap base mildy wash, and this kind of product is that formula system is distinguished from structure, should include following five part:Fat
Acid+alkali, polyalcohol, emulsifier, surfactant, emollient and other additives.Wherein fatty acid+alkali is to constitute face cleaning lotion
The skeleton of system, the stability and cleaning capacity of product, foam effect, pearlescent appearance, irritation etc. both depend on fatty acid
Selection and proportion.The product lotion of this kind of formula is more sticky, and cleaning force is stronger, easily rinses, and it is salubrious to wash rear dermal sensation, is disappeared very much
The welcome of the person of expense.
Its soap base mildy wash there are the problem of have degreasing and higher pH value, in drying, the lower day gas bar of temperature
It is dry, tight to will lead to face skin under part after use, or even keeps skin impaired, and the high-temperature stability of Soap-base facial cleanser compared with
Difference, production preparation and filling control are more difficult, and often will cause Soap-base facial cleanser at 40~45 DEG C will become very dilute, transparent, put
2~3 days even severe delaminations are set, therefore launch the sample into market, are easy to appear the Material of opening part in hose packing,
Thinning, water outlet, and the thicker phenomenon of Material in managing, cause huge loss to most of manufacturing enterprises.
In the consumer of face cleaning class product complains, it is uneven that the overwhelming majority concentrates on lotion, using having granular sensation, lotion
It is not easy very much to be rubbed open firmly, the sensory aspects such as use feeling difference.Therefore it prepared by the production of face cleaning product especially face cleaning cream and filling
Technique improves, and promotes the apparent condition of product and use feeling significantly, so that reducing the complaint of consumer has weight
Want meaning.Soap-base facial cleanser not only washes away extra grease and dirt, is also removed to physiology grease, causes skin dry
It is dry tight, or even stimulation.Soap base type cosmetics are when actual production, it will generate certain bubble, Producing reason master
It is divided into the following aspects:
First, it is more to generate bubble situation in Soap-base facial cleanser saponification process, among these mixing speed and homogeneous speed sheet
The bad control of body, at this time generates that bubble process is more obvious, while these bubbles are not easy to be eliminated, influence finally at
Product reduce production efficiency.
Second, it is easy to produce a large amount of bubbles in the saponification process of constant temperature, in the constant temperature saponification course of work, needs to keep
The stirring of low speed as far as possible, while also needing for saponification temperature to control effectively.When process heating, it is especially desirable to infuse
Meaning can not be easy to produce so more bubbles by the way of vacuumizing, and influence subsequent operation.
The problem of third, surfactant, will also will lead to if time and mode that surfactant is added are inappropriate
More bubbles generate, it is difficult to eliminate.
In modern society, with the promotion of living standard, consumer also gradually promotes the concern of face cleaning product.Have
High-efficiency cleaning and the stable face cleaning product of performance will similarly obtain the receiving and affirmative in market.Therefore, in following face cleaning
On Cosmetic Market, under the premise of guaranteeing product safety, high-efficiency cleaning is pursued, performance stabilization is still face cleaning cosmetic art
Where the theme and focus of pursuit.Therefore face cleaning cream production preparation and filling process are improved, its more environmentally friendly energy conservation is made, it is simple to grasp
Make, performance stabilization will become the development trend in face cleaning industry future.
Summary of the invention
In view of this, the present invention provides a kind of Soap-base facial cleansers and preparation method thereof.Product of the present invention is by reducing soap
The high pH of base face cleaning cream, to lower the tight, dry of sample, irritation.The production preparation work of soap base mildy wash is improved simultaneously
Skill and filling process make the more environmentally friendly energy conservation of its process, and it is easier to be easy to operate, and product lotion uniformity, performance is stablized, to subtract
Few consumer complains.
In order to achieve the above-mentioned object of the invention, the present invention provides following technical scheme:
The present invention provides a kind of Soap-base facial cleanser, raw material includes:
Glycerol, arginine glycerol, 1,3 butylene glycol, EDETATE SODIUM, potassium hydroxide, myristic acid, stearic acid, lauric acid,
Stearine, emulsifier, alkyl glycosides, sodium methyl cocoyl taurate, hydrolecithin, ceramide, glycyrrhizic acid
Dipotassium, opopanax alcohol and water.
The present invention carries out optimised process with emulsifying soap base face cleaning formula and parameter determines.The decontamination of common soap base mildy wash
Power is strong, and alkalinity is higher, determines its stronger degreasing power.The microcosmos alkali content remained in soap base facial cleanser can make to disappear
Facial skin is dry after Fei Zheyong, tight, especially be air-dried temperature it is low in the case where it is especially significant.Therefore, alkali is reduced
Property, and then tight, dry sensation and the irritation for mitigating its skin for using skin are reduced, become common soap base facial cleanser needs
It solves the problems, such as.
The present invention uses emulsifying soap base face cleaning technology, reduces the irritation of soap base, promotion mildly washes shield performance, by adding
Add arginine glycerol and ceramide, hydrolecithin, promote the performance of keeping humidity of washing-off type face cleaning product, repairs skin barrier.
The present invention uses emulsifying soap base mildy wash, and the emulsifier contained has unique chemical structure, in soap base and height
, can be acid emulsifier by remaining mixing-in fat under conditions of pH value, the pH value of product is reduced, stable soap base is played and reduces skin
Irritating effect.Soap base mildy wash prepared by the present invention remains low, low irritant with its foaming abundancy, strong cleaning force after,
Simple production process, it is easy to use.
1) fatty acid mixed
Fatty acid mixed is the framework ingredient for constituting Soap-base facial cleanser system.The stability of such personal cleansing product and
Cleaning capacity, foam effect, pearlescent appearance, irritation etc. both depend on the selection and proportion of fatty acid.Usually with lauric acid/dodecanoic acid, ten
Tetracid, hexadecylic acid, stearic acid mix and match use.The blend proportion of these types of acid should be in addition several to be based on one kind
Auxiliary element uses on a small quantity.
The property of fatty acid itself has certain difference, is mainly reflected in:
(1) foam gradually becomes tiny with the increase of molecular weight, and stability is stronger, but the difficulty that foam generates
Degree is gradually increased, especially lauric acid/dodecanoic acid, generates foam maximum, and be easiest to disappearance, the foam that corresponding stearic acid generates
Though it is small, more persistently;
(2) in terms of pearl effect, in 4 kinds of fatty acid, pearl effect most notably stearic acid and tetradecylic acid are influenced, it is preceding
The pearly-lustre that person generates is mainly strong white flash shape pearly-lustre, and the latter has primarily formed the similar ceramic surface of sub-translucent type
Milky pearly-lustre.
The performance of fatty acid soaps is as follows:
The performance and cost factor of comprehensive assessment fatty acid of the present invention, use based on tetradecylic acid, lauric acid/dodecanoic acid and 18
Acid is used as auxiliary acid.Saponification is generally divided into the progress of three stages:The solubility of long-chain carbon chain fatty acid in water is low, therefore anti-
Answer the initial stage for the emulsification saponification stage, fatty acid and lye are reacted under milkiness state, are reacted and are slowly carried out, with soap
Generation, the soap of generation plays Action of Surfactant, and micellar catalysis is presented in reaction, and reaction is gradually accelerated, therefore saponification
It is a self-catalyzed reaction, this stage, which is known as being saponified, to be started;Due to autocatalysis, within the second stage short time, soap
Change reaction and understand fierceness, until fatty acid part becomes soap;Phase III is the final saponification stage, since fatty acid amount subtracts
Few, this elementary reaction is mild and gradually slack-off, finally reaches saponification and completes.
Generally between 28%-35%, sour total amount directly affects dosage fatty acid in Soap-base facial cleanser formula system
The knot cream temperature and hardness of final products, the content of soap is bigger, and knot cream temperature is higher, and lotion is harder.Vice versa.
2) alkali
Alkali for carrying out neutralizing saponification with fatty acid has potassium hydroxide, sodium hydroxide, triethanolamine etc..Wherein, hydrogen-oxygen
Change the soap that the soap that sodium generates is partially hard, and triethanolamine generates, performance is milder, but detergency is lower, and is easy discoloration.
The dosage of potassium hydroxide depends on the requirement of the degree of neutralization of fatty acid and potassium hydroxide in formula system.Fatty acid acid
Dosage it is high, high to the degree of neutralization of fatty acid, the dosage of potassium hydroxide will also improve.
According to saponification, all saponification must use excessive alkali to fatty acid, and excess base facilitates fully reacting.But
Excessively increase the amount of potassium hydroxide, it is unpractical in actual production, and also the presence of excess base causes system pH value excessively high, from
And having very big stimulation to skin, the degree of neutralization general control of fatty acid and potassium hydroxide is in 75%-90%, this hair in face cleaning cream
It is bright using potassium hydroxide as the alkali in face cleaning cream, control degree of neutralization is 78%-85%, and formula is made to have mildness.Degree of neutralization
It can be calculated by the dosage of potassium hydroxide and the acid value of various acid.Degree of neutralization calculation method:
Degree of neutralization=(the dosage * potassium hydroxide purity of potassium hydroxide)/(acid value of the dosage * fatty acid of fatty acid))
The definition of acid value is the milligram number of potassium hydroxide needed for neutralizing 1g fatty acid, unit mgKOH/g;The dosage of acid is hundred
Divide and compares dosage.
3) polyalcohol
Polyalcohol mainly disperses in formula system and the effect of dissolved fat acid soap, while polyalcohol is to final products
Candle light property and stabilization also have a significant impact.Leading to common polyalcohol has glycerol, propylene glycol, 1,3 butylene glycol, polyethylene glycol, double
Glycerol etc..The present invention is dispersion to the effect of soap using glycerol, therefore the pearly-lustre being precipitated in product not will receive the influence of glycerol;
It is to have dissolution to soap, therefore also will affect pearly-lustre precipitation while dissolving soap using 1,3 butanediol, the present invention is by most
Good proportion realizes the optimum balance of dispersion soap and dissolution soap,
The present invention is given to washing away property face cleaning cream using arginine glycerol and provides skin moist moisturizing.Arginine glycerol
(Amitose R) is the completely new ingredient being born after glycerol and arginine fusion.Arginine glycerol is by moistening effect and absorption
Power combines the lasting moistening effect to be formed, and skin surface is stablized and is adsorbed, long-acting moisturizing still is able to after flushing, sufficiently wet
Moisture feeling does not stick greasy bring and well experiences after use, assign skin emolliency sense of touch.Arginine glycerol be by glycerol again Lai hydroxyl
Under the collective effect of the strong cation of (hydrogen bond) effect and arginine (ionic bond), for the skin (cutin of anionic property is presented
Layer) generate strength adsorption effect.Arginine glycerol is low molecule, under the collective effect of hydrogen bond and ionic bond, along with skin
The water-washing process of skin, can skin permeation cuticula so that moistening effect is more longlasting, can conditioning skin, keep the strong of skin
Health situation improves the unevenness that falls off, and improves wrinkle, improves mechanism, improves pore, prevents inflammation.Arginine glycerol is appointed after washing
It so can be securely adsorbed in skin surface, so that skin persistently keeps water moisture feeling.
4) emulsifier
In theory, as long as degree of neutralization can be reduced, pH value can be reduced to a certain extent, and reducing part stimulates.Together
When, if can rapid dispersion at soap, and unreacted fatty acid is fully emulsified, suspend, wrap up, so that it may solve soap base
High-temperature stability and production technology be difficult to control the problems such as, allow Soap-base facial cleanser as general surface reactive systems
Easily realize large-scale production.Emulsifier effect mainly solves the problems, such as system stability, precisely, it should be to play auxiliary
Stabilization, the appropriate emulsifier that adds can effectively solve the high-temperature stability of product, and prevent product system from restoring room temperature
After there is coarse phenomenon.Simultaneously because unique chemical structure, under the conditions of soap base and high pH value, it can be by remaining mixing rouge
Fat is acid emulsifier, so that product pH value reduces, makees to play stable soap base and reduce common Soap-base facial cleanser to the stimulation of skin
With.Emulsifier has a significant impact on the influence of the pearl effect of product, and if emulsifier is excessive in system, final products will be without pearl
Light is precipitated, and therefore, selects the minimum amount that emulsifier is also contemplated that when emulsifier, i.e., under the premise of guarantee system is stablized
The dosage of emulsifier is reduced as far as possible.The present invention is guaranteeing product pearl effect using stearine, and it is clean to reduce its soap base
The irritation in face is promoted and uses mild performance.
5) surfactant
In Soap-base facial cleanser system, surfactant has buffer function to the high pH value of soap base, to reduce soap base
Irritation.Improve the property of foam simultaneously, improves skin sense when using.Moreover it is possible to play dispersion soap base, saponification process is reduced
The effects of viscosity of middle soap base.
The present invention uses the alkyl glycosides with biological degradation activity, can be effectively reduced the irritation of soap base, increases bubble
The elasticity of foam effectively uses soap base and surfactant compound, has taken into account two aspects of foam and identical property, while can add
The self-catalysis efficiency of fast saponification, shortens the time of saponification, improves production efficiency, reduces energy consumption and cost.
6) emollient
The present invention is added in Soap-base facial cleanser system with moisturizing and repairs the active component lecithin of skin barrier
And ceramide, for repairing because of soap base degreasing caused by skin barrier physiological grease lose damage, effectively reparation skin
Barrier.
(1) lecithin
Lecithin, also known as lecithin are known as " third nutrient " arranged side by side with protein, vitamin, however, really
The people for understanding lecithin is seldom.Frenchman Gohley in 1844 has found lecithin from yolk, and is named as with Greek
Lecithos (lecithin), general nomenclature of drug are Lecithin, have also opened its mysterious veil since then.
Lecithin is the indispensable substance of each cell of human body, if lacked, will reduce the regeneration of Skin Cell
Ability leads to pachylosis, has wrinkle.As can suitably absorbing lecithin, skin regeneration vigor can be ensured, add lecithin
The good hydrophily of rouge and lipophilicity, skin are certainly just glossy
(2) ceramide
Ceramide forms sphingoin matter one kind by sphingosine long chain base and fatty acid.Ceramide
(Ceramide) it is a kind of phosphatide using ceramide as skeleton, mainly there is ceramide phosphocholine and ceramide phosphoric acid second
Hydramine, phosphatide are the main components of cell membrane, and 40%~50% sebum is made of ceramide in cuticula, and ceramide is
The major part of intercellular matrix plays an important role in the balance for keeping cuticula moisture.
Moisture content of skin about percentage of liveweight 18%~20%, skin is moist and elasticity is with epidermis contained humidity substantial connection,
Moisture of skin, which is excessively lost, will lead to dry skin, or even chap.Imokawa etc. is using organic solvent processing removal cuticula rouge
Matter, discovery continuous skin (>4 days) chap, there is flakey, skin electric conductivity is decreased obviously.Horny layer of epidermis rouge will be extracted
Matter component carries out local skin test under the same conditions respectively, and inquiring into any lipid composition can restore what has to moisture of skin
Effect.Clearly increase as a result, it has been found that ceramide local use can lead to skin electric conductivity, cholesterol is secondly, free rouge
Fat acid and cholesteryl ester effect are then unobvious.Ceramide has hydrone ability of associating by force very much, it passes through the shape in cuticula
It reticulates structure and maintains moisture of skin.Therefore, ceramide, which has, keeps moisture of skin effect.
7) anti-sensitizer
Present invention employs dipotassium glycyrrhizinates and bisabolol as anti-sensitizer, can effectively reduce skin caused by soap base product
Skin stimulation.
Preferably, in parts by weight, the dosage of each raw material is:
20~30 parts of glycerol, 0.1~2 part of arginine glycerol, 3~7 parts of 1,3-BDO, 0.1~0.5 part of EDETATE SODIUM,
6~7 parts of potassium hydroxide, 18~22 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, stearine 0.4~
1.2 parts, 1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01
~0.5 part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, water is supplied
To 100 parts.
Preferably, in parts by weight, the dosage of each raw material is:
22~23 parts of glycerol, 0.1~2 part of arginine glycerol, 4~6 parts of 1,3-BDO, 0.2~0.3 part of EDETATE SODIUM,
6~7 parts of potassium hydroxide, 19~20 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, stearine 0.4~
1.2 parts, 1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01
~0.5 part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, water is supplied
To 100 parts.
In a specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 0.1 part of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, potassium hydroxide 6.6
Part, 19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 0.4 part of stearine, 1 part of emulsifier, alkyl
0.1 part of glucosides, 1 part of sodium methyl cocoyl taurate, 0.01 part of hydrolecithin, 0.01 part of ceramide, dipotassium glycyrrhizinate
0.01 part, 0.01 part of bisabolol, water complements to 100 parts.
In another specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 1 part of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, 6.6 parts of potassium hydroxide,
19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 0.8 part of stearine, 2.5 parts of emulsifier, alkyl sugar
0.5 part of glycosides, 3 parts of sodium methyl cocoyl taurate, 0.1 part of hydrolecithin, 0.1 part of ceramide, dipotassium glycyrrhizinate 0.15
Part, 0.2 part of bisabolol, water complements to 100 parts.
In another specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 2 parts of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, 6.6 parts of potassium hydroxide,
19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 1.2 parts of stearine, 3 parts of emulsifier, alkyl glycosides
It is 1 part, 5 parts of sodium methyl cocoyl taurate, 0.5 part of hydrolecithin, 0.5 part of ceramide, 0.2 part of dipotassium glycyrrhizinate, red
0.5 part of bisabol, water complements to 100 parts.
Preferably, emulsifier is rilanit special, in stearic acid, glycol distearate, tocopherol acetate
It is one or more of.
Preferably, Soap-base facial cleanser further includes preservative and/or essence.
Preferably, in parts by weight, the dosage of raw material is:
20~30 parts of glycerol, 0.1~2 part of arginine glycerol, 3~7 parts of 1,3-BDO, 0.1~0.5 part of EDETATE SODIUM,
6~7 parts of potassium hydroxide, 18~22 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, stearine 0.4~
1.2 parts, 1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01
~0.5 part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, preservative
0.1~0.5 part, 0.1~0.5 part of essence, water complements to 100 parts.
Preferably, in parts by weight, the dosage of raw material is:
22~23 parts of glycerol, 0.1~2 part of arginine glycerol, 4~6 parts of 1,3-BDO, 0.2~0.3 part of EDETATE SODIUM,
6~7 parts of potassium hydroxide, 19~20 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, stearine 0.4~
1.2 parts, 1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01
~0.5 part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, preservative
0.2~0.4 part, 0.2~0.4 part of essence, water complements to 100 parts.
In a specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 0.1 part of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, potassium hydroxide 6.6
Part, 19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 0.4 part of stearine, 1 part of emulsifier, alkyl
0.1 part of glucosides, 1 part of sodium methyl cocoyl taurate, 0.01 part of hydrolecithin, 0.01 part of ceramide, dipotassium glycyrrhizinate
0.01 part, 0.01 part of bisabolol, 0.3 part of preservative, 0.3 part of essence, water complements to 100 parts.
In another specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 1 part of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, 6.6 parts of potassium hydroxide,
19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 0.8 part of stearine, 2.5 parts of emulsifier, alkyl sugar
0.5 part of glycosides, 3 parts of sodium methyl cocoyl taurate, 0.1 part of hydrolecithin, 0.1 part of ceramide, dipotassium glycyrrhizinate 0.15
Part, 0.2 part of bisabolol, 0.3 part of preservative, 0.3 part of essence, water complements to 100 parts.
In another specific embodiment provided by the invention, in parts by weight, the dosage of each raw material is:
22.85 parts of glycerol, 2 parts of arginine glycerol, 5 parts of 1,3-BDO, 0.25 part of EDETATE SODIUM, 6.6 parts of potassium hydroxide,
19.55 parts of myristic acid, 5.75 parts of stearic acid, 4.6 parts of lauric acid, 1.2 parts of stearine, 3 parts of emulsifier, alkyl glycosides
It is 1 part, 5 parts of sodium methyl cocoyl taurate, 0.5 part of hydrolecithin, 0.5 part of ceramide, 0.2 part of dipotassium glycyrrhizinate, red
0.5 part of bisabol, 0.3 part of preservative, 0.3 part of essence, water complements to 100 parts.
Preferably, preservative is hydantoins.
The present invention also provides the preparation methods of the Soap-base facial cleanser, include the following steps:
Glycerol, arginine glycerol, 1,3-BDO, EDETATE SODIUM, potassium hydroxide and water are mixed, are heated to 70~80
DEG C, obtain A phase;
Myristic acid, stearic acid, lauric acid are mixed, 70~80 DEG C is heated to, obtains B phase;
A phase and B are mixed, is saponified under conditions of being not less than 80 DEG C, obtains saponification mixture;
Stearine, emulsifier are mixed with saponification mixture, surplus stock is added after being cooled to 50~60 DEG C;
It keeps the temperature, stirs after being cooled to 40~45 DEG C.
In embodiment provided by the invention, the preparation method of the Soap-base facial cleanser includes the following steps:
Glycerol, arginine glycerol, 1,3-BDO, EDETATE SODIUM, potassium hydroxide and water are mixed, 75 DEG C is heated to, obtains
To A phase;
Myristic acid, stearic acid, lauric acid are mixed, 75 DEG C is heated to, obtains B phase;
A phase and B are mixed, is saponified under conditions of being not less than 80 DEG C, obtains saponification mixture;
Stearine, emulsifier are mixed with saponification mixture, surplus stock is added after being cooled to 55 DEG C;
It keeps the temperature, stirs after being cooled to 40~45 DEG C.
Preferably, the time of saponification is 30~60min.
Preferably, the time of stirring is 30~90min.
The present invention provides a kind of Soap-base facial cleansers and preparation method thereof.The raw material of Soap-base facial cleanser includes:Glycerol, smart ammonia
Acid glycerol, 1,3 butylene glycol, EDETATE SODIUM, potassium hydroxide, myristic acid, stearic acid, lauric acid, stearine, emulsification
Agent, alkyl glycosides, sodium methyl cocoyl taurate, hydrolecithin, ceramide, dipotassium glycyrrhizinate, opopanax alcohol and water.
The technical effect that the present invention has is:
1) present invention uses emulsifying soap base mildy wash, and the emulsifier contained has unique chemical structure, in soap base and
, can be acid emulsifier by remaining mixing-in fat under conditions of high pH value, the pH value of product is reduced, stable soap base is played and reduces skin
The irritating effect of skin.Soap base mildy wash prepared by the present invention remains low, low stimulation with its foaming abundancy, strong cleaning force after
Property, simple production process is easy to use;
2) for the present invention using potassium hydroxide as the alkali in face cleaning cream, control degree of neutralization is 78%-85%, has formula
Mildness;
3) present invention uses glycerol, 1, and 3 butanediols, arginine glycerol are polyol systems, and wherein arginine glycerol can
It is adsorbed on after face cleaning and is trapped in skin surface and can effectively promote the moisture content of skin;
4) present invention uses alkyl glycosides and sodium methyl cocoyl taurate in face cleaning formula as surface-active
Agent promotes saponification self-catalysis efficiency, shortens the saponification time, reduces cost, raising efficiency;Alkyl glycosides disperses its rouge
Fat acid, reduces its irritation, so that formula is mild;
5) present invention uses hydrolecithin and ceramide in mildy wash formula, repairs soap base removal grease and simultaneously will
Physiology grease excessively removes the damage to skin barrier, reduces moisture of skin and scatters and disappears, promotes skin moisture content;
6) present invention reduces the thorn in formula use process using dipotassium glycyrrhizinate and bisabolol in face cleaning lotion system
Property is swashed, so that Soap-base facial cleanser is milder;
7) present invention using arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and red does not have
The face cleaning cream of medicine alcohol composition preparation is 390mL~435mL in initial foam volume, 135mL is higher by than control sample, after 30min
Foam volume is 355~405mL, and the present invention has excellent foaming characteristic and foam stability.
8) present invention using arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and red does not have
The face cleaning cream of medicine alcohol composition preparation can be effectively reduced skin oil and fat and reduce 79.51%~82.14%, and the present invention has preferable
Cleaning force, because the irritation of soap base face cleaning product is effectively reduced in alkyl glycosides, dipotassium glycyrrhizinate, bisabolol, promoted its temperature
And performance.
9) water loss amount of the present invention is only 6.67%~19.64%, and blank sample moisture loss is up to 42.45%, energy
It is 22.81%~35.78% that moisture of skin windage relative quantity, which is effectively reduced, and the present invention uses arginine glycerol, ceramide
And moisture of skin is effectively reduced in hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and the face cleaning cream of bisabolol composition preparation
It scatters and disappears, repairs skin barrier function.
10) present invention is using arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and red
The face cleaning cream of myrrh alcohol composition preparation effectively increases skin moisture content 8.29%~15.21%, and common Soap-base facial cleanser
Its skin moisture content causes water content to reduce by 13.48%, this is clean in washing-off type soap base due to cleaning the damage to skin barrier
It is the technological break-through of essence in the product of face.
Detailed description of the invention
Fig. 1 shows the foam volume of Soap-base facial cleanser;
Fig. 2 shows the skin oil and fat reduction amount of Soap-base facial cleanser;
Fig. 3 shows the lost increment of the moisture of skin of Soap-base facial cleanser;
Fig. 4 shows the incrementss of the skin moisture content of Soap-base facial cleanser.
Specific embodiment
The invention discloses a kind of Soap-base facial cleanser and preparation method thereof, those skilled in the art can be used for reference in this paper
Hold, is suitably modified realization of process parameters.In particular, it should be pointed out that all similar substitutions and modifications are to those skilled in the art
For be it will be apparent that they are considered as being included in the present invention.Method and application of the invention, which has passed through, preferably to be implemented
Example is described, related personnel obviously can not depart from the content of present invention, in spirit and scope to method described herein and
Using being modified or appropriate changes and combinations, carry out implementation and application the technology of the present invention.
Raw materials used or auxiliary material is available on the market in Soap-base facial cleanser provided by the invention and preparation method thereof.
Below with reference to embodiment, the present invention is further explained:
Embodiment 1
The formula of Soap-base facial cleanser is as follows in the present embodiment:
1 Soap-base facial cleanser formula of table
Its saponification process is as follows:
(1) A is added to auxiliary reaction pot, is heated to 75 DEG C;
(2) emulsion pot is become owner of into B addition, is heated to 75 DEG C;
(3) first B phase is put into main emulsion pot, opens stirring, then A phase is added rapidly in B phase, if A is added to
During, of short duration a small amount of soap blank may temporarily occur in system, then natural to disappear;
(4) after the completion of A phase is added, in the case where keeping system temperature to be not less than 80 DEG C, heat preservation saponification 30-60 minutes;
(5) C phase is added after being saponified, at this time it should be noted that avoiding that system is made to generate bubble because of stirring;
(6) 55 DEG C of addition E phases, F phase, G phases, H phase are cooled to;
(7) 40 DEG C -45 DEG C, when system can tie cream are cooled to, keeps temperature-resistant, is stirred to 30 minutes or more, stirring knot
It discharges after beam.
Embodiment 2
The formula of Soap-base facial cleanser is as follows in the present embodiment:
2 Soap-base facial cleanser formula of table
Its saponification process is the same as embodiment 1.
Embodiment 3
The formula of Soap-base facial cleanser is as follows in the present embodiment:
3 Soap-base facial cleanser formula of table
Its saponification process is the same as embodiment 1.
Comparative example 1
The formula of Soap-base facial cleanser is as follows in this comparative example:
4 Soap-base facial cleanser formula of table
Its saponification process is as follows:According to the technique of formula adjustment embodiment 1.
Comparative example 2
The formula of Soap-base facial cleanser is as follows in this comparative example:
5 Soap-base facial cleanser formula of table
Its saponification process is as follows:According to the technique of formula adjustment embodiment 1.
Comparative example 3
The formula of Soap-base facial cleanser is as follows in this comparative example:
6 Soap-base facial cleanser formula of table
Its saponification process is as follows:According to the technique of formula adjustment embodiment 1.
Comparative example 4
The formula of Soap-base facial cleanser is as follows in this comparative example:
7 Soap-base facial cleanser formula of table
Its saponification process is as follows:According to the technique of formula adjustment embodiment 1.
Comparative example 5
The formula of Soap-base facial cleanser is as follows in this comparative example:
8 Soap-base facial cleanser formula of table
Its saponification process is as follows:According to the technique of formula adjustment embodiment 1.
The evaluation and test of 1 effect of test example
(1) foaming power and foam stability test
Each face cleaning cream solution 100mL that mass percentage is 1% is prepared respectively, is placed in 500mL tool plug graduated cylinder, on
Reverse plumbness 20 times down, record foam volume (mL) at once, record foam volume after 30min again, and replication 3 times,
Take average valuation.Test result is shown in Table 9, Fig. 1:
9 face cleaning cream foam volume of table
Conclusion:The present invention use arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and
The face cleaning cream of bisabolol composition preparation is 390mL-435mL in initial foam volume, is higher by 135mL than control sample,
Foam volume is 355-405mL after 30min, and the present invention has excellent foaming characteristic and foam stability.
(2) oil-control is assessed
1) test philosophy
The present invention carries out the function of oil-Absorbing Sheets using effect using the skin oil and fat tester Sebumeter SM815 of Germany CK
Effect evaluation.Oil content test is using universally acknowledged SEBUMETER method, it is based on photometer principle, and a kind of 0.1mm is thick
After special delustring adhesive tape absorbs grease on human skin, a kind of translucent adhesive tape just will become, its light transmission capacity will be sent out
The grease of changing, absorption is more, and light transmission capacity will be bigger, can thus measure the content of skin oil and fat.It is maximum excellent
Point is that test probe size is small, easy to use, can test any position of skin.This is a kind of indirect survey of grease glandular secretion object
As a result amount method can be used to distinguish different skin types, make accurately to understand the grease as caused by inside and outside reason
Variation is possibly realized.
2) test method
The present invention this time tests 21 test objects of selection, and 3 one group of people are divided into 7 groups, respectively forehead draw 3 having a size of
The region 3cm × 3cm carries out the evaluation and test of skin oil and fat content for blank sample (not wipe samples), control sample and patent sample respectively, often
A control sample takes three fat contents that value calculates cleaning front and back for each person to carry out related judge.
(1) select test object skin health, the age 18-30 year old, after tested object know, agreement, study subject into
Enter constant temperature and humidity effect evaluation and test room after 30 minutes, measures its forehead fat content as initial value.
(2) sample is not smeared in subject's forehead blank area, it is clear that control sample area, patent sample area weigh the cleaning of 0.1g face cleaning cream
Corresponding test section is washed, waits for quietly 30 minutes, carries out fat content measurement for three regions respectively;
(3) environment is tested:T=25 DEG C of environment temperature of test, humidity H=50;
(4) testing time:Enter constant temperature and humidity evaluation and test room before testing and waits for testing for 30 minutes initial fat content and clean quietly
Skin oil and fat content behind face.
(5) test position:Forehead marks blank, control sample, the test zone of patent sample.
(6) test result is shown in Fig. 2.
Conclusion:The present invention using arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and
Bisabolol composition preparation face cleaning cream, can be effectively reduced skin oil and fat reduce 79.51%-82.14%, the present invention have compared with
Good cleaning force promotes it because the irritation of soap base face cleaning product is effectively reduced in alkyl glycosides, dipotassium glycyrrhizinate, bisabolol
Mild performance.
(3) percutaneous moisture loss evaluation
(1) test philosophy
The measuring principle of the test apparatus derives from FICK Fick's law of diffusion:Dm/dt=D.A.dp/dx.Pass through two groups
Temperature-humidity sensor measures the water vapor pressure ladder that nearly epidermis (about in 1cm) is formed by cuticula moisture loss in different bright spots
Degree, directly measures the amount of moisture percutaneously distributed.TEWL value is an important symbol of skin barrier quality, and the TEWL value of skin is got over
It is low, illustrate that the barrier function of skin is better, on the contrary it is poorer.
(2) experimental condition and volunteer require
Test environment conditions:Testing environment temperature is 22 ± 1 DEG C, and humidity is 50 ± 5%, and carries out dynamic in real time and examine
It surveys;
Volunteer requires:Effective volunteer at least 30 people, the age, (gestation or the newborn phase women in Pu removed between 16-65 years old
Outside):Forearm test zone capacitance method moisture of skin measures the basic value of meaning between 15-100:Without serious systemic disease, nothing
Immune deficiency or autoimmune disease person;No active anaphylactic disease person;Previously to skin-care cosmetics without severe allergy history
Person;Hormone medicine and immunosuppressor person are not used in nearly one month:To participate in other clinical test persons;It uses according to regulations
Test medicine and all information;All volunteers should fill in informed consent form before testing;
(3) prepare before test
Any product (cosmetics or topical drug) cannot be used within 2-3 days before recipient site.Before experiment, subject needs same
It is surveyed in meaning cleaning both hands forearm, with dry face tissue wiped clean.It is surveyed in subject's both hands forearm after cleaning and carries out measured zone
Label.At least 30min that sits quietly in room should be being complied with standard before official testing, cannot drunk water, forearm exposure is put in test mode
It sets, keeps loosening.
(4) testing procedure
3 × 3cm of label on the inside of left and right arm in experiment2Test area, same arm can mark multiple regions, interregional
Every 1cm.Test product and blank control are randomly dispersed in left and right arm.Tested area is carried out using capacitance method skin analyzer
The measurement in domain and control zone.Each region is according to parallel determination 15 times.The plain pape for first measuring each test zone, is then pressed
2.0 ± 0.1mg sample/cm2Dosage, test is spread evenly across in trial zone using latex finger cot.Smearing measures respectively
The moisture content of skin (being measured when verifying by this time) in 30min, 60min, 90min, tested region and blank control region, it is same
The test of a volunteer is completed by the same survey crew.
(5) test result
Measure the TEWL value of day part respectively by experimental design.Test result is shown in Table 10 and Fig. 3.
10 moisture of skin of table scatters and disappears increment
Conclusion:Water loss amount of the present invention is only 6.67%-19.64%, and blank sample moisture loss is up to 42.45%,
It is 22.81%-35.78% that moisture of skin windage relative quantity, which can be effectively reduced, and the present invention uses arginine glycerol, ceramide
And moisture of skin is effectively reduced in hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and the face cleaning cream of bisabolol composition preparation
It scatters and disappears, repairs skin barrier function.
(4) skin moisture content MMV test method
(1) test philosophy
For the method using the moisture content of capacitance method test human body keratoderma, its principle is based on water and other objects
The difference in dielectric constant of matter is significant, and according to moisture content of skin difference, the capacitance for measuring skin is different, and observed parameter can represent
Skin moisture value.
Test equipment:
German CK company Multi-functional skin tester, model C UTOMETER DUAL MPA 580, the present invention select skin
Moisture content test probe and the lost TEWL test probe of moisture of skin.
(2) experimental condition and volunteer require
Test environment conditions:Testing environment temperature is 22 ± 1 DEG C, and humidity is 50 ± 5%, and carries out dynamic in real time and examine
It surveys;
Volunteer requires:Effective volunteer at least 30 people, the age, (gestation or the newborn phase women in Pu removed between 16-65 years old
Outside):Forearm test zone capacitance method moisture of skin measures the basic value of meaning between 15-100:Without serious systemic disease, nothing
Immune deficiency or autoimmune disease person;No active anaphylactic disease person;Previously to skin-care cosmetics without severe allergy history
Person;Hormone medicine and immunosuppressor person are not used in nearly one month:To participate in other clinical test persons;It uses according to regulations
Test medicine and all information;All volunteers should fill in informed consent form before testing;
(3) prepare before test
Any product (cosmetics or topical drug) cannot be used within 2-3 days before recipient site.Before experiment, subject needs same
It is surveyed in meaning cleaning both hands forearm, with dry face tissue wiped clean.It is surveyed in subject's both hands forearm after cleaning and carries out measured zone
Label.At least 30min that sits quietly in room should be being complied with standard before official testing, cannot drunk water, forearm exposure is put in test mode
It sets, keeps loosening.
(4) testing procedure
3 × 3cm of label on the inside of left and right arm in experiment2Test area, same arm can mark multiple regions, interregional
Every 1cm.Test product and blank control are randomly dispersed in left and right arm.Tested area is carried out using capacitance method skin analyzer
The measurement in domain and control zone.Each region is according to parallel determination 15 times.The plain pape for first measuring each test zone, is then pressed
2.0 ± 0.1mg sample/cm2Dosage, test is spread evenly across in trial zone using latex finger cot.Smearing measures respectively
The moisture content of skin (being measured when verifying by this time) in 30min, 60min, 90min, tested region and blank control region, it is same
The test of a volunteer is completed by the same survey crew.
(5) test result
The MMV value of each period is measured by the design decibel of experiment.Test result is shown in Table 11 and Fig. 4.
The incrementss of 11 skin moisture content of table
Conclusion:The present invention using arginine glycerol, ceramide and hydrolecithin, alkyl glycosides, dipotassium glycyrrhizinate and
The face cleaning cream of bisabolol composition preparation effectively increases skin moisture content 8.29%-15.21%, and common Soap-base facial cleanser
Its skin moisture content causes water content to reduce by 13.48%, this is clean in washing-off type soap base due to cleaning the damage to skin barrier
It is the technological break-through of essence in the product of face.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of Soap-base facial cleanser, which is characterized in that its raw material includes:
Glycerol, arginine glycerol, 1,3 butylene glycol, EDETATE SODIUM, potassium hydroxide, myristic acid, stearic acid, lauric acid, glycerol
Stearate, emulsifier, alkyl glycosides, sodium methyl cocoyl taurate, hydrolecithin, ceramide, dipotassium glycyrrhizinate,
Opopanax alcohol and water.
2. Soap-base facial cleanser according to claim 1, which is characterized in that in parts by weight, the dosage of each raw material is:
20~30 parts of glycerol, 0.1~2 part of arginine glycerol, 3~7 parts of 1,3-BDO, 0.1~0.5 part of EDETATE SODIUM, hydrogen-oxygen
6~7 parts of potassium of change, 18~22 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, 0.4~1.2 part of stearine,
1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01~0.5
Part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, water complements to 100
Part.
3. Soap-base facial cleanser according to claim 1, which is characterized in that in parts by weight, the dosage of each raw material is:
22~23 parts of glycerol, 0.1~2 part of arginine glycerol, 4~6 parts of 1,3-BDO, 0.2~0.3 part of EDETATE SODIUM, hydrogen-oxygen
6~7 parts of potassium of change, 19~20 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, 0.4~1.2 part of stearine,
1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01~0.5
Part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, water complements to 100
Part.
4. Soap-base facial cleanser according to claim 1, which is characterized in that the emulsifier be rilanit special, stearic acid,
One or more of glycol distearate, tocopherol acetate.
5. Soap-base facial cleanser according to claim 1, which is characterized in that the Soap-base facial cleanser further include preservative and/
Or essence.
6. Soap-base facial cleanser according to claim 5, which is characterized in that in parts by weight, the dosage of the raw material is:
20~30 parts of glycerol, 0.1~2 part of arginine glycerol, 3~7 parts of 1,3-BDO, 0.1~0.5 part of EDETATE SODIUM, hydrogen-oxygen
6~7 parts of potassium of change, 18~22 parts of myristic acid, 5~6 parts of stearic acid, 4~5 parts of lauric acid, 0.4~1.2 part of stearine,
1~3 part of emulsifier, 0.1~1 part of alkyl glycosides, 1~5 part of sodium methyl cocoyl taurate, hydrolecithin 0.01~0.5
Part, 0.01~0.5 part of ceramide, 0.01~0.2 part of dipotassium glycyrrhizinate, 0.01~0.5 part of bisabolol, preservative 0.1~
0.5 part, 0.1~0.5 part of essence, water complements to 100 parts.
7. Soap-base facial cleanser according to claim 5 or 6, which is characterized in that the preservative is hydantoins.
8. the preparation method of Soap-base facial cleanser described in any one of claims 1 to 7, which is characterized in that include the following steps:
Glycerol, arginine glycerol, 1,3-BDO, EDETATE SODIUM, potassium hydroxide and water are mixed, 70~80 DEG C is heated to, obtains
To A phase;
Myristic acid, stearic acid, lauric acid are mixed, 70~80 DEG C is heated to, obtains B phase;
The A phase and the B are mixed, is saponified under conditions of being not less than 80 DEG C, obtains saponification mixture;
Stearine, emulsifier are mixed with the saponification mixture, surplus stock is added after being cooled to 50~60 DEG C;
It keeps the temperature, stirs after being cooled to 40~45 DEG C.
9. preparation method according to claim 8, which is characterized in that the time of the saponification is 30~60min.
10. preparation method according to claim 8 or claim 9, which is characterized in that the time of the stirring is 30~90min.
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WO2020164086A1 (en) * | 2019-02-15 | 2020-08-20 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | A cleansing composition releasable in form of a stable foam |
CN111617005A (en) * | 2020-06-30 | 2020-09-04 | 广州市瑞芬化妆品有限公司 | High-foam fine soap-based mixed facial cleanser and preparation method thereof |
CN112274446A (en) * | 2020-10-30 | 2021-01-29 | 广州市妆妍生物技术有限公司 | Ceramide refreshing amino acid facial cleanser and preparation method thereof |
CN113069942A (en) * | 2021-04-07 | 2021-07-06 | 杨梦玲 | Mild amino acid soap-based facial cleanser and preparation method thereof |
CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
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WO2020164086A1 (en) * | 2019-02-15 | 2020-08-20 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | A cleansing composition releasable in form of a stable foam |
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CN111617005A (en) * | 2020-06-30 | 2020-09-04 | 广州市瑞芬化妆品有限公司 | High-foam fine soap-based mixed facial cleanser and preparation method thereof |
CN112274446A (en) * | 2020-10-30 | 2021-01-29 | 广州市妆妍生物技术有限公司 | Ceramide refreshing amino acid facial cleanser and preparation method thereof |
CN113069942A (en) * | 2021-04-07 | 2021-07-06 | 杨梦玲 | Mild amino acid soap-based facial cleanser and preparation method thereof |
IT202100010493A1 (en) * | 2021-04-26 | 2022-10-26 | Nuu Bionature S R L | IMPROVED COSMETIC PRODUCT FOR CLEANSING AND PERSONAL CARE |
CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
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CN113845984A (en) * | 2021-11-04 | 2021-12-28 | 天津郁美净集团有限公司 | Mild and stable soap-based cleansing cream and preparation process thereof |
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CN114099382B (en) * | 2021-11-22 | 2024-03-12 | 福建片仔癀化妆品有限公司 | Soap-based facial cleanser and preparation method thereof |
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